REDUCING AMALGAM WASTE & MERCURY LOADS TO SEWER FROM VICTORIAN DENTAL SURGERIES Rohan Ash URS Australia, Melbourne, VIC ABSTRACT AiGroup, ADA Victorian Branch and Melbourne’s water industry (represented by South East Water) engaged URS to investigate mercury loads to sewer from Victorian dental surgeries through dentist surveys, interviews, waste audits, literature reviews and development of an amalgam/mercury cycle. It was estimated that Victorian sewers received about 210kg/yr of mercury from dental clinics about 80% of this to Melbourne’s sewers. Significant mercury load reductions to sewer are possible by installing amalgam separators in dental surgeries. This should help to improve biosolids quality produced at wastewater treatment plants, and facilitate the recovery and reuse of mercury and other useful metals used in amalgam alloys. INTRODUCTION In 2006 URS were engaged by the Australian Industry Group (AiGroup) to carry out an investigation of amalgam waste management practices and mercury loads to sewers from Victorian dental surgeries. AiGroup commissioned this study in partnership with the Australian Dental Association Victorian Branch (ADAVB) and the Melbourne water industry, represented by South East Water (SEW) as part of AiGroup’s Sustainability Covenant with EPA Victoria. This paper gives an overview of the study including background on amalgam waste generation and management and the potential impacts of mercury on recycled water and biosolids. Dentist surveys, interviews, surgery waste audits, literature reviews and other data collection and assessment methods were employed to estimate quantities of amalgam mass and mercury loads generated by dentists. This paper summarises the key findings, outcomes and expected benefits of the study. The first phase of surveys and associated data collection activities were carried out by URS in close collaboration with project partners: AiGroup, ADAVB and SEW. Two online surveys were posted on the ADAVB website in early 2007 comprising a detailed quesionnaire, and then a shorter followup quick survey. The surveys were road tested and reality checked by focus groups and follow-up interviews with a cross section of dental practitioners. Note that this paper does not discuss the survey results, but the key outcomes of the surveys are reflected in the discussion on the assessment of mercury loads. URS audited the collection of amalgam waste from six surgeries and the subsequent recovery of the mercury by distillation at a specialist mercury waste recycling facility in Melbourne (CMA EcoCycle). The dentist surveys, interviews, audits, literature reviews and other data collection activities collectively provided the basis to estimate quantities of amalgam and recoverable mercury likely to be generated from Victorian dental surgeries. The assessment phase provided indicative estimates of current mercury loads to sewer as well as the potential reductions that might be achieved through installation of amalgam separators. URS also assessed the costs and benefits to the industry of installing amalgam separators in dental clinics. BACKGROUND & PROJECT DRIVERS Victoria’s Dental Industry The dental industry comprises both private and public sectors. This study mainly focussed on the private sector, but it was important to understand the relative size and location of public dental hospitals and clinics, which also generate amalgam wastes and contribute mercury loads to sewer. PROJECT METHODS Private Sector Dental Surgeries The study involved two key phases as follows: There are around 1370 dental surgeries across Victoria. These represent about 2800 practising dentists and roughly 3560 dental chairs considered to be generating amalgam wastes. In Metropolitan Melbourne, there are approximately 1070 surgeries (about 2782 chairs) believed to be generating amalgam wastes. 1. Survey of private sector dentists (ADAVB members) as the main data collection phase 2. Estimation of amalgam waste generation rates and overall mercury loads to sewer. Dental surgeries are spread all over Melbourne area, but with clusters within the CBD and inner suburbs as well as around major commercial centres in outer suburbs. About 300 private sector dental surgeries are located within country Victoria, with most located in larger regional towns such as Geelong, Ballarat and Bendigo. Public Sector Clinics (PSC) There are 70 PSCs across Victoria, comprising about 228 chairs. Over 30 of these are located in Melbourne’s sewerage catchments. Royal Dental Hospital Melbourne (RDHM) The RDHM has 139 chairs. Based on its amalgam purchasing records (inspected by URS), RDHM is the largest amalgam user in Melbourne and Victoria. On amalgam usage alone it is reasonable to assume that RDHM