Getting Started with Algebra 2 Balance Me – ID: XXXX By Pat Flynn Time required 60 minutes Activity Overview Students will balance chemical equations using systems of equations, inverse matrices, and determinants. Concepts Inverse matrix method for solving systems of equations Teacher Preparation This activity is intended for use with students who are enrolled or were enrolled in high school chemistry. If this is not the case, then some introductory work needs to be done with the students in terms of chemical equations and the balancing of them. Seek the help of your school’s chemistry instructor for help in this. In chemistry, many students encounter difficulties balancing chemical equations—even when they are following steps outlined by their instructor. The purpose of this activity is to provide the students a method to use when all else fails. Students should already be familiar with matrix representation for a system of equations as well as the concept of the determinant. Mathematical prerequisites from Algebra 2 include familiarity with different methods of solving systems of equations, including a brief exposure to the use of matrices in doing so. The screenshots on pages 2–5 demonstrate expected student results. Refer to the screenshots on pages 6 and 7 for a preview of the student TI-Nspire document (.tns file). To download the student .tns file and student worksheet, go to education.ti.com/exchange and enter “XXXX” in the quick search box. Classroom Management This activity is intended to be completed individually, with the teacher facilitating instruction. Use the following pages as needed to assist the class in completing the activity. If time is limited, you may choose to have students complete Problems 1 and 2 in class, assigning the exercises from Problem 3 as homework. There is no student worksheet for this activity. The student TI-Nspire document provides a place for students to record their answers. Alternatively, you may wish to have the class record their answers on separate sheets of paper, or just use the questions posed to engage a class discussion. The TI-Nspire solution document Alg2Act22_BalanceMe_Soln_EN.tns shows the expected results of working through the activity. TI-Nspire™ Applications Calculator, Notes ©2008 Texas Instruments Incorporated Page 1 Getting Started with Algebra 2 Problem 1 – Balancing Al O2 Al2O3 Problem 1 walks students through how to balance the chemical equation Al O2 Al2O3 . There are no actions to be performed by students for the first three steps; they should just be sure they read and understand each step. Step 1: Assign a variable coefficient to each of the c Al2O3 three terms in the equation: a Al b O2 Step 2: Translate the chemical equation into a mathematical system of equations, as shown in the screenshot to the right. There should be an equation for each element in the chemical equation. If needed, remind students that the coefficients in these two equations are derived from the number of atoms of the element in each chemical compound. Step 3: Write the system of equations as a matrix equation. For students who are comfortable with using matrices to solve equations, this matrix equation should look familiar, except for the appearance of the scalar, c. Tell students that a value will be chosen for c in the next step. Step 4: Page 1.6 explains that the absolute value of the determinant of the coefficient matrix should be used as the value of c. Using the determinant ensures that the values found for a and b in the next step are integers. Ask students why it makes sense to use the absolute value of the determinant (c must be a positive integer; it represents a number of molecules.) Students may recall that the determinant of a a b 2×2 matrix A is given by c d det( A) ad bc , but students can use the mathematical capabilities of the Notes application to evaluate the determinant. Instruct them to hold down the SHIFT key (g) while they arrow over the expression to select it, and choose Evaluate Selection from the Actions menu. Pressing · will return the value of c; here, 2. ©2008 Texas Instruments Incorporated Page 2 Getting Started with Algebra 2 Step 5: To solve this equation for a , both sides of b the equation must be multiplied by the inverse of the coefficient matrix. Remind students that matrix multiplication is not commutative, and must be done in the order shown. Students should substitute 2 for c and then they can use Evaluate Selection on the selection shown to the right to a 4 determine . b 3 Step 6: Now, students need to substitute the values they obtained for a, b, and c, and check that the values indeed balance the chemical equation. 