Manufactured from 99.995%
PRIMARY ZINC
MATERIAL SAFETY
DATA SHEET
Conforms to 2001/58/EC & ISO 11014-1
ZINC PHOSPHATE
Page 1 of 5
1. IDENTIFICATION OF SUBSTANCE/PREPARATION & OF THE COMPANY/UNDERTAKING
Product name : Zinc Phosphate
Chemical product name : Trizinc bis (orthophosphate)
Synonyms: Delaphos 4 (D4), Delaphos 2 (D2) Delaphos 2M (D2M)
Use of the substance/preparation: Anti-Corrosive coatings.
Chemical formula : Zn3(PO4)2. 4H2 O
CAS Number : 7779-90-0
EINECS Number : 231-944-3
Manufacturer : Mazak Limited Willenhall Lane, Bloxwich, Walsall, WS3 2XN
Emergency telephone number:
Tel:
+44 (0) 192 2 71 4430
Fax:
+44 (0) 192 2 71 4433
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/preparation : Substance
Information on hazardous ingredients *
Chemical name / % / CAS No. / EC Number / Symbol / R-Phrases
Zinc Phosphate/ 84 – 92% / 7779-90-0 / 231-944-3 / N / R50/53
Water / 8 – 16% / 7732-18-5 / 231-791-2
* Occupational Exposure Limit(s), if available, are listed in section 8
* R-phrases (complete text) are listed in section 16
3. HAZARDS IDENTIFICATION
Physical/chemical hazards: The data available do not support any physical or chemical hazard.
Human health hazards: Based on the data available, this product does not present any human health hazard.
Environmental hazards: Very toxic to aquatic organisms may cause long-term adverse effects in the aquatic
environment.
4
FIRST AID MEASURES
Effects and symptoms: No specific effects and/or symptoms have been reported or known.
First-aid measures: Remove person from area of exposure.
Inhalation: Supply fresh air. Consult a doctor in the event of any complaints.
Ingestion: Wash out mouth with water. Make affected person drink plenty of water. Consult a doctor in the
event of any complaints.
Skin contact: Wash off with water and soap immediately.
Eye contact: Wash out with plenty of water. After initial flushing, remove any contact lenses and continue
flushing. Consult a doctor in the event of any complaints.
Protection of first-aiders: Avoid exposure. Use appropriate protection (see section 8).
Mazak Limited, Willenhall Lane
Bloxwich, Walsall, WS3 2XN, UK.
Tel: +44 (0) 1922 714430
Fax: +44(0) 1922 714433
[email protected]
www.mazak-limited.co.uk
Manufactured from 99.995%
PRIMARY ZINC
MATERIAL SAFETY
DATA SHEET
Conforms to 2001/58/EC & ISO 11014-1
ZINC PHOSPHATE
Page 2 of 5
5. FIRE-FIGHTING MEASURES
Extinguishing media
Suitable: Not combustible. Use extinguishing media based on surroundings.
Not suitable: None.
Special fire-fighting Procedures: Dike fire control water for later disposal.
Hazardous thermal (de) composition products: None.
Protection of fire-fighters: Use breathing apparatus (self-contained breathing apparatus with full face shield).
Wear suitable protective clothing.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Wear suitable protective clothing and gloves (See section 8). Avoid generation of dust.
Environmental precautions: Prevent dispersion. Do not allow to enter sewage system.
Keep away from drains, surface and ground water. Avoid soil contamination.
Methods for cleaning up: Take up mechanically. Collect spilled material in sealable containers.
Re-use/recycling of waste highly recommended .
7. HANDLING AND STORAGE
Handling: Avoid exposure. Use appropriate protection (see section 8). Avoid generation of dust.
Storage: Usual precautions for nuisance dust should be followed. Keep in a dry place.
Keep in sealable containers. Keep away from acids and bases.
Packaging materials - Suitable: Keep only in the original packaging.
Specific use(s) : Not applicable.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering measures: Ventilation recommended.
Hygiene measures: Practice good personal hygiene procedures.
Occupational Exposure Limits OEL (United Kingdom)
Chemical name: Zinc Phosphate
TWA - 8 hour: 5 mg/m 3 (nuisance dust)
STEL - 15 minutes: 10 mg/m 3 (nuisance dust)
Personal protective equipment
Respiratory system: With sufficient extraction or closed system, breathing apparatus not necessary.
If occupational exposure limits are exceeded use dust filter P2.
Skin and body: Working clothing.
Hands: Working gloves.
Material: leather gloves, cotton gloves, rubber gloves.
Breakthrough time: Not applicable.
Eyes: Safety glasses.
Environmental exposure controls:
Water (76/464/EEC): Not listed.
Air (1999/30/EC): Not listed.
Mazak Limited, Willenhall Lane
Bloxwich, Walsall, WS3 2XN, UK.
Tel: +44 (0) 1922 714430
Fax: +44(0) 1922 714433
[email protected]
www.mazak-limited.co.uk
Manufactured from 99.995%
PRIMARY ZINC
MATERIAL SAFETY
DATA SHEET
Conforms to 2001/58/EC & ISO 11014-1
ZINC PHOSPHATE
Page 3 of 5
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Solid (powder or granules).
Colour: White-yellowish.
Odour: Odourless.
Molecular weight : 458.13
Boiling point : Not applicable.
o
Melting point : 912 C
Bulk density : 1.1 g/cm
3
o
Solubility in water : < 0.1% (20 C) (DIN ISO 787 Part 3)
Solubility in other ingredients: Negligible.
