Dear AP Chemistry Student and Parents, Welcome to AP Chemistry! I applaud you for wanting to challenge yourself and am very excited about embarking upon this rewarding journey with you. Important information to ensure your success in AP Chemistry: This is a College level Course so students can earn up to 8 hours college credit upon successful completion of this course and a score of 3-5 (varies by college) on the AP Exam. Students will be expected to work independently and utilize their resources. Problem-solving skills are emphasized in this curriculum and will be developed throughout the year. This is a challenging, fun and extremely rewarding class. The pace is fast and classroom attendance is imperative, especially on lab days. Labs will be on the same day each week to facilitate scheduling of appointments. To be successful on the AP Exam, students must be prepared to spend an average of 5-8 additional hours per week, outside the classroom, working on AP Chemistry. This time will be spent on homework assignments, lab reports, problem solving, etc. If students use their time efficiently, many tasks can be accomplished during class. I will do my very best to provide a college course experience, which not only prepares you for the AP Exam but also provides a solid foundation in Chemistry. It may have been almost a year since some of you completed Chemistry. The fast pace of this class will not allow a lot of time for review of basic concepts so attached is a Summer assignment packet. This will facilitate your review of material you have already learned in Chemistry. So all will turn up on the first day of class totally fluent in the language of Chemistry! The SUMMER ASSIGNMENT is MANDATORY. You might get bored without elements and ions floating around your heads! Some parts of the Summer Assignment are designed to test your resourcefulness. Translation: Look it up if you don’t know it! You have so many available resources. Students should not worry if their prior Chemistry course did not cover some of the material – it is easily mastered. The Summer Assignment will be taken up for a grade a WEEK AFTER SCHOOL starts. Please read the following statement carefully: My signature below indicates that I am aware of the mandatory Summer Assignment and the rigorous course expectations for AP Chemistry. I understand the high expectations regarding coursework and attendance. I am aware that I will need to spend 1 – 1.5 hours per night doing homework and preparing for the AP Course and exam Best wishes for a safe and relaxing summer, Mrs. Milam --------------------------------------------------------------------------------------------------------------------------------------- __________________________________ ___________________________________ ___________________________________ ___________________________________ ___________________________________ ___________________________________ ___________________________________ ___________________________________ Student Name (Print) Student Signature Parent Name (Print) Parent Signature Student e-mail Date Parent e-mail Date Please return to Mrs. Milam, in Room 604, by Friday, May 20th 1 AP CHEMISTRY SUMMER ASSIGNMENT The Summer Assignments consists of two parts: Part A: Material to be memorized by the second day of school Part B: A packet to be turned in the second day of school, which involves review, and practice in: Nomenclature Solubility rules Balancing equations Problem-solving Oxidation numbers PART A – MATERIAL TO BE MEMORIZED There will be a test the second