ISN IV: Bonding Chemicals # Item Check IN Value 1-2 Cover & Things 2 Know 0 Text Pages 119-129 1 3-4 Notes & Ions List 0 Ionic Bonding Chips 5 Text Pages 130-135 1 6-7 LAB: IONIC COMPOUNDS SAMPLER Text Pages 136-7 1 Review of Ionic Bonding 1 Text 138-142 1 9-11 Bonding & Electron Dot Diagrams 1 Formula Review 1 13-14 Lab: Compounds & Bonding 0 15-16 LAB: Molecular Models 10 Parent signature and Date 4 5 8 12 10 Total !1 36 Lost Parent signature ___________________________________date_______________ name:________________________________________per_____ Updated Things 2 Know 1. SAFETY FIRST!! 2. You are required to have a pencil or erasable pen, ISN with cover, and calculator everyday. 3. Any missed labs or in class work should be made up during lunch or X-Block or tutorial 4. Stout’s email address: [email protected] 5. Stout’s web site: www1.northbrook28.net/~cstout 6. Matter is anything with mass and volume 7. Matter is made of tiny particles that are always in some motion. 8. Matter can exist in several states(or phases), the most common are solid, liquid, gas and plasma. 9. Temperature is how fast the particles are vibrating 10. Matter can be described by physical and chemical properties 11. The Metric System is used to measure matter. Some common measurements are length, mass, volume and density. 12. An element is the most basic type of matter that is still unique. 13. Atoms are composed of protons, neutrons and electrons. 14. The number of protons(atomic number) determines the identity of an element 15. The periodic table is organized on several levels, including by: atomic number, electron arrangement, and similar properties. !2 NOTES • # of valence electrons determines chemical properties of an element/atom • valence electrons involved in chemical bonding • valence electrons located in highest energy level • chemical bond: force of attraction that holds atoms together • Valence electrons: group 1 = 1, group 2= 2, groups 3-12= varies, group 13=3, group 14=4, group 15 = 5, group 16=6, group 17=7, group 18= 8 • Group 18 (Noble Gases) most stable group on table it has all 8 valence electrons (octet) • Metals left side of staircase (Cu and Zn) & non metals right side of staircase Ionic Bonds • ion: atoms that have a + or - charge • Polyatomic ions: ions made of more than 1 atom • Example: HCO3- (bicarbonate) —-> Big clue: 2 capital letters next to each other • Metal + Non Metal • “Opposites Attract” • Metal lose valence electrons = + ions • Non metals gain valence electrons = - ions • Ionic bonds form ionic compounds • Valence electrons are transferred !3 Positive & Negative Ions List Positive 1+ Potassium Lithium Silver Sodium Copper (I) Mercury(I) Hydrogen Cesium Ammonium Negative 1K Li Ag Na Cu Hg H Cs NH4 Hydronium H3O Positive 2+ Barium Beryllium Cadmium Calcium Cobalt(II) Copper(II) Iron(II) Lead(II) Magnesium Mercury(II) Nickel(II) Strontium Tin(II) Zinc Positive 3+ Ba Be Cd Ca Co Cu Fe Pb Mg Hg Ni Sr Sn Zn Aluminum Chromium(III) Iron(III) Boron Al Cr Fe B Acetate Bicarbonate Bisulfate HCO3 HSO4 Bromide Chloride Chlorate Br Cl ClO3 Chlorite ClO2 Cyanide Fluoride Hydroxide Hydride Iodide Nitrate CN F OH H I NO3 Nitrite NO2 Permanganate Negative 2CO3 Chromate CrO4 Dichromate Cr2O7 Oxide O Sulfate SO4 Sulfide S Nitride Negative 3 Phosphate Diatomic Molecules: H2 O2 I2 !4 MnO4 Carbonate Positive 4+ Tin(IV) Sn Manganese Mn C2H3O2 N PO4 N2 Cl2 F2 Br2 Ionic Bonds Write the chemical formula for each compound: 1. potassium hydroxide ___________________ 2. potassium chloride _____________________ 3. potassium oxide _____________________ 4. potassium sulfate___________________ 5. potassium nitride_____________________ 6. potassium phosphate___________________ 7. sodium hydroxide _____________________ 8. sodium chloride _____________________ 9. sodium oxide_____________________ 10. sodium sulfate_____________________ 11. sodium nitride_____________________ 12. sodium phosphate_____________________ 13. calcium hydroxide_____________________ 14. calcium chloride_____________________ 15. calcium oxide____________________ 16. iron (II) hydroxide_____________________ 17. iron (III) hydroxide_____________________ 18. aluminum oxide_____________________ !5 LAB: Ionic Compounds Sampler Nightingale: 1.Describe copper(II) sulfate: color, state (s-l-g) Name and Describe each of the three elements that make up copper sulfate (HINT: look up sulfate on the IONS LIST on ISN page 4) 2. 