Wolfe/Lentz Unit 7 Study Guide Terms (define): Empirical Formula Mole Average Atomic Mass (amu) Molar Mass Mass Percent Molecular Formula Percent Composition Avogadros number Empirical Formula Application: How do you calculate the following? Molar Mass Ex: Calculate the molar mass of Sodium Nitride, Na3N Number of Moles Ex: What mass of cobalt contains the same number of atoms as 57.0 g of fluorine Number of Molecules Ex: Percent Composition Ex: Calculate the percent by mass of each element in the following compounds Potassium Phosphate Sodium Sulfate How would you determine the following: Empirical Formula What does it represent? How does it differ from molecular formula? Ex: Give the empirical formula for Sodium Peroxide, Na2O2 Ex: A compound has the following percentages by mass: barium 58.84%, sulfur 13.74%, Oxygen 27.43%. Determine the empirical formula Molecular Formula What information do we need? How does it differ from empirical formula? Ex: A compound with the empirical formula CH4O was found in a subsequent experiment to have a molar mass of approximately 192 grams. What is the molecular formula? Chapter 8 Study Guide Vocabulary Excess reactant Stoichiometry Percent yield Limiting reactant Theoretical yield Actual yield Product Reactant Mass Moles Atoms Concepts/Application Calculating Molar Mass Ex: Molar Mass of NaOH Balancing Equations Ex: NaOH + CO2-Na2CO3 + H2O Molar Ratio Ex: 2Al + 6HCl 2AlCl3 + 3H2 What is the ratio of the above? Dimensional Analysis Ex: How many grams of Hydrogen are released when 50.0 grams of aluminum reacts with 49.0 grams Hydrochloric Acid Unit 9 Study Guide Vocabulary Types of Bonds Covalent Polar Covalent Ionic Single bond Double bond Triple Bond Resonance Geometric shapes Linear Trigonal Planar Tetrahedral Trigonal Pyramid Bent (or V-shaped) Rules Octet Rule Duet Rule Electronegativity Application Lewis Dot Structure How do you represent: N2, H20 How to determine number of Valence Electrons (label each family and number of valence electrons) How to determine electronegativity Study Guide Vocabulary Solid Liquid Gas Specific Heat (Cp) Change in Temp ( T) Heat of fusion (Hf) Heat vaporization (Hv) Evaporation Condensation Intermolecular forces Intramolecular forces Dipole-dipole attraction Hydrogen bonding London dispersion forces Formulas: Q= Cp= T= Q (for Hf) = Q (for Hv) = Application: What are the arrangements, states, and energy required for the graph above? Calculate the total heat energy in Joules required to raise the temperature of 36.04 g of water from 11˚C to 150˚C. Heating and Cooling Curve for Water (label temperatures, states of matter, m.p and b.p) Unit 11 Study Guide Dalton’s Law Formula: Example Problem: What is the total pressure when 5.0 L of Hydrogen (H2) at 1.00 atm is pumped into a 5.0 L container along with 5.0 L of Oxygen (O2) at 1.00 atm? Avogadro’s Law Formula: Relationship between variables: Example problem: If 0.412 moles of argon gas occupies a volume of 602 mL at a particular temperature and pressure, what volume would 0.573 moles of argon occupy under the same conditions? Charles Law Formula: Relationship between variables: Example problem: A 20 L sample of nitrogen gas is cooled from 25 deg. Celsius to a final temperature of -100 deg. Celsius. What is the new volume of the gas? Combined Gas Law Formula: Relationship between variables: Example problem: A 250 cm3 of nitrogen gas is at 20 deg Celsius and 758 torr. What volume (in cm3) will it occupy at -15.0 deg Celsius and 1.2 atm? Ideal Gas Law Formula: Relationship between variables: How to convert grams to moles, if needed: Example problem: Calculate the pressure in atm of .456 mol of carbon dioxide in a 1.21 liter container at 312K. Boyle’s Law Formula: Relationship between variables: Example problem: A submarine with a volume of 13000L has an internal pressure of 1.2 atm. If the submarine ruptures underwater at a pressure of 250 atm and the gas is released, how large will the bubble be? Pressure: Units/Conversions for Pressure STP: Conditions: Unit m.p b.p. Change in Temperature Formula Farenheit Celsius Kelvin Unit 12 Study Guide Vocabulary Dilute Concentrated Solution Concentrated Solution Dilute Solution Saturated solution Unsaturated Solution Supersaturated Solution Solute Solvent Molarity Mass Percent Formula for mass percent: Application problems: What relationship exists between solubility and temperature for most of the substances shown? What is the exception? What general principle accounts for this exception? A 135 g sample of seawater is evaporated to dryness, leaving 4.73 g of solid residue (the salts formerly dissolved in the seawater). Calculate the mass percent of solute present in the original seawater. What is the concentration of 81.0 mL of a 7.0 M HCL stock solution is diluted to a new volume of 2.00L. The concentration of this new solution is? A 1.2 M HNO3 solution contains 3.3 moles of KNO3. How much solution is needed? Understand how to interpret information from the following chart Example: A saturated solution of KNO3 in 200 g of H2O at 50oC is cooled to 20oC. How much KNO3 will precipitate out of solution?
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