week of school on the concepts below. Memorization is not encouraged in this course, as it is a problem-solving course. However, certain basic topics and rules need to be memorized to facilitate instant recall in quickly solving problems on the AP exam in May. Tips on Memorization: Make flashcards, bingo games, etc. Use quizlet.com - a flashcard website. It makes memorization fun by offering games and quizzes. AP Chemistry review material can be accessed at: http://quizlet.com/subject/ap-chemistry Have your friends and family quiz you or form study groups with other students in the class. Be able to quickly recall the information below for success in this class. Information to be Memorized by the 2nd week of School Topic Where do I find this information? Element name & symbols: The Periodic Table Element symbols 1-40 along with Ag, Au, Cd, I, Xe, Cs, Ba, W, Hg, Pb, Sb, Sn, Rn, Fr, U, Th, Pu, and Am You should be able to locate elements quickly on the periodic table. The table used on the AP exam does NOT include element names 1. Monatomic ions Listed at the end of this table (& ones with multiple oxidation states) 2. Polyatomic ions and corresponding acids Listed at the end of this table (if you master the system for naming acids, you do not have to memorize them) 3. Six Strong Acids “CBSPIN” (for practical purposes, all others are weak acids) Hydrochloric acid (HCl) Hydrobromic acid (HBr) Sulfuric Acid (H2SO4) Perchloric acid (HClO4) Hydroiodic acid (HI) Nitric acid (HNO3) 4. Strong bases Group 1 metal hydroxides (NaOH, KOH, etc.) (all others are weak, such as NH3) Group 2 metal hydroxides (Ba(OH)2, Sr(OH)2) 5. Solubility rules Listed at the end of this table 6. Intermolecular Forces Listed at the end of this table 2 1. & 2.Common Ions: Positive ions (cations) Negative ions (anions) +1 Charge -1 Charge Ammonium (NH4+) Copper (I) or cuprous (Cu+) Hydrogen (H+) or “proton” Hydronium ion (H3O+) Silver (Ag+) Group 1 (Li +, Na+, K+, Rb+, Cs+, Fr+) Acetate (C2H3O2-) Cyanide (CN-1) dihydrogen phosphate (H2PO4-) Hydrogen carbonate or bicarbonate (HCO3-) Hydrogen sulfate or bisulfate (HSO4-) Hydroxide (OH-) Nitrate (NO3-) Nitrite (NO2-) Perchlorate (ClO4-) Chlorate (ClO3-) Chlorite (ClO2-) Hypochlorite (ClO-) Permanganate MnO4-) Thiocyanate (SCN-) Group 17 anions (F-, Cl-, Br-, I-,) +2 Charge Cadmium (Cd2+) Chromium (II) or chromous (Cr 2+) Cobalt (II) or cobaltous (Co2+) Copper (II) or cupric (Cu2+) Iron (II) or ferrous (Fe2+) Lead (II) or plumbous (Pb2+) Manganese (II) or manganous (Mn2+) Mercury (I) or mercurous (Hg22+) Mercury (II) or mercuric (Hg2+) Nckel (Ni2+) Tin (II) or stannous (Sn2+) Zinc (Zn2+) Group 2 (Be2+, Mg2+, Ca2+, Sr2+, Ba2+, Ra2+) +3 Charge Aluminum (Al3+) Chromium (III) or chromic (Cr3+) Iron (III) or ferric (Fe3+) +4 Charge lead (IV) or plumbic (Pb4+) Tin (IV) or stannic (Sn4+) -2 Charge Carbonate (CO32-) Chromate (CrO42-) Dichromate (Cr2O72-) Hydrogen phosphate (HPO42-) Oxalate (C2O42-) Oxide (O2-) Peroxide (O22-) Sulfate (SO42-) Sulfite (SO32-) Sulfide (S2-) Thiosulfate (S2O32-) -3 Charge Arsenate (AsO43-) Phosphate (PO43-) Phosphite (PO33-) Group 15 – nitride (N3-), phosphide (P3-) Summary of metal ions with more than one charge: Cu+, Cu2+; Hg22+, Hg2+; Co2+, Co3+; Cr2+, Cr3+; Fe2+, Fe3+; Mn2+, Mn3+; Pb2+, Pb4+; Sn2+, Sn4+ Manganese and several other metals can form several ions with different charge. You should know the ones listed. Tips for Monoatomic ions: These can be organized into two groups: 1. Their position on the periodic table indicates the charge on the ion, since a neutral atom