Sea Water Cooled Chillers Amar Farjo Senior Staff Engineer Industrial Systems, Building Efficiency Why do we need to consider sea water cooled chillers? Because they can save 57,600 Gallons (218,016 Liters) of potable water per 1,000 Tons of cooling everyday Agenda - Sea water cooled chiller products by YORK - Chiller Operation - Sea Water Quality Specification - Material Options - YORK Reliability 3 YORK Products with Sea Water Capability YDYKSingle Compressor Dual Compressors YB & YGGas- engine Drive CYKCompound Compressors YIASingle Stage Titan OMYPCTwo Stage 4 Customer Designed YSTSteam Turbine Agenda - Sea water cooled chiller products by YORK - Chiller Operation - Sea Water Quality Specification - Material Options - YORK Reliability 5 Centrifugal Chiller Prerotation Vanes Impeller Mist Eliminator Diffuser Plate Condenser Flooded Evaporator Subcooler 6 Orifice Pressure – Enthalpy Diagram Pressure Condenser Lift (or Head Pressure) Metering Device Evaporator Enthalpy 7 Refrigerant rejects heat to atmosphere Compressor Refrigerant absorbs heat from load Pressure – Enthalpy Diagram Pressure 90° F 32° C 100° F 38° C Lift (or Head Pressure) 54° F 12° C 44° F 7° C Enthalpy 8 Agenda - Sea water cooled chiller products by YORK - Chiller Operation - Sea Water Quality Specification - Material Options. - YORK Reliability 9 Water Quality Specification for Filtered Brackish or Seawater: pH Total Suspended Solids, ppm Make-up Water 4 Concentrated Cooling Tower Water 2,5 pH 6.5 - 8.8 < 9.0 Total Dissolved Solids, ppm < 50,000 [Dissolved Solids] must be below the solubility limits 200 - 350 450 - 650 < 0.02 < 0.01 < 525 < 975 < 2.0 < 0.1 [Cl] must be below the solubility limit for the chemical treatment program [SO4] must be below the solubility limit for the chemical treatment program < 150 Parameter 6.5 - 8.8 < 2.0 Total Alkalinity, ppm as CaCO Total Suspended Total Hardness (Ca + Mg), ppm as CaCO Iron, ppm as Fe Solids, ppm Copper, ppm as Cu < 2.0 Chloride, ppm as Cl 1000 - 28,000 Sulfate, ppm as SO4 1000 - 4,000 Silica, ppm as SiO2 < 100 at 1.5 cycles 3 3 Phosphonate, ppm as P2O5 1000 < 0.5 28,000 < 0.5 Chlorine, free, ppm as Cl TOC (mg/L) Ammonia, ppm as NH3 Sulfides, ppm as SO2 Aerobic Bacteria, CFU/ml Anaerobic Bacteria, CFU/ml Coliform, (counts per 100/ml) E-Coli, (counts per 100/ml) BOD (mg/L) COD (mg/L) 0.1 - 0.5 <2 06 0 2 < 1x10 6 0 0 0 0 0 Chloride, ppm as Cl Phosphate, ppm as PO4 Ammonia, ppm as NH3 0 < 9.0 < 10 < 10 [Cl] must be below the solubility limit the Phosphate-based corrosion inhibitors for are seldom added. Phosphonate-based corrosion inhibitors are seldom chemical treatment added. 0.2 - 1.0 program 2 Requires good feed control of oxidizing biocide <1 3 0 < 1x103 3 0 0 0 0 0 2 Chlorine, free [Clfree] = 2.0 ppm may be required in systems with high nutrient loading and/or drift. 3 Limit applies to CuNi tubes only. No limit for titanium. 4 Make up water concentration levels may change based on number of cycles. 5 Water that will be utilized for condenser heat exchanger. 6 Make-up water with even trace amounts of ammonia is considered to be polluted. <1 3 Limit applies to CuNi tubes only. No limit for titanium. 10 Agenda - Sea water cooled chiller products by YORK - Chiller Operation - Sea Water Quality Specification - Material Options - YORK Reliability 11 Recommendations protection against: - Corrosion - Erosion - Deposition Heat Exchanger Tube Options Options Material Wall Thickness Baseline 1 Copper 0.025 Baseline Baseline Base line Baseline #1 70/30 CuNi 0.028 ↑ ↓ ↑ ↑ #2 Titanium 0.028 ↑↑ ↓↓ ↑ ↑↑ 1 Copper Life Pressure Kw/ Chiller Maintenance Expectancy Drop ton First Cost tubes are shown in the table above for baseline comparison purposes only. Copper tubes are not suitable for sea water applications. Copper Nickel (CuNi) - 70% Cu/30% Ni offers reliable operation, acceptable if, water is consistent in quality, Maintenance is performed routinely . -90% Cu/10% has been used but there is increased risk due to the reduced corrosion resistance Titanium - Gold standard, immune to erosion & corrosion - Upgrade in tube material - Longest life expectancy - Highest cost option 12 Baseline Chiller Efficiency 4.95 Efficiency Copper 4.9 4.85 COP 4.8 4.75 4.7 CU/NI 70/30 Titanium 4.65 4.6 13 Tube Material Chiller Cost 2.25 Cost 2.00 Titanium Cost 1.75 1.50 CU/NI 70/30 1.25 1.00 Copper 0.75 14 Tube Material Tubesheet Options Carbon Steel with Ceramic Coating -Will ensure reliable operation and protection against corrosion/erosion. -But maintenance and annodes are required Carbon Steel with Cladding - Best option for tubesheet protection - Higher costs but expected service life is higher - Cladding material for the tubesheet must be the same as the tubes 15 Explosion Titanium or CUNI Clad Tubesheets Manufacturing Explosive powder Space between Plates 1. Plane material inspection 2. Grind Mating services 3. Assembly: Backer, Cladder, Explosive Metallurgical Weld Line 4. Explosion Collision Point Mechanical Test Specimens 5.Flattening and cutting 6.Testing & Inspection 7. Cut Parts for shipment Ultrasonic Examination of bond, Mechanical Test Physical Measurement, Certification removes Any Edge Defects. Cutting by Torch, Waterjet, or Saw Source: DMC, Dynamic Materials Corporation 16 Edge Trim- Scrap Waterbox Recommendation Carbon Steel with Ceramic Coating - Ceramic Coating (Polymer Composite) - Ensure reliable operation - Protect against corrosion/erosion - Anodes should be provided and maintained if coatings is requested to protect against corrosion if coating holidays* occur *Holidays- discontinuity or break in a coating, exposing the base bare metal underneath 17 Additional Recommendations Couplings/ Plugs, Thermowells, Flow Switches -Monel will ensure reliable operation Unit Accessories - Evaporator water should be used as cooling water for VSD or SSS and used with water cooled oil coolers for sea water applications , Motors ??? Anodes (serve as an electrode, electric current flows into a polarized electrical device capturing charged materials in water ; reducing corrosion) - Correct anode material will protect against corrosion if coating holiday occurs 18 Agenda - Sea water cooled chiller products by YORK - Chiller Operation - Sea Water Quality Specification - Material Recommendations - YORK Reliability 19 YORK Sea Water Chiller Installations Proven Reliability United States Navy Surface and Subsurface Vessels Bahrain Bay 20 Hong Kong Bay Questions 21
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