tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:51 Art: [American Journal of Science, Vol. 310, December, 2010, P. 1210 –1249, DOI 10.2475/10.2010.02] ACCRETIONARY OROGEN AND EVOLUTION OF THE JAPANESE ISLANDS—IMPLICATIONS FROM A Sr-Nd ISOTOPIC STUDY OF THE PHANEROZOIC GRANITOIDS FROM SW JAPAN BOR-MING JAHN*,** ABSTRACT. The Japanese Islands represent a segment of a 450 Ma old subductionrelated orogen developed along the western Pacific convergent margin, and most tectonic units are composed of late Paleozoic to Cenozoic accretionary complexes and their high P/T metamorphic equivalents. The formation of the Japanese Islands has been taken as the standard model for an accretionary orogeny. According to Maruyama (1997), the most important cause of the orogeny is the subduction of an oceanic ridge, by which the continental mass increases through the transfer of granitic melt from the subducting oceanic crust to the orogenic belt. Sengor and Natal’in (1996) named the orogenic complex the “Nipponides,” consisting predominantly of Permian to Recent subduction-accretion complexes with very few fragments of older continental crust. These authors pointed out the resemblance in orogenic style between Japan and the Central Asian Orogenic Belt (CAOB). The present work uses new and published Sr-Nd isotopic data from the literature to test the statements made by these authors. A large proportion of the granitoids from SW Japan have high initial 87Sr/86Sr ratios, negative Nd(T) values and Proterozoic Sm-Nd model ages. The Japanese isotopic data are in strong contrast with those of two celebrated accretionary orogens, the Central Asian Orogenic Belt and Arabian-Nubian Shield, but are quite comparable with those observed in SE China and Taiwan, or in classical collisional orogens in the European Hercynides and Caledonides. This raises questions about the bulk composition of the continental crust in SW Japan, or the type of material accreted in accretionary complexes, and negates the hypothesis that the “Nipponides” contains very few fragments of older continental crust. The subduction-accretion complexes in Japan are composed mainly of recycled continental crust, probably of Proterozoic age. This study supports the idea that proto-Japan was initially developed along the southeastern margin of the South China Block. Key words: Accretionary orogen, accretionary complex, Japanese Islands, Sr-Nd isotope tracer, Mesozoic granitoids, Nipponides, crustal growth, juvenile/recycled crust, Central Asian Orogenic Belt (CAOB), Arabian-Nubian Shield (ANS), SE China, Taiwan. introduction Accretionary orogens are known to be the most important sites of continental growth and mineralization (for example, Windley, 1992; Sengor and others, 1993; Sengor and Natal’in, 1996; Jahn, 2004; Kovalenko and others, 2004; Condie, 2007; Cawood and others, 2009). They include Archean greenstone belts, Proterozoic orogens (for example, the Birimian of West Africa, Svecofennian of S. Finland, Cadomian of NW Europe, and the Arabian-Nubian Shield or ANS), Late Neoproterozoic to Mesozoic orogens of the Central Asian Orogenic Belt (CAOB), as well as Paleozoic to Recent orogens of the circum-Pacific, including the Canadian Cordillera, and the Caribbean. Accretionary orogens consist of accretionary wedges containing material eroded from the upper plate and accreted from the downgoing plate, plus island arcs, ophiolites, oceanic plateaux, old continental blocks, metamorphic rocks and syn- and post-orogenic granitoids (for example, Cawood and others, 2009; Isozaki and others, 2010). In the past two decades, studies of accretionary orogens in the * Institute of Earth Sciences, Academia Sinica, P. O. Box 1-55, Nangang, Taipei 11529, Taiwan ** Present address: Department of Geosciences, National Taiwan University, P. O. Box 13-318, Taipei, 106 Taiwan; [email protected] 1210 Fn* tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:51 Art: Bor-Ming Jahn 1211 Canadian Cordillera (Samson and others, 1989; Samson and Patchett, 1991), CAOB (Sengor and others, 1993; Sengor and Natal’in, 1996; Jahn, 2004; Kovalenko and others, 2004) and ANS (Stern, 1994, 2002, 2008; Stein and Goldstein, 1996) have confirmed the massive generation of juvenile granitoid crust in the Neoproterozoic and Phanerozoic. This important period of crustal growth was seldom recognized or down-graded in the classic models of continental growth (Armstrong, 1981; Reymer and Schubert, 1984; McCulloch and Bennett, 1994; Taylor and McLennan, 1995), but is gaining appreciation in the last two decades (for example, Samson and others, 1989; Sengor and others, 1993; Jahn, 2004; Kovalenko and others, 2004; Condie, 2007). The Japanese Islands represent a segment of a 450 Ma old subduction-related orogen developed along the western Pacific convergent margin, and most tectonic units are composed of late Paleozoic to Cenozoic accretionary complexes (AC) and their high P/T metamorphic equivalents (Isozaki, 1996; Isozaki and others, 2010). Japan appears to provide an ideal model of oceanward growth of an active continental margin by subduction-accretion processes. In fact, the formation of the Japanese Islands has been taken as the classic model for accretionary orogeny and often serves as an example for understanding the crustal evolution of the CAOB and other accretionary orogens (Sengor and Natal’in, 1996; Condie, 2007; Cawood and others, 2009). According to Maruyama (1997), the most important cause of the orogeny is the subduction of an oceanic ridge, by which the continental mass increases through the transfer of granitic melt from the subducting oceanic crust and/or the mantle wedge to an orogenic belt. Sengor and Natal’in (1996) named the Japanese orogenic complex the “Nipponides,” which consists predominantly of Permian to Recent subduction-accretion complexes with very few fragments of older continental crust. These authors pointed out the resemblance in orogenic style between Japan and the CAOB, and further emphasized the large mass proportion of the accretionary complex relative to older continental crust. By implication, the accretionary complex in Japan must be quite “juvenile” as a whole, and consists mainly of mantle-derived crustal materials. In this scenario, voluminous granitic melts emplaced in SW Japan and elsewhere in the Japanese Islands would and should possess Sr-Nd isotopic signatures indicative of juvenile crust, as observed in many parts of the CAOB or ANS. In the first instance, this appears to be in agreement with the absence of Precambrian rocks in Japan. However, the available Sr-Nd isotopic data from the literature and the new analyses presented here of Cretaceous granites from the Sanyo Belt, Miocene granites from the Shimanto Belt, and Quaternary granites from the Japan Alps, indicate that they are in strong contrast with those observed in the CAOB and ANS. In fact, the isotopic signatures are more comparable with those observed in SE China and Taiwan, or in classical collisional orogens, such as the European Hercynides and Caledonides. In this paper, I will summarize the available Sr-Nd isotopic data for granitic rocks generated in the Japanese Islands from the Paleozoic to Recent, and argue that, in addition to the accreted oceanic mafic rocks, the exposed continental crust in SW Japan was produced mainly by remelting or recycling of Proterozoic crust; whereas juvenile crust of mantle-derivation constitutes only a small proportion. This is contrary to what was predicted by Sengor and Natal’in (1996) for the “Niponides” with respect to the importance of the lithological assemblages of an “ocean plate stratigraphy.” I will conclude that the subduction-accretion complexes in Japan are composed mainly of recycled continental crust, probably of Proterozoic age for the main part. On the other hand, the isotopic data support the tectonic evolution model that proto-Japan was developed initially along SE China as a part of Cathaysia and shared the same geochemical and isotopic characteristics as the South China Block (sensu lato; Isozaki and Maruyama, 1991; Maruyama and others, 1997; Isozaki and others, 2010). The microcontinent was later separated from SE China and drifted northeastward to form proto-Japan. tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:51 Art: 1212 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— methodology and source of data In this paper, the technique of radiogenic isotope tracers (Sr-Nd) will be adopted to discuss the generation of the continental crust of Japan. The tracers are in a way comparable to the genetic code (DNA) in biology. The continental crust comprises a variety of lithologic types; some of them represent “recycled” products of ancient crust, whereas others show “juvenile” character if they are produced by melting of mantle peridotites or remelting of mantle-derived rocks such as basalts or andesites. A terrane composed only of island arc or ophiolite assemblages has clearly a juvenile nature, but a terrane comprising essentially granitic rocks, like that of SW Japan or Transbaikalia, cannot be easily classified as juvenile or recycled. In this case, the isotope tracer technique is the most powerful tool in the determination of the proportion of the mantle component in the making of a continent. While basaltic rocks are the most commonly used material in studies of the composition and evolution of the upper mantle, the genesis and evolution of the continental crust must be understood through studies of granitoids because they are generally produced by melting of the middle to lower crust, and hence serve as an excellent probe for the bulk of the continental crust. In the specific case of the Japanese Islands, only granitic rocks will be examined. The source of data used in this paper is mainly from the literature (see Appendix 1), supplemented by new analyses on fourteen Late Cretaceous granitoids from the Sanyo Belt of SW Japan, two Miocene granitoids from the Shimanto belt of southern Shikoku and two Pleistocene granodiorites (Takidani Pluton) from the Japan Alps in north-central Japan (table 1). The complete set of new chemical and isotopic analyses, as well as zircon age determinations, will be published separately in a paper dedicated to the petrogenetic study (Jahn and others, in preparation). Only the Sr-Nd isotopic data (Appendix 1) will be used in this paper for discussion and illustration. general geological and tectonic setting of the japanese islands The Japanese Islands are composed mainly of subhorizontal nappe piles of an accretionary complex (AC) and their metamorphic equivalents with late Paleozoic to Cenozoic ages (Faure, 1985; Isozaki, 1996; Isozaki and Maruyama, 1991; Isozaki and others, 2010). Japan is divided into several geologic units with broadly four periods of accretion: Permo-Triassic, Jurassic, Cretaceous and Tertiary (Faure and others, 1986; Taira and others, 1989; Ichikawa, 1990; Isozaki and Maruyama 1991). The accreted nappe-pile structures are best preserved and studied in SW Japan (for example, Faure, 1985; Faure and others, 1986), so the present study deals only with the crustal evolution of SW Japan. According to Maruyama and others (1997), Japan originated from a rifted continental margin about 750 to 700 million years ago, when the South China Block rifted apart from the Neoproterozoic supercontinent Rodinia to open the PaleoPacific Ocean (Hoffman, 1991; Dalziel, 1992; Powell and others, 1993; Park and others, 1995). Since the tectonic inversion from a passive continental margin to an active convergent margin at ca. 450 Ma, proto-Japan has grown asymmetrically oceanward for nearly 400 km across-arc, through successive subduction of the “Pacific plate,” which included the Farallon, Izanagi-Kula, Pacific and Philippine Sea plates. It was in the Miocene that proto-Japan converted to an island arc isolated from mainland Asia through the opening of the Japan Sea. At present, Japan is situated at the junction of four distinct plates: the Eurasian, Philippine Sea, Pacific and North American. The Eurasian plate includes SW Japan (western Honshu, Shikoku and Kyushu) and the Ryukyu Islands, whereas NE Japan and Hokkaido together belong to the North American plate. The Philippine Sea plate is subducting northwestwards at a rate of 4 cm/yr under SW Japan along the Nankai Trough and Ryukyu trench. The Pacific plate is subducting at a rate of 10 cm/yr beneath NE Japan, with its leading slab reaching a depth of 660 km under Beijing, T1b tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:51 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1213 China, as revealed by a tomographic study (Zhao and others, 2007; see also a review by Isozaki and others, 2010). Within the main island (Honshu), NE Japan collided against SW Japan and formed a high mountain chain (elevation ⬎2000 m) called the “Japan Alps.” The mountain chain extends across the Honshu arc and is uplifting very rapidly since 2 Ma (based on our zircon U-Pb and fission track data; Jahn and others, in preparation). Two of our analyzed granitoid samples reported herein were collected from the Takidani pluton (or stock) of the Japan Alps (fig. 1). The predominance of accretionary complexes and the association of detached continental fragments