gains or loses a predictable number of electrons (oxidation number) in order to obtain the noble gas configuration. a. All group 1 elements (alkali metals) lose one electron to form a 1+ ion b. All group 2 elements (alkaline earth metals) lose two electrons to form an ion with a 2+ charge c. Group 13 metals lose three electrons to form an ion with a 3+ charge d. All group 17 elements (halogens) gain one electron to form an ion with a 1- charge e. All group 16 nonmetals gain two electrons to form an ion with a 2- charge f. All group 15 nonmetals gain three electrons to form an ion with a 3- charge Notice that cations keep their name (sodium ion, calcium ion) while the anions get an “-ide” ending (chloride ion, oxide ion) 3 2. Metals that can form more than one ion will have their positive charge denoted by a roman numeral in parenthesis immediately next to the name of the ion (iron (III) chloride) Tips to Memorizing the Polyatomic Ions: 1. A quick way to memorize some of the polyatomic ions is to use: “Nick the Camel ate a Clam for Supper in Phoenix on Crates” Number of vowels = charge; Number of consonants = number of oxygen atoms Nick – Nitrate; NO3Camel – Carbonate; CO32Clam – Chlorate; ClO3Supper – Sulfate; SO42Phoenix – Phosphate; PO43Crates – Chromate; CrO422. “ate” anions have ONE more oxygen than the “ite” ion, but the same charge. If you memorize the “ate” ions, then you should be able to derive the formula for the “ite’ and vice versa. a. Sulfate is SO42-, so sulfite has the same charge but one less oxygen (SO32-) b. Nitrate is NO3-, so nitrite has the same charge but one less oxygen (NO2-) 3. If you know that a sulfate ion is SO42-, then to get the formula for the hydrogen sulfate ion, you add a hydrogen ion to the front of the formula. Since hydrogen has a 1+ charge, the net charge on the new ion is less one. a. PO43- HPO42 H2PO4phosphate hydrogen phosphate dihydrogen phosphate 4. Learn the hypochlorite Chlorite chlorate perchlorate series, and you also know the series containing iodite/iodate as well as bromite/bromate. a. The relationship between the “ite” and the “ate” is predictable, as always. Learn one and you know the other. b. The prefix hypo” means “under” or “too little” (think hypodermic, hypothermic or hypoglycemic) i. hypochlorite is “under” chlorite, meaning it has one less oxygen c. The prefix “hyper” means “above” or ‘too much” (think “hyperactive”) i. The prefix “per” is derived from “hyper” so perchlorate (hyperchlorate) has one more oxygen than chlorate. d. Notice how this sequence increases in oxygen while retaining the same charge: ClOhypochlorite ClO2chlorite ClO3chlorate ClO4perchlorate 3. Acids Rules for naming acids: A. Binary acids – Contain hydrogen and one other atom (not oxygen) “Hydro(anion)ic acid” o Ex. H2S is hydrosulfuric acid. Exception: HCN = hydrocyanic acid B. Oxyacids – contain hydrogen and a polyatomic ion containing oxygen (oxyanion) (Anion name) suffix acid o If the oxyanion ends with –ate, the suffix is –ic Ex. HNO3 is nitric acid (nitrate ion) o If the oxyanion ends with –ite, the suffix is ous Ex. HNO2 is Nitrous acid (nitrite anion) 4 Polyatomic Ions and Acids Formula Name Ion Ion Name H2SO4 Sulfuric acid SO42Sulfate ion 2H2SO3 Sulfurous acid SO3 Sulfite ion HNO3 Nitric acid NO31Nitrate ion HNO2 Nitrous acid NO21Nitrite ion H3PO4 Phosphoric acid PO43Phosphate ion H2CO3 Carbonic acid CO32Carbonate ion 1HMnO4 Permanganic acid MnO4 Permanganate ion HCN Hydrocyanic acid CN1Cyanide ion HOCN Cyanic acid OCN1Cyanate ion HSCN Thiocyanic acid SCN1Thiocyanate