Effective and Simple Solutions to Soil and Water Management TECHNOLOGY FOCUS: Understanding Water Repellent Soils and the Use of Irrigation Additives 2005 / DIAMOND K GYPSUM INC. / ALL RIGHTS RESERVED / PHONE 435-896-8870 / FAX 435-896-8893 Understanding Water Repellent Soil and the Use of Irrigation Additives • Highly productive, irrigated soils must be managed very carefully to mitigate and manage the problem of hydrophobic soil conditions. These problematic conditions result in soil particles that literally repel water. • Research shows that hydrophobic soils develop from a biological process involving the natural decomposition of organic minerals such as those found in crop residue and other soil amendments, all resulting in a water repellent organic coating formation on sand and soil particles. • These water repellent soil challenges are hastened under the circumstances of frequent wet-dry-wet cycles associated with intense irrigation. The development of this soil condition can also be accelerated by inefficient irrigation patterns, soil compaction, reduced tillage systems, and certain diseases. Normal sand particle. Water repellent sand particle. How to manage the inevitable condition of soil water repellency? • Over the past 50 years, there have been many technological advancements leading to the development of countless irrigation additives and soil treatments positioned for use in managing soil and water challenges. • Hundreds claim to make water wetter, improve irrigation efficiency, increase the holding capacity of the soil, reduce runoff, etc… Droplet of water placed on a water repellent soil sample. • The use of these various products and additives provide a legitimate means of sound environmental stewardship for agricultural production. It is important to understand each technology and the difference between the available management options. Understanding Water Repellent Soil and the Use of Irrigation Additives • Most irrigation additive products involve some type of surfactant system. Surfactants are specialty chemicals that uniquely modify the physical and chemical characteristics of water and/or the materials where they are applied. • Surfactant chemistry is used in nearly every aspect of our lives. Detergents, soaps, shampoos, medicines, and even food products all use some type of surfactant chemistry to improve and manage product performance. • To be used as a legitimate irrigation additive in agricultural crop production, these products must be manufactured with ingredients that are certified for this specific use in agricultural. When choosing an irrigation additive, be certain to validate with the manufacturer that the product is approved for use under… 40 CFR 180.910 (materials exempt and approved for use on growing crops and raw ag commodities) or 40 CFR 180.920 (materials exempt and approved for use on growing crops only) Understanding Water Repellent Soil and the Use of Irrigation Additives • Different kinds of irrigation additives and soil wetters are approved for use as legitimate management tools for hydrophobic soil conditions and improved irrigation efficiency. However, it is important to understand the different types of chemistry and the expected performance of each surfactant. • Generally all soil wetting and penetrating products on the market today can be organized into three primary groups of surfactant chemistry: Anionic Surfactants, Nonionic Surfactants, and block polymer Nonionic Surfactants. The Irrigation Additive Market… Three general types of soil commercial soil wetting chemistry: • Anionic Surfactants • Nonionic Surfactants • Block Polymer Surfactants General Overview of Surfactants Used as Irrigation Additives… Anionic Surfactants Nonionic Surfactants Block Polymer Surfactants Water Water Water & Soil Reduces Surface Tension Excellent Excellent Good Compatibility in Mixing Poor Good Good Crop & Plant Safety Problematic Good Good Hard Water Antagonism Yes None None Residual Performance Limited Limited Excellent Primary Use in Ag/Turf Foam Marker Spray Adjuvant Soil Wetter Primary Mode of Action Understanding Water Repellent Soil and the Use of Irrigation Additives The earliest wetting agents utilized for