is the largest individual contributor of mercury load to sewer from the Victorian dental industry. A key driver for this study was that mercury levels in biosolids (i.e. ongoing by-products generated) remain at levels above or close to maximum contaminant limits specified in EPA Victoria’s biosolids land application and geotechnical fill guidelines. Elevated mercury levels in biosolids also restricts opportunities for energy recovery because of the high cost of control for mercury emissions in flue gases from combustion, gasification or pyrolysis of biosolids. Types of Dental Wastewater Systems A conventional dental wastewater system would consist of chairside traps for each chair followed by a vacuum pump filter (usually only for a wet system), then an air water separator prior to discharge to the sewer outlet. For more recent or advanced systems, an amalgam separator could be installed either before or after the vacuum pump or air/water separator. Figure 1 illustrates typical wet and dry dental wastewater system configurations, and optional locations for an amalgam separator. What is Amalgam & Amalgam Waste? Amalgam has been used by dentists for more than 150 years for dental restorations traditionally called “silver fillings”. Dental amalgam used in Australia typically contains up to 45-50% mercury, 35% silver, 9% tin, 6% copper and 1% of other metals including zinc. NHMRC (1999) reported that amalgam use by Australian dentists was reducing at around 10% per year, due to alternative restorative materials such as plastics and composites becoming increasingly used by dentists and preferred by patients. Amalgam waste is produced during dental drilling, carving and polishing procedures when amalgam fillings are placed, removed or repaired. Removal and repair of old amalgam fillings is still the major proportion of restorative work carried out by general dental practitioners, and this generates the largest amount of amalgam waste from dental clinics. The quantities of amalgam waste generated and therefore mercury loads to sewers from dental surgeries is expected to slowly reduce as amalgam usage decreases. However, in the short to medium term, mercury loads to sewer from the dental industry could still remain significant given continued restorative procedures involving amalgam for a sizeable proportion of the middle and older aged population. The form of mercury in dental amalgam is regarded as inert and insoluble, having the ability to form relatively stable alloys with other metals. Mercury and as an alloy in amalgam has very high specfic gravity. Therefore almost all amalgam particles are expected to settle out at treatment plants within sludge and biosolids by-products as one of many of potential low level contaminants. [adapted from Washington State Department of Ecology, www.ecy.wa.gov] Figure 1: Dental Wastewater Systems (Wet & Dry) Chairside Traps A conventional chairside trap has 0.7 mm holes (#25 mesh), with the literature quoting about 50% removal efficiency of amalgam solids prior to discharge to the dental wastewater system. This capture efficiency can be increased through smaller mesh size traps and more frequent cleaning. Vacuum Pump Systems Pump filters (typical screen pore size of 0.425 mm or #40 mesh) are almost always required for wet systems, to protect vacuum pumps from damage or blockage from solids that may enter the surgery wastewater system. Dry vacuum systems may also have a filter, but the air/water separator installed before the pump prevents pump damage or blockage. An additional 25% removal by pump filters (ie. 50% of that which passes the chairside filter) is typical mid-range quoted in the literature. Amalgam Separators A range modern amalgam separator designs are commercially available employing sedimentation, filtration, centrifugation and/or ion exchange processes and capable of removing a wide range of particle sizes including dissolved mercury. Many amalgam separator suppliers with combined or multiple stages claim amalgam removal efficiencies of 99% and higher. The literature reports removal rates as high as this, and some even higher (Fan et al. 2002, Diroff 2004). To obtain certification to International Standard (ISO 11143), amalgam separators are subjected to rigorous independent testing to demonstrate 95% removal efficiency. A very low percentage of Victoria’s (and Australia’s) dental surgeries had installed amalgam separators at the time of this study. Amalgam wastes not discharged to sewer Amalgam wastes that are not normally discharged to sewer include: “non-contact” amalgam (or scrap) comprising: - used capsules containing residual amalgam; - unused (damaged or expired) capsules; - amalgam carvings from fillings prior to placement in human