4 Al 3 O2 2 Al2O3 According to these values, there are 4 aluminum atoms on the left-hand side and 2 × 2 = 4 aluminum atoms on the right-hand side, so the aluminum is balanced. Similarly, there are 3 × 2 = 6 oxygen atoms on the left and 2 × 3 = 6 oxygen atoms on the right. Therefore, the chemical equation is balanced. Problem 2 – Balancing C2H6 O2 CO2 H2O Problem 2 asks students to balance the chemical CO2 H2O . Note that this equation C2H6 O2 equation has four terms and three elements, so it will require a system of three equations, rather than two. For this example, students will complete more of the required steps themselves. Step 1: Assign a variable coefficient to each of the four terms in the equation. Step 2: Translate the chemical equation into a mathematical system of equations, as shown. On page 2.3, students will find there is an extra step required here. The “c” terms should be subtracted from both sides in order to isolate the “d” term on the right-side of the equation. Students can copy (/ + C) and paste (/ + V) their equations from page 2.2 to page 2.3 instead of retyping them.) After manipulation, the equations should be as shown below. C: 2a 0b 1c 0d H: 6a 0b 0c 2d O: 0a 2b 2c 1d ©2008 Texas Instruments Incorporated Page 3 Getting Started with Algebra 2 Step 3: Write the system as a matrix equation. Here, the coefficient matrix is a 3×3 matrix, as shown to the right. Step 4: Find the value of d. This coefficient matrix has a determinant of –12, so this is an example of why you should use the absolute value of the determinant. Again, students can use copy/paste and the mathematical capabilities of the Notes application to find this value. Step 5: The values for a, b, and c may then be found as shown below. a b 2 0 6 0 1 0 c 0 2 2 1 0 12 2 4 14 1 8 Step 6: Now, the values of a, b, c, and d may be substituted back into the original chemical equation. However, students are not ready to check their solutions. Be sure students understand the information on page 2.6 regarding reducing the coefficients in a chemical by any common factors. Students should then check these reduced values, as before, on page 2.7. Problem 3 – More practice Problem 3 provides students with eight exercises to practice balancing chemical equations using inverse matrices and determinants. Students may answer directly in the student TI-Nspire document (see TI-Nspire solution document) or on separate sheets of paper. Solutions to each problem and given below. 1. Mg P4 Mg3P2 2. H2 aMg bP4 cMg3P2 Mg: 1a 0b 3c 1 0 a P: 0a 4b 2c 0 4 b c 4; a 12 b 2 12Mg 2P4 aH2 c ©2008 Texas Instruments Incorporated bN2 cNH3 H: 2a 0b 3c 2 0 2 N: 0a 2b 1c 0 2 b c 2Mg3P2 NH3 3 4Mg3P2 , which reduces to: 6Mg P4 N2 6H2 4; a 6 b 2 2N2 3H2 a c 3 1 4NH3 , which reduces to: N2 2NH3 Page 4 Getting Started with Algebra 2 3. aP4 bO2 cP2O5 P: 4a 0b 2c 4 0 O: 0a 2b 5c 0 2 b c 8; 4P4 a 4 b 20 5. aKO2 a c Sb: 1a 0b 4c 1 0 a 5 O: 0a 2b 6c 0 2 b c 5O2 2; a 8 b 6 8Sb 6O2 cK 2CO3 dO2 6. aFe2O3 c 4 6 2Sb4O6 , which reduces to: 4Sb 3O2 2P2O5 bCO2 cSb4O6 2 8P2O5 , which reduces to: 20O2 P4 bCO Sb4O6 cFe dCO2 K: 1a 0b 2c 0d 1 0 2 a 0 Fe: 2a 0b 1c 0d 2 0 O: 2a 2b 3c 2d 2 2 3 b d 2 O: 3a 1b 0c 2d 3 1 0 b d 2 C: 0a 1b 1c 0d 0 1 1 c 0 C: 0a 1b 0c 1d 0 1 0 c 1 d 3; a 4 b 2 c 2 4KO2 7. 4. aSb bO2 aC3H8 d 2CO2 bO2 C: 3a 0b 1c 2K2CO3 cCO2 0d 1 b 3 c 2 Fe2O3 3O2 dH2O 3 0 3; a 3CO 8. aC2H3Cl bO2 1 a cCO2 0 C: 2a 0b 1c 0d 0e 1e H: 8a 0b 0c 2d 8 0 0 b d 2 O: 0a 2b 2c 1d 0 2 c 1 Cl: 1a 0b 0c 0d 1e O: 0a 2b 2c 1d 0e d 16; 4C3H8 a 4 b 20 c 12 20O2 5O2 16H2O , 3CO2 a b 1 0 0 0 c 0 2 2 1 d which reduces to: C3H8 dH2O eHCl 2 0 1 0 3 0 0 2 12CO2 4H2O e 4; a b 4 10 c d 8 4 4C2H3Cl 10O2 0 2Fe 3CO2 H: 3a 0b 0c 2d 2 1 a 8CO2 e 0 1 1 0 4H2O 4HCl , which reduces to: 2C2H3Cl 5O2 ©2008 Texas Instruments Incorporated 4CO2 2H2O 2HCl Page 5 Getting Started with Algebra 2 Balance Me – ID: XXXX (Student)TI-Nspire File: Alg2Act22_BalanceMe_EN.tns ©2008 Texas Instruments Incorporated Page 6 Getting Started with Algebra 2 ©2008 Texas Instruments Incorporated Page 7
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