improvement of irrigation efficiency in agricultural and turf production were based on the conventional general purpose anionic surfactants. Performance Strengths of Anionic Surfactants… - Primary mode of action…treats the water by effectively reducing surface tension. - Anionic electrostatic charge aids in temporary adsorption onto the soil particles, acting as an agglomeration aid for fine clay particles. Performance Limitations of Anionic Surfactants… - Degrade quickly in the soil solution and are antagonized by hard water minerals and deliver very limited residual control. - Can be phytotoxic to sensitive plants under certain circumstance. - Limited tank mix compatibility, preventing co-application with soil amendments and fertilizers. Anionic Surfactants… Typical Ingredient Statements: Ammonium Lauryl Ether Sulfates Sodium Lignosulfonates Sodium Alkyl Sulfosuccinates EXCELLENT FOR USE AS FOAM MARKERS AND SHAMPOOS Naiad® and Agri-SC Naiad Wetting Agent Functioning Agents: 2-Hydroxyethyl Ammonium Alkyl Benzene Sulfonate…………….………………..………..…8.77% Alkyl Phenoxy Poly (Ethylene Oxy) Ethanol CIS-9 Octadecenoate Octyl Alkyldiamide……..…2.50% Simethyl Silicone……………….……………..…1.00% Inert………………………………….……….…83.24% Initial application of 1 to 2 pints per acre, followed with 1 to 2 pints per acre every 3 to 4 weeks through harvest. PENEX (Ammonium Laureth Sulfate) PENEX Soil Conditioner Active Ingredients: Ammonium Laureth Sulfate. ……………….15% Amino Acid…………………………………..5% Inert Ingredients…………………………….80% Total……………………………….………100% Some Products That Contain Ammonium Laureth Sulfate: Imina Renewing Moisture Body Wash Selsun Blue Dandruff Shampoo, Medicated Treatment New Finesse Hydrating Silk Protein Enriched Adj. Shampoo Suave Salon Formula Shampoo Suave Dandruff 2-In-1 Shampoo and Conditioner Head & Shoulders I Refresh Dandruff Shampoo Pert Plus Dandruff Control All-In-One Shampoo Data from Household Products Database Website Naiad (Ammonium Dodecylbenzenesulfonate) Naiad Wetting Agent Functioning Agents: 2-Hydroxyethyl Ammonium Alkyl Benzene Sulfonate…………….………………..….…8.77% Alkyl Phenoxy Poly (Ethylene Oxy) Ethanol CIS-9 Octadecenoate Octyl Alkyldiamide…2.50% Simethyl Silicone…………………………………………………….……………….……1.00% Inert………………………………………………………………………………….……83.24% Some Products That Contain Ammonium Dodecylbenzenesulfonate Dove Hand Dishwashing Liquid Sunlight Hand Dishwashing Liquid Data from Household Products Database Website PENEX, Naiad, Agri-SC Ø Represent departure from block copolymer type chemistry Ø They are “flash” type surfactants typically used in detergents Ø PENEX, Naiad and Agri-SC contain an anionic surfactant (negatively charged) Ø These chemistries have high HLB (water attraction) and do not readily attach to soil particles thereby exhibit poor residual performance Ø These chemistries are lower cost and are typically found in soap and detergent industry ANIONIC AGRICULTURAL INDUSTRY Commercial Soil Wetter Technology Matrix Product Brand Manufacturer Primary Active Ingredient Description % Active Ingredient Surfactant Class Transflo Trans National Agronomy - Grand Rapids, MI Ammonium laureth sulfate unknown anionic surfactant National Ag Soil Treatment National Ag Products Development Inc Grand Rapids, MI Ammonium Laureth Sulfate and alpha pinene 62% anionic surfactant Agri-II Agri-World Products - Rockford, OH Ammonium Laureth Sulfate and alpha pinene 59% anionic surfactant Panhandler Ag Nation Products - Canton, OH Ammonium Laureth Ether Sulfate 58% anionic surfactant Ag 10-12 Soil Conditioner Ag Nation Products - Canton, OH Alkoxy polyoxyethylene sulfate 56% anionic surfactant Eco-Soil Life Soil Conditioner Eco-Soil and Water Corp - Hickman, NE Ammonium Laureth Sulfate 50% anionic surfactant Plen-T-4 Soil Conditioner Trico Ag Products, Inc - Storm Lake, IA Ammonium alkyl ether sulfate 48% anionic surfactant J and J Soil Conditioner J and J Agri-Products and Services Dillsburg, PA Ammonium Laureth Ether Sulfate 48% anionic surfactant Agri-SC Four Star Services, Inc - Bluffton, IN Ammonium Laureth Sulfate 48% anionic surfactant Advantage Wilbur-Ellis - Fresno, CA Ammonium Laureth Sulfate & Alkyl Aryl Polyethoxylates 31% anionic surfactant Penex JH