ion 1HC2H3O2 Acetic acid C2H3O2 Acetate ion H2C2O4 Oxalic acid C2O42Oxalate ion H2CrO4 Chromic acid CrO42Chromate ion H2Cr2O7 Dichromic acid Cr2O72Dichromate ion H2S2O3 Thiosulfuric acid S2O32Thiosulfate ion 3H3AsO4 Arsenic acid AsO4 Arsenate ion H3AsO3 Arsenous acid AsO33Arsenite ion Oxyhalogen Acids Formula Oxy name Ion Ion Name HClO Hypochlorous acid ClO1Hypochlorite HClO2 Chlorous acid ClO21Chlorite HClO3 Chloric acid ClO31Chlorate ion 1HClO4 Perchloric acid ClO4 Perchlorate ion Br, I can be substituted for Cl. F may form hypofluorous acid and the hypofluorite ion. 5. Solubility Rules 1. All compounds of Group 1 and ammonium ions are soluble 2. All nitrates, acetate, and chlorates are soluble 3. All binary compounds of the halogens (except F) are soluble except those of Ag, Hg(I), and Pb 4. All sulfates are soluble except those of barium, strontium, calcium and lead 5. Sulfides and hydroxides are INsoluble except for Ca, Ba, Sr, ammonium and the alkali metals 6. Except for rule 1, carbonates, oxides, silicates, and phosphates are INsoluble Note on Solubility Rules: Solubility rules allow you to predict whether the product of a double replacement reaction will be a precipitate or not: If the compound is soluble it will dissociate into free ions into solution If the compound is INSOLUBLE it will form a precipitate Ex. AgNO3(aq) + NaCl (aq) AgCl(s) + NaNO3(aq) According to rule 3 – AgCl is insoluble and will form a precipitate According to rules 1 & 2, NaNO3 is soluble and will remain in solution 5 6. Intermolecular Forces - Attractive forces between solid or liquid molecules. Network Covalent Ionic (electrostatic attraction) Metallic Hydrogen Bonding Dipole-dipole London Dispersion Force Direction covalent bond C (graphite, diamond) Si, SiO2 (sand) Forces between adjacent ions (Na+ --- Cl-) Forces between metal nuclei (Cu, Ag) sea of electrons Forces between adjacent molecules with H & F, O, N or Cl. (H2O, NH3) Forces between adjacent polar molecules Forces between adjacent nonpolar molecules (CO2, Cl2) *These can be strong in atoms & molecules w/large numbers of electrons Strongest (generally) Weakest 6 AP CHEMISTRY SUMMER ASSIGNMENT PART B – REVIEW PACKET I. Due - 2nd week of school NOMENCLATURE REVIEW IONIC COMPOUNDS a. Formula for Binary Ionic Compounds The total positive charge must equal the total negative charge. The best way to write the formula is to use the “Criss Cross Method“(also called “Swap & Drop”) Example: What ionic compound is formed when calcium combines with fluorine? Steps to the Criss Cross Method: a. Write the ions with their charges; cations always are first Ca2+ F1b. Cross over absolute value of charges and drop as subscript Ca1 F2 c. Check to ensure the subscripts are the lowest whole number ratio possible. Then write the formula: CaF2 b. Naming Binary Ionic Compounds Combine the name of the cation (1st) and anion (2nd). The cation name stays the same and the ending of the anion changes to –ide. Example: BaCl2 is named barium chloride If the cation has more than one oxidation state, this is indicated by using roman numerals Example : FeCl2 is iron (II) chloride c. Naming Ionic Compounds with Polyatomic Ions The rules are the same as above except the ending of the polyatomic is not changed. Example: Na2CO3 is sodium carbonate II. MOLECULAR COMPOUNDS a. Naming Binary Molecular Compounds – use prefixes Number 1 2 3 4 5 6 Prefix monoditritetrapentahexa Number 7 8 9 10 11 12 Prefix heptaocta nonadecaundecadodeca The less electronegative atom (farthest from F) is written first. It only