in Japan suggest that the Japanese Islands have developed mainly through convergence between oceanic and continental plates along active margins (Isozaki, 1997; Isozaki and others, 2010). Isozaki (1996) stated that several major oceanic plates have subducted beneath the South China Block margin, leaving more than 10 distinct AC (accretionary complex) belts (now reduced to 9 AC belts, based on the latest reappraisal of the geotectonic framework of Japan, by Isozaki and others, 2010). All the AC belts occur as thin subhorizontal fault-bounded geologic bodies, that is, nappes, and show a clear downward and oceanward younging polarity (Isozaki and Itaya, 1991; Isozaki and Maruyama, 1991). Numerous oceanic fragments derived from subducted oceanic plates, including deep-sea sediments and seamount basalts and reef limestone, were accreted to Japan. In the tectonic evolution of the Japanese Islands, the Permo-Triassic tectonics is regarded as most important because the basic framework of the Japanese orogenic belts was established and stabilized at that time (Isozaki, 1996). The occurrence of Permo-Triassic tectonic units is well developed in SW Japan and the Ryukyu Islands. By contrast, Permo-Triassic rocks are rarely recognized in NE Honshu and Hokkaido, except the Hitachi-Takanuki Belt at the southern tip of NE Japan. Figure 1 shows two major components of the Permo-Triassic orogen in SW Japan: (1) the accretionary complexes and their high-P metamorphic equivalents, which were generated by subduction of the Farallon plate, and (2) the continent-continent collisional orogenic units, as represented by the Hida and Oki belts (Isozaki, 1996, 1997). In the Ryukyu Islands, the high-P metamorphic AC on Ishigaki Island, close to Taiwan, represents the southwestern extension of the Permo-Triassic accretionary orogen in SW Japan. The Median Tectonic Line (MTL) is a prominent strike-slip fault running through most of SW Japan. It divides SW Japan into two zones: the “Inner Zone” on the back-arc side, and the “Outer Zone” on the fore-arc side (fig. 1). In the Outer Zone, the post-Jurassic accretionary complexes are arranged to show oceanward younging from the Cretaceous to Miocene (Taira and others, 1988), and beyond to the present accretionary prism at the Nankai Trough. No collision-related Permo-Triassic units have been identified. The deep parts of the accretionary complexes are exposed as a low-pressure to high-pressure regional metamorphic belt, which includes the famous Sanbagawa Belt. The Sanbagawa Belt is generally non-eclogitic and consists mainly of meta-sedimentary rocks and mafic schists. Most meta-sedimentary rocks are pelitic to psammistic schists and phylites, with rare metachert (quartz schist) and calcareous schists. However, several eclogite bodies occur in the Besshi and Kotsu areas on Shikoku Island (Okamoto and others, 2000; Ota and others, 2004; Utsunomiya and others, 2011). Conspicuous Miocene granitic rocks also occur on the Pacific side of SW Japan. These granitoids intrude into the Cretaceous and Tertiary accretionary complexes, and they were likely produced by remelting of the Shimanto accretionary complex (Stein and others, 1996; Shinjoe, 1997). In the Inner Zone (fig. 1), Cretaceous to Paleogene granitoids are extensively distributed. Note that the majority of granitic intrusions were emplaced in the Cretaceous, and they intruded into the pre-Cretaceous accretionary complexes which include regional metamorphic rocks. The intrusive granitoids are associated with F1 60 BJ06-204 R12915 15 1.9 R12911 15 1.9 BJ03-2 BJ06-201a 85 72TO-287 BJ06-202b 85 85 6910-157A 85 6910-105 74 TKM 3 74 74 TKM 2 TKM 6 74 TKM 1 67 64 6911-211 74 64 75T-175A TKM 4 64 6911-213 TKM 5 72 Age (Ma) 70N-508 Sample No. Hotaka Dake area, Japan Alps Hotaka Dake area, Japan Alps Kashiwajima, SW Shikoku Kashiwajima, SW Shikoku Shimanto Belt, S coast Shikoku Miyoshi mine area Kaneishi quarry, Hirukawa Odou rive dam-site, Ohtsu Misuji water-fall, Ohtsu Miyamachi, Shigaraki-cho Kouga Golf, Kozai-cho Kouga Golf, south end Myokanji, Kozai-cho Takamatsu-cho, Okayama Miyoshi mine gulch, Okayama Sosha, Okayama Matsuda quarry, Naegi Iwamoto quarry, Hirukawa Shinden, Hirukawa Locality Table 1 mélange belt Takidani Takidani S Okayama S Okayama S Okayama S Okayama Tanakami Tanakami Tanakami Tanakami Tanakami Tanakami Naegi West Naegi West Naegi West Naegi East Pluton name or formation mudstone gt-bio granite hb-bio granodiorite hb-bio granodiorite bio granite fine biotite leucogranite fine biotite granite very fine leucogranite med. biotite granite co. biotite granite co. biotite granite fine biotite granite fine biotite granite co. biotite granite hb-bio granite co. biotite granite med. biotite granite med. biotite granite biotite granite Rock type 21.6 209 34.9 4.99 7.63 458 137 102.9 126.5 126.2 148 141 295.1 107 80.1 328.3 9.17 10.0 163.2 3.87 3.21 3.38 1.05 0.706 177 122 114 2.62 42.3 7.74 65.9 18.8 209 6.34 188 67.5 77.4 Sr 8.61 86 Rb 87 4.80 101.5 5.40 14.6 12.6 68.5 383 390 148 307 354 260 176 340 223 346 338 335 204 [Rb] [Sr] (ppm) (ppm) Sr 137 141 148 12 12 13 11 13 80.1 107 9 8 8 11 16 22 26 458 383 390 148 307 354 260 9 10 340 176 6 7 8 20 9 ±2σm 223 346 338 335 Sr 204 86 87 0.71242 0.70797 0.70797 0.70732 0.70748 0.70708 0.70904 0.70998 0.70671 0.71337 0.70849 0.70737 0.71052 0.69855 0.71108 0.70757 0.70853 0.70811 0.70810 I(Sr) 85 86 86 50 83 67 72 97 71 108 64 65 64 73 85 86 87 77 85 68 75 106 71 119 64 66 65 81 4.72 7.13 6.93 6.07 4.03 7.87 7.20 7.29 4.75 6.90 12.60 5.84 6.22 7.60 6.21 9.25 7.18 7.10 7.06 25.49 32.46 30.83 29.52 19.85 22.20 21.80 22.09 21.64 22.29 33.67 22.44 25.92 21.69 24.23 25.47 23.50 23.09 31.94 TM (Ma) [Sm] [Nd] TM (Ma) (I = 0.708) (I = 0.707) (ppm) (ppm) 0.1119 0.512329 0.1328 0.512393 0.1359 0.512387 0.1243 0.512469 0.1227 0.512462 0.2132 0.512446 0.1997 0.512427 0.1995 0.512419 0.1327 0.512400 0.1871 0.512147 0.2283 0.512185 0.1572 0.512145 0.1450 0.512048 0.2118 0.512257 0.1548 0.512084 0.2195 0.512223 0.1847 0.512198 0.1858 0.512220 144 Nd 143 Nd Nd 0.1335 0.512175 Sm 144 147 6 8 12 14 6 5 4 4 5 6 14 6 4 5 5 4 7 4 3 -6.0 -4.8 -4.9 -3.3 -3.4 -3.7 -4.1 -4.3 -4.6 -9.6 -8.8 -9.6 -11.5 -7.4 -10.8 -8.1 -8.6 -8.2 -9.0 -5.4 -4.7 -0.43 -0.32 -0.31 -0.37 -3.3 -4.8 -0.38 0.08 0.02 0.01 -0.33 -0.05 0.16 -0.20 -0.26 0.08 -0.21 0.12 -0.06 -0.06 -0.32 1614 1580 1581 1756 1661 1800 1268 1281 1220 1699 1229 1424 1492 1160 1152 1306 1232 1245 1099 1108 134373 1256 7699 7675 1409 5660 -10456 1694 2696 2433 58909 1557 2743 -26628 1621 4939 5014 1848 TDM-1 TDM-2 f (Sm/Nd) (Ma) (Ma) -3.4 -3.9 -4.1 -4.3 -3.9 -9.5 -9.1 -9.2 -11.0 -7.6 -10.4 -8.3 -8.5 -8.1 -8.5 ±2σm εNd(0) εNd(T) 1214 Sr-Nd isotopic data of granitoids and sediments of accretionary complexes from SW Japan tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:51 Art: Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— 240 180 BJ06-211 BJ06-212 Shimanto Belt, S coast Shikoku Shimanto Belt, S coast Shikoku Shimanto Belt, S coast Shikoku Shimanto Belt, S coast Shikoku Shimanto Belt, S coast Shikoku Jurassic AC in Inuyama Jurassic AC in Inuyama Triassic AC near Inuyama Inuyama area, Aichi Prefecture Locality rhythmic layer rhythmic layer mélange belt mélange belt mélange belt mélange belt mélange belt Pluton name or formation 73.1 siltstone 31.4 409.0 44.8 basaltic sill 35.5 79.1 105.1 82.3 49.0 168.2 mudstone mudstone 37.5 13.9 red chert chert 25.8 siltstone 493.5 161 22.5 red chert siltstone 240.6 [Rb] [Sr] (ppm) (ppm) 38.7 Rock type Sr 86 87 0.723833 0.317 0.708468 0.722299 2.18 0.724548 0.728854 6.71 3.46 0.822 0.709406 0.443 0.708648 0.132 0.706805 6.38 Sr Sr 0.466 0.708632 86 Rb 87 13 11 10 13 12 15 11 11 11 ±2σm 0.70766 0.71486 0.71167 0.71570 0.70871 0.70827 0.70669 0.71839 0.70823 I(Sr) 4.61 6.08 2.66 1.10 1.75 2.12 5.05 4.79 2.80 18.81 28.32 13.29 5.34 7.44 10.93 21.61 23.93 15.17 TM (Ma) TM (Ma) [Sm] [Nd] (I = 0.708) (I = 0.707) (ppm) (ppm) Nd 0.1482 0.512660 0.1298 0.512179 0.1210 0.512447 0.1245 0.512140 0.1422 0.512476 0.1173 0.512452 0.1413 0.512904 0.1210 0.512229 144 143 Nd Nd 0.1116 0.512296 Sm 144 147 6 12 20 6 8 12 6 6 8 0.4 -9.0 -3.7 -9.7 -3.2 -3.6 5.2 -8.0 -6.7 1.5 -6.9 -2.0 -8.1 -2.7 -3.0 5.6 -7.4 -6.0 ±2σm εNd(0) εNd(T) -0.25 -0.34 -0.38 -0.37 -0.28 -0.40 -0.28 -0.38 -0.43 1139 1759 1155 1722 1435 1103 519 1512 1273 826 1570 1129 1625 1112 1116 426 1478 1358 f TDM-1 TDM-2 (Sm/Nd) (Ma) (Ma) (1) Rb-Sr model ages (TM, in Ma) are calculated assuming initial 87Sr/86Sr ratio of 0.708 and 0.707. (2) The one-stage model age (TDM-1) is calculated assuming a linear Nd isotopic growth of the depleted mantle reservoir from εNd(T) ⫽ 0 at 4.56 Ga to ⫹10 at the present time. TDM-1 ⫽ 1/ ln[(143Nd/144Nd)s ⫺ 0.51315]/[(147Sm/144Nd)s ⫺ 0.2137]), where s ⫽ sample, ⫽ decay constant of 147Sm (0.00654 Ga-1). The two-stage model age (TDM-2) is obtained assuming that the protolith of the granitic magmas has a Sm/Nd ratio (or fSm/Nd value) of the average continental crust (Keto and Jacobsen, 1987). TDM-2 ⫽ TDM1 ⫺ (TDM1 ⫺ t)(fcc ⫺ fs)/(fcc ⫺ fDM), where fcc, fs, fDM ⫽ fSm/Nd are values of the average continental crust, the sample and the depleted mantle, respectively. In our calculation, fcc ⫽ ⫺0.4 and fDM ⫽ 0.08592 are used, and t ⫽ the intrusive age of granite. To obtain meaningful model ages, TDM were calculated for samples with f(Sm/Nd) ranges from ⫺0.2 to ⫺0.6 (Wu and others, 2002). co ⫽ coarse, med ⫽ medium, hb ⫽ hornblende, bio ⫽ biotite, gt ⫽ garnet. 180 60 BJ06-208 180 60 BJ06-207b BJ06-209 60 BJ06-210 60 BJ06-206 60 BJ06-205 BJ06-207a Age (Ma) Sample No. Table 1 (continued) tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:51 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1215 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1216 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— Granitoid Accretionary complex Metamorphic belt Hida Tertiary Cretaceous - Tertiary Jurassic - Cretaceous Cretaceous Jurassic - Cretaceous Pre-Jurassic Jurassic Pre-Jurassic 4 1 ultramafic rock 6 11 Sedimentary rock Cenozoic volcanic rock 2 Oki 12 n Sani Cretaceous volcanic rock 5 San yo Takidani 8 ke o Ry 12 7 10 6 8 3 8 8 MTL 9 200 km Kashiwajima Fig. 1. General geologic map of SW Japan. The Median Tectonic Line (MTL) separates the granitoiddominated terrane to the north from the Mesozoic-Cenozoic accretionary wedge to the south. The granitoid terrane is divided into three granitic belts (Ryoke, Sanyo and Sanin) based on the type of mineral deposits and oxygen fugacity (Ishihara, 1971). New isotopic analyses were done on granitic rocks from the Sanyo Belt, a small granite pluton (or plug) at Kashiwajima on SW Shikoku Island, and the Takidani granodiorite of the Japan Alps. Their localities are given in table 1. The numerals in yellow circles correspond to the following literature data sources with the localities of study areas given in Appendix 1: (1) Arakawa (1990), Arakawa and Shimura (1995), (2) Arakawa (1989), Arakawa and Shimura (1995), (3) Fujii and others (2000), (4) Iizumi and others (2000), (5) Ishioka and Iizumi (2003), (6) Kagami and others (1992), (7) Kagami and others (2000), (8) Morioka and others (2000), (9) Nakajima and others (2004), (10) Shinjoe (1997), (11) Takagi and Kagami (1995), (12) Terakado and Nohda (1993). coeval rhyolites and ignimbrites even though much of this cover series has been eroded to expose the intrusive rocks. In addition, a few collisional belts, or nonaccretionary units (Hida and Oki belts, fig. 1), occur in the northern part, and they are composed of polymetamorphic gneiss and schist complexes, with Triassic (230 Ma) regional metamorphism of intermediate pressure facies (Komatsu, 1990). Ishihara (1971) made a detailed study of the granitoids and associated ore deposits. He divided the Inner Zone into three metallogenic provinces, from south to north, a Barren, a Tungsten, and a Molybdenum Province (see also Ishihara and Murakami, 2006). The three provinces correspond to the Ryoke, Sanyo and Sanin Belts as delineated by Murakami (1974) on the basis of granite petrography and age data. Subsequently, in a study of opaque mineral in the granitoids, Ishihara (1977) classified the Sanin Belt as belonging to the magnetite-series, whereas the two other belts belong to the ilmenite-series. The magnetite-series rocks contain higher Fe2O3/FeO ratios than the ilmenite-series rocks. The lithological types in the Inner Zone are more extensive than granitoids and acid volcanic rocks alone. In fact, the Ryoke belt is a plutonic-metamorphic terrane that comprises unmetamorphosed pre-Cretaceous accretionary complexes with highlevel granites, as well as high-grade, but low P/T, metasediments with migmatites and C O L O R tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1217 gneissic granites. Granitic rocks are dominant over metamorphic rocks. Based on the apparent along-arc variation of isotopic ages, it has been suggested that the Ryoke and Sanyo granitoids were produced by Cretaceous subduction of the Kula-Pacific ridge and that the magmatism migrated eastward with passage of the ridge along the SW Japan margin (for example, Nakajima, 1994). However, such eastward migration of magmatic activities has not been verified. Isozaki and others (2010) described that the continental side of the MTL (⫽ Inner Zone) is