3. 4. 5. What is the formula for copper(II) sulfate?________________________ Newton 6. Describe ammonium dichromate 7. What four elements make up ammonium dichromate? ______________________ _______________________ ______________________ _______________________ 8. Describe ammonia 9. Describe chromium 10. What is the formula for ammonium dichromate?___________________ Curie 11. Describe calcium carbonate: 12. Name and Describe each of the three elements that make up calcium carbonate. (HINT: look up sulfate on the IONS LIST on ISN page 7) 12313. What is the formula for calcium carbonate? _______________________ !6 LAB: Ionic Compounds continued Galileo 14. Describe lead oxide 15.Name and Describe each of the two elements that make up lead oxide? 1216. What is the formula for lead oxide?____________________________ Goodall 17.What two elements make up hydrogen hydroxide? _________________&___________________ 18.What is the formula for hydrogen hydroxide? ____________________________ 19. Figure out the common name of hydrogen hydroxide? __________________(hint:use your brain) 20. What is the common way to write the formula for hydrogen hydroxide? ________________ Einstein’s Questions: 21. What are some common characteristics of ionic compounds due to their crystal structure? (see Text 136-137) 22. What happens to electrons in ionic compounds? 23. What is the overall charge of an ionic compound? !7 REVIEW of IONIC BONDING Use your Ions List to answer these questions & textbook p. 84-85 1. How many electrons does sodium lose in a chemical reaction? ______ 2. How many electrons does phosphorous gain in a chemical reaction? _______ 3. Name two metals that do not always lose the same number of electrons. 4. How can you tell that those two do not always lose the same number of electrons? 5. Name four nonmetals that could take the electron(s) that lithium loses in a chemical reaction. 6. In a chemical compound, would you expect an oxide ion to be joined with one atom of calcium or one atom of potassium? 7. A compound of sodium nitride would contain how many sodium ions? 8. Predict the number of atoms of each element that would be needed to form a compound of cadmium sulfide. 9. What is the formula for hydronium carbonate? !8 Determining Ionic,Covalent or Metallic Bonding From the name of a compound, can we determine whether it is ionic or covalent or metallic Bonding? Yes, from the name of the compound, you have to be able to figure out whether you have metal bonding with metal, non-metal with non-metal, or metal and non-metal. Remember, metals are on the left side of the “staircase” non-metals are on the right. Fe (Iron), the metal iron with metal iron so it is metallic bonding H2O (water), is non-metal hydrogen with non-metal oxygen is covalent bonding Na2O (sodium), metal sodium with non-metal oxygen so it is ionic bonding There are some exceptions to those rules. The exceptions involve the polyatomic ion ammonium. Ammonium(NH4) is a polyatomic positive ion and contains only non-metals. So it is possible to have nonmetals that are found in ammonium(nitrogen and hydrogen) in the form of NH4 with a positive charge. When combined with negatively charged non-metal you get an ionic compound but you have no metal atoms contained in it! QUESTIONS: Which of the following compounds are ionic and which are covalent? 1. ammonia(NH3) ________________ 3. tin(IV) oxide _________________ 2. potassium nitrate ________________ 4. hydrogen (H2) !9 _______________ Electron Dot Diagrams Almost all chemical reactions occur between electrons in the outer energy level of atoms. For that reason, the outer energy level will be the only one considered here. 1. In the most stable atoms, the noble gases- their outer energy level is full 2. In somewhat stable atoms - the sub-levels of their outer energy level are about half-filled, like Carbon 3. Octet Rule -the maximum number of electrons in the outer energy level is 8. (a)Atoms will combine to form compounds in order to reach eight electrons in their outer energy level. (b)Atoms with less than 4 electrons in their outer level tend to lose electrons to form compounds. (c)Atoms with more than 4 electrons in their outer level tend to gain electrons to form compounds. 