Super Duper Solutions Review Name _________________________ Pd ______ Use the terms below to complete the passage. aqueous immiscible liquid insoluble miscible soluble solute solution solvent All (1) _ solutions _ are homogeneous mixtures. Since air is 20% oxygen and 79% nitrogen air is a(n) (2) _ solution _ of oxygen gas dissolved in nitrogen gas. The oxygen in air is the (3)_ solute _, and nitrogen is the (4) _ solvent _. Because oxygen gas dissolves in a solvent, oxygen gas is a(n) (5) _ soluble _ substance. A substance that does not dissolve is (6) _ insoluble _. (7) _ Liquid _ solutions are the most common type of solutions. If one liquid is soluble in another liquid, such as acetic acid in water, the two liquids are (8) _ miscible _. However, if one liquid is insoluble in another, the liquids are (9) _ immiscible _. 10. Fill in the following blanks with the word polar or the word nonpolar or the word ionic: a. Polar molecules can only dissolve other _ polar _ molecules or _ ionic _ compounds b. Nonpolar molecules can only dissolve other _ nonpolar _ molecules. c. Polar molecules WILL NOT dissolve _ nonpolar _ molecules. 11. Fill in the chart with the appropriate information. Compound C6H12O6 Ionic or Covalent? Polar or Nonpolar? C Nonpolar (Slightly polar) I Will dissolve better in… H2O Oil X X (somewhat) NH3 C Ionic – polar nonpolar X refers to covalent molec. P X C6H14 C N MgCl2 X 12. Fill in the following blanks with one of the following terms: soluble, insoluble, immiscible, miscible. a. Chalk will not dissolve in water. It is said to be _ insoluble _. b. Oil will not dissolve in water. It is said to be _ immiscible _. c. Sucrose (sugar) will dissolve in water. It is said to be _ soluble _. d. Lemon juice will dissolve in water. It is said to be _ miscible _. e. _ Miscible _ and _ immiscible _ refer to solutions made of two liquids. 13. Water allows many substances to dissolve in it because of its polar nature. It is often referred to as the _ Universal Solvent _. In a(n) _ aqueous _ solution, water is the solvent. Directions: Use the graph below to answer 14 - 25. SHOW ALL WORk for Calculations!!! 14. How much sodium nitrate is dissolved in 100 g of water at 60C?_ 124 g + 2 g_ 15. How much ammonium chloride is dissolved in 100 g of water at 10C? _ 35 g _ 16. What is the mass of KNO3 than can dissolve in 800 g of water at 50C? _ 640 g _ 17. What is the minimum mass of water at 100C needed to dissolve 80 g NaCl? _ 200 g H2O_ 18. If 50 g of ammonium chloride is dissolved at 40C, is the solution saturated, unsaturated or supersaturated? _ supersaturated _ 19. If 70 g of KNO3 is dissolved at 60C, how much more solute can be added before the solution becomes saturated? 100-70 = 30 g KNO3 20. At 50C, 115 g of sodium nitrate is dissolved. If the solution is cooled to 10C, how much solute will precipitate out of solution? _5 g_ 21. What happens to the solubility of a solid as temperature increases? _ increases _ 22. What happens to the solubility of a gas as temperature increases? _ decreases _ Refer to the solubility graph and tell if the solution described is unsaturated (US), saturated (S) or supersaturated (SS) 22. 100 g KNO3 in 100 grams of water at 50OC __ SS __ 23. 50 g KCl in 100 grams of water at 80OC __ S _ 24. 50 g KCl in 200 grams of water at 80OC _ US __ 25. 70 grams of ammonium chloride at 90OC _ SS _ Use the terms unsaturated (US), saturated (S) or supersaturated (SS) to identify each solution described below: 26. When more solute is added the additional solute “disappears” _ US _ 27. When a crystal of solute is added the excess precipitates out _ SS _ 28. When more solute is added the additional solute just falls to the bottom _ S _ 29. A solution containing more solute than it “should” be able to hold at that temperature _ SS _ 30. A solution containing exactly the amount of solute the graph shows it can hold at a specific temperature __ S _ 31. A solution containing less solute than it can hold at a specific temperature _ US _ Solution Concentration 32. Determine the molarity of a 1000 mL solution containing 3.5 mol of sodium nitrate. 3.5 M 33. Calculate the number of grams of silver(I) nitrate (AgNO3) needed to make 200 L of a 4M solution. 800 mol = 169.9 g/mol AgNO3 = 135,968 g 34. Calculate the volume of a 0.25M solution containing 20 g of NaOH. 0.5 mol NaOH 35. Calculate molarity of a solution containing 20 g of sodium oxide (Na2O) in 200 mL of solution. Is this solution dilute or concentrated? 1.6 M dilute Solution Dilution M1V1 = M2V2 36. What will be the final concentration of the solution indicated that will result from the following dilutions? a. 14.0 mL of a 4.20 M Na2CO3 solution is diluted to 86.0 mL. M2 = 0.68 M b. 450. mL of a 1.22 M HCl solution is diluted to 1.26 liters. M2 = 0.436 M 37. To what volume should the indicated solution be diluted to produce a solution of the desired concentration? a. 12.0 mL of a 0.64 M KCl solution to produce a 0.19 M solution. V2 = 40.4 mL b. 84.2 mL of a 4.60 M KMnO4 solution to produce a 1.42 M solution. V2 = 272.8 mL 38. What volume of the indicated solution is needed to produce the volume and concentration of a diluted solution as indicated? a. 2.73 M NaOH solution to prepare 142 mL of a 0.540 M solution. V1 = 28.1 mL b. 0.0076 M SnF2 solution to prepare 25.0 mL of a 0.00027 M solution. V1 = 0.964 mL Colligative Properties 39. What is Freezing Point? How does adding a solute to a pure solvent influence freezing point of the solution? Lowers Freezing Point 40. What is Boiling Point? How does adding a solute to a pure solvent influence boiling point of the solution? Raises Boiling Point More: 41. Circle all of the following solutes that will dissolve in H2O a. KBr b. NaCl c. CH4 (nonpolar) d. NH3 (polar) 42. Nonpolar solutes dissolve in _ nonpolar _ solvents 43. The unit used for molarity (molar concentration) is __ Molar ___ _ M _ 44. _ 1000 _ mL = 1 L 45. Identify the solute and solvent in a liquid solution of sugar water: Solute: _ Sugar _ Solvent: _ Water _ 46. Explain the difference between a solution, a colloid and a suspension. Identify each as homogeneous or heterogeneous. The primary difference is the size of the solute or suspended particle. - Solutions have the smallest particles and are homogeneous – solute particles and solvent particles are the same size. - Colloids are heterogeneous; the particles are still very small and stay suspended in the solvent but they are large enough to reflect light (Tyndall Effect) - Suspension particles are so large that they settle out, making a suspension a heterogeneous mixture
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