composed of a 15 km-thick lower crust of unknown composition, a 20 km-thick granitic upper crust and thin roof-pendants of Paleozoic to Jurassic AC (⫹meta-AC) units at the surface. These AC units are characterized by subhorizontal stacks of multiple fault-bounded units, previously recognized as “nappes,” with a gentle dip towards the Eurasian continent. sample descriptions In this paper new Sr-Nd isotopic analyses (table 1) of samples, including granitoids, siltstones and cherts, are used in graphic representations. The collection of these samples was not systematic and different samples serve different purposes. The new data only supplement the existing large dataset in the literature used in this paper (see Appendix 1). The granitic rocks were collected by S. Ishihara from four plutons (Naegi East, Naegi West, Tanakami, and S. Okayama) of the Sanyo Belt, SW Japan. The age information was obtained from the literature. The Naegi granites were dated at 64 to 72 Ma (K-Ar mineral ages) by Ishihara and others (1988). The Tanakami granites have K-Ar biotite ages of 73.3 and 74.7 Ma for the central part, but 67.9 Ma for the eastern part of the pluton (Sawada and Itaya, 1993). For the granites of the Okayama area, a muscovite greisen from the Miyoshi mine was dated at 86.6 Ma by the K-Ar method (Ishihara and others, 1988), whereas a whole-rock Rb-Sr isochron age of 84 Ma was obtained for the southern Okayama batholith (Kagami and others, 1988). Two hornblende-biotite granodiorite samples from the Takidani pluton of the Japan Alps and two biotite granites from the Kashiwajima pluton of SW Shikoku were also analyzed. The emplacement ages of these granitoids have been firmly established at 1.9 Ma for Takidani and 15 Ma for Kashiwajima by the SHRIMP zircon U-Pb method. The complete geochronological data (zircon U-Pb, zircon fission-track, biotite and K-feldspar Ar-Ar) will be reported in another paper (Jahn and others, in preparation). The Takidani pluton is the youngest plutonic intrusive in the world. In addition, sedimentary rocks from the Shimanto Belt and a Jurassic to Triassic accretionary complex (Inuyama area) were also included for analysis. This was to test the source of the sediments from the “ocean plate stratigraphy,” long considered to be the principal component of the accretionary complexes of Japan. sr-nd isotope data For the new samples, Sr and Nd isotopic compositions were analyzed at the University of Rennes 1 (France) and the Institute of Earth Sciences, Academia Sinica (Taiwan). In both laboratories the analyses were performed using two similar Finnigan MAT-262 Thermal Ionization Mass Spectrometers (TIMS). Mass fractionation was corrected against 86Sr/88Sr ⫽ 0.1194 and 146Nd/144Nd ⫽ 0.7219. All isotopic ratios were finally adjusted against the standard salts of NBS-987 Sr ⫽ 0.710250 and La Jolla Nd ⫽ 0.511860. The in-run precisions as shown in the analytical tables are expressed as 2 standard errors (2 sigma-mean), and they are approximately equal to 0.1 epsilon unit. However, the external precisions based on long-term duplicate analyses on standard salts yielded about 0.4 epsilon unit. All the new and literature Sr-Nd data used in the present paper are summarized in Appendix 1 and further illustrated in figures 2, 3, 4 and 5. Figure 2 shows a plot of initial 87Sr/86Sr ratios as a function of intrusive ages of granitoids and depositional ages of sedimentary rocks (siltstone and mudstone). The new data for granitoids are F2 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1218 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— C O L O R Fig. 2. Initial Sr isotopic ratios (⫽ISr) of granitoids and sedimentary rocks of two accretionary complexes from SW Japan. A line at ISr ⫽ 0.705 is drawn for reference. Granitoids with ISr lower than this line are considered “juvenile” and those with values higher than 0.710 are mainly “recycled.” The proportion of the recycled crustal component increases with increasing ISr values. Data sources: New data (table 1); Kagami and others (1992, 1995), Terakado and Nohda (1993), Arakawa and Shinmura (1995), Stein and others (1996), Shinjoe (1997), Ishioka and Iizumi (2003), Takagi (2004). All the data used in this figure can be found in table 1 and Appendix table. expressed as solid red circles (Sanyo belt and Takidani granodiorite of the Japan Alps) and solid yellow circles (Kashiwajima, Shimanto belt, SW Shikoku). The new analyses of siltstones and cherts from the accretionary complex are shown with solid blue and green circles. The rest are literature data. Based on the dataset of 565 analyses, important points can be outlined as follows: (1) All granitoids are younger than 250 Ma, but the majority of them were emplaced in the Cretaceous (145-65 Ma); Triassic and Jurassic granites are relatively rare. (2) Most granitic rocks are characterized by initial 87Sr/86Sr ratios higher than 0.705, which is a value typically observed for granitoids of the Central Asian Orogenic Belt (for example, Jahn, 2004). (3) Granitoids with initial 87Sr/86Sr ratios lower than 0.705 are mainly from the Jurassic Hida Belt (185-190 Ma), or were emplaced in the Early Cretaceous (140-100 Ma) and Cenozoic (50-10 Ma). The low ratios suggest that these granitic rocks were likely produced by remelting of mantle-derived rocks (gabbros), or a lithological assemblage containing a large proportion of mantle component (accreted ocean plate stratigraphy). (4) The high initial 87Sr/86Sr ratios (ISr value) indicate that the generation of granitic rocks must have involved a participation of much older rocks. That is, a significant proportion of Precambrian crust is required in the source regions for the generation of these granites. Although no Precambrian rocks have been identified in Japan, the presence of protoliths with Precambrian heritage in the middle to lower crust is strongly implied. Figure 3 illustrates the variation of initial 143Nd/144Nd ratios, expressed as εNd(T) values, in the granitic rocks of different ages. Note that the number of data points F3 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1219 C O L O R Fig. 3. Nd isotopic compositions of granitoids and sedimentary rocks from SW Japan. “Juvenile” granitoids are generally characterized by positive εNd(T), whereas granitoids of recycled origin have negative values. Samples show negative values as low as ⫺15. Data sources: New data (table 1), Kagami and others (1992, 1993), Arakawa and Shinmura (1995), Stein and others (1996), Shinjoe (1997), Ishioka and Iizumi (2003), Takagi (2004). (235) is reduced to about a half of the Sr isotope data. However, the distribution of data points, with respect to the reference line of εNd(T) ⫽ 0, form an impressive mirror image of the Sr isotope data (fig. 2). The majority of the data points show negative values. Granitic rocks with a large proportion of mantle component are expected to have positive εNd(T) values, as commonly observed in granitoids of the CAOB or ANS (see later sections), but this is not the case for SW Japan. The scenario shown in figure 3 indicates that most of the granitic rocks were derived by melting of protoliths with a large proportion of recycled crust of Precambrian age. εNd(T) and ISr values are commonly anti-correlated in most rocks. Figure 4 shows that the majority of granitoids from SW Japan fall in the fourth quadrangle of the εNd(T) vs (87Sr/86Sr)o (⫽ISr) diagram, which is segmented by two reference lines—a horizontal zero εNd(T) line (or CHUR, Chondritic Uniform Reservoir) and a vertical line of ISr ⫽ 0.7045 for Earth’s primitive mantle (PM). The data array is very similar to that commonly observed for crustal rocks. Most mantle-derived mafic rocks and “juvenile” granitoids would reside in the second quadrangle, but only a few granitoids of SW Japan are found there. Granitoids of the Hida Belt are distinguished from the bulk of the Japanese granitic rocks and have Sr-Nd isotope compositions close to the reference point of the primitive Earth (⫽ intersection of the two reference lines). The Sr-Nd isotopic characteristics of the Japanese granitoids indicate that they had a long crustal residence time. Figure 5 shows a plot of εNd(T) vs depleted-mantle- F4 F5 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1220 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— C O L O R Fig. 4. εNd(T) vs (87Sr/86Sr)o plot for granitoids and sedimentary rocks from SW Japan. The majority of granitoid data points fall in the fourth quadrangle, suggesting their “recycled” nature. Data sources as in figure 3. based single-stage and 2-stage model ages (TDM-1 and TDM-2). The reason for using the 2-stage model age calculation is that some of the new analyses were obtained on highly differentiated granitic rocks with the lanthanide tetrad effect, which often leads to aberrant very large or negative model ages due to the increase of Sm/Nd ratios in the final stage of differentiation (Jahn and others, 2001). In figure 5, while the intrusive ages of the granitoids are younger than 250 Ma (shown by the yellow band), their model ages are much older, from ca. 700 to over 2000 Ma. This suggests that the protoliths of the granitoids contain a significant proportion of Precambrian crust. The scenario is much the same as that for the Cenozoic sedimentary rocks of Taiwan, to be illustrated in a later section. discussion Together with the Japanese Islands, the Central Asian Orogenic Belt (CAOB) and the Arabian-Nubian Shield (ANS) are three well-known “young” accretionary orogens formed in the Neoproterozoic or later. Therefore, a comparison between the three accretionary orogens in terms of their crustal development could be instructive. Numerous Sr-Nd isotopic analyses have confirmed that much of the crustal mass of the CAOB and ANS is juvenile, produced by melting of accreted island arc assemblages. The process may include melting of mantle peridotites (for basalts and andesites), remelting of mantle-derived basaltic and andesitic rocks, and/or fractional crystallization of basaltic and andesitic magmas (for granitoids). Juvenile crust has substantially contributed to the growth of the continent in the CAOB and ANS (Sengor and others, 1993; Stern, 1994, 2002, 2008; Jahn and others, 2000a, 2000b; Jahn, 2004; Kovalenko and others, 2004; Eyal and others, 2010). tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1221 C O L O R Fig. 5. εNd(T) vs TDM (depleted-mantle-based model ages) plot for granitoids from SW Japan. Because some granites show the REE tetrad effect, which produced aberrant age values in the single-stage TDM calculation, the 2-stage model ages (TDM-2) values for the granitoids are also calculated for comparison (inset). The figure shows that TDM ranges from ca. 700 to 2000 Ma, except for the granitoids of the Hida Belt. Data sources as in figure 3. Comparison with the CAOB The Central Asian Orogenic Belt (CAOB) covers an immense surface area (ca. 5.3 million km2) and spans from the Urals in the west to the Pacific coast in the east. It represents about 11 percent of Asia. NE China is also included even though most of it has been named as the “Manchurides” by Sengor and Natal’in (1996). The Nd isotopic characteristics of granitoids from the different terranes of the CAOB are summarized and illustrated in figure 6. NE China and Inner Mongolia.