gets a prefix if it has more than one atom. The 2nd element gets a prefix and the ending –ide. The o or a at the end of the prefix is dropped when the following word begins with a vowel, for example monoxide or pentoxide. Exercise 1 – Nomenclature: Simple, inorganic formulas & nomenclature 1. In the first column, classify each of the following as molecular(=covalent) (C) or ionic (I). In the 2nd column, name each compound: M or I 1)CaF2 2) P4O10 3) K2S 4) NaH 5) Al2Se3 6) N2O 7) O2F 8) SBr6 9) Li2Te Name C or I Name 10) SrI2 11) CO 12) Cs2Po 13) ZnAt2 14) P2S3 15) AgCl 16) Na3N 17) Mg3P2 18)XeF6 7 2. In the first column, write the chemical formula (formula unit) for the compound formed between the two given elements. In the second column, name the compound: Elements Formula Unit Name 1 magnesium & iodine 2 potassium & sulfur 3 chlorine and aluminum 4 zinc & bromine 5 strontium & oxygen 6 calcium & nitrogen 7 calcium & oxygen 8 copper (I) & oxygen 9 copper (II) & chlorine 10 mercury (II) & oxygen 11 nitrogen & aluminum 12 sulfur & cesium Exercise 2 – Nomenclature: Oxidation numbers: anions & cations Summary of Rules for Oxidation Numbers (you did not learn this in 1st year chemistry): Rule 1: Atoms in a pure element have an oxidation number of zero Rule 2: The most electronegative element in a binary compound is assigned the number equal to the negative charge it would have as an anion. The less electronegative atom is assigned the number equal to the positive charge it would have as a cation. o Example: group 1 is +1; Group 2 is +2; Group 13 is +3; Group 17 is -1; Group 16 is -2; Group 15 is 3, etc Rule 3: Fluorine has an oxidation # of -1 in all its compounds because it is the most electronegative element. Rule 4: Oxygen has an oxidation # of -2 in almost all compounds o Exceptions: Peroxides such as H2O2 in which its oxidation # is -1 When oxygen is with halogens such as OF2, its oxidation # is +2 Rule 5: Hydrogen has an oxidation # of +1 in all compounds that are more electronegative that it is; it has an oxidation # of -1 in all compounds with metals Rule 6: The algebraic sum of the oxidation numbers of all atoms in a neutral compound is zero Rule 7: The algebraic sum of the oxidation numbers of all atoms in a polyatomic ion is equal to the charge on the ion Rule 8: Rules 1-7 apply to covalently bonded atoms; however, oxidation numbers can also be assigned to atoms in ionic compounds. Determine the Oxidation Number of each of the underlined elements in the table below: 1) K2S 6) S8 11) C60 2) NaClO4 7) Mg 12) ZrO2 3) BrCl 8) K2W4O13 13) K2Cr2O7 4) Li2CO3 9) Mg(BF4)2 14) Al2(CrO4)3 5) OF2 10) Au2O3 15) Cs2TeF8 Exercise 3: More Nomenclature – Ternary Nomenclature: Acids & Salts 1. Name the following substances: Formula Name Formula Name 1) FeSO4 16) Fe2O3 2) Cu(NO3)2 17) (NH4)2SO3 3) Hg2Cl2 18) Ca(MnO4)2 8 4) AgBr 19) PF5 5) KClO3 20) LiH 6) MgCO3 21) HIO3 7) BaO2 22) NaBrO2 8) KO2 23) Ca3(PO4)2 9) SnO2 24) HIO4 10) Ni3(PO4)2 25) Fe(IO2)3 11) Pb(OH)2 26) HAt 12) CuCH3COO 27) C6H5COOH 13) N2O4 28) Hg2(IO)2 14) Rb3P 29) H3PO3 15) S8 30) NH4BrO3 2. Write the formulas for the following substances: Name 1) vanadium (V) oxide Formula Name 16) francium dichromate Formula 2) dihydrogen monoxide 17) calcium carbide 3) ammonium oxalate 18) mercury (I) nitrate 4) polonium (VI) thiocyanate 19) cerium (IV) benzoate 5) tetraphosphorus decoxide 20) potassium hydrogen phthalate 6) zinc hydroxide 21) carbonic acid 7) potassium cyanide 22) calcium hypochlorite 8) cesium thiosulfate 23) hydrotelluric acid 9) oxygen molecule 