APPENDIX I Definition of terms Introduction In the concise description of the soils of the Netherlands (chapter 2), a number of lithological properties - like texture and organic matter content - are introduced to describe and classify the soil and sediment in the Netherlands. The same classification and nomenclature is used throughout this thesis. For some of these properties, there is a worldwide consensus about their definition and terminology (e.g. the sand or clay fraction), whereas others are typical for the Dutch classification system (e.g. the term “zavel” for sandy and silty clays). Even within the Netherlands, there is already considerable discrepancy between the geological and pedological textural nomenclature (see e.g. fig. I.1, I.2 and I.3). In order to have consistency throughout this thesis, and to allow for comparison with other classifications, the most important lithological properties and their terminology are described here. For a more detailed overview, the reader is refered to De Bakker and Schelling (1989), Van der Sluijs and Locher (1987) and Janssen et al. (1987). Texture The major texture classification is based on the < 2 mm fraction of the mineral soil/sediment, so on an organic matter and carbonate free and 105 °C dry weight basis. Herein discerned are the sand fraction (50-2000 µm), silt fraction (2-50 µm) and clay fraction (< 2 µm), which are classically represented in a texture triangle. The loam fraction is defined as the weight percentage of all grains <50 um (silt and clay fraction), but this fraction is not used in the texture classification. The classification of the coarser material (> 2 mm), like the gravel and pebble fraction, is not discussed here (see e.g. Van der Sluijs and Locher, 1989). In the Netherlands, the pedological and geological communities use different texture classifications. In pedology, different classifications are used for eolian and noneolian sediments (fig. I.1 and I.2). This difference is not made in the geological classification (fig. I.3). The delineation of the grain size classes is however largely comparable in both systems, and they basically differ in terms of nomenclature. The sand fraction can further be described in terms of coarseness, which is based on the median grain size of the sand fraction and applies to sandy as well as loamy and clayey samples (table I.1). For the concise description of the Netherlands and throughout the rest of this thesis, the pedological texture classification has been followed unless stated. The reason is that this review is concerned mainly with the soils in the Netherlands. Moreover eolian and non-eolian sediments do have different ranges in grain size distribution (see chapter 2, section 2.3.3). Also the terminology used for different clays appears more intuitive. Just as for the Dutch soil classification system (chapter 2, section 2.6), the texture classification in the Netherlands is quite different from those used in other parts of the world (see for example the classification used by US Department of Agriculture in figure I.4). For the non-eolian sediments (fig. I.2), the Dutch term “zavel” is translated by “sandy and silty clay” and no further differentiation is made into heavy and light “zavel”. 210 G. van der Veer (2006), Geochemical soil survey of the Netherlands, NGS 347. Figure I.1 Texture classification used by Stiboka for eolian sediments (e.g. De Bakker and Schelling, 1989). L.P.= loam-poor, S.L. = slightly loamy, V.L. = very loamy, E.L. = extremely loamy (applies to sand). Figure I.2 Texture classification used by Stiboka for non-eolian sediments (e.g. De Bakker and Schelling, 1989). The grey line in the fields of sand and silt separate clay-poor and clayey sand and silt. The grey line in the field of light “zavel” separates very and moderlately light “zavel”. In the text, no differentiation is used for “zavel”, which is translated as “sandy to silty clay”. G. van der Veer (2006), Geochemical soil survey of the Netherlands, NGS 347. 211 Figure I.3 Texture classification of sediments according to the Netherlands Normalization Institute (NEN, 1989). L.P.= loam-poor, S.L. = slightly loamy, V.L. = very loamy, E.L. = extremely loamy, CL. = clayey (applies to sand). S.S.loam = slightly silty loam. Grey lines in the field of sandy clay separate the slightly sandy, moderately sandy and very sandy clays. Figure I.4 Texture classification of sediments according to the US Department of Agriculture (Soil Survey Division Staff, 1993). L.sand = loamy sand. 212 G. van der Veer (2006), Geochemical soil survey of the Netherlands, NGS 347. Table I.1 Coarseness of the sand fraction (50-2000 µm), which is based on its median grain size (M50; after De Bakker and Schelling, 1989). For sand For clay/loam M50 between (µ µm) 50-105 Extremely fine Extremely fine sandy 105-150 Very fine Very fine sandy 150-210 Moderately fine Moderately fine sandy 210-420 420-2000 Moderately coarse Very coarse Moderately coarse sandy Very coarse sandy Organic matter content The organic matter content is expressed on the fraction < 2 mm and based on 105 °C dry weight of the total soil. With respect to the organic matter content, two basic groups can be discerned (fig. I.5): Mineral soil/sediments having less than 15-30 wt% organic matter and organic soil/sediment with more than 15-30 wt.% organic matter. The latter group is in Dutch referred to as “moerig”, which is here consequently translated as “peaty”. Soil/sediments having more than 35-70 wt% rganic matter (peat) are not further differentiated into texture, whereas the remaining organic rich soil/sediment is further divided into sand or clay (fig. I.5). For the mineral soil/sediment, the normal textural classification applies (fig. I.1 and I.2). The classification of organic rich soils and sediments is empirical and based on the experience that sandy samples are more easily classified as organic matter rich than clayey samples that have the same amount of organic matter. In other words, the finer the texture, the higher the organic matter content should be to fall within the same class. As mentioned by De Bakker and Schelling (1989), this effect is not fully understood, but it is assumed that samples that fall onto the lines in figure I.5 have more or less a constant volume fraction of mineral and organic matter. Notice at last that in contrast to the textural classifications, the classification of organic matter content uses the weight percentages based on the total soil, so including the organic matter and carbonate content. When present in significant amounts, the carbonate content should be added to the sand+silt fraction in order to derive the appropriate organic matter class in figure I.5. Carbonate content Another important property of the soil/sediment is the carbonate content, expressed as the weight percentage CaCO3 (105 °C dry weight). Often, the amount of inorganic CO2 is estimated and allocated to calcium, i.e. assuming pure calcite. The following empirical classification is used for the Dutch soils (De Bakker and Schelling, 1989): • Less than 0.5 wt% = non-calcareous (no reaction with 10% HCl) • Between 0.5 wt% and 1 wt% = carbonate-poor (audible reaction with 10 % HCl) • More than 1 wt% = calcareous, (visible reaction with 10% HCl). Carbonate content is mainly used in the further classification of fluviatile and marine soils, as the Pleistocene soils (sand and loess) are generally non-calcareous. G. van der Veer (2006), Geochemical soil survey of the Netherlands, NGS 347. 213 Figure I.5 Classification of organic matter content according to Stiboka (e.g. De Bakker and Schelling, 1989). If present in significant amounts, the amount of carbonate material should be added to the sand and silt fraction. Peat, clayey (sandy) peat and peaty (sandy) clay are considered as organic rich or peaty material, whereas the remaining groups are regarded as mineral material. Grey lines in the field of humic clay (sand) separate the humic poor, moderately humic and humic clay (or sand). NEN-classification is comparable and only uses a slightly different terminology (NEN, 1989). The grey line on the right side of the triangle indicates the upper textural limit found in the Netherlands (80 wt. % clay fraction). 214 G. van der Veer (2006), Geochemical soil survey of the Netherlands, NGS 347.
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