—In NE China, more than 350 granitic bodies were emplaced in the Great Xing’an (or Khinggan), Lesser Xing’an and Zhangguangcai Ranges, and mostly during Mesozoic times (Wu and others, 2011). The granites are composed mainly of I-type and subordinate A-type granites (Wu and others, 2000, 2002, 2003a, 2003b). They are accompanied by extensive Mesozoic and Tertiary acid volcanic rocks. Isotope tracer analysis and age determination of deep-drill cores from the Songliao Basin in central NE China revealed that the Basin is underlain by granitic rocks and deformed granitic gneisses of Phanerozoic age (Wu and others, 2001). Precambrian zircons have been identified, but they are substantially rarer (Wu and others, 2011). Based on the time-space distribution of the granitic rocks, Wu and F6 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1222 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— 15 15 A NE China I nner M ongolia Hida B elt, J apan Depleted mantle 10 5 5 CH UR 0 ε Nd(T ) εNd(T ) K azakhstan X injiang - A ltai M tns X injiang -J unggar X injiang - A latau M tns Depleted mantle 10 -5 E ar ly-middle P roter ozoic crust -10 CH UR 0 -5 E ar ly-middle P roterozoic crust -10 -15 B -15 -20 -20 Ar chean crust -25 0 100 200 300 400 500 600 700 800 Ar chean cr ust -25 900 1000 0 100 200 300 Intr usive Age (M a) 15 Depleted M antle 10 400 500 600 700 800 900 1000 Intr usive Age (M a) 15 C 10 Post-collisional granites (CAOB) D Depleted Mantle 5 CH UR 0 -5 ε Nd(T) ε Nd(T ) 5 E ar ly-middle P roter ozoic crust 0 -10 -10 -15 -15 C aledonides Hercynides Pr e-Riphean (in Caled) Pr e-Riphean (in Hercy ) -20 -25 0 100 200 300 400 CHUR -5 Early-middle Proterozoic crust NE China East Junggar Inner Mongolia Transbaikalia W Altai-Sayan Ar chean crust -20 Archean crust Data: Kovalenk o and others (1996) 500 600 700 Intr usive Age (M a) 800 900 1000 -25 100 150 200 250 300 350 400 450 500 Intrusive Age (Ma) Fig. 6. εNd(T) vs. intrusive ages of granitic rocks from the Central Asian Orogenic Belt. Data sources: (A) NE China (Wu and others, 2000, 2002; Jahn and others, 2001), Inner Mongolia (Chen and others, 2000), and Hida Belt (Arakawa and Shimura, 1995; Arakawa and others, 2000). (B) Kazakhstan (Heinhosrt and others, 2000; Kröner and others, 2008), Xinjiang—Altai Mountains (Zhao and others, 1993; Wang and others, 2009), Junggar (Han and others, 1997; Chen and Jahn, 2002), Alatau (Zhou and others, 1995). (C) Data for Mongolia and Transbaikalia (Kovalenko and others, 1996, 2004). (D) Post-collisional granites (NE China: Wu and others, 2002; East Junggar: Chen and Jahn, 2002; Inner Mongolia: Hong and others, 1996; Jahn, unpublished; Transbaikalia: Jahn and others, 2009; western Sayan-Gorny Altai: Kruk and others, 2001). others (2011) suggested that the Jurassic granites in the Zhangguangcai Range were probably related to Paleo-Pacific plate subduction, whereas the Early Cretaceous granites in the Great Xing’an Range resulted from delamination or extension of the previously thickened lithosphere. In Inner Mongolia, several periods of granitic intrusion took place from Devonian to Jurassic times. The samples used in this study came from a Paleozoic anorogenic A-type suite (280 Ma; Hong and others, 1995, 1996), an arc-related calc-alkaline magmatic belt composed of gabbroic diorite, quartz diorite, tonalite and granodiorite (SHRIMP zircon age ⫽ 309 ⫾ 8 Ma, Chen and others, 2000) and a Mesozoic collision-type granitic suite comprising monzogranite (adamellite), granodiorite and leucogranite (Rb-Sr isochron age of 230 ⫾ 20 Ma; Chen and others, 2000). Figure 6A shows that the majority (75%) of the samples have positive εNd(T) values. Most of the samples with negative εNd(T) values came from the Precambrian Jiamusi Massif (εNd(200 Ma) ⫽ ⫺7 to ⫺12). Such a close relationship between the isotopic compositions of granitoids and the ages and nature of their intruded “basement” rocks is also demonstrated by the granitoids from northern Xinjiang (Hu and others, 2000) and Mongolia (Kovalenko and others, 1996, 2004; Jahn and others, 2004). The lowering of the εNd(T) values was effected by the participation of old crustal rocks in their magma genesis. C O L O R tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1223 Xinjiang and Kazakhstan.—A variety of Phanerozoic granitoids occur throughout northern Xinjiang. As for the case of NE China, the majority of granitoids have positive εNd(T) values which suggest a dominance of the mantle component in the generation of these rocks (fig. 6B). This is particularly true for the granitoids from the E and W Junggar terranes (Zhao and others, 1993; Han and others, 1997; Chen and Jahn, 2004). The Junggar Basin is covered by Cenozoic desert sands and thick continental basin sediments (ⱖ10 km) of Permian and younger ages. Drilling records indicate little deformation within the basin, suggesting stability of the basement at least since the Permian (Coleman, 1989). The nature of the Junggar basement has been much debated; some consider that it represents a micro-continent with Precambrian basement (Wu, 1987), whereas others regard it as trapped Paleozoic oceanic crust of various origins (Feng and others, 1989; Hsü, 1989; Coleman, 1989; Carroll and others, 1990). Surrounding the Junggar Basin are exposed numerous ophiolites in the East and West Junggar terranes, as well as in its southern margin. These terranes can be appropriately referred to as “island-arc assemblages,” and no rocks of Precambrian age have been documented. Coleman (1989) considered these terranes as oceanic arc assemblages, and compared them with those in the present western Pacific. Based on a trace-element and Sr-Nd isotopic study, Chen and Jahn (2004) concluded that the basement is most likely underlain by Early to Middle Paleozoic arc rocks and oceanic crustal assemblages that were trapped during the Late Paleozoic tectonic consolidation of Central Asia. This is consistent with the very young model ages ranging from 400 to 1000 Ma (400 to 600 Ma in a two-stage model) for the Junggar granites (fig. 6B). Also shown in figure 6B, the granitoids emplaced in the Chinese Altai composite terrane show a wide range of isotopic composition and model ages (Hu and others, 2000; Wang and others, 2009). A tight relationship between the isotopic compositions of granitoids and the nature of their basement rocks can be established. The Sm-Nd isotope study by Hu and others (2000) revealed that the basement rocks of the Altai and Tianshan were largely produced in the Proterozoic. The parallel manifestation of isotopic compositions and model ages between basement rocks and intrusive granites argues for the significant role of crustal “contamination” in the genesis of the Phanerozoic granitoids. An implication is that the presence of old Precambrian microcontinents is significant in the accretionary history of Central Asia (Kröner and others, 2007). A more quantitative study on the proportion of the mantle component in the crust of the Altai Mountains was presented by Wang and others (2009). Heinhorst and others (2000) undertook a comprehensive study of mineralization in association with a variety of magmatic rocks in east-central Kazakhstan. Although the types of mineralization (Au, Cu, rare-metal, or REE) may be related to a particular magmatic suite or a lithological variety, most granitic rocks have positive εNd(T) values irrespective of their bulk compositions and types of mineralization (Heinhorst and others, 2000). The granitoids were intruded in several episodes: 450 and 300 Ma for magmatic suites with gold mineralization, about 300 Ma for granitoids with rare-metal mineralization, and ca. 250 Ma for A-type granites with REE mineralization. There is a slight tendency for an increase of εNd(T) with younger ages of the rocks. Single-stage model ages for all cases are between 400 and 1500 Ma. Mongolia and Transbaikalia.—Figure 6C shows the Nd-Sr isotopic compositions of granitoids from the northern belt of central Mongolia to Transbaikalia. This area has been extensively studied by Kovalenko and others (1996, 2004). These authors delineated four isotope provinces (Precambrian, “Caledonian,” “Hercynian,” and “Indonesian”), which coincide with three tectonic zones of corresponding ages for the northern belt of the CAOB, and with one (Indonesian) in Inner Mongolia and NE China (Kovalenko and others, 2004). The Transbaikalian and northern Mongolian terranes roughly correspond to the “Barguzin” belt and “Caledonides” of Kovalenko and others (2004). The Baydrag tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1224 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— terrane is the only early Precambrian microcontinent containing granulitic and amphibolitic gneisses of Archean age. The Barguzin Belt and the Hangay-Hentey Basin are known to be “composite” terranes comprising Proterozoic and Phanerozoic formations. The Hangay-Hentey Basin is intruded by impressive amounts of Early Palaeozoic to Mesozoic granitoids. The granitoid belt extends to Transbaikalia and further to the Sea of Okhotsk. As shown in figure 6C, the Phanerozoic granites emplaced into “Caledonian” and “Hercynian” provinces have positive εNd(T) values, suggesting their juvenile characteristics, whereas those intruded into the Baydrag and the composite terranes (Barguzin and Hangay-Hentay) show εNd(T) values from positive to negative, indicating variable contributions of Precambrian crust in the generation of the granitic rocks. Note that some Late Neoproterozoic to Early Palaeozoic granites (600-500 Ma) have εNd(T) values as high as ⫹10, suggesting their derivation from an almost pure depleted mantle component (⫽100% basaltic and/or andesitic source). Most plutons and batholiths of the CAOB have calc-alkaline characteristics typical of subduction zone magmatism, but the emplacement of voluminous granites of the alkaline and peralkaline series also deserves attention. Petrogenetically, these rocks are akin to the A-type granites, which are generally known to form in post-collisional extensional environments (for example, Jahn and others, 2009). Figure 6D summarizes the isotopic characters of this kind of granite from the CAOB. The majority of these rocks possess positive εNd(T) values; only a few show negative values. All of them have young model ages (TDM) from 500 to 1300 Ma. This indicates that the source of post-accretionary granitoids in the CAOB is dominated by the mantle-derived component. Comparison with the ANS The Arabian-Nubian Shield (ANS) is well-known as one of the best examples for crustal growth in the Neoproterozoic. The crust of the ANS is essentially juvenile formed by protracted accretion of island arc terranes (Bentor, 1985; Stern, 1994, 2002; Stein and Goldstein, 1996; Meert, 2003; Jarrar and others, 2003; Johnson, 2003; Johnson and Woldehaimanot, 2003; Stoeser and Frost, 2006; Stern and others, 2010). Island arc accretion is thought to have ended in the ANS by ⬃700 Ma and was followed by continental collision at 640 to 650 Ma (Stern, 1994, 2002, and references therein). The Late Neoproterozoic post-collisional stage of tectonomagmatic evolution of the ANS commenced at ⬃640 Ma. Transition from collision to extension occurred at ⬃600 Ma (Stern, 1994; Garfunkel, 1999; Genna and others, 2002; Jarrar and others, 2003) and was finally followed with a stable craton and platform setting (Garfunkel, 1999). The evolution of the ANS (⬃820 to 570 Ma) involved vast amounts of granitoid magmatism, thought to be well correlated with the changing tectonic setting (Bentor, 1985; Stern and Hedge, 1985; Bentor and Eyal, 1987; Kröner and others, 1990; Stern, 1994; Garfunkel, 1999; Moghazi, 1999, 2002; Jarrar and others, 2003, 2008; Johnson, 2003; Johnson and Woldehaimanot, 2003; Katzir and others, 2007b; Stern and others, 2010). Four stages of magmatic activity are recognized: (1) island arc magmatism including early medium-K calc-alkaline plutons (now gneisses) and metavolcanic rocks occurred at ⬃820 to 740 Ma; (2) late syn-collisional medium- to high-K calc-alkaline granitoids and gabbro that bear evidence for penetrative deformation and low-grade metamorphism intruded at ⬃670 to 635 Ma; (3) the most voluminous post-collisional (undeformed) high-K calk-alkaline gabbro-granodiorite-granite suite formed at ⬃640 to 610 Ma; and (4) within-plate alkaline and peralkaline granite suites preceded by intensive bimodal volcanism at ⬃600 to 550 Ma. Eyal and others (2010) recently conducted a petrological and geochemical study of 27 calc-alkaline and alkaline plutons/complexes and one dike swarm from the Sinai Peninsula, in the northern part of the ANS. Granites of the alkaline suite were studied in 16 plutons ranging in size from 1 to 400 km2, some of which are central plutons in tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1225 ring complexes. The most celebrated example is the Katherina ring complex (Katzir and others, 2007a), in which granite is intrusive into volcanic rocks and ring dikes and often shows miarolitic texture, indicating crystallization at shallow depth. The majority of alkaline plutons are composed of syenogranite, alkali feldspar granite and peralkaline granite. The granitoids from the northern ANS were emplaced during the period of ca. 750 to 550 Ma. The available Sm-Nd isotope data indicate that all the rock types are characterized by positive εNd(T) values with no exception (figs. 7A, 7B, 7C, and 7D). Two-stage model ages vary from ca. 860 to 1200 Ma for the calk-alkaline suite, and from ca. 800 to 1100 Ma for the alkaline suite. Single-stage model ages are quite similar to the two-stage model ages, suggesting that fSm/Nd values for most rocks are close to that of the average continental crust (ca. ⫺0.4). The Nd model ages suggest that little Archean or early Proterozoic rocks exist in the lower to middle crust of the northern ANS. This inference is supported by the U-Pb dating of individual zircon grains from various plutonic rocks (Be’eri-Shlevin and others, 2009). The petrogenesis and sequence of emplacement for the alkaline and post-collisional granitoids from the Sinai Peninsula have been discussed in detail by Eyal and others (2010). Comparison Between Japan, CAOB and ANS The distinction in Nd isotopic composition between the granitoids formed in the three classic accretionary orogens (Japan, CAOB, and ANS) is clearly demonstrated. The entirely positive εNd(T) values for the ANS granitoids suggest that they were produced by partial melting of mantle-derived protoliths with little contribution from much older rocks. More specifically, granitoids were generated by differentiation of mantle-derived dioritic magma in the early stage of arc formation; by remelting of mantle-derived arc rocks in later stages, with only very small amounts of PreNeoproterozoic crustal component; and by remelting of underplated basic rocks in post-orogenic stages. The dominance of positive εNd(T) values for the CAOB granitoids indicates that most granitoids are “relatively juvenile,” and that others have witnessed a greater contribution from Archean to early Proterozoic micro-continents, hence producing granitoids with negative εNd(T) values. By contrast, the granitoids from SW Japan have