24) copper (II) nitrite 10) mercury (II) acetate 25) nitrous acid 11) silver chromate 26) hypoiodous acid 12) tin (II) carbonate 27) cyanic acid 13) sodium hydrogen carbonate 28) phthalic acid 14) manganese (VII) oxide 29) tin (IV) chromate 15) copper (II) dihydrogen phosphate 30) hydrocyanic acid 3. Practice with Acids. Recall: -IC from –ATE -OUS from –ITE HYDRO-, -IC from –IDE Compete the Following Table: Name of Acid hydrochloric Formula of Acid HCl Name of Anion chloride sulfuric acid H2SO4 sulfate HI 9 sulfite chlorous acid nitrate HC2H3O2 or CH3COOH hydrobromic acid sulfide HNO2 chromic acid phosphate Exercise 4 – Balancing Equations 1. Balance the following equations by adding coefficients as needed. Some equations may already be balanced. 1) ___ C6H6 + ___ O2 ___ H2O + ___ CO2 2) ___ NaI + ___ Pb(SO4)2 ___ PbI4 + ___ Na2SO4 3) ___ NH3 + ___ O2 ___ NO + ___ H2O 4) ___ HNO3 + ___ Mg(OH)2 ___ H2O + ___ Mg(NO3)2 5) ___ H3PO4 + NaBr ___ HBR + Na3PO4 6) ___ CaO + ___ MnI4 MnO2 + ___ CaI2 7) ___ C2H2 + ___ H2 ___ C2H6 8) ___ VF6 + ___ HI V2I12 + ___ HF 9) ___ OsO4 + ___ PtCl4 ___ PtO2 + ___ OsCl8 10) ___ Hg2I2 + ___ O2 ___ Hg2O + ___ I2 Exercise 5 – Reaction Prediction Practice I. Predict the products, write the equation and then balance. COMBUSTION 1. C4H9OH + oxygen 2. C7H14 + oxygen SYNTHESIS 1. Sodium + oxygen 2. Calcium + nitrogen 10 3. Potassium + bromine DECOMPOSITION 1. Strontium carbonate 2. Mercury (II) oxide 3. Aluminum chlorate DOUBLE REPLACEMENT (all are aqueous solutions) 1. Iron (III) sulfate + calcium hydroxide 2. Sodium hydroxide + sulfuric acid 3. Sodium sulfide + manganese (VI) acetate 4. Chromium (III) bromide + sodium sulfite 5. Barium hydroxide + chlorous acid SINGLE REPLACEMENT Use the activity series online to complete and balance these equations. If no reaction occurs, write NR. 1. Nickel + steam 2. Chlorine + aluminum iodide 3. Potassium + water 4. Lead + copper (II) chloride 5. Zinc + hydrochloric acid Exercise 6 – Solubility Rules: using the Solubility Rules Table on page 5-6 of this handout For the compounds in the table, write the formula for each compound in the first column and then use the solubility rules to determine if each compound is soluble or insoluble in water. In the second column, write an (S) for those that are soluble and an (I) for those that are insoluble in water. Name Formula (S) or (I) Silver nitrate cobalt (II) sulfate Zinc hydroxide 11 iron (III) iodide nickel (II) chloride lead (II) iodide sodium carbonate barium sulfate lead (II) sulfide silver phosphate lithium phosphate nickel (II) carbonate copper (II) hydroxide tin (IV) sulfate lead (II) nitrate Exercise 7 : Calculations Review Complete all the problems below – show your work and circle your final answers. Record your answers with the correct number of significant figures and remember units! Rules for Significant Figures THREE rules: RULE 1: Non-zero digits are ALWAYS significant RULE 2: Zeroes between two significant digits are significant RULE 3: If a decimal is PRESENT, only the zeroes AFTER the non-zero numbers count Number 35,456 415,002 0.001010 0.300000 100.0000 12303000 Rule Follow Rule 1 Follow Rule 2 Decimal point present - Follow Rule 3 Decimal point present: only count zeroes after 3 Decimal point present : Follow rule 3 Follow rule 1 and 2 Significant Figures 5 6 4 6 7 5 12 Rules for Using Significant Figures in Calculations: 1. When adding or subtracting, the answer should have the same number of figures to the right of the decimal as the value with the fewest decimal places. For example, 3.4 + 5.023 = 8.423. Round to 8.4, because 3.4 has only one digit to the right of the decimal. 