mouths; fillings and whole teeth containing amalgam fillings removed from patients mouths; and particles/sludges from chairside traps, pump filters and amalgam separators (if installed). These amalgam wastes are disposed by dentists by three possible routes: 1. dedicated amalgam waste containers for collection by mercury recyclers (only 1 recycler currently exists in Victoria), 2. biomedical waste or sharps containers for transport to waste incinerators, and/or 3. general rubbish bins for disposal in municipal landfills. Mercury Discharges to Sewer from Dentists Urban sewers receive wastes from a wide range of industrial, commercial and human sources. The dental industry is reported as a significant contributor of mercury sewer loads, eg. 10% to 80% of total mercury received at US and Canadian treatment plants (Sussman 2006). Dental mercury sewer discharges are considered to contribute to elevated concentrations of mercury and other heavy metals in raw sewage inflows and biosolids produced at sewage treatment plants, with potential to limit the range of beneficial reuse opportunities such as land application and energy recovery. At the time of this study ADAVB and the Victorian Water Industry were proposing voluntary installation of amalgam separators capable of >95% amalgam removal in accordance with International Standard ISO 11143:2008. The target was installation of amalgam separators in 90% of “eligible” dental surgeries within a 3 year period. Eligible dentists are those expected to be using amalgam and discharging to sewer including General Practitioners and specialists such as endodontists, prosthodontists and paediatrists. Potential Impacts of Mercury Mercury is produced mainly by volcanic emissions but also by a range of other natural and manmade processes such as mining, coal burning, chlorine and vaccine manufacture, and dental surgeries. Mercury and its compounds are persistent in the environment and can readily bio-metabolise into methyl-mercury, which is considered the most toxic form. Methyl-mercury can bioaccumulate in the food chain with potential impacts on higher level animals such as fish, shellfish, sharks and birds. Fish consumption is widely reported in the literature as a main source of methyl-mercury intake in humans (Kao, Dault, Pichay 2004, Jacobsson-Hunt 2007, Commission of the European Communities, CEC 2005, USEPA July 2006). Methyl-mercury is a known neuro-toxicant potential affecting development of brains and in acute doses is highly toxic to humans and animals. Environmental agencies and wastewater treatment plant operators in Australia and overseas continue to take a precautionary approach to mercury from the dental industry and other industries, given the potential for these significant loads to be an ongoing contaminant source or “pool” entering the soil, surface water and air environments via effluent and biosolids treatment and disposal/reuse pathways. In many regions of Europe, United Kingdom, USA and Canada the installation of amalgam separators in dental surgeries has become law due to active mercury reduction strategies in those countries. Melbourne Water has recently undertaken phytotoxicity and phytoextraction trials for selected plant species grown in biosolids from Western Treatment Plant. It was reported that some plant species exhibited mercury stress or did not grow in biosolids containing mercury levels ranging 3.5-8.4 mg/kg (Lomonte C et al, 2009). Extensive coverage of mercury chemistry, potential exposure pathways, toxicity (acute and chronic), and impacts on humans, plants, soils and the environment are found throughout the literature, and is not discussed further in this paper. LITERATURE REVIEW There is very limited data in Australia on mercury loads to sewers from the dental industry. However there is extensive literature overseas including from the USA, Canada, Europe and the UK. Most Australian literature quotes overseas studies. A wide-range of dental industry mercury loads from and equally wide-ranging relative contributions (10% to 80%) to overall sewerage system mercury loads has been reported in overseas literature (Sussman 2006). A summary of the key literature reviewed in this study is listed in Table 1. Table 1: Reported Dental Mercury Mass Loads Daily Annual mg/dentist/day g/dentist/yr 35 – 522 Scarmoutzos L, et al 2003 (11 refs. around the world) 100 101 (dry systems) Reference WLSSD 1996 (USA) 22 Barron T 2002 (USA) 138 (wet systems) 99-198 24.7 - 49.6 246 61.5 30-300 2.5 - 223 (0% - 100% separators installed) DEFRA 2001 (UK) Environment Canada 2003 Johnson EIP Associates. 