CHEM 130 PROBLEM SET Ch.2 Key begins on page 5. 1. Rubidium has two naturally occuring isotopes of mass 85.0 and 87.0 amu. What percent of Rubidium-85 is normally present given that its reported atomic mass is 85.47 amu? ______________ 2. Balance the following equations. a) ____UO2 + ____HF -----> ____UF4 + ____H2O b) ____H3BO3 ---------> ____B2O3 + ____ H2O c) ____B2O3 + ____HF -------> ____BF3 + ____H2O d) ____C2H3Cl + ____O2 ------> ____CO2 + ____H2O + ____HCl e) ____PH3 + ____O2 -------> ____P4O10 + ____H2O 3. Indicate whether the following compounds are ionic or covalent. a) CCl4 _______________________ c) NaF ________________________ _______________________ d) PF3 ________________________ b) CO2 4. Give names for the following ionic compounds. a) Na2CO3 ____________________ b) AlP ____________________ c) Ba(ClO3)2 ______________________ d) Cu2CrO4 ______________________ 5. Give formulas for each of the following ionic compounds. a) zinc sulfate _________________ c) aluminum phosphate ______________ b) silver nitrate ________________ d) magnesium nitride ______________ 6. Give names for the following covalent compounds. a) PCl3 ____________________ c) CS2 ___________________________ b) SO2 ____________________ d) N2O5 ___________________________ 7. Give formulas for the following covalent compounds. a) nitrogen triiodide ____________ c) phosphorus trifluoride __________ b) oxygen difluoride ____________ d) diphosphorus tetroxide __________ 8. Indicate the "pet" name associated with each of the following. a) Mg ____________________ c) K _______________________ b) Ar ____________________ d) Cl _______________________ 9. Briefly distinguish between homogeneous and heterogeneous mixtures. 10. Briefly distinguish between periods and groups on the periodic table. 11. Briefly describe the difference betwween anions and cations. Naming Ionic and Covalent Compounds Give the names of the following ionic compounds Write the formulas for the following ionic compounds Al(NO3)3 calcium hydroxide HgI2 magnesium nitride Fe2(CrO4)3 copper(I) cyanide NH4NO2 silver nitrate Li2CO3 potassium bromide SrO lead(IV) bromide Ba(OH)2 tin(II) sulfide Mg3P2 potassium phosphate CoF3 mercury(I) iodide Ca(C2H3O2)2 ammonium hydroxide PbCl4 potassium dichromate Cu2S lead(II) carbonate KMnO4 barium sulfite Na2HPO4 lithium phosphide Give the name the following covalent compounds Write the formula for the following covalent compounds SeBr4 carbon monoxide F2O2 nitrogen triiodide IBr2 tetraphosphorus decasulfide OF2 disulfur dichloride N2S5 dichlorine heptoxide Br3O8 diphosphorus tetraoxide CS2 dinitrogen monoxide S4N4 selenium hexafluoride Valences of Some Common Ions Cations (positive charge) Anions +1 H+ Li + Na + K+ Ag + Cu + NH4 + hydrogen lithium sodium potassium silver copper(I) ammonium –1 H3O + hydronium Hg + mercury(I) H– F– Cl – Br – I– OH – NO2 – NO3 – CN – hydride fluoride chloride bromide iodide hydroxide nitrite nitrate cyanide +2 Mg 2+ Ca 2+ Sr 2+ Ba 2+ Zn 2+ Cu 2+ Fe 2+ Hg 2+ magnesium calcium strontium barium zinc copper(II) iron(II) mercury(II) Cr 2+ Co 2+ Mn 2+ Cd 2+ Sn 2+ Pb 2+ Ni 2+ aluminum iron(III) Cr 3+ Co 3+ +4 Sn 4+ Pb 4+ tin(IV) lead(IV) MnO4 – ClO – ClO2 – ClO3 – ClO4 – HCO3 – C2H3O2 – HSO3 – HSO4 – H2PO4 – permanganate hypochlorite chlorite chlorate perchlorate hydrogen carbonate acetate hydrogen sulfite hydrogen sulfate dihydrogen phosphate –2 chromium(II) cobalt(II) magnanese(II) cadmium tin(II) lead(II) nickel(II) O 2– S 2– CO3 2– SO3 2– SO4 2– CrO4 2– Cr2O7 2– oxide sulfide carbonate sulfite sulfate chromate dichromate +3 Al 3+ Fe 3+ (negative charge) C2O4 2– S2O3 2– HPO4 2– O22– oxalate thiosulfate monohydrogen phosphate peroxide –3 chromium(III) N 3– cobalt(III) P 3– nitride phosphide PO4 3– phosphate
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