Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Global Water, Water Cycle, and Properties of Water Stations Investigation Introduction Water is the most important chemical compound on the face of the Earth and is responsible for supporting life. Approximately 70% of the surface of the Earth is covered with water, as shown by the “blue marble” photos taken from space. So, why then is water considered a limited resource? Although we generally take the availability of potable water- water available for human consumption- for granted in this country, most of the water that covers planet Earth is saltwater. If you remember back to Biology, humans can only survive about a week without potable water and cannot drink saltwater - it dehydrates cells and would cause death sooner than not drinking any water at all! Of the total water available on Earth, approximately 97% of it is salt water, and approximately 3% is freshwater. Of the total freshwater resources, approximately 30% is underground and approximately 1% is surface water. That leaves approximately 69% of freshwater that is unavailable due to being locked up in glaciers and ice caps, which is why potable water is considered a limited resource. Objective In this investigation, you will complete activities related to the chemistry of water and demonstrating the global distribution of water, per capita water usage, and the continuous flow of water on, above, and below the surface of the Earth as it changes states between solid, liquid, and gas. Procedure Read through the investigation handout thoroughly before beginning any activities, visit all stations, and restore the station to its original condition. Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 1. Global Water Distribution. Examine the global water distribution chart below and then answer the questions. 1. What % of water is saline (saltwater)? ________ Freshwater? _________ 2. What % of total freshwater is locked up in ice caps and glaciers? ________ 3. What % of freshwater is ground water? _________. Surface water? _______ 4. What % of surface fresh water do lakes and rivers make up? __________ Why is this % so important? ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 2. Per capita water usage. How much water do you use daily? How much water do you use when you take a shower? Wash a load of clothes? Flush a toilet? Even brush your teeth? One important measurement of water use is how much water one person uses in one day, or per-capita water use (per is Latin for by and capita is Latin for head). The number is usually expressed as gallons of water used per person per day. To make things consistent for this activity, let's consider a rainy and cold Saturday when you happen to stay home all day. Think of the water-using activities you do: take a shower, brush your teeth, maybe wash dishes and clothes, etc. Go to the following USGS website: http://ga.water.usgs.gov/edu/sq3.html and complete the online questionnaire. Fill in the boxes with your water-use activities using the drop down tabs, choose the submit button, and then you’ll receive an estimate of how many gallons of water you used. Answer the following (make sure to include units where applicable): 1. What is your per capita use of water: _____________________________ 2. Looking at the US map of water usage, what is the total estimated usage of water in New Jersey daily? ____________________________ 3. What is the population in New Jersey? ________________________ 4. Using your answers from #3 & #4, calculate the average water usage per person in New Jersey? ________________ 5. How does your per capita use of water compare to the number calculated in