1999 (6 US refs., 1 Denmark) Adegbembo A O Watson P A 2004 (Canada) Dental industry mercury loads reported in the literature are usually based on amalgam waste monitoring programs at dental surgeries or theoretical mass balances of the mercury cycle in surgeries. Reported loads are at best indicative estimates or ranges, which are an indication of the high variability between surgeries and at any one point in time. Dentist mercury loads depend on a wide range of factors including: quantity of amalgam used, and quantification of non-contact amalgam; numbers and types of dental procedures carried out involving amalgam use or waste generation; proportion of amalgam carvings swallowed by patients during amalgam placements; proportion of amalgam carvings lost to dental wastewater systems during placements; efficiency of dental wastewater systems ie. chairside traps, pump filters and separators; proportion of surgeries having wet or dry systems, pump filters and amalgam separators; disposal/recycling routes for non-contact amalgam and amalgam wastes captured by filter systems. Desktop mass balancing methods employed to estimate dentist mercury loads require a large number of assumption to be made regarding some or all of the above factors. AMALGAM WASTE COLLECTION AUDIT In a parallel project with SEW and CMA Ecocycle, amalgam waste was collected from amalgam separators from 6 dental surgeries in Victoria during May and June 2007. Four of these were in Melbourne and two in rural Victoria. All of these surgeries had ISO11143 compliant amalgam separators installed within the previous 2-3 years. URS accompanied Ecocycle collectors to these dental surgeries to observe the collection of amalgam wastes from the separators, and obtain data on amalgam use rates and procedures involving amalgam placements and removal. The collected wastes were transported to Ecocycle’s factory in Campbellfield Victoria, and weighed (wet and after oven drying). The dried wastes were then subject to distillation to volatise the mercury. The residue (char) left over was sent to a spectrographic laboratory for analyses of other metals including silver, tin, copper and zinc. Mercury loads found from the six surgeries ranged 60 - 90 g/chair/Yr, or 160 - 230 g/surgery/Yr. These mercury loads were at the higher end of the range reported in the literature (Table 1). It was considered that these surgeries represented higher amalgam usage compared with Victoria-wide averages from the URS survey and RDHM amalgam purchase records as reviewed by URS. ASSESSMENT OF MERCURY LOADS Amalgam/Mercury Cycle An “amalgam/mercury cycle” was developed for a an average sized GP dental surgery to illustrate amalgam waste disposal pathways from surgery to sewer – see Figures 3, 4 and 5 at end of this paper. The amalgam/mercury cycle for the Victorian dental industry was developed based on data from URS and ADAVB surveys, follow up interviews, dental surgery audits, RDHM amalgam purchase records, and literature reviews. Amount of amalgam waste generated per dental procedure was estimated as a proportion of the amalgam used or removed in each procedure, and in turn the proportion of this waste trapped by the dental wastewater system before sewer discharge. The amount of amalgam waste trapped by the surgery’s wastewater system depends on whether a pump filter and amalgam separator is installed. All dental surgeries were assumed to have a chairside trap for each dental chair. The URS survey indicated pump filters in around 60% of surgeries. URS assumed as the “Base Case” Scenario an existing “uptake” of amalgam separators in the dental private sector of less than 2%. The total amalgam waste loss to sewer for a typical dental surgery was then estimated from average weekly number of placement and removal procedures carried out (from the URS survey). The annual loads days/year. were based on 250 working Key Assumptions Due to the data gaps from the URS and ADAVB surveys, and high variability of amalgam usage and types of dental procedures across different dental surgeries, numerous various assumptions were made to ensure that the estimate of mercury loads to sewer were reasonably representative of current dental amalgam waste management practices. Described below is an overview of key assumptions used in the amalgam/mercury cycle. Percentage Mercury in Amalgam Amalgam was assumed to contain on average 45% mercury, 35% silver, 9% tin, 6% copper and <1% of other metals (eg. zinc, platinum). This is typical for amalgam products supplied to Australian dentists by Southern Dental Industries (SDI), which supplies most of the amalgam to Victorian Dentists Industry (pers. comm. SDI 2006, and Dental Logistics 2007). Amount of Non-Contact Amalgam There is a proportion of amalgam that is not used and is excess generated during preparation of the amalgam. It is not place in the patient’s mouth and is