4. Electron-dot diagram - a way of drawing the outer energy level electrons of an Lewis Dot Diagrams atom. of the Elements 5. The chemical symbol for the atom is placed in the center of an imaginary rectangle. The symbol represents the nucleus and all electrons of the atom, Lewis Dot Diagrams of Selected symbol represents an electron energy sub-level. Elements "dots". 6. Electrons are represented by except the valence electrons. Each side of the imaginary box around the Examples of Electron-dot diagrams Index Chemical concepts Chemistry of the Elements Periodic Table Lewis Symbols Electron!10Configuration into Shells Go Back Electron Dot Diagrams (continued) 1. Draw the electron-dot diagram for calcium. 2. Draw the electron-dot diagram for sodium. 3. Draw the electron-dot diagram for chlorine. 4. Draw the electron-dot diagram lithium fluoride 5. Draw the electron-dot diagram for a water molecule. !11 Formula Review Instructions: Compounds that form Ionic bonds (metal+ non metal) Use charges on the IONS LIST on ISN page 4 to give the formula and the name for each of the following compounds. NOTE: if there is no reaction possible between the ions indicate by writing “NR.” 1 problem No Reaction (NR) Ions in Compound Formula Name 1. Mg O 2. Al Cl 3. Zn I 4. Li CO3 5. Al Ba 6. Fe(II) 7. Ca N PO4 8. K Cl 9. Na HCO3 10. Mn O !12 COMPOUNDS & BONDING REVIEW COMPOUND- ions combine chemically in a specific ratio, the ratio is indicated by a formula CHEMICAL FORMULA - shows the ratio by using SUBSCRIPTS examples: H2O CuCl2 Al(CO3)3 How atoms combine is determined by the electrons in the outer energy level (VALENCE ELECTRONS). The goal is to be STABLE with 8 electrons in the outer energy level. The exception to this is an atom that just has one energy level then the number would be 2. Atoms will gain, lose, or share electrons with each other to do this. BOND - the force that holds atoms together - this bond is electrical in nature (+ or -) ION - is a charged particle - if an atom loses electrons it becomes a positive ion - if an atom gains electrons it becomes a negative ion IONIC BONDING - bonding that occurs between opposite charged ions this happens as one atom transfers electron(s) to another atom forming ions. Ionic bonding usually occurs between metals and nonmetals COVALENT BONDING - bonding that occurs between atoms as the share electrons to become stable. Covalent bonding usually occurs between nonmetals Hydrogen always covalently bonds METALLIC BONDING - Occurs between metals. Metallic Bonding has free moving electrons or “sea of electrons” MOLECULE - a name applied to substances that are formed with covalent bonding. FORMULA WRITING OXIDATION NUMBER = VALENCE=Charge number This is the combining ability of an atom. It tells how many electrons an atom will gain, lose, or share when forming a compound. This is usually determined by the number of electrons in the outer energy level but it can vary. The sum of the oxidation numbers in compounds must equal 0 All compounds are electrically neutral !13 COMPOUNDS & BONDING REVIEW Part 2 When writing a formulas the metal or the element with the positive (+) oxidation number/ is always written first example: NaCl or table salt. Na is positive and Cl is negative The “Old” FORMULA TRICK 1. write oxidation numbers above the symbols 2. check to see if you have a positive(+) and negative(-) 3. check to see if they already add to 0 - if not go to 4 4. cross oxidation numbers to determine subscripts. note: the number 1 is always implied disregard negative sign 2+ Mg -1 Cl 2+ Mg -1 Cl MgCl2 NAMING COMPOUNDS BINARY COMPOUNDS - compounds made of 2 elements IDE - in a binary compound, end the name of the second element with the ide suffix sodium and chlorine make sodium chloride POLYATOMIC IONS • a group of atoms which act together as one charged particle called an ion. They have their own name and oxidation number • when you name compounds that have polyatomic ions in them you just use the name of the polyatomic ion NOTE - you must use ( )when you have more than one in the formula example: Al2(CO3)3 is correct. !14 Al2CO33 is NOT correct !15
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