dominantly negative εNd(T) values and relatively high initial 87Sr/86Sr ratios (⬎0.707), suggesting involvement of a significant amount of recycled crustal rocks. Their formation and emplacement in Japan do not imply a net growth of the continental crust. If the granitoids were derived by partial melting of accreted terranes, it suggests that the essential component of the accreted material is recycled crust of ultimately Precambrian derivation. In fact, abundant clasts of Proterozoic granites and gneisses (up to 1.8 Ga of age) were found in the Jurassic conglomerate of the Mino-Tanba accretionary complex (Shibata and Adachi, 1974). Maruyama (1997) hypothesized that the most important cause of the orogeny in SW Japan is the subduction of an oceanic ridge, by which the continental mass increases through the transfer of granitic melt from the subducting oceanic crust to the orogenic belt. The present analysis of Sr-Nd isotopic data does not support such a hypothesis. Comparison with SE China and Taiwan While the Nd isotopic characteristics of the Japanese accretionary orogen can be distinguished from those of the CAOB and ANS, they are surprisingly comparable with that of well-known “collisional orogens,” such as the Caledonides and Hercynides of western Europe (Jahn and others, 2000a, 2000b; Jahn, 2004), the Paleozoic to Mesozoic orogens of SE China, and the Cenozoic orogen of Taiwan. Chen and Jahn (1998) made a synthesis of the crustal evolution in SE China based on extensive Nd and Sr isotopic data compiled from the pre-1998 literature for intrusive granitoids, volcanic, sedimentary and metamorphic rocks from three major tectonic units of SE F7 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1226 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— 12 10 8 Southern Israel 6 εNd(T) A DM Elat schists 4 2 granitic gneisses 0 CHUR -2 -4 Granitoids & rhyolites Mafic dikes and trachydolerites Elat schists -6 -8 -10 0 100 200 300 400 500 600 700 800 900 1000 Age (Ma) 12 10 8 Southwestern Jordan 6 εNd(T) B DM Araba Complex 4 Aqaba Complex 2 0 CHUR -2 -4 Granitoids of Aqaba Complex A-type granites - Humrat-Feinan suite Monzogabbro, monzodiorite, Q monzodiorite -6 -8 -10 0 100 200 300 400 500 600 700 800 900 1000 Age (Ma) Fig. 7. εNd(T) vs. intrusive ages of granitic rocks from the northern part of the Arabian Nubian Shield. (A) Southern Israel (Data sources: Beyth and others, 1994; Stein and Goldstein, 1996; Mushkin and others, 2003). (B) SW Jordan (Jarrar and others, 2003). C O L O R tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1227 Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 12 10 Sinai Peninsula Egypt 8 6 εNd(T) C DM 4 2 0 CHUR -2 -4 Granitoids of Katherina Complex Granitoids - Kid area (SE Sinai) Syenogranites - Kid area -6 -8 -10 0 100 200 300 400 500 600 700 800 900 1000 Age (Ma) 12 10 Eastern Desert Egypt 8 6 εNd(T) D DM 4 2 0 CHUR -2 Granites - Wadi El-Imra district Gabbro-diorite complex Wadi El-Imra district Granitoids - Gebel El-Urf area -4 -6 -8 -10 0 100 200 300 400 500 600 700 800 900 1000 Age (Ma) Fig. 7. (continued) (C) Sinai Peninsula (Katherina Complex: Stein and Goldstein, 1996; Katzir and others, 2007a, 2007b; Eyal and others, 2010. Kid area, SE Sinai: Moghazi and others, 1998). (D) Eastern Desert (Wadi El-Imra: Furnes and others, 1996; Gebel El-urf area: Moghazi, 1999). Data compilation by Boris Litvinovsky. C O L O R tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1228 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— C O L O R Fig. 8. (A) εNd(T) vs. intrusive age plot of granitic rocks from the South China Block (Yangtze and Cathaysia). Data sources: Chen and Jahn, 1998 and references therein; additional data from Hsieh and others (2008), Jiang and others (2009), Li and others (2007), Wan and others (2010), Wang and others (2007), Yu and others (2007). (B) εNd(T) vs. model age plot of granitic rocks from South China Block. Data sources as for (A). tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1229 China: Dabie, Yangtze and Cathaysia. In the present compilation, literature data published since 1999 are included with the pre-1998 data. The combined data are illustrated in figure 8. Phanerozoic granitoids from SE China were emplaced from about 470 to 80 Ma, and are characterized by negative εNd(T) values from ⫺17 to about 0, with a few exceptions (fig. 8A). The granitoids have depleted-mantle-based model ages (TDM) of 500 to 2800 Ma, but are mainly in the range of 1000 to 2200 Ma (fig. 8B). The model age data indicate that the most important crustal formation events took place in the Proterozoic, possibly with a very minor proportion produced in the Late Archean. I defend this statement even though an increasing number of Archean zircon grains have been identified in recent years in the Yangtze craton (for example, Zheng and others, 2006; Zheng and Zhang, 2007). In summary, the crustal evolution in SE China, including the Yangtze Craton and Cathaysia, is distinctly different from the Archean-dominated North China Block (Chen and Jahn, 1998). Interestingly, the ranges of εNd(T) and TDM are very similar to those of the Hercynian and Caledonian belts in Europe (Jahn and others, 2000a, 2000b; Jahn, 2004). The island of Taiwan is geologically young. The oldest rocks are the marble sequences from the Tanan’ao Complex in the east and from the “Peikang High” in the west of the island, which were dated at about 250 Ma using their Sr isotopic compositions and the Pb-Pb isochron technique (Jahn and others, 1992). Granitic intrusions are rare. A few small plutons of Cretaceous granitoids were emplaced in the Tanan’ao Complex, whereas a small Jurassic granite stock occurs within the schist belt of the southern Central Range (Yui and others, 2009). The mountain belts were formed by the collision between the Eurasian and the Philippine Sea plates. A close geological correlation between Taiwan and SE China has long been established using geochronological and geochemical data of the Mesozoic granitoids and the Late Permian carbonates (Jahn and others, 1986, 1990, 1992; Lan and others, 1996, 1997, 2002, 2008; Chen and Jahn, 1998; Yui and others, 2009). Figure 9 summarizes the Nd isotopic composition and model ages of granitoids and metasedimentary rocks from Taiwan. The main figure is a plot of εNd(T) vs one-stage model age (TDM-1), whereas the inset is a plot of εNd(T) vs two-stage model age (TDM-2). In both representations, the εNd(T) values are shown to vary from zero to ⫺16, except for four analyses of the Early Jurassic granites (191 Ma) from Taiwan (Yui and others, 2009). Single-stage model ages vary from 700 to 2000 Ma. This scenario is surprisingly similar to that of SW Japan (fig. 5). The Sm-Nd isotopic data of sedimentary rocks from Japan and Taiwan are shown in figure 10 for comparison. In this figure, lines radiating from the depleted mantle reference point (DM) represent calculated model ages (TDM). The model ages of sediments from Taiwan range from ca. 1200 to 2300 Ma, whereas those from Japan show a wider range from 700 to 2600 Ma. The younger model ages of Japan indicate that these sedimentary rocks contain a higher proportion of the mafic component from the “ocean plate stratigraphy.” Nevertheless, the dominance of model ages between 1200 to 2500 Ma suggests that the sedimentary rocks represent recycled Precambrian protoliths. Note that recent zircon geochronology of the Cenozoic sedimentary rocks in Taiwan has revealed many zircon grains of Archean age (Shao and others, 2010). In fact, the Cenozoic accretionary wedge of Taiwan is dominated by sediments of Cathaysian derivation. tectonic implications Since the early Paleozoic, westward subduction of the Paleo-Pacific plate has governed the tectonic evolution of the eastern Eurasian margin by building wide belts of accretionary wedge along trench and plate-marginal volcanic-plutonic belts (Isozaki, 1996, 1997; Kimura, 1997; Maruyama, 1997; Maruyama and others, 1997; Isozaki and others, 2010). In the preceding sections, only SW Japan was discussed because the pattern of crustal growth of the Paleozoic to Mesozoic accretionary complexes is best exemplified in SW Japan, due to the rapid Quaternary uplift and erosion of the F8 F9 F10 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1230 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— C O L O R Fig. 9. εNd(T) vs. model age plots of granitoids and metasedimentary rocks from Taiwan. (A) TDM-1 model ages are calculated with a single-stage model in which the Sm/Nd ratio of a rock is assumed to be identical to that of its protolith. (B) TDM-2 model ages are obtained with a two-stage model in which the protolith of the first stage is assumed to have evolved as the average continental crust with 147Sm/144Nd ⫽ 0.12, or f(Sm/Nd) ⫽ ⫺0.4 (see footnote of table 1). Data sources: Chen and others (1990), Lan and others (2008). Because some granites show the REE tetrad effect, which produced aberrant age values in the single-stage TDM calculation, the 2-stage model ages (TDM-2) values are also calculated for comparison (B). Cenozoic cover. SW Japan is composed, from the continental side to ocean, of nine accretionary complex units (Oeyama, Renge, Akiyoshi, Suo, Ultra-Tanba, Mino-TanbaChichibu, Sanbagawa, Northern Shimanto and Southern Shimanto belts (Isozaki and others, 2010). The units have almost the same rock assemblages of the “ocean plate stratigraphy,” including MORB-type basalt, chert, hemipelagic mudstone, limestone, turbidite or sandstone and conglomerate. The ocean plate stratigraphy records the history of sedimentation on the ocean floor as it travels from a ridge to a trench. In the scheme of tectonic evolution presented by Isozaki (1996) and Maruyama (1997), Mesozoic granitoids appear to be generated by melting of the subducted oceanic crust (see fig. 11), or produced in the middle to lower crust apparently overlain by the accretionary complexes. However, it is not clearly shown whether the protoliths of the granitoids were the accretionary complexes or the old Yangtze lower crust. The idea of slab melting for the genesis of the vast amounts of granitic rocks (Maruyama, 1997) was deemed unlikely from the present analysis. The revelation of the dominantly Precambrian heritage for granitoids of SW Japan is critical to the tectonic reconstruction of the Japanese Islands. An important question is why, in terms of the Sr-Nd isotopic compositions, the Japanese accretionary orogen is so different from other accretionary orogens, such as the CAOB and ANS. By contrast, the accretionary orogens of SW Japan are more comparable with the F11 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1231 C O L O R Fig. 10. Comparison of Sm-Nd isotopic compositions of sedimentary and metasedimentary rocks from Taiwan and Japan. Lines radiating from DM (depleted mantle) represent depleted mantle model ages (single-stage model). The data for Japan (Kagami and others, 2006) are more scattered than the data for Taiwan. The “young” sediments (500-1000 Ma) of Japan are likely to contain more materials from the ocean plate stratigraphy, such as siltstones from the early Tertiary accretionary complex of the Shimanto Belt in southern Shikoku. collisional orogens in SE China, Taiwan, and even the European Caledonides and Hercynides. On the other hand, the similarity of isotopic signatures between Japan and SE China supports the models of tectonic evolution and paleogeographic position of proto-Japan proposed by Maruyama and others (1997) and Sengor and Natal’in (1996). Both models proposed that the Pre-Cenozoic accreted terranes were developed along the continental margin of SE China (fig. 11). According to Maruyama and others (1997), the Ryoke low P/T and the Sanbagawa high P/T belts, as well as the Shimanto accretionary complex, began to develop close to the present coast of SE China in the Late Cretaceous (ca. 90 Ma). In the model of Sengor and Natal’in (1996), the South Japan microcontinent was initially separated from SE China (near Fujian) in the Early Jurassic (ca. 160 Ma). By 145 Ma, at the Jurassic/Cretaceous boundary, the constituent terranes of the microcontinent began to migrate northeastwards by transpression. They arrived and docked at the Eurasian margin to the east of the “Manchurides” in the Oligocene. The Japan Sea was later opened and thus rearranged and formed the essential framework of the present Japanese Islands. If the two models as described above are accepted, the similar Nd isotopic signatures between SW Japan, SE China and Taiwan can be satisfactorily explained. The terranes or tectonic units of SW Japan were thus initially formed at the continental margin of SE China. Since they are part of the South China Block, the granitoid formation and crustal evolution in SW Japan must have shared the same processes and tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1232 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— C O L O R Fig. 11. Paleogeographic reconstruction of Late Cretaceous Japan at ca. 90 Ma (Maruyama and others, 1997). Note that the Ryoke granitic belt, the Sanbagawa high P/T schist belt and the Shimanto accretionary complex were developed along the continental margin in proximity of SE China. The cross-section depicts a “transfer” of granitic magmas from the subducting slab or melting of the lower crust and possibly the accretionary complexes. conserved similar isotopic signatures. Using the age information, Sr-Nd isotopic signature and geochemical data of the end-Permian marble sequence and Cretaceous granitoids of the Tanan’ao Complex, Jahn and others (1992) hypothesized that the paleogeographic position of proto-Taiwan was situated to the south of Guangdong Province. This hypothesis has later been supported by an exhaustive monazite age study of the Tertiary sandstones of Taiwan (Yokoyama and others, 2007), and a zircon age study of Early Tertiary andesite and rhyolite (Chen and others, 2010). Because the crustal and tectonic development of SW Japan and Taiwan took place in the proximal SE part of the South China Block, their sharing of Sr-Nd isotopic characteristics is clearly explained. conclusions In a recent review on accretionary orogens, Cawood and others (2009) stated that accretionary orogens form at intraoceanic and active continental margin plate boundaries. They include the supra-subduction zone forearc, magmatic arc and back-arc components. They further separated accretionary orogens into retreating and advancing types. The case of Japan is of the retreating type. Similarly, in a discussion on tectonic models for accretion of the Central Asian Orogenic Belt, Windley and others tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1233 (2007) summarized that the CAOB was formed by accretion of island arcs, ophiolites, ocean islands, seamounts, accretionary wedges, oceanic plateaux and microcontinents in a manner comparable with that of circum-Pacific Mesozoic-Cenozoic accretionary orogens. In both syntheses, accretionary orogens appear to consist dominantly of rocks of mantle origin; hence granitoids derived by remelting of these rocks are generally “juvenile.” This is generally true for the CAOB and ANS. However, the present study argues that accretionary orogens could be distinguished by the nature of the accreted lithological assemblages. Orogens with dominantly island arc assemblages would witness generation of granitoids with juvenile characters. This is best exemplified by the granitoids of the ANS and many parts of the CAOB. By contrast, orogens with accretionary complexes with a large proportion of recycled Precambrian crust relative to mantle-derived rocks would produce granitic rocks with a more crustal signature. This is represented by the Japanese Islands. The Sr-Nd isotopic compositions of Japanese granitoids shown in figures 2 to 5 indicate that the source regions varied from dominantly mantle-derived rocks to an assemblage with a large proportion of recycled Precambrian crust. This implies that the proportion of eroded Precambrian crust in the trench to the ocean plate stratigraphy was very variable in the subducted accretionary complexes during the Mesozoic. Alternatively, the accreted fragments, including MORB, basalts of seamounts and ocean plateaux, have not significantly participated in the generation of granitic magmas. In conclusion, accretionary orogens can be distinguished by the nature of accreted lithologic assemblages. The Arabian-Nubian Shield contains the highest proportion of mantle-derived rocks, or island arc suites, and juvenile granitoids. SE Japan shows the opposite scenario. Though the CAOB was mainly developed through accretion of island arcs, it also contains accreted Precambrian continental fragments. This is well demonstrated by the isotopic compositions of granitoids from west-central Mongolia (Jahn and others, 2004; Kovalenko and others, 2004) and the Chinese Altai Mountains (Hu and others, 2000; Wang and others, 2009). Finally, this study demonstrates that, despite the well-documented accretionary complexes (Isozaki and others, 2010), the generation of extensive granitoids in SW Japan was probably dominated by remelting of Precambrian crustal sources underlying the “thin” roof-pendants of accretionary complexes (Isozaki and others, 2010). The oceanic component of the “ocean plate stratigraphy” has not participated to a significant amount in the production of the continental crust in SW Japan. On the other hand, the isotopic data support the idea that proto-Japan was initially developed along the southeastern part of the South China Block, as advocated by several authors (Isozaki, 1996, 1997; Sengor and Natal’in, 1996; Maruyama and others, 1997; Isozaki and others, 2010). acknowledgments This article is dedicated to Professor Alfred Kröner, a highly distinguished scholar and long-time friend, in honor of his 70th birthday. The content of this paper was first presented in 2006 in the second ERAS International Workshop on “Accretionary orogens and Continental Growth,” held at Kochi University, Japan, and convened by Gaku Kimura and Yukio Isozaki. I benefited from discussions with many participants during the meeting. The company of Kazu Okamoto and Aoki-san during the sample collection of Miocene granites at Kashiwajima, SW Shikoku, is highly appreciated. Shunso Ishihara provided a suite of granite samples from the Sanyo belt and the analytical results are used in this paper. Nicole Morin (Rennes), Po-Hsuan Lin and Masako Usuki (Taipei) helped in the laboratory work. Kazu Okamoto taught me some geology of Japan. The assistance of Atsushi Utsunomiya, Qingguo Zhai, and Po-Hsuen Lin in the preparation of this paper is deeply acknowledged. The paper was improved by the comments and suggestions of Michel Faure, Fuyuan Wu and Simon Wilde. This work is supported by NSC-Taiwan grant numbers 96-2116-M-001-004, 97-2752-M-002003-PAE; 97-2116-M-001-011; 98-2116-M-001-009. tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1234 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— Appendix Table A1 Rb-Sr and Sm-Nd isotope data of granitoid rocks (granites, qz-diorite, tonalite, granodiorite, adamelite (monzogranite), adakitic granite, granophyre) from Japan Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) 147 143 144 144 Sm Nd Nd Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 (Ga) (Ga) Arakawa, Y., 1990 Two types of granitic intrusions in the Hida belt, Japan: Sr isotopic and chemical characteristics of the Mesozoic Funatsu granitic rocks. Chemical Geology, 85, 101-117 UB01 195 31.3 650 0.70530 UB06 195 58.3 572 0.70531 UB08 195 50.2 449 0.70528 UB09 195 96.3 281 0.70537 UB10 195 66.9 470 0.70521 UB11 195 142 289 0.70537 UB12 195 142 248 0.70541 ON01234*1 195 53 649 — ON01230*1 195 43.6 746 0.70732 SN102 195 56.81 959.3 0.70725 SN101 195 107.3 547.9 0.70940 SN0-2 195 116 336 0.70979 TG02 195 67.03 532.8 0.70664 TG05 195 100 546 0.70654 YT06 YT07 YT08 YT10 YT14 YT18 YT20 YT21 YT24 YT11 YT28 YT29 IN01 IN02 IN03 YT12 YT19 YT22 YT23 Hd03 Hd04 Hd06 Hd08 Hd09 Hd13 Hd18 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 185 Ng01 Ng02 Ng03 Ng08 185 185 185 185 Hs02 190 Hs03 190 Hs04 190 Hs05 190 Hs108 190 Iori intrusion Ir01 190 Ir02 190 Ir03 190 Ir04 190 Ir05 190 Ir06 190 Ir07 190 190 Ir08 190 Ir09 30.4 580 38.7 508 39.3 578 29.2 598 41.8 572 53.2 462 51.1 633 36.1 726 50.7 738 48.6 697.7 55.1 377 49.8 884 60.4 465 58 637 61.3 538.1 53.1 768 76 470.2 54 668 52.8 696 47.8 777.1 66.1 862.7 59.1 605.5 61.7 606.2 42.2 1213 34.1 1011.1 172.6 205.6 0.15 0.22 0.20 0.14 0.21 0.33 0.23 0.14 0.20 0.20 0.42 0.16 0.38 0.26 0.33 0.20 0.47 0.23 0.22 0.18 0.22 0.28 0.29 0.10 0.10 2.43 0.707290 0.707440 0.707370 0.707410 0.708520 0.707600 0.708040 0.707430 0.707010 0.707350 0.707830 0.707130 0.707730 0.709050 0.709300 0.706480 0.707260 0.706820 0.706690 0.706950 0.706270 0.707630 0.709290 0.706200 0.706680 0.716950 0.70689 0.70686 0.70685 0.70704 0.70796 0.70672 0.70742 0.70705 0.70649 0.70682 0.70672 0.70670 0.70674 0.70836 0.70843 0.70595 0.70603 0.70620 0.70611 0.70648 0.70569 0.70689 0.70851 0.70594 0.70642 0.71055 643.2 625 686.2 683.2 0.20 0.26 0.23 0.35 0.706720 0.706960 0.707580 0.709780 0.70620 0.70627 0.70697 0.70886 48.7 653.9 46.4 678 91.3 484.3 89 481.7 35.4 1147.1 0.22 0.20 0.55 0.53 0.09 0.704980 0.704980 0.706160 0.705980 0.704740 0.70440 0.70444 0.70469 0.70454 0.70450 0.707810 0.707900 0.706770 0.706870 0.707400 0.707220 0.707290 0.707890 0.707550 0.70658 0.70682 0.70642 0.70636 0.70668 0.70661 0.70678 0.70695 0.70632 44.1 56.6 54.5 82.6 80.3 510 73 527 46.3 1032 49.7 767 64.2 696 64.3 828 54.6 837 76.5 636 84.4 535 0.46 0.40 0.13 0.19 0.27 0.23 0.19 0.35 0.46 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1235 Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) 147 143 144 144 Sm Nd Nd Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 (Ga) (Ga) Arakawa, Y., 1990. Two types of granitic intrusions in the Hida belt , Japan: Sr isotopic and chemical characteristics of the Mesozoic Funatsu granitic rocks. Chemical Geology, 85, 101-117 Kegachidake intrusion Kg02* 185.8 78.2 373 0.61 0.706470 0.70487 Kg03* 185.8 103.2 147.7 2.02 0.710310 0.70497 Kg07* 185.8 134 226.5 1.71 0.709380 0.70485 Kg09* 185.8 130.7 184 2.06 0.710290 0.70486 Okumayama intrusion Ok01 190 46.9 370 0.37 0.705750 0.70476 Ok02 190 57 355 0.47 0.706270 0.70501 Ok05 190 78.4 430 0.53 0.706460 0.70503 Komagatake intrusion Km03* 192.6 51.4 612 0.24 0.706090 0.70542 Arakawa Y. and Shinmura T., 1995. Nd-Sr isotopic and geochemical characteristics of two constrasting types of calc-alkaline plutons in the Hida belt, Japan. Chemical Geology, 124, 217-232 TYPE-1 PLUTON UB03 184 0.70528 2.41 12.71 0.1146 0.512551 -1.7 -0.42 0.2 0.92 0.95 UB05 184 0.70539 2.85 12.53 0.1373 0.512570 -1.3 -0.30 0.1 1.16 0.95 UB10 184 0.70521 3.82 28.08 0.0822 0.512591 -0.9 -0.58 1.8 0.65 0.85 UB11 184 0.70536 3.33 19.83 0.1016 0.512633 -0.1 -0.48 2.1 0.70 0.81 UB12 184 0.70539 3.23 19.74 0.0990 0.512635 -0.1 -0.50 2.2 0.69 0.80 OK01 190 46.9 370 0.37 0.705750 0.70476 2.79 13.13 0.1283 0.512510 -2.5 -0.35 -0.8 1.14 1.04 OK25 190 0.70550 2.42 10.89 0.1344 0.512750 2.2 -0.32 3.7 0.77 0.66 TYPE-2 PLUTON SN03 190 5.03 29.13 0.1044 0.512060 -11.3 -0.47 -9.0 1.52 1.73 SN04 190 4.54 28.58 0.0961 0.512085 -10.8 -0.51 -8.3 1.38 1.67 ON32 190 3.88 24.32 0.0963 0.512416 -4.3 -0.51 -1.9 0.95 1.15 OM03 190 5.72 32.30 0.1071 0.512402 -4.6 -0.46 -2.4 1.07 1.18 OM04 190 3.13 12.11 0.1562 0.512624 -0.3 -0.21 0.7 1.39 0.89 OM05 190 3.47 14.88 0.1408 0.512406 -4.5 -0.28 -3.2 1.55 1.22 YT06 190 4.67 19.49 0.1448 0.512459 -3.5 -0.26 -2.2 1.53 1.14 YT22 190 10.05 24.40 0.2489 0.512674 0.7 0.27 -0.6 -2.08 0.94 YT29 190 4.03 27.38 0.0890 0.512413 -4.4 -0.55 -1.8 0.90 1.14 Hd03 190 7.41 47.47 0.0944 0.512402 -4.6 -0.52 -2.1 0.96 1.17 Hd13 190 5.25 29.04 0.1393 0.512443 -3.8 -0.29 -2.4 1.45 1.16 Hd18 190 2.57 13.50 0.1152 0.512012 -12.2 -0.41 -10.2 1.76 1.82 GY2120 190 86.6 637 0.39 0.710600 0.70954 2.07 11.32 0.1105 0.511965 -13.1 -0.44 -11.0 1.75 1.89 GY1717 190 240 741 0.94 0.715180 0.71264 1.84 10.51 0.1058 0.511936 -13.7 -0.46 -11.5 1.71 1.93 GY2403 190 178 592 0.87 0.715070 0.71273 3.52 25.27 0.0842 0.511820 -16.0 -0.57 -13.2 1.56 2.08 Fujii and others, 2000. Sr-Nd isotopic systematics and geochemistry of the intermediate plutonic rocks from Ikoma mountains, Southewest Japan: evidence for a sequence of Mesozoic magmatic activity in the Ryoke belt. The Island Arc, 9, 37-45 K95091204-3 K 94101010 K 96030105 K 96030101 K 96061902 K 96061903 K 96070302 K 96070303 K95091203-1 F 95072106 F 95072107 F 95072109 F 96022502-1 F95022502-2 F 96022503 F 94103002 F 94103008 F 96071904 F 96071907-1 F 94080404 161 161 161 161 161 161 161 161 161 121 121 121 121 121 121 121 121 121 121 121 20 33 40 85.9 47 49 24 30 9 78 468 532 430 434 455 427 453 486 368 342 0.13 0.18 0.27 0.57 0.30 0.33 0.16 0.18 0.07 0.66 0.707446 0.707684 0.707866 0.708566 0.707955 0.708035 0.707702 0.707737 0.707424 0.708615 0.70716 0.70727 0.70725 0.70726 0.70727 0.70728 0.70734 0.70732 0.70727 0.70749 67 73 78 79 79 98 76 78 69 415 383 383 388 359 399 406 400 417 0.46 0.55 0.59 0.59 0.65 0.71 0.54 0.57 0.48 0.708335 0.708480 0.708493 0.708538 0.708727 0.708752 0.708518 0.708502 0.708364 0.70754 0.70753 0.70748 0.70752 0.70761 0.70753 0.70759 0.70753 0.70754 1.95 3.53 5.55 4.01 5.76 5.60 4.40 5.40 4.47 0.65 4.52 8.74 17.20 24.60 17.90 21.50 21.20 17.10 20.10 15.10 3.26 21.50 0.1347 0.1244 0.1363 0.1353 0.1619 0.1595 0.1551 0.1621 0.1792 0.1202 0.1270 0.512358 0.512355 0.512304 0.512362 0.512338 0.512312 0.512394 0.512315 0.512336 0.512302 0.512303 -5.5 -5.5 -6.5 -5.4 -5.9 -6.4 -4.8 -6.3 -5.9 -6.6 -6.5 6.55 39.30 0.1280 0.512317 5.21 16.70 0.1879 0.512315 -0.32 -0.37 -0.31 -0.31 -0.18 -0.19 -0.21 -0.18 -0.09 -0.39 -0.35 1.29 1.28 1.38 1.28 1.36 1.40 1.26 1.40 1.39 1.36 1.37 -6.3 -6.3 -4.2 1.53 -4.0 1.36 -5.3 1.66 -4.1 1.53 -5.1 2.38 -5.6 2.35 -3.9 1.96 -5.6 2.45 -5.5 3.57 -5.4 1.38 -5.5 1.49 (Age 161 Ma) -0.35 -5.2 1.48 -0.04 -6.2 4.87 8.66 45.20 0.1159 0.512303 -6.5 -0.41 -5.3 1.32 1.35 7.92 29.80 0.1609 0.512336 6.41 23.20 0.1667 0.512335 6.38 24.50 0.1576 0.512340 -5.9 -5.9 -5.8 -0.18 -5.3 -0.15 -5.4 -0.20 -5.2 2.34 2.63 2.19 1.36 1.37 1.35 1.35 1.43 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1236 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) 147 143 144 144 Sm Nd Nd Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 (Ga) (Ga) Iizumi and others, 2000. Sr-Nd isotope ratios of gabbroic and dioritic rocks in a Cretaceous-Paleogene grainte terrain, Southwest