disposed of via offsite disposal/recycling routes. Non-contact scrap amalgam was assumed as 20% of the amalgam prepared and includes used capsules. Most literature indicated higher noncontact amalgam proportions than the 10% as suggested by the URS survey. Amalgam Ingested by Patient and attached to tooth Amalgam swallowed has been assumed at 10%, occurring when amalgam is carved from the patient’s teeth during placements or when amalgam is drilled from teeth during removal procedures. This is a conservative estimate based on various overseas literature sources. For removals, it was assumed 10% of the amalgam remained attached to the tooth, based on review of overseas literature. The assumed amount of amalgam swallowed or still attached to the tooth in removals is closely related to the assumed size of restorations removed. Size of one Restoration (Filling) Amalgam is supplied to dentists as sealed twocompartment capsules (one part mercury, the other part alloy powder) ranging in size 800-2400mg (total amalgam mix). The amalgam contained in one filling ranges 500-1500mg as reported in various US, EU and UK literature sources. It was assumed that the average size of one filling attached to the tooth is about 900mg. Placements It was assumed an average 1200mg of amalgam is prepared, 200mg is non-contact amalgam scrap (carved before placement and amalgam remaining in the used capsules), 1000mg of amalgam is placed in the patient’s mouth, 100mg is then carved from the filling into the dental wastewater system, leaving a 900mg filling attached to the tooth. Removals It was assumed that when amalgam fillings are removed (assumed 900mg in size attached to tooth), that about 80% of is drilled out and enters the dental wastewater system, 10% is ingested by the patient and another 10% stays attached to the tooth. It was assumed that numbers of amalgam removal procedures are about three times greater than the numbers of amalgam placement procedures, based on the URS Survey and interviews with GPs utilising amalgam. The amount of amalgam waste generated by a removal procedure is roughly ten times higher than the placement procedure. Whole Teeth Extractions Mass of amalgam in whole teeth extractions was assumed 900mg (same as placements), but assumed to by-pass the dental wastewater system. Dental Wastewater Solids Removal Efficiencies The 50% removal efficiency for chairside traps is widely quoted in the literature. The additional 25% removal by pump filters (ie. 50% of that which passes the chairside filter) is mid-range of that quoted in the literature. The amalgam/mercury cycle assumed any dental surgery that has an amalgam separator in combination with a chairside filter and with or without a pump filter, will achieve 95% amalgam solids removal consistent with ISO11143 standards. Amalgam/Mercury Load Estimates per Dentist URS estimates of mercury mass loads for a typical GP dental surgery (2 chairs) are shown in Table 2. Table 2: Dental Mercury Mass Loads - URS Study Daily Annual mg/dentist/day g/dentist/yr Basis Basecase Scenario (2% of surgeries with amalgam separators) 205 75 300 mg mercury/ dentist/working day Best Practice Scenario (90% of surgeries with amalgam separators) 33 12 50mg mercury/ dentist/working day Daily mercury load estimates were averaged over the year, based on 250 working days/year. URS mercury load estimates per dentist were at the upper end of the range reported in the literature (Table 1). These estimates may reflect the low uptake of amalgam separators (<2%) across Victoria at the time, but also the conservative nature of assumptions made by URS. The literature reviewed for this report indicated that mercury loads from dentists ranged 30 - 520 mg/dentist/day or 10 - 130 g/dentist/year. Loads are highly variable from surgery to surgery and at any particular time. Most of these reported dental industry loads are indicative estimates only. Some of the overseas reported mercury loads are associated with areas having higher uptake of amalgam separators compared to Victoria. Amalgam/Mercury Loads to Sewer VictoriaWide Figure 5 at the end of this paper provides a conceptual Victoria-wide dental amalgam/mercury cycle showing key data assumptions and estimates for amalgam usage, waste generation and mercury loads to sewers from both private and public sector dental surgeries including RDHM. Overall mercury loads to sewer from all dentists were estimated by individual dentist loads discussed earlier in this paper, and estimated numbers of dental chairs in private and public surgeries across Victoria. The overall mercury loads to Victoria’s sewers from both the Private and Public Sector Dentists (including RDHM) were estimated to be of the order 210kg/yr. Indicative estimates