Octanol/water partition coefficient: Not applicable.
o
PH : 6 - 8 (100g/l H2O/20 C) (DIN ISO 787 Part 9)
Explosion properties: Not explosive (VDI 2263).
Oxidation properties: Not applicable.
10. STABILITY AND REACTIVITY
Stability: Stable under normal conditions.
Conditions to avoid: None.
Materials to avoid: Keep away from acids and bases.
Hazardous reactions: None.
Hazardous decomposition products: None.
11. TOXICOLOGICAL INFORMATION
Acute toxicity - Oral: LD 50 (rat): > 5,000 mg / kg
Skin irritation: Not irritating (rabbit).
Eye irritation: Not irritating (rabbit).
Other information: Zinc fume fever is predominantly attributable to exposure to ultra-fine zinc oxide particles
(generated for example during welding and cutting of galvanised steel), but is not experienced
in inhalation exposure to commercially traded Zinc oxide.
Mazak Limited, Willenhall Lane
Bloxwich, Walsall, WS3 2XN, UK.
Tel: +44 (0) 1922 714430
Fax: +44(0) 1922 714433
[email protected]
Manufactured from 99.995%
PRIMARY ZINC
MATERIAL SAFETY
DATA SHEET
Conforms to 2001/58/EC & ISO 11014-1
ZINC PHOSPHATE
Page 4 of 5
12. ECOLOGICAL INFORMATION
Ecotoxical Effects
Acute toxicity for fish (Oncorhynchus mykiss)
Acute toxicity for crustacea (Daphnia magna)
Acute toxicity for algae (Selenastrum capriocornutum)
2+
LC(50) (96h) 0.14-0.26 mg Zn /L
2+
EC(50) (48h) 0.04 – 0.86 mg Zn /L
2+
EC(50) (72h) 0.136 – 0.150 mg Zn /L
Additional Ecological information
2+
The solubility of Zn was tested in accordance with Council Directive 67/548/EEC, Annex V, part C, C1 Acute
toxicity for Fish, enclosure 1 “Prepared water” and C2 Acute Toxicity for Daphnia, enclosure 1 “Prepared water”
(ISO 6341) by dispersing 10,000g Zinc Phosphate in 1000ml prepared water, stirring for 24 hours, filtration over
2+
45µm membrane filter and ICP determination of Zn. This test resulted in a solubility finding for water soluble Zn of
2+
25 mg Zn /L.
13. DISPOSAL CONSIDERATIONS
Methods of disposal: Disposal according to national/regional regulations.
Waste of residues: Keep waste separate. Because of possible pollution, remove as industrial waste or hazardous
waste.
Contaminated packaging: Keep waste packaging separate. Because of possible pollution, remove as industrial
waste or hazardous waste.
14. TRANSPORT INFORMATION
UN number : 3077
Land Road/Railway Proper shipping name : Environmentally hazardous substance, solid, n.o.s. (Trizincbiz
(Orthophosphate))
ADR/RID Class : 9
Classification code : M7 (Formerly: Item number 12c)
Packing group : III
Hazard Identification Number : 90
TREMCARD : 90G02
Inland waterways
Proper shipping name : Environmentally hazardous substance, solid, n.o.s. (TRIZINCBIZ (ORTHOPHOSPHATE))
ADNR Class : 9
Classification code : M7 (Formerly: Item number 12c)
Packing group : III
Sea
Proper shipping name : Environmentally hazardous substance, solid, n.o.s. (TRIZINCBIZ (ORTHOPHOSPHATE))
IMDG Class : 9 + MP
Packing group : III
Emergency Schedules (EmS): Air
Proper shipping name : Environmentally hazardous substance, solid, n.o.s. (TRIZINCBIZ (ORTHOPHOSPHATE))
UN/ID Number : 3077
IATA-DGR Class : 9
Packing group : III
National transport regulations - United Kingdom :
No additional national transport regulations are known to the supplier.
Mazak Limited, Willenhall Lane
Bloxwich, Walsall, WS3 2XN, UK.
Tel: +44 (0) 1922 714430
Fax: +44(0) 1922 714433
[email protected]
www.mazak-limited.co.uk
Manufactured from 99.995%
PRIMARY ZINC
MATERIAL SAFETY
DATA SHEET
Conforms to 2001/58/EC & ISO 11014-1
ZINC PHOSPHATE
Page 5 of 5
15. REGULATORY INFORMATION
EU Regulations
EU Classification (67/548/EEC-1999/45/EC)
Hazard symbol(s) : N
DANGEROUS FOR THE ENVIRONMENT
Risk phrases :
R50/53: Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Safety phrases:
S60: This material and its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions/Safety data sheets.
National regulations - United Kingdom:
No additional national regulations are known to the supplier.
16. OTHER INFORMATION
The information contained in the Safety data sheet is correct to the best of our knowledge at the date of issue. It is
intended as a guide for the safe use, handling, disposal, storage and transportation and is not intended as warranty or
as a specification. The information relates only to the product specified and may not be suitable for combinations with
other materials or in processes other than those specifically described herein.
List of relevant R-phrases: R50/53: Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
st
Revision: 01 September 2002
Mazak Limited, Willenhall Lane
Bloxwich, Walsall, WS3 2XN, UK.
Tel: +44 (0) 1922 714430
Fax: +44(0) 1922 714433
[email protected]
www.mazak-limited.co.uk