Japan. The Island Arc, 9, 113-127 4110205 82.9 129 199 1.88 0.709426 0.70700 4.77 26.10 0.1110 0.512392 -4.8 -0.44 -3.9 4110206 82.9 98 225 1.26 0.708696 0.70710 5.45 26.50 0.1240 0.512394 -4.8 -0.37 -4.0 AG005 82.9 79 313 0.73 0.706692 0.70580 3.92 19.20 0.1230 0.512596 -0.8 -0.37 0.0 correct 950915 82.9 63 336 0.54 0.706577 0.70590 5.10 23.90 0.1290 0.512572 -1.3 -0.34 -0.6 Omishima 82.9 0.70580 — 4110302 82.9 98 264 1.07 0.708008 0.70660 4.99 31.80 0.0950 — 4110303 82.9 99 274 1.05 0.707317 0.70600 4.82 25.30 0.1150 — 4110309 82.9 119 328 1.05 0.706770 0.70540 4.96 26.30 0.1140 0.512565 -1.4 -0.42 -0.5 correct KO-005 82.9 129 324 1.15 0.706181 0.70470 5.25 28.60 0.1110 0.512664 0.5 -0.44 1.4 TMS-01 82.9 31 399 0.23 0.706802 0.70650 4.68 25.20 0.1120 0.512571 -1.3 -0.43 -0.4 TMO20 82.9 99 306 0.94 0.705540 0.70430 3.20 15.50 0.1250 — TMO11 82.9 68 334 0.59 0.706100 0.70530 4.47 24.40 0.1110 0.512626 -0.2 -0.44 0.7 6010507 82.9 73 301 0.70 0.708388 0.70750 4.96 25.10 0.1190 0.512389 -4.9 -0.40 -4.0 correct 6010505 82.9 94 268 1.02 0.708681 0.70740 5.34 27.80 0.1160 0.512390 -4.8 -0.41 -4.0 6010402 82.9 122 315 1.12 0.708782 0.70730 5.93 28.20 0.1270 0.512370 -5.2 -0.35 -4.5 6062205 82.9 66 277 0.69 0.707548 0.70670 5.52 27.70 0.1200 0.512408 -4.5 -0.39 -3.7 4103002 85.2 82 384 0.62 0.707138 0.70630 6.71 34.20 0.1190 0.512322 -6.2 -0.40 -5.3 correct 5081901 85.2 51 386 0.38 0.707076 0.70660 6.18 29.80 0.1250 0.512431 -4.0 -0.36 -3.3 32219 85.2 41 491 0.24 0.706272 0.70600 3.84 18.60 0.1250 0.512421 -4.2 -0.36 -3.5 6062203 85.2 93 341 0.79 0.707419 0.70640 4.19 22.80 0.1110 0.512391 -4.8 -0.44 -3.9 6062204 85.2 91 348 0.76 0.707447 0.70650 4.07 22.10 0.1110 0.512378 -5.1 -0.44 -4.1 correct 6062101 85.2 46 632 0.21 0.706685 0.70640 3.04 15.60 0.1180 0.512446 -3.7 -0.40 -2.9 7690503 85.2 17.8 576 0.09 0.704881 0.70480 5.00 20.80 0.1460 0.512725 1.7 -0.26 2.2 Ishioka and Iizumi, 2003. Petrochemical and Sr-Nd isotope investigations of Cretaceous intrusive rocks and their enclaves in the TogouchiYoshiwa d istrict, northwest Hiroshima prefecture, SW Japan. Geochemical Journal, 37, 449-470 Togouchi granodiorite TO01 85.6 88 243 1.05 0.707590 0.70631 — — — — — TO02 85.6 76 223 0.99 0.707570 0.70637 — — — — — TO10 85.6 106 182 1.70 0.708380 0.70632 3.70 23.90 0.0936 0.512421 -4.2 -0.52 -3.1 0.93 1.13 TO12 85.6 63 294 0.62 0.707010 0.70626 — — — — — TO15 85.6 100 207 1.39 0.707990 0.70629 — — — — — TO16 85.6 122 178 1.99 0.708650 0.70624 5.55 29.30 0.1145 0.512463 -3.4 -0.42 -2.5 1.06 1.09 TO23 85.6 105 198 1.53 0.708140 0.70628 4.64 25.80 0.1087 0.512466 -3.4 -0.45 -2.4 0.99 1.08 TO28 85.6 111 202 1.60 0.708220 0.70629 — — — — — TO48 85.6 113 178 1.84 0.708770 0.70653 — — — 0.512506 -2.6 — TO52 85.6 79 232 0.98 0.707720 0.70652 4.01 21.70 0.1117 0.512509 -2.5 -0.43 -1.6 0.96 1.02 TO02B 85.6 108 153 2.05 0.708800 0.70632 — — — — — TO05B 85.6 115 107 3.09 0.710160 0.70638 — — — — — TO09B 85.6 128 62 5.94 0.713520 0.70626 — — — — Togouchi phenocryst-free microdiorite enclaves (PFME) TO12E 85.6 76 312 0.71 0.706590 0.70574 — — — 0.512517 -2.4 — TO15E 85.6 53 283 0.54 0.706530 0.70587 4.02 19.60 0.1240 0.512520 -2.3 -0.37 -1.5 1.07 1.02 TO16AE 85.6 84 344 0.70 0.706760 0.70590 4.43 19.90 0.1346 0.512529 -2.1 -0.32 -1.4 1.20 1.02 TO16BE 85.6 109 258 1.23 0.707350 0.70587 4.20 22.30 0.1139 0.512455 -3.6 -0.42 -2.7 1.06 1.11 TO23AE 85.6 89 280 0.92 0.706890 0.70577 — — — — — TO23BE 85.6 93 346 0.77 0.706800 0.70585 4.58 21.20 0.1306 0.512508 -2.5 -0.34 -1.8 1.18 1.04 TO28E 85.6 126 210 1.74 0.707830 0.70571 11.60 49.70 0.1411 0.512487 -2.9 -0.28 -2.3 1.39 1.09 Togouchi phenocryst-free microdiorite enclaves (PFME) TO36AE 85.6 126 163 2.24 0.708610 0.70589 9.52 42.80 0.1345 0.512465 -3.4 -0.32 -2.7 1.32 1.12 TO36BE 85.6 180 151 3.45 0.709750 0.70555 — — — 0.512476 -3.2 — TO52E 85.6 88 269 0.95 0.706830 0.70567 — — — — — TO66AE 85.6 110 203 1.57 0.707860 0.70595 — — — — — TO66BE 85.6 110 197 1.61 0.707850 0.70588 5.80 29.90 0.1173 0.512468 -3.3 -0.40 -2.4 1.08 1.09 Togouchi phenocryst-bearing microdiorite enclaves (PBME) TO01E 97 236 1.19 0.707600 0.70615 — — — — — TO30E 81 298 0.79 0.707200 0.70624 — — — — — tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1237 Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) 147 143 144 144 Sm Nd Nd Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 (Ga) (Ga) Ishioka and Iizumi, 2003. Petrochemical and Sr-Nd isotope investigations of Cretaceous intrusive rocks and their enclaves in the TogouchiYoshiwa d istrict, northwest Hiroshima prefecture, SW Japan. Geochemical Journal, 37, 449-470 Tateiwayama granite porphyry TA71 77.4 143 151 2.74 0.709480 0.70647 4.53 25.90 0.1057 0.512441 -3.8 -0.46 -2.9 1.00 1.12 TA73A 77.4 149 73 5.88 0.712940 0.70644 — — — 0.512460 -3.5 — TA73B 77.4 163 80 5.92 0.713080 0.70659 — — — — — TA78 77.4 141 131 3.11 0.709970 0.70655 — — — 0.512447 -3.7 — TA82 77.4 127 151 2.43 0.709220 0.70655 — — — 0.512418 -4.3 — TA111 77.4 123 131 2.70 0.709570 0.70658 — — — — — TA112 77.4 132 135 2.82 0.709550 0.70644 6.18 32.50 0.1150 0.512431 -4.0 -0.42 -3.2 1.11 1.15 Tateiwayama phenocryst-free microdiorite enclaves (PFME) TA71E 77.4 174 277 1.82 0.707880 0.70588 5.28 26.40 0.1209 0.512489 -2.9 -0.39 -2.2 1.09 1.06 TA73E 77.4 170 239 2.06 0.708160 0.70589 5.34 25.20 0.1281 0.512462 -3.4 -0.35 -2.8 1.22 1.11 TA76E 77.4 68 387 0.51 0.706300 0.70574 — — — 0.512498 -2.7 — Yoshiwa quartz diorite YO74 161.6 13 502 0.08 0.706410 0.70625 — — — — — YO81 161.6 77 311 0.72 0.707970 0.70632 — — — 0.512410 -4.4 — YO86 161.6 113 269 1.22 0.709040 0.70624 — — — 0.512379 -5.1 — YO93 161.6 38 514 0.22 0.706710 0.70623 3.41 16.40 0.1257 0.512448 -3.7 -0.36 -2.2 1.21 1.13 YO94 161.6 16 532 0.09 0.706550 0.70634 — — — 0.512496 -2.8 — YO95 161.6 45 396 0.33 0.706820 0.70606 4.23 20.30 0.1260 0.512465 -3.4 -0.36 -1.9 1.19 1.11 YO96 161.6 31 329 0.27 0.706920 0.70630 4.68 22.90 0.1235 0.512425 -4.2 -0.37 -2.6 1.22 1.17 Kagami and others, 1992. Spatial variations of Sr and Nd isotope ratios of Cretaceous-Paleogene granitoid rocks, SW Japan Arc. Contributions to Mineralogy and Petrology, 112, 165-177 1 65 113 271 1.20 0.705990 0.70488 4.34 22.10 0.1188 0.512618 -0.4 -0.40 0.3 0.85 0.85 2 65 125 135 2.68 0.707410 0.70494 4.08 19.90 0.1244 0.512636 0.0 -0.37 0.6 0.88 0.83 3 65 171 54.4 9.08 0.713190 0.70481 — — 4 65 197 45 12.67 0.716620 0.70492 — — 5 75 69.8 513 0.39 0.706000 0.70558 — — 6 75 78.5 483 0.47 0.705930 0.70543 6.56 28.90 0.1371 0.512580 -1.1 -0.30 -0.6 1.13 0.94 7 75 159 194 2.38 0.708140 0.70561 6.21 29.70 0.1263 0.512526 -2.2 -0.36 -1.5 1.09 1.01 8 75 152 241 1.82 0.707390 0.70545 — — 9 75 45.8 524 0.25 0.705850 0.70558 — — 10 75 100 420 0.69 0.706290 0.70556 — — 11 75 161 251 1.85 0.707570 0.70560 — — 12 75 162 216 2.16 0.707720 0.70541 — — 13 70 180 64.5 8.07 0.713640 0.70562 3.86 20.30 0.1150 0.512519 -2.3 -0.42 -1.6 0.97 1.01 14 70 166 75.3 6.39 0.711940 0.70559 — — 15 70 158 61.2 7.46 0.712900 0.70549 — — 16 72 162 83.9 5.57 0.712530 0.70683 7.87 36.20 0.1272 0.512492 -2.8 -0.35 -2.2 1.16 1.07 17 72 140 94.2 4.29 0.711210 0.70682 6.56 29.80 0.1332 0.512504 -2.6 -0.32 -2.0 1.22 1.05 18 39 68.8 238 0.83 0.705500 0.70504 4.11 19.70 0.1260 0.512683 0.9 -0.36 1.2 0.81 0.76 19 39 65.3 258 0.73 0.705630 0.70522 — — 20 39 88.6 125 2.06 0.706210 0.70507 2.70 14.50 0.1126 0.512639 0.0 -0.43 0.4 0.77 0.81 21 39 78.9 144 1.59 0.705970 0.70509 — — 22 39 86.7 165 1.52 0.705850 0.70501 2.31 12.30 0.1142 0.512649 0.2 -0.42 0.6 0.77 0.80 23 39 75.2 181 1.21 0.705820 0.70515 — — 24 65 88.3 282 0.91 0.706680 0.70584 3.32 16.20 0.1244 0.512510 -2.5 -0.37 -1.9 1.09 1.03 25 65 100 217 1.33 0.707070 0.70584 3.54 19.80 0.1083 0.512497 -2.8 -0.45 -2.0 0.94 1.03 26 72 72 468 0.44 0.707880 0.70742 4.80 23.50 0.1235 0.512346 -5.7 -0.37 -5.0 1.36 1.29 27 72 62.8 330 0.55 0.707080 0.70652 3.56 18.00 0.1201 0.512403 -4.6 -0.39 -3.9 1.22 1.20 28 72 72.6 484 0.43 0.707260 0.70682 5.86 27.30 0.1298 0.512371 -5.2 -0.34 -4.6 1.41 1.26 29 72 93.9 257 1.06 0.707760 0.70668 3.79 19.60 0.1169 0.512425 -4.2 -0.41 -3.4 1.14 1.16 30 16 64.5 418 0.45 0.706300 0.70620 3.57 18.10 0.1197 0.512523 -2.2 -0.39 -2.1 1.02 1.01 31 75 60.3 319 0.55 0.705820 0.70524 2.83 22.70 0.0756 0.512515 -2.4 -0.62 -1.2 0.70 0.96 32 75 103 365 0.82 0.708680 0.70781 4.02 21.20 0.1145 0.512246 -7.6 -0.42 -6.9 1.39 1.44 33 84 169 175 2.80 0.711060 0.70772 — — 34 84 177 180 2.86 0.711120 0.70771 7.12 32.00 0.1348 0.512367 -5.3 -0.31 -4.6 1.51 1.28 35 84 112 206 1.58 0.709230 0.70735 4.30 20.50 0.1269 0.512381 -5.0 -0.35 -4.3 1.35 1.24 36 84 171 109 4.54 0.712760 0.70734 5.37 22.30 0.1454 0.512391 -4.8 -0.26 -4.3 1.69 1.25 37 84 164 107 4.44 0.712520 0.70722 5.17 24.30 0.1285 0.512390 -4.8 -0.35 -4.1 1.36 1.23 38 84 124 130 2.76 0.710730 0.70743 4.12 20.00 0.1245 0.512307 -6.5 -0.37 -5.7 1.44 1.36 39 84 35.3 390 0.26 0.707760 0.70745 4.55 20.20 0.1367 0.512306 -6.5 -0.31 -5.8 1.67 1.38 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1238 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) 147 143 144 144 Sm Nd Nd Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 (Ga) (Ga) Kagami and others, 1992. Spatial variations of Sr and Nd isotope ratios of Cretaceous-Paleogene granitoid rocks, SW Japan Arc. Contributions to Mineralogy and Petrology, 112, 165-177 40 84 27.5 369 0.22 0.707480 0.70722 4.53 19.70 0.1389 0.512361 -5.4 -0.29 -4.8 1.60 1.29 41 84 206 35.2 17.00 0.727470 0.70718 4.22 17.20 0.1483 0.512388 -4.9 -0.25 -4.4 1.77 1.26 42 84 147 134 3.19 0.711120 0.70731 4.77 25.90 0.1115 0.512363 -5.4 -0.43 -4.5 1.17 1.25 43 84 228 17.1 38.76 0.754560 0.70830 4.69 15.40 0.1843 0.512415 -4.4 -0.06 -4.2 3.78 1.27 44 84 126 158 2.30 0.710040 0.70729 4.16 23.10 0.1089 0.512333 -5.9 -0.45 -5.0 1.19 1.30 45 82 107 312 0.99 0.708440 0.70729 5.79 36.80 0.0952 0.512369 -5.2 -0.52 -4.2 1.00 1.22 46 82 84.2 312 0.78 0.708220 0.70731 4.64 34.70 0.0810 0.512362 -5.4 -0.59 -4.2 0.91 1.21 47 93 118 270 1.27 0.709090 0.70741 3.62 20.20 0.1083 0.512377 -5.1 -0.45 -4.0 1.12 1.22 48 93 123 176 2.05 0.710330 0.70763 — — 49 93 129 133 2.80 0.711010 0.70731 — — Kagami and others, 2000. Continental basalts in the accretionary complexes of the South-west Japan Arc: Constraints from geochemical and Sr and Nd isotopic data of metadiabase. The Island Arc, 9, 3-20 1 192 87.4 458 0.55 0.707588 0.70608 7.51 30.80 0.1475 0.512424 -4.2 -0.25 -3.0 2 192 56.7 438 0.37 0.709428 0.70841 6.90 32.50 0.1283 0.512252 -7.5 -0.35 -5.9 16 240 38.6 329 0.34 0.708269 0.70711 6.54 29.50 0.1341 0.512344 -5.7 -0.32 -3.8 17 240 46.7 371 0.36 0.708814 0.70757 7.68 35.80 0.1296 0.512275 -7.1 -0.34 -5.0 Morioka and others, 2000. Rb-Sr isochron age of the Cretaceous granitoids in the Ryoke belt, Kinki district, Southwest Japan. The Island Arc, 9, 46-54. Ya gyu granite YGr-1 74.6 83 292 0.82 0.710190 0.70932 YGr-2 74.6 81 318 0.73 0.710100 0.70932 YGr-3 74.6 22 124 0.52 0.709820 0.70927 YGr-4 74.6 104 133 2.27 0.711810 0.70940 YGr-5 74.6 109 192 1.64 0.710920 0.70918 70301 74.6 71 301 0.69 0.710100 0.70937 70302 74.6 75 257 0.84 0.710370 0.70948 70303 74.6 56 282 0.57 0.710050 0.70944 70304 74.6 61 282 0.63 0.709920 0.70926 70305 74.6 67 295 0.66 0.710320 0.70962 70305Bio 74.6 378 23 48.00 0.758610 0.70774 70306Ef. 74.6 16 377 0.12 0.709760 0.70963 Narukawa granite B83032803 79.5 198 183 3.13 0.712300 0.70876 B82032801 79.5 112 136 2.39 0.711180 0.70848 A820327-10 79.5 99 197 1.45 0.710210 0.70857 B83032803Bio 79.5 890 12 215.00 0.951870 0.70902 Takijiri adamellite Y1601 78.3 204 103 5.74 0.713870 0.70748 Y1602 78.3 276 57 14.00 0.722970 0.70740 Y1603 78.3 226 57 11.50 0.720310 0.70752 Y1604 78.3 209 106 5.70 0.714280 0.70794 Y1605 78.3 220 63 10.10 0.714280 0.70304 Y1606 78.3 143 270 1.53 0.709400 0.70770 Y1607 78.3 183 296 1.79 0.709950 0.70796 Katsuragi quartz diorite 61901 85.1 38 481 0.23 0.707540 0.70727 61902 85.1 36 467 0.22 0.707580 0.70731 70402 85.1 19 640 0.09 0.707370 0.70727 70403 85.1 32 545 0.17 0.707500 0.70729 70405 85.1 49 458 0.31 0.707640 0.70727 61901Bio 85.1 189 9 63.60 0.774770 0.69787 61902Ef. 85.1 4 660 0.02 0.707250 0.70723 70405Bio 85.1 188 12 45.50 0.756960 0.70194 70405Ef. 85.1 6 599 0.03 0.707270 0.70723 Minamikawachi granite 50503 72.8 249 80 9.00 0.717980 0.70867 51407 72.8 279 36 22.70 0.732660 0.70918 51420 72.8 219 260 2.44 0.711610 0.70909 52205 72.8 145 246 1.71 0.710690 0.70892 52208 72.8 180 145 3.61 0.712560 0.70883 52209 72.8 191 134 4.13 0.713170 0.70890 Nakajima and others, 2004. Mafic rocks from the Ryoke Belt, Southwest Japan: implications for Cretaceous Ryoke/San-yo granitic magama genesis. Transactions of the Royal Society of Edinburgh: Earth Sciences, 95, 249-263 95101702 258 125 0.70892 91030804 128 218 0.70813 99112902A 51 343 0.70807 99120101A 72 58 471 0.70734 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1239 Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) 147 143 144 144 Sm Nd Nd Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 (Ga) (Ga) Shinjoe H., 1997. Origin of the granodiorite in the forearc region of SW Japan: melting of the Shimanto accretionary prism. Chemical Geology, 134, 237-255 Uwajima and Miuchi plutons 1302host 14 142 216 1.90 0.708047 0.70767 4.50 28.60 0.0951 0.512353 -5.6 -0.52 -5.4 1.02 1.24 1304A 14 159 209 2.20 0.708335 0.70790 4.40 27.30 0.0974 0.512344 -5.7 -0.50 -5.6 1.06 1.26 O202 14 167 