of overall Victoria-wide amalgam/mercury waste loads to sewers relative to amalgam usage and solid waste disposal routes are summarised as follows: to the Melbourne’s two main treatment plants: Western Treatment Plant (WTP) and Eastern Treatment Plant (ETP). Melbourne Water supplied extensive data on annual mercury loads contained in WTP and ETP inflows and in biosolids, providing best indications of total load from all potential sources (domestic, industrial, commercial, stormwater inflow, groundwater infiltration, etc). The estimated dentist mercury loads to Melbourne’s sewers were found to be close to or in excess of combined mercury loads to WTP and ETP as reported by Melbourne Water. The private sector dental industry loads predicted in this study could be more than 90% of the overall loads received by Melbourne’s sewers - based on mercury levels in treatment plant biosolids where over 95% of the mercury is expected to have settled out (Balogh and Liang 1995). Discussion – Load Estimation Uncertainties The literature reports wide-ranging mercury loads from dental surgeries and equally wide-ranging relative contributions (10% to 80%) to overall sewerage system mercury loads (Sussman 2006). The impact of dental industry loads depends on the relative contributions from all other mercury load sources in the sewerage catchment including human, industrial, commercial, stormwater inflow and groundwater infiltration. It is also widely reported in the literature that amalgam particles may be accumulating in dental surgery wastewater pipes and within the sewerage system. This could result in lower mercury loads being measured in sewage treatment plant inflows than the sum total loads from all sources in the sewerage catchment discharging to sewer. Total amalgam use (Private Sector & Public Sector) 630 kg/yr Total mercury mass in amalgam used (Private Sector & Public Sector) 284 kg/yr URS estimates of mercury loads to sewer were also particularly sensitive to the following assumptions: Net mercury discharged to all Victorian Sewers 210 kg/yr (i) Total mercury mass in amalgam waste diverted from sewers (disposed to biomedical waste, landfill or recycled) 600 kg/yr (ii) mass of amalgam in each filling, estimated from survey cross-checked against literature, Amalgam waste not discharged to sewer, is disposed of either to biomedical incinerators or landfills or reused by mercury recyclers in roughly equal proportions – based on the URS survey. Amalgam/Mercury Loads to Melbourne’s Sewer The load to Melbourne’s sewers was roughly 162 kg/yr, with about 93% of this from the private sector dental surgeries, about 4.4% from the PSC’s and 2.6% from RDHM. To determine the relative contribution of mercury loads in Melbourne’s sewerage catchment, the dental mercury loads were divided by the total estimated mercury loads in combined raw inflows amount of amalgam used, estimated from the URS survey and RDHM amalgam use records, (iii) numbers of placements and removals carried out, estimated from URS survey, and (iv) Amalgam waste removal efficiencies for dental wastewater systems as published in literature and accounting for very low percentage of amalgam separators in Victoria at the time. Notwithstanding the above uncertainties and assumptions, even if lower mercury loads of say ~25g mercury/dentist/year were adopted (ie. lower end of that reported in the literature – see Table 1), dental industry mercury loads could still be of the order 30% of overall loads to Melbourne’s two treatment plants. This is based on mercury concentrations in biosolids. Despite the limited accuracy of many of the dental mercury loads reported in the literature and also in this study, the dental industry is still regarded as one of the more significant contributors of mercury loads to Victoria’s sewers. Mercury Reduction from Improved Practices The mercury loads from dentists could reduce from year 2007 levels of around 210kg/yr to about 33kg/yr (84% reduction) within the three years proposed for the voluntary amalgam separator installation program. For Melbourne’s sewers, it was forecast that mercury loads could reduce from about 162.5kg/yr to 25.3 kg/yr – see Figure 2 at end of this paper. If only the private dentists participated in the voluntary amalgam separator installation program, then mercury reductions would be about 77%. The best practice scenario was for 90% of Victoria’s dental surgeries (private and public including RDHM) to voluntarily install amalgam separators within 3 years and implement other best practice measures to divert amalgam wastes from sewers. Amalgam Separator Installation Costs The estimated overall cost of amalgam separator purchase, installation and associated works across 90% of Victoria’s dental