Cargo Handling Sheet Ethylene Glycol all Grades Document date: 31 January 2012 Revision 6 Cargo handling Sheet: Ethylene Glycol all Grades Document date: 31 January 2012 Revision 6 Product Details: Product Name: Ethylene Glycol IMO Shipping Name: Ethylene Glycol Chemical Family: Glycol Product Code: U1281, U1284, U1285, U1286 MSDS: http://www.euapps.shell.com/MSDS/GotoMsds?loc=shellchemicals Physical Properties: Density: 1,113 kg/m3 @ 20 deg C. Specific Gravity: 1.12 @ 20 deg C. Viscosity: 24.8 (mPas) @ 20 deg C. Vapor Pressure: <10 (Pa) @ 20 deg C. Boiling Point: 197 deg C. Melting Point: -13 deg C. Flash Point: 116 deg C. Notes: Transshipments are not permitted unless the responsible Shell Chemical charterer has been consulted and the operation approved by the Regional Marine Technical Advisor. Marpol Details: Marpol Annex: II IMO Ship Type: 3 Shell Chemicals requires a type 2 ship IMO Pollution Category: Y Oil Like: No High Viscosity: No Solidifying: No USCG : USCG compatibility group 20, not compatible with group 12 Isocyanates 2 Cargo handling Sheet: Ethylene Glycol all Grades Document date: 31 January 2012 Revision 6 Cargo Handling Requirements: Prepurging of Vessel’s Tanks: No N2 Blanket Required: Yes Percent Oxygen in Nitrogen Blanket: See Regional Requirements Vapor Space Purge: No Loading Temperature Range: Ambient Transit Temperature Range: Ambient Discharge Temperature Range: Ambient Maximum Heating Coil Temperature: Blanked off Adjacent Maximum Cargo Temperature: 40 deg C. Regional Requirements: See notes Notes: Tank acceptance:- EU Stainless steel or coated tank requirements, see below. Notes: Padding tanks:Inter Europe <5 days MEG Fibre grade, Oxygen content max <10% All other voyages MEG Fibre grade, Oxygen content max 3%. Inter Europe <10 days MEG Industrial and MEG Antifreeze, Oxygen content max 10% International MEG Industrial and MEG Antifreeze, Oxygen content max 3% Notes: If Nitrogen blanket is in place and Carrier chooses to transship, carrier must reapply nitrogen blanket on the cargo, both on the discharging and receiving ship, at their time, risk, and expense. Notes: Padding should be carried out using high purity nitrogen (99.99%). The preferred method is to introduce the nitrogen through a small tank lid at one end of the tank away from the main tank hatch. The nitrogen is introduced through the small tank lid from where it will flow to the tank hatch, and out the vent line. If this method cannot be used, the nitrogen must be bubbled through the drop line until the required oxygen reading is obtained. Using this method, the tank should be retested after 24 hours and topped up as necessary. Oxygen readings should be taken with recently calibrated meters. Notes: Any single seal tank hatches should have the gasket reinforced with silicone, 3 Cargo handling Sheet: Ethylene Glycol all Grades Document date: 31 January 2012 Revision 6 Tank Acceptance Requirements: All shore and ship cargo lines and tanks are to be presented clean (residual free), dry, odor free, and rust free, with good gaskets and pressure tested heating coils. If cargo is not heated, heating coils to be flushed, dried with nitrogen and blanked off. Stainless Steel or Coated Tanks: Stainless preferred. Coated tanks, zinc not allowed, to be in very good condition with minimal blistering or breakdown. All blisters to be scraped to hard coating. All defects to be noted by the surveyor. Carrier to verify suitability of coating for product. Pipelines and fittings to be of stainless steel. For Europe Stainless, if coated presented, Chemicals MTA to review and approve on a case by case basis. Wall Wash Required: Yes (Inter Europe <10 days Fibre grade only) Tank Acceptance Requirements: Wash Specifications: An ASTM E2664-09a standard methanol wallwash should be taken from at least four spots (at least 6” width and 6’ height) on each bulkhead, and also four spots on the tank top. The following composite tests should be run. Results Appearance Clear bright and particle free Chlorides 0.249 ppm Hydrocarbons Pass (ASTM D-1722) Color 5 max Pt-Co (ASTM D-1209a) 4 Cargo handling Sheet: Ethylene Glycol all Grades Document date: 31 January 2012 Revision 6 Surveyors instructions: See appendix “II” for Additional tests for U1285, U1286 Prior Cargoes: If coated tanks are presented, the following products, which include Aromatics, CPP, Benzenes, Xylenes, and products which polymerize, may not be first prior cargoes. Refer to appendix “I” for list of products. The appendix also lists potential contamination sources. Stainless steel tanks, if prior cargo has polymerizing properties, surveyor should be additionally vigilant for prior residues Link to Appendices I & II: See appendices. Safety Information and Incident Reporting. Safety Information: For more detailed information, refer to the MSDS or e-SDS for reportable spill/release quantities whether in the water, air or ground. Incident Reporting: If an incident occurs outside the territorial limits of the USA, call Shell International Trading and Shipping in London on (44) 207-934-7777. If the spill/release marine incident occurs within the territorial limits of the USA, call the Shell 24 hr. incident number at 713-241-2532. The USA National response center telephone number is 1-800-424-8802 For additional marine cargo handling advice or information, contact Captain Eddie Trotter at (+1 713 241 3535) 5 Cargo handling Sheet: Ethylene Glycol all Grades Document date: 31 January 2012 Revision 6 Shell Chemical LP PO Box 4407 Houston Texas 77210 USA Tel +1 866 897 4355 Internet http://www.shell.com/chemicals Disclaimer The information contained in this publication is, to the best of our knowledge, true and accurate, but any recommendations or suggestions that may be made are without guarantee, since the conditions of use are beyond our control. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use. Shell Chemicals The expression “Shell Chemicals” refers to the companies of the Shell Group of companies that are engaged in the chemical businesses. Each of the companies that make up the Shell Group of companies is an independent entity and has its own separate identity. 6
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