182 2.65 0.707237 0.70671 4.50 29.40 0.0925 0.512426 -4.1 -0.53 -3.9 0.91 1.12 O613D 14 149 202 2.13 0.707351 0.70693 4.60 30.90 0.0900 0.512423 -4.2 -0.54 -4.0 0.90 1.13 2102 14 150 217 2.00 0.707126 0.70673 4.70 29.70 0.0957 0.512456 -3.6 -0.51 -3.4 0.90 1.08 2507 14 129 236 1.58 0.707004 0.70669 4.20 16.90 0.1502 0.512437 -3.9 -0.24 -3.8 1.71 1.19 2509 14 162 213 2.20 0.707123 0.70669 4.90 30.10 0.0984 0.512358 -5.5 -0.50 -5.3 1.05 1.24 1406 14 132 166 2.30 0.709281 0.70882 4.50 28.80 0.0945 0.512343 -5.8 -0.52 -5.6 1.03 1.26 1202 14 133 188 2.05 0.707339 0.70693 4.30 16.60 0.1566 0.512459 -3.5 -0.20 -3.4 1.84 1.16 1205 14 167 198 2.44 0.706855 0.70637 4.80 20.10 0.1444 0.512402 -4.6 -0.27 -4.5 1.64 1.23 1302SA 14 116 262 1.28 0.706013 0.70576 7.50 37.60 0.1206 0.512512 -2.5 -0.39 -2.3 1.04 1.02 1305B 14 69 264 0.76 0.706194 0.70604 4.80 28.90 0.1004 0.512499 -2.7 -0.49 -2.5 0.88 1.02 1401D 14 82 234 1.01 0.706133 0.70593 4.60 28.90 0.0962 0.512484 -3.0 -0.51 -2.8 0.86 1.04 1504A 14 130 236 1.59 0.706222 0.70591 4.90 22.30 0.1328 0.512465 -3.4 -0.32 -3.3 1.29 1.12 2105 14 160 252 1.84 0.705678 0.70531 10.50 43.00 0.1476 0.512550 -1.7 -0.25 -1.6 1.38 1.00 2405A 14 180 111 4.69 0.707878 0.70695 3.10 17.70 0.1059 0.512422 -4.2 -0.46 -4.1 1.03 1.15 Stein G and others, 1996. The Miocene Ashizuri complex (SW Japan): source and magma differentiation of an alkaline plutonic assemblage in an island-arc environment. Bull Soc Geol France, 167, 125-139. A17 13 281 124 0.705430 0.70413 11.78 62.28 0.1143 0.512651 0.3 -0.42 0.4 0.77 0.79 A13 13 283 30 0.709640 0.70421 11.65 61.17 0.1151 0.512731 1.8 -0.41 1.9 0.65 0.67 A1 13 312 43 0.708910 0.70469 6.19 32.83 0.1140 0.512600 -0.7 -0.42 -0.6 0.84 0.88 Other acid rocks from Outer Zone of SW Japan: A6 13 101 192 0.707660 0.70736 5.19 24.13 0.1300 0.512440 -3.9 -0.34 -3.8 1.29 1.15 A7 13 186 96 0.708050 0.70894 5.20 17.10 0.1838 0.512406 -4.5 -0.07 -4.5 3.76 1.28 A9 13 134 205 0.708440 0.70806 5.22 27.27 0.1157 0.512368 -5.3 -0.41 -5.1 1.22 1.25 OS4 13 210 43 0.713240 0.71043 2.54 8.98 0.1710 0.512326 -6.1 -0.13 -6.0 2.92 1.39 OS9 13 125 165 0.710180 0.70972 6.86 35.15 0.1180 0.512365 -5.3 -0.40 -5.2 1.25 1.26 Takagi, T. and Kagami, H., 1995. Rb-Sr isochron ages and initial Sr isotope rarios of the Ukan granodiorite and Kayo granite central Okayama prefecture, southwest Japan. Bulletin of the Geological Survey of Japan, v. 46, 219-224. 31106 92 96 234 1.19 0.708530 0.70691 12102 92 101 243 1.20 0.708530 0.70680 81011 92 108 242 1.29 0.708620 0.70664 80905 92 131 261 1.45 0.708810 0.70611 73108 92 127 218 1.69 0.709200 0.70616 73107 92 127 208 1.77 0.709280 0.70609 12105 92 141 205 1.99 0.709530 0.70554 80409 92 73 300 0.70 0.708020 0.70729 31108 92 70 268 0.76 0.708120 0.70737 62602 92 85 252 0.98 0.708270 0.70709 31102 92 106 220 1.39 0.708700 0.70660 31012 81 54 291 0.54 0.707410 0.70700 31607 81 68 308 0.64 0.707600 0.70698 30801 81 76 301 0.73 0.707740 0.70695 102301 81 99 191 1.50 0.708560 0.70645 31603 81 103 185 1.61 0.708680 0.70632 30803 81 103 168 1.77 0.708780 0.70618 12209 81 135 203 1.92 0.709170 0.70548 102108 81 114 144 2.29 0.709480 0.70577 Takagi T., 2004. Origin of magnetite- and ilmenite-series granitic rocks in the Japan Arc. American Journal of Science, 304, 169-202. (compiled data, from 85 sources) Kyushu district and SW islands Ilmenite-series 143 0.70442 Ilmenite-series 164 0.70452 Ilmenite-series 102 0.70544 Ilmenite-series 117 0.70521 Ilmenite-series 101 0.70649 Ilmenite-series 118 0.70557 Ilmenite-series 121 0.70542 Ilmenite-series 117 0.70530 Ilmenite-series 14.6 0.70630 Ilmenite-series 13.8 0.70552 Ilmenite-series 143 0.70441 Ilmenite-series 70 0.70462 Ilmenite-series 61 0.70639 Ilmenite-series 69 0.70987 Ilmenite-series 41 0.70586 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1240 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 Nd (Ga) (Ga) 147 143 144 144 Sm Nd Takagi T., 2004. Origin of magnetite- and ilmenite-series granitic rocks in the Japan Arc. American Journal of Science, 304, 169-202. (compiled data, from 85 sources) Kyushu district and SW islands Magnetite-series 229 0.70678 Magnetite-series 116 0.70506 0.6 Ilmenite-series 114 0.70516 1.0 Magnetite-series 108 0.70517 -2.1 Magnetite-series 96 0.70635 -3.8 Ilmenite-series 88 0.70526 0.3 Magnetite-series 121 0.70493 Ilmenite-series 39 0.70478 Magnetite-series 210 2.8 Magnetite-series 115 0.6 Ilmenite-series 13.8 0.70537 -6.6 Ilmenite-series 16.2 0.70869 -5.8 Ilmenite-series 15 0.70643 -3.5 Chugoku and Shikoku districts Ilmenite-series 78 0.70857 -4.2 Ilmenite-series 79 0.70650 Ilmenite-series 81 0.70596 -3.8 Ilmenite-series 84 0.70745 -4.7 Ilmenite-series 91 0.70770 Ilmenite-series 92 0.70696 Ilmenite-series 84 0.70568 Ilmenite-series 80 0.70595 Ilmenite-series 93 0.70627 Ilmenite-series 91 0.70631 Ilmenite-series 88 0.70678 Ilmenite-series 73 0.70733 Ilmenite-series 94 0.70660 Ilmenite-series 89 0.70749 Ilmenite-series 93 0.70662 Ilmenite-series 95 0.70740 Ilmenite-series 94 0.70750 Ilmenite-series 93 0.70510 Ilmenite-series 99 0.70616 Ilmenite-series 92 0.70727 Ilmenite-series 92 0.70734 Ilmenite-series 82 0.70731 -4.5 Ilmenite-series 91 0.70745 -4.1 Ilmenite-series 93 0.70769 Ilmenite-series 93 0.70752 Ilmenite-series 83 0.70803 -5.7 Ilmenite-series 95 0.70741 -5.6 Ilmenite-series 99 0.70734 -5.3 Ilmenite-series 84 0.70749 -5.5 Ilmenite-series 84 0.70791 -5.9 Ilmenite-series 76 0.70794 -5.5 Ilmenite-series 76 0.70774 -5.3 Ilmenite-series 16 0.70740 -5.2 Ilmenite-series 14 0.70676 Ilmenite-series 85 0.70526 0.2 Ilmenite-series 84 0.70583 Ilmenite-series 85 0.70635 Ilmenite-series 77 0.70653 Magnetite-series 60 0.70661 Magnetite-series 61 0.70558 Magnetite-series 60 0.70554 Magnetite-series 65 0.70475 -1.8 Magnetite-series 65 0.70550 0.5 Magnetite-series 73 0.70557 Magnetite-series 75 0.70553 Magnetite-series 70 0.70550 -1.7 Magnetite-series 72 0.70681 -2.1 Magnetite-series 128 0.70487 Magnetite-series 58 0.70617 Magnetite-series 29 0.70489 Magnetite-series 40 0.70730 Magnetite-series 44 0.70449 Magnetite-series 85 0.70730 Magnetite-series 69 0.70574 Magnetite-series 36 0.70532 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1241 Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 Nd (Ga) (Ga) 147 143 144 144 Sm Nd Takagi T., 2004. Origin of magnetite- and ilmenite-series granitic rocks in the Japan Arc. American Journal of Science, 304, 169-202. (compiled data, from 85 sources) Chugoku and Shikoku districts Magnetite-series 85 0.70535 -0.2 Magnetite-series 39 0.70507 0.8 Magnetite-series 81 0.70684 Magnetite-series 81 0.70590 Magnetite-series 102 0.70570 Magnetite-series 82 0.70620 Magnetite-series 84 0.70639 Magnetite-series 87 0.70572 -0.1 Magnetite-series 61 0.70499 Ilmenite-series 83 0.70773 -3.9 Ilmenite-series 80 0.70521 Ilmenite-series 83 0.70581 Ilmenite-series 83 0.70595 Magnetite-series 62 0.70725 Magnetite-series 60 0.70769 Ilmenite-series 63 0.70793 Ilmenite-series 72 0.70740 Ilmenite-series 72 0.70840 Ilmenite-series 71 0.70760 Ilmenite-series 81 0.70766 Ilmenite-series 80 0.70796 Ilmenite-series 100 0.70790 Ilmenite-series 89 0.70730 Ilmenite-series 94 0.70790 Ilmenite-series 97 0.70607 -3.0 Magnetite-series 80 0.70519 Ilmenite-series 83 0.70775 Magnetite-series 64 0.70574 Ilm (S-type granite) 16 0.70913 -5.8 Ilm (S-type granite) 14 0.70747 -5.3 Ilmenite-series 66 0.70624 Kinki and Chubu districts Ilmenite-series 161 0.70727 Ilmenite-series 121 0.70753 Ilmenite-series 121 0.70754 -5.7 Ilmenite-series 71 0.71243 -13.4 Ilmenite-series 99 0.71026 -9.8 Ilmenite-series 93 0.70910 -7.6 Ilmenite-series 82 0.70769 -5.3 Ilmenite-series 149 0.70605 Ilmenite-series 72 0.70711 Ilmenite-series 72 0.71060 Ilmenite-series 83 0.70960 Ilmenite-series 99 0.71010 Ilmenite-series 75 0.70938 Ilmenite-series 78 0.70764 Ilmenite-series 85 0.70728 Ilmenite-series 72 0.70895 Ilmenite-series 78 0.70914 Ilmenite-series 80 0.70951 Ilmenite-series 95 0.70989 Ilmenite-series 80 0.70984 Ilmenite-series 96 0.70687 Magnetite-series 69 0.70912 Magnetite-series 66 0.71000 Ilmenite-series 57 0.71179 Ilmenite-series 79 0.70831 -5.6 Ilmenite-series 85 0.70774 -5.8 Ilmenite-series 67 0.71247 Ilmenite-series 55 0.71052 Ilmenite-series 79 0.70719 Ilmenite-series 62 0.70740 Ilmenite-series 64 0.70803 Ilmenite-series 94 0.70740 Ilmenite-series 55 0.71073 Ilmenite-series 63 0.70778 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: 1242 Bor-Ming Jahn—Accretionary orogen and evolution of the Japanese Islands— Table A1 (continued) Sample No. Age Rb Sr (Ma) (ppm) (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Sm Nd (ppm) (ppm) Nd εNd(0) fSm/Nd εNd(T) TDM-1 TDM-2 Nd (Ga) (Ga) 147 143 144 144 Sm Nd Takagi T., 2004. Origin of magnetite- and ilmenite-series granitic rocks in the Japan Arc. American Journal of Science, 304, 169-202. (compiled data, from 85 sources) Hida and Kanto districts Ilmenite-series 62 0.71291 -10.3 Ilmenite-series 60 0.71138 Magnetite-series 183 0.70529 1.3 Magnetite-series 186 0.70487 Magnetite-series 193 0.70441 8.0 Magnetite-series 69 0.70800 Magnetite-series 201 0.70474 Magnetite-series 184 0.70485 Ilmenite-series 58 0.70969 Ilmenite-series 60 0.71320 Ilmenite-series 60 0.71063 Ilmenite-series 92 0.70817 -6.2 Magnetite-series 166 -5.2 Magnetite-series 183 0.70499 1.3 Magnetite-series 173 0.70681 -1.7 Magnetite-series 211 0.70617 Magnetite-series 7 0.70365 9.0 Tohoku district Ilmenite-series 106 0.70518 0.0 Ilmenite-series 106 0.70553 Ilmenite-series 112 0.70645 Ilmenite-series 115 0.70521 Ilmenite-series 112 0.70493 Ilmenite-series 120 0.70518 Ilmenite-series 119 0.70489 Magnetite-series 107 0.70463 Magnetite-series 128 0.70392 Magnetite-series 157 0.70363 Magnetite-series 157 0.70415 Magnetite-series 124 0.70419 Magnetite-series 107 0.70445 Magnetite-series 132 0.70435 Magnetite-series 142 0.70420 Magnetite-series 138 0.70427 Magnetite-series 118 0.70390 Magnetite-series 135 0.70355 Ilmenite-series 90 0.70496 Ilmenite-series 100 0.70541 Hida and Kanto districts Ilmenite-series 94 0.70537 -1.9 Ilmenite-series 97 0.70630 -5.7 Ilmenite-series 100 0.70492 -3.9 Ilmenite-series 71 0.70736 -4.8 Ilmenite-series 91 0.70564 -2.6 Ilmenite-series 74 0.70779 -4.7 Ilmenite-series 44 0.70935 -5.3 Magnetite-series 24 0.70528 0.6 Ilmenite-series 95 0.70535 0.5 Ilmenite-series 90 0.70528 0.5 Ilmenite-series 95 0.70521 -0.5 Magnetite-series 128 0.70377 2.7 Magnetite-series 107 0.70398 2.3 Magnetite-series 10 0.70439 4.6 Ilmenite-series 51 0.70452 Ilmenite-series 130 0.70487 Ilmenite-series 134 0.70500 Ilmenite-series 104 0.70536 Ilmenite-series 17.3 0.70460 tapraid4/zqn-ajsc/zqn-ajsc/zqn01010/zqn2165d10a metzgerm S⫽18 3/11/11 16:52 Art: Implications from a Sr-Nd isotopic study of the Phanerozoic granitoids 1243 Table A1 (continued) Sample No. Age Rb (Ma) (ppm) Sr (ppm) 87 87 86 86 Rb Sr Sr Sr I (Sr) Terakado and Nohda, 1993. Rb-Sr dating of acidic rocks from the middle part of the Inner Zone of southwest Japan: tectonic implications for the migration of the Cretaceous to Paleogene igneous activity. Chemical Geology, 109, issue 1-4, 69-87 MIYAZ U-IZUSHI area KyMi-2 61.9 105 186 1.64 0.708731 0.70729 KyMi-10 60.4 145 154 2.71 0.710017 0.70769 KyMi-12 60.4 129 311 1.19 0.708638 0.70762 KyTa-4 60.4 140 199 2.04 0.710009 0.70826 HyIz-43 62.6 139 93.7 4.28 0.711676 0.70787 HyIz-46 62.6 142 119 3.45 0.710537 0.70747 MIYAZ U-IZUSHI area HyIz-11 62.6 90.3 321 0.82 0.708332 0.70761 HyY-21 62.6 132 128 2.98 0.710682 0.70803 HyIz-21 62.6 62.9 325 0.56 0.708614 0.70812 HyIz-26 62.6 85.9 499 0.50 0.707608 0.70717 HyIz-42 62.6 159 53.2 8.64 0.715588 0.70790 ROKKO-HIRAKI area ROK-1 72.1 124 81.9 4.37 0.711857 0.70738 ROK-8 71.9 168 63.5 7.67 0.716192 0.70836 ROK-10 71.2 228 18.4 36.00 0.743993 0.70758 ROK-3 71.2 226 21.8 30.10 0.739365 0.70892 ROK-6 71.2 194 65.8 8.56 0.716863 0.70820 ROK-9 71.2 86.7 190 1.32 0.708478 0.70714 ROK-11 71.2 85.3 219 1.13 0.708330 0.70719 ROK-15 71.2 168 45.1 10.80 0.719367 0.70844 NUN-1 70 83.4 249 0.97 0.708379 0.70741 NUN-4 70 72.1 262 0.80 0.708330 0.70754 HRK-1 70.1 92.8 325 0.83 0.708311 0.70749 HRK-2 70.1 163 35.1 13.50 0.720701 0.70726 HRK-4 70.1 139 91.7 4.40 0.711671 0.70729 HRK-13 70.1 122 87.8 4.02 0.711294 0.70729 HyK-1 70.1 127 217 1.69 0.709760 0.70808 HyK-2 70.1 103 191 1.56 0.708920 0.70737 HyTa-1 70.1 123 157 2.27 0.710795 0.70853 HyTa-5 70.1 108 129 2.42 0.710672 0.70826 HyTa-6 70.1 124 174 2.06 0.710277 0.70823 ROK-12 70.1 158 139 3.27 0.711223 0.70797 AWAJI area AwOz-1 80.9 161 174 2.67 0.710746 0.70768 AwTu-5 80.4 102 189 1.56 0.709770 0.70799 AwNi-1 85.8 125 196 1.85 0.710342 0.70809 HyN-1 80 140 151 2.68 0.711460 0.70841 HyN-2 80 146 142 2.98 0.711820 0.70843 HyAi-17 78.4 120 190 1.83 0.709839 0.70780 HyAi-11 78.4 114 193 1.71 0.709721 0.70782 HyAi-1 78.4 163 121 3.90 0.712260 0.70792 References Arakawa, Y., 1989, Strontium isotopic compositions of Mesozoic granitic rocks in the Hida belt, central Japan: diversities of magma sources and of processes of magma evolution in a continental margin area: Lithos, v. 24, p. 261–273, doi:10.1016/0024-4937(89)90047-9. –––––– 1990, Two types of granitic intrusions in the Hida belt, Japan: Sr isotopic and chemical characteristics of the Mesozoic Funatsu granitic rocks: Chemical Geology, v. 85,n. 1–2, p. 101–117, doi:10.1016/00092541(90)90125-Q. 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