Biotech, Inc - Ventura, CA Ammonium Laureth Sulfate & Amino Acid 20% anionic surfactant PAL / PolyCal Northwest Ag Products Polyacrylamide (2.13%) and Calcium (6.43%) 8.56% not surfactant chemistry RSA Cal-Pam RSA MicroTech - St Paul, MN Polyacrylamide (1%) and Calcium (7%) 8% not surfactant chemistry Understanding Water Repellent Soil and the Use of Irrigation Additives Nonionic surfactants represent the most widely used type of surfactant chemistry in agricultural production. This chemistry is widely used in many spray adjuvant systems to aid in pesticidal spray performance. Performance Strengths of Nonionic Surfactants… - Primary mode of action…effectively reduce the surface tension of water improving infiltration. - Wide range of compatibility and plant safety. The nonionic properties render the chemistry mostly non-reactive with most other materials. - Readily available and generally less expensive. Nonionic Surfactants… (Foliar Applied) Typical Ingredient Statements: Nonyl Phenol Ethoxylates Performance Limitations of Nonionic Surfactants… - Very small, low molecular weight molecules that tend to deliver poor adsorption and retention properties in soil. - Easily leached through the treatment zone and only provide a short term benefit. Alcohol Ethoxylates Modified organosilicones and blends EXCELLENT FOR USE AS SPRAY ADJUVANTS WITH PESTICIDES NONIONIC AGRICULTURAL INDUSTRY Commercial Soil Wetter Technology Matrix Primary Active Ingredient Description % Active Ingredient Surfactant Class Water In - Lodi, CA Alkyl polyethylene glycol ether unknown nonionic surfactant Penmax Western Nutrients Corporation - Bakersfield, CA unknown unknown nonionic surfactant Amway Spray Adjuvant Amway Corp - Ada, MI Alkylpolyethoxylated alcohol unknown nonionic surfactant Perc-o-late Creative Marketing Research - Fresno, CA Nonyl phenoxypoly ethanol, biodegradable glucosides, isopropyl alcohol 62% nonionic surfactant Basic H Shaklee Corp - Emeryville, CA Linear alcohol alkoxylates 28% nonionic surfactant EZ Wet Grow More - Gardena, Ca Isoalkyl, alkyl polyoxyethylene & alkylaryl polyethylene ethanols 26% nonionic surfactant Wex Conklin Company - Minneapolis, MN alcohol ethoxylates 21.68% nonionic surfactant Pennasoil Tabox, Inc. - Bozeman, MT Saponins and small amounts of minerals, proteins, and fats unknown organic Product Brand Manufacturer Water-In Understanding Water Repellent Soil and the Use of Irrigation Additives Because block polymer surfactants treat the soil in addition to the water, this class of chemistry represents a quantum improvement in the approach for wetting hydrophobic soils and the management of intensely irrigated agricultural and turf production systems. Performance Strengths of Block Polymer Surfactants… - Primary mode of action treats the soil by adsorbing strongly onto soil particles and improves wetting characteristics of treated water. - Residual control with good rewetting performance and long lasting effect. - Good compatibility with crop safety and can be used effectively in a wide range of application conditions. Performance Limitations of Block Polymer Surfactants… - Not as readily available because they are manufactured with more costly raw materials. - Do not reduce the surface tension of water as dramatically as anionic and nonionic surfactants. Block Polymer Surfactants… (Soil Applied) Typical Ingredient Statements: Alkoxylated polyols Co-polymers of polyethylene and polypropylene glycols Nonionic polyol EXCELLENT BASE SURFACTANT FOR USE AS SOIL WETTING AGENTS Understanding Water Repellent Soil and the Use of Irrigation Additives Block Polymer Surfactant Chain… • The chemical structure of block polymer surfactants is represented in a chain of many surfactant molecules. “Poly” means “many” and thus the term block polymer surfactant. • This organized block polymer chain provides chemistry residual and longer lasting effect than either anionic or nonionic surfactants. • The chemistry works so well as a soil wetter because each molecule is composed of a hydrophilic (water loving) head and a hydrophobic (water repelling) tail. • When applied and incorporated into the soil solution, the hydrophobic tail of the wetting agent is attracted to