surgeries (both private and public) was of the order $6.5 – 13 Million. For Victoria’s private sector dentists, the cost was roughly $5 - 10 million, including $3.7 - 7.4 Million for Melbourne’s private dentists. CONCLUSIONS The URS study estimated 84% reduction in mercury loads to sewer from private dental surgeries could be achieved by installing ISO11143 compliant amalgam separators in 90% of dentists across Victoria, at estimated cost range to the industry of $5-10 Million. There are a range of key benefits of mercury reduction by Victoria’s dentist, such as: (i) Significant mercury load reductions to sewers and sewage treatment plants; (ii) Reduced mercury concentrations in biosolids and recycled water; (iii) Increased diversion of amalgam wastes from current disposal routes to sewer, landfills (reduced groundwater impacts) and biomedical incinerators (lower mercury air emissions); and (iv) Promotion of increased recycling and recovery of mercury and other valuable metals (silver, copper, tin, zinc) contained in the amalgam. ACKNOWLEDGEMENTS URS acknowledges the support and contributions to this study by the following organisations: Vicki Pryse, Sustainable Industry Consultant, AiGroup Garry Pearson, Chief Executive Officer, Australian Dental Association, Victoria Branch. Terry Anderson, South East Water, Victoria. CMA Ecocycle, Campbellfield, Victoria. REFERENCES Adegbembo A O, Watson P A 2004. Estimated quantity of Mercury in Amalgam Waste Water Residue Released by Dentists into the Sewerage System. Ontario Canada. J. Canadian Dental Assoc. Dec 2004 ADA 2004. American Dental Association “Best Management Practices For Amalgam Wastes”. Balogh S & Liang L 1995. Mercury Pathways in Municipal Wastewater Treatment Plants. J. Water, Air & Soil Poll., Vol80, No.1-4, Feb 1995. Barron T 2002. Mercury Headworks Analyses 2000. Union Sanitary District 2002. CA. USA CEC 2005. Communication from the Commission to the Council and the European Parliament, Community Strategy Concerning Mercury. Commission of The European Communities, Brussels 28.01.2005, COM(2005) 20 final. DEFRA UK 2001. Environment Protection Consultations, Department for Environment, Food & Rural Affairs (DEFRA), United Kingdom (UK), 2001 Diroff N and Thomas A 2004. Options for Dental Mercury Reduction Programs: Information for State/Provincial and Local Governments. A report of the Binational Toxics Strategy Mercury Workgroup Co-chairs. Report for Great Lakes National program Office, USEPA, Chicago August 2004. Fan P L, Batchu H, Chou H-N, Gasparac W, Sandrick J, Meyer D M 2002. Laboratory Evaluation of Amalgam Separators. J. of the American Dental Association (JADA) May 2002. 133:577-584. Kao R T, Dault S, Pichay T 2004. Understanding the Mercury Reduction issue: The Impact of Mercury on the Environment and Human Health. CDA Journal. Vol. 32, No.7, July 2004. Environment Canada 2003. Dental Amalgam Waste Mercury & Dentistry. Environment Canada. Toronto Canada 2003 (Reference to Watson et al 2003/04). Jacobsson-Hunt 2007 Amalgam and Mercury in the Dental Setting and the Efficiency of Amalgam Separators. Ulla Jacobsson-Hunt DDS, DMD. Master of Science Thesis, Env. Sci. programme, Linköpings University, Sweden 2007. Johnson EIP Associates 1999, Technical Memo Mercury Source Identification Update. Dental Offices and Human Wastes. Palo Alto RWQCP. Fillings. J. Water, Air, & Soil Poll. Vol.80, No.1-4. Feb 1995. Scarmoutzos L, et al 2003. Scarmoutzos L M, Boyd O E, MVS Solutions, Solmetex (US amalgam separator supplier). Mass., USA 2003 Lomonte C, et al 2009. Phytotoxicity of biosolids and screening of selected plant species with potential for mercury phytoextraction. University of Melbourne, Melbourne Water, August 2009. Sussman M 2006. A Comprehensive Approach to Waste Management for the Dental Profession. J. US Dentistry 2006, PP58-60. NHMRC 1999. Dental Amalgam and Mercury in Dentistry. Report of an NHMRC working party. National Health & Medical Research Council, Commonwealth of Australia. March 1999. WLSSD 1996. Western Lake Superior Sanitary District (WLSSD). Draft Wisconsin Mercury Sourcebook, 1996 Skare I 1995. Mass Balance and Systemic Uptake of Mercury Released from Dental Amalgam USEPA July 2006. EPA’s Roadmap for Mercury. Dental Industry Mercury Load (kg/Yr) Reduction to Melbourne's Sewers Voluntary Amalgam Separator Installation Program 180 Voluntary Separator Program Starts 160 Load (kg/Yr) Mercury Mercury Load (kg/Yr) 140 Best Management Practice Scenario 120 RDHM Separator Installed in (say) 2009 100 PSC (90% uptake of separators within 3 Years) 80 Private Sector (90% uptake of separators within 3 Years) 60 40 20 0 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 Year Figure 2: Dental Industry Mercury Load