2. When multiplying or dividing, the answer should have the same number of significant figures as the value with the fewest significant figures. For example, 1.220 x 3.4870 = 4.25414. Round this answer to 4.254, because 1.220 has only four significant figures. Significant Figure learning Aid – Atlantic – Pacific If decimal is PRESENT, start counting from LEFT (Pacific side) at first NON-ZERO digit & keep counting If decimal is ABSENT, start counting from RIGHT (Atlantic side) at first NON-ZERO digit & keep counting Significant Figures 1. perform the following calculations with correct significant figures: a. 22.3411 x 42,68 8.36 b. (9.24 + 43.1120 + 12.0) / 5.7821 Density 2. Calculate the mass of a sample of copper that occupies 5.3 x 10-2 cm3 if the density of copper is 8.94 g.cm3. 3. A 9.46 g sample of a solid is placed in a 25.00 mL flask. The remaining volume of the flask is filled with benzene in which the solid is insoluble. The solid and the benzene together weigh 26.83 g. The density of the benzene is 0.879 g/ mL. What is the density of the solid? Dimensional Analysis 4. 2.54cm = 1 inch; 1Kg = 2.205 Lb; 1 meter = 1.094 yards; 1 mile = 1760 yards A pencil is 7.00 inches long. What is its length in centimeters? 5. A student has entered a 10.0 km run. How long is the run in miles? 13 Exercise 8: Atomic Theory, Electron Configuration & Periodicity 1. Fill in the following table: Element/ion Fe # of Protons # of Neutrons # of Electrons Na+ 27 25 S2Cr3+ 2. Write the electron configuration for: a. Ca2+ b. 3. 4. For Se write: a. the complete electron configuration b. the noble gas configuration c. the orbital diagram d. the dot diagram Draw the Lewis dot structures for the following elements: a. 5. Br-1 Pb b. N c. F d. Ca e. He Place the elements S, Se, I, Ca and Be in: a. order of increasing atomic radius b. decreasing ionization energy Exercise 9: The Mole & Stoichiometry 1. Convert 3.47 x 1020 molecules of SO2 to moles. What is the mass of this quantity? 2. A solution containing 4.5g of sodium phosphate is mixed with a solution containing 3.75 g of barium nitrate. How many grams of barium phosphate can be produced? 3. The thermite reaction (mixing solid iron (III) oxide with aluminum metal) ihas been used over the years to weld railroad rails, in incendiary bombs, and to ignite solid-fuel rocket motors: a. Write a balanced equation for the reaction b. What masses of iron (III) oxide and aluminum must be used to produce 15.0g of iron? 14 Exercise 10: Molarity (M = mol solute/L solution) 1. How many grams of solute are present in 100 mL of 1.50 M MgSO4? 2. What is the molarity of 35 g of iron (II) acetate dissolved in enough water to make 250 mL of solution? Exercise 11: Thermochemistry Q = mCT Q – Heat energy in joules or calories; C = Specific heat capacity of substance; T = Final – initial temperature Note: The heat capacity of water should be known and is 4.184J/gC or is 1 cal/g C 1. The specific heat capacity of graphite is 0.71J/gC. Calculate the energy (in calories) required to raise the temperature of 1.8 kg of graphite by 100 C. Resources to help you review: http://www.khanacademy.org/science/chemistry http://www.brightstorm.com/science/chemistry http://quizlet.com/subject/ap-chemistry http://www.bozemanscience.com/ap-chemistry/ Highly Recommended AP Chemistry Review Books: Barron’s*, Princeton Review, Adrian Dingle’s Crash Course Chemistry 15
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