the hydrophobic coating on the soil particles. • While the tail of these molecules adhere to the water repellent organic coating, the hydrophilic head remains a readily accessible site for water to attach, driving water into the soil profile rather than forcing water to run off the surface of the soil particle. Hydrophilic – water loving heads Hydrophobic – water repelling tail Understanding Water Repellent Soil and the Use of Irrigation Additives Hydrophilic Block Polymer Surfactant Soil Performance… 1. Hydrophobic tail is attracted to the hydrophobic, water repellent soil particle. – water loving heads Hydrophobic – water repelling tail 2. Surfactant molecule attaches to the soil particle, large molecular structure is strongly attracted. 3. The hydrophilic head attracts and retains moisture, improving soil wetting and moisture retention. Surfactant in Water Surface tension is reduced as water molecules “push” outward toward the hydrophil of surfactant When surfactants are applied to soil with water as the carrier (such as irrigation), the water grabbing ends of the surfactant molecules are strongly attracted to other molecules while the water repellent ends are forced outward. Surfactants in a Soil Profile •Surfactants in a Soil Profile When a surfactant is applied to the soil profile, water repellent (hydrophobic), region of the surfactant attaches to the water repellent site on the soil particle. This serves as an attachment site for water molecules allowing the soil to hydrate. Definition of “Block Co-Polymer” A polymer comprising molecules in which there is a linear arrangement of blocks. Standard Block Polymer - More Water Attracting Standard Block (Aqua-Drive) Reverse Block Polymer - More Oil Attracting Reverse Block (Aquatrols IrrigAid) Comparing Block Copolymers and Reverse Block Copolymers Ø Block Copolymers: Ø are better emulsifiers Ø are better dispersants Ø cover a broader range of molecular weights Ø effective at reducing repellency Ø Reverse Block Copolymers: Ø exhibit lower foaming Ø are better defoamers Ø exhibit reduced gelling tendencies Ø tend to attach to organic material In Soil Wetters Combinations of the two allow for balancing the right properties for deep/lateral soil water movement, adsorption onto soil particles and rewetting, and acceptable handling properties. Surfactant Chemistry Standard Block Polymer This chemistry has a higher affinity for water and is effective at initial surface tension reduction. It exhibits a moderate affinity for organic matter resulting in moderate residual activity. Advantages: Initial surface tension reduction Effective repellency reduction Moderate residual Surfactant Chemistry Reverse Block Co-Polymers: This chemistry uses EO and PO in reverse order. When the order is reversed, the plant safety increases. The surfactant ability is good. There is a long lasting effect but in a narrow range of soil depth which causes wetting agent to adhere to organic matter in upper soil profile. Reverse block co-polymers have a greater affinity for oil than do standard block polymers. Advantages: Improved residual performance Greater plant safety How APG’s are Made Ø Fischer Glycosidation Process Ø Ø Over 100-years-old Starting Materials Ø Ø Ø Glucose (dextrose) from corn, wheat, potatoes Fatty alcohol; palm, palm kernel, coconut, other An acid catalyst (sulfuric or other acid) Some Agricultural Uses of APG’s Ø Adjuvants Ø As a mix with fertilizers (electrolyte) Ø Compatibility to formulations Ø Foaming agents Ø Emulsification in combinations with other nonionics How are APG’s different from other surfactants? Ø Very low or no toxicity Ø Readily biodegradable Ø Fertilizer compatibility with other chemicals Ø From renewable resources (corn and coconut) Ø Food source for soil microbes Advantages of APG’s Ø Derived from agricultural or renewable products Ø Enhances soil microbial activity (food source) Ø Very low phytotoxicity Ø Good wetting & surface tension reduction Ø Biodegradable Ø Ø Aerobic conditions 90% is fully broken down after three weeks Anaerobic conditions 84% is broken down after eight weeks Block Polymer AGRICULTURAL INDUSTRY Commercial Soil Wetter Technology Matrix % Active Ingredient Product