Reductions (illustrative representation only) Offsite Disposal/Recycling Methods 10001000 mg 67.5 mg Swallowed by patient (10% of scrapings) Preparation of amalgam (2 spill 600 mg alloy, 1200mg amalgam) Placement of amalgam restorations (900mg retained in tooth) 10 mg Non-contact amalgam (20% of amalgam used) 200 mg Scrapings in mouth 100 mg 90 mg Chairside traps and Pump Filters Rinsed down sink (~10% depending on surgery practices) Captured Amalgam 45 mg 22.5 mg Chairside trap (50% amalgam removal) Not trapped 45 mg Vacuum Pump Filter (50% removal of amalgam passing Chairside trap) Not trapped To Sewer 22.5 mg Non-Contact amalgam Sucked up with vacuum (5%) Sources 720 mg Removal of Teeth containing amalgam (900mg removed per tooth) 900 mg Swallowed by patient (10%) + still attached to tooth (10%) 900 mg Whole Teeth Extracted Removal of amalgam (900mg removed per tooth) Chairside Traps present in 100% of dentists (URS Survey) Chairside trap (50% amalgam removal) Not trapped 360 mg Pump filters only present in 60% of dentists (URS Survey) Vacuum Pump Filter (50% removal of amalgam passing Chairside trap) 180 mg Not trapped To Sewer S E W E R 180 mg 360 mg Captured Amalgam 540 mg Chairside traps and Pump Filters Rinsed down sink (~10% depending on surgery practices) 180 mg Offsite Disposal/Recycling Methods Figure 3: Dental Surgery Amalgam Cycle with conventional wastewater system (indicative values only) Offsite Disposal/Recycling Methods 10001000 mg 85.5 mg Swallowed by patient (10% of scrapings) Preparation of amalgam (2 spill 600 mg alloy, 1200mg amalgam) Placement of amalgam restorations (900mg retained in tooth) 10 mg Non-contact amalgam (20% of amalgam used) 200 mg Scrapings in mouth 100 mg 90 mg Chairside traps and Pump Filters Rinsed down sink (~10% depending on surgery practices) Captured Amalgam 45 mg 18 mg 22.5 mg Chairside trap (50% amalgam removal) Not trapped 45 mg Vacuum Pump Filter (50% removal of amalgam passing Chairside trap) Not trapped 22.5 mg ISO 11143 Separator (80% removal of amalgam passing pump filter) To sewer 4.5 mg Non-Contact amalgam Sucked up with vacuum (5%) Sources 720 mg Removal of Teeth containing amalgam (900mg removed per tooth) 900 mg Swallowed by patient (10%) + still attached to tooth (10%) 900 mg Whole Teeth Extracted Removal of amalgam (900mg removed per tooth) Chairside Traps present in 100% of dentists (URS Survey) Chairside trap (50% amalgam removal) Pump filters only present in 60% of dentists (URS Survey) Not trapped 360 mg Vacuum Pump Filter (50% removal of amalgam passing Chairside trap) 180 mg 360 mg URS Survey indicated Separators are in ~32% of dentists, but Basecase assumes 2% Not trapped 180 mg ISO 11143 Separator (80% removal of amalgam passing pump filter) To sewer 36 mg S E W E R 144 mg Captured Amalgam 684 mg Chairside traps and Pump Filters Rinsed down sink (~10% depending on surgery practices) 180 mg Offsite Disposal/Recycling Methods Figure 4: Dental Surgery Amalgam Cycle with amalgam separator installed (indicative values only) Note to figure: Amalgam use Victoria wide in kg/yr Mercury loads Victoria wide in kg/yr all values are indicative only Amalgam Cycle in Dental Surgeries Amalgam Purchased TOTAL 748 kg/yr 337 kg/yr Amalgam Stored On-Site 117 kg Amalgam 53 kg Mercury Private Sector 1370 3562 P.S.C. 690 310 Old/Expired/ Damaged Caps 70 228 RDHM 44 20 1 139 No. Sites No. Chairs 14 7 Amalgam kg/yr Mercury kg/yr Empty Caps & Non-Contract Amalgam Sewerage System Route Air 60kg/yr Mercury 5% Amalgam Used TOTAL 631 kg/yr 284 kg/yr Private Sector 160 g/chair/yr 500 260 160 g/chair/yr 37 17 RDHM Hospital School Total 11 3 14 7 Swallowed Amalgam Scrapings Placements (new fillings & repairs) Dental WW System 630 kg/yr Mercury Human Waste (domestic sewage) Teeth Removed 170 kg/yr Mercury Removals (old fillings) Captured Amalgam (chairside traps, pump filters, separators) 420 kg/yr Mercury Deceased Flue Gas Treatment (scrubbers, ESP, etc) Amalgam kg/yr Mercury kg/yr Amalgam Fillings in Patients & Swallowed Biomedical Incinerator 200 kg/yr Mercury Rubbish/ Garbage 200 kg/yr Mercury Rinsed to sewer 10% Air Landfill ~95% of Mercury Sewer 210 kg/yr Mercury Recycling 200 kg/yr Mercury Ash/Dust Waste from Flue Gas Treatment Biogas/ Energy Recovery Amalgam Total Waste 600 kg/yr Mercury Sewer ~50 kg/yr Mercury Human Waste Route P.S.C. Metal Recovery Sewage Treatment Plant ~5% of Mercury Sludge Treatment Storage at STP Recycled Water Land Application Effluent Discharge Surface Waters Ocean Internment Cremation Dental Industry/ Other Waste Disposal Route Figure 5: Victoria-wide Dental Industry Amalgam/Mercury Cycle (indicative values shown only) This figure is copyright URS Australia Pty Ltd Prescribed Waste Facility
© Copyright 2026 Paperzz