Brand Manufacturer Primary Active Ingredient Description Surfactant Class Aqua-Drive Elite Diamond K - Richfield, UT Blend of propanediol and glycoside ingredients 30% block polymer surfactant Aqua-Drive Diamond K - Richfield, UT Blend of polyoxyethylenepolyoxypropolene and siloxane surfactants 25% block polymer surfactant Water Maxx Western Farm Service - Fresno, CA Nonionic Polyol 20% block polymer surfactant Irrigaid Aquatrols - Paulsboro, NJ Co-polymers of polyethylene and polypropylene glycols 20% block polymer surfactant Water Maxx II Western Farm Service - Fresno, CA Alkoxylated polyols and Glucoethers 17% block polymer surfactant Irrigaid Gold Aquatrols - Paulsboro, NJ Alkoxylated polyols and Glucoethers 17% block polymer surfactant Adsorption is the Key Ø Different surfactants have varying degrees of ability to adsorb onto soils Ø Adsorption has an effect upon lateral and vertical movement as well as residual capability Ø Surfactant component should have moderate affinity to organic matter for residual Ø Ideally, the surfactant should stage adsorption to modulate water movement Ø Balance rewetting with flash wetting Soil Wetting Technology and Irrigation Additives Aqua-Drive is a soil penetrant designed to enhance infiltration and penetration of applied irrigation water used on agricultural crops. AquaDrive improves soil moisture content while increasing water uniformity and distribution. Aqua-Drive can be used both preventatively or curatively as a soil penetrant and does provide extended residual activity. Aqua-Drive Elite is a unique soil surfactant designed to lower surface tension, improve soil conditions, increase water penetration and water percolation, and activate soil organisms. Aqua-Drive Elite is formulated using renewable resource ingredients that act as a food source, which enhances higher populations of beneficial soil microorganisms. Diamond K Soil Wetting Technology and Irrigation Additives Active Ingredients Block Polymer Surfactant Block Polymer Surfactant + Reversed Block Polymer + APG Water Treatment Performance Excellent Excellent Soil Treatment Performance Excellent Excellent – Triple Action Cost of Use Economical Premium Treatment Targets Moderate to Severe Wetting Challenges Moderate to Severe Wetting Challenges Corrective Treatment & Preventative Corrective Treatment & Preventative Management of Problematic Soils Management of Problematic Soils Regulatory Status 40 CFR 180.910* 40 CFR 180.910* * Exempt and approved for use on growing crops and raw ag commodities. Designed to DRIVE Water into Hydrophobic Soils. TWO MODES OF ACTION: Aqua-Drive is an irrigation additive designed to improve soil wetting and penetration characteristics of treated irrigation water. “Making water wetter” by reducing the surface tension of the irrigation water is one dimension of performance, but Aqua-Drive does much more than that. As the name suggests, Aqua-Drive literally helps “drive” irrigation water into hard-to-wet and hydrophobic soils. 1. Improved Water Surfactancy Reduces surface tension and improves wetting properties of irrigation water. 2. Enhanced Soil Penetration & Re-Wetting Characteristics. Surfactant molecules attach to hydrophobic soil colloids “driving” water and hydration into hard to wet soil profiles. University of Georgia Study Soil WATER REPELLENCY as affected by Aqua-Drive. 8 oz./1,000 + 4 oz./1,000 for five months. 4.0 Aqua-Drive Untreated Water Repellency Ratings 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 6/17 6/24 7/16 8/16 9/15 10/15 11/15 12/15 1/14 2/14 3/15 4/14 Evaluation Dates Scale of 0.0 to 4.0 (0.0 = non-water repellent and 4.0 = extremely water repellent). Leading Edge Performance and A Better Idea. Aqua-Drive Elite is formulated with the same block polymer surfactants as Aqua-Drive, BUT ALSO supplemented with other proprietary ingredients designed to dramatically reduce the surface tension of water and hasten microbial activity in the soil. Aqua-Drive Elite is one of the first soil surfactant systems in agriculture designed to address the problems of hydrophobic soil conditions with a comprehensive combination of three synergistic modes of action…water, soil, microbial. Bottom line: Aqua-Drive Elite hastens a healthier soil complex for plant growth and development. COMPREHENSIVE PERFORMANCE WITH THREE SYNERGYSTIC MODES OF ACTION: 1. WATER 2. SOIL 3. MICROBIAL University of Georgia Study Objective Determine the effects of Aqua-Drive Elite on soil water repellency. Results Aqua-Drive Elite significantly reduced soil water repellency. Dr. Keith Karnok Department of Crop and Soil Sciences University of Georgia December 2002 University of Georgia Study Soil WATER REPELLENCY as affected by Aqua-Drive Elite. Water Repellency Ratings 4.0 8 oz. initially followed by 4oz. each month for four months. Aqua-Drive Elite Untreated 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 5/23 5/30 6/20 7/18 8/15 9/12 10/10 11/7 Evaluation Dates Scale of 0.0 to 4.0 (0.0 = non-water repellent and 4.0 = extremely water repellent). University of Arkansas Study Objective Research conducted to determine the effects of “Aqua-Drive Elite” wetting agent on the microbial activity of a sandy type soil media compared to two leading commercial wetting agents and a control. Result Aqua-Drive Elite has no negative effects on the microbial activity of the soil. When compared to control plots, microbial activity was increased, on average, when Aqua-Drive Elite was applied. Aqua-Drive Elite provided slightly enhanced soil respiration data (microbial activity) compared to control and competitive wetting agents. Douglas Karcher, Ph.D. Department of Horticulture University of Arkansas February 2002 Proven Performance…Microbial Activity Soil Respiration as Affected by Wetting Agent Applications* Aqua-Drive Elite increased soil respiration by 57% over untreated soil! 16.00 mg Co2 / 100g Soil Douglas Karcher, Ph. D. Department of Horticulture University of Arkansas February 2002 14.00 12.00 13.75 10.00 8.00 10.00 10.50 Other Brand 1 Other Brand 2 8.75 6.00 4.00 2.00 0.00 Aqua-Drive Elite Untreated *Samples collected 14 days following final wetting treatment. Values represent cumulative respiration following 9 days of incubation. The Importance of Post Harvest Irrigation with Aqua-Drive Products! For perennial crops such as grapes, tree fruits and nut crops, post harvest irrigation has a direct effect on next years crop set. During the harvest period, crops are stressed to the maximum limits. Through this extended period of time without irrigation water and nutrient uptake, crops are depleted of substantial energy reserves. The growth cycle is a continual process and a lack of adequate moisture inhibits the plants ability to re-build the nutritional reserves required to set next years crop. Post harvest irrigation efficiency is negatively impacted by the excessive dry down during harvest, which creates a hydrophobic soil condition. Managing the natural physical characteristics (adhesion and cohesion) of water under these hard-to-wet environmental conditions is critical to maximize the returns of post harvest watering cycles. Pre-Emergent Herbicide Use Consideration for Aqua-Drive Products… Every year, pre-emergent herbicides are applied to many acres of orchards and vineyards. Getting the water to uniformly incorporate and distribute the herbicide is difficult. Water will follow a path of least resistance and that will affect the results. If the water doesn’t uniformly and effectively incorporate the herbicide then two problems can occur. Weeds can emerge when they shouldn’t and the herbicide won’t last as long as it should. Adding Aqua-Drive to the tank-mix will improve the uniformity and distribution of the herbicide. These improvements will insure that the herbicide gets to where it is supposed to be. Aqua-Drive insures better targeting of the herbicide. And the weed control is at the level intended and for the length of time intended. …are specifically formulated to effectively assist in the management and conservation of water in agricultural production systems …may be used with center pivot irrigation systems, drip irrigation systems, and ground applicators …formulated with proven block polymer chemistry …are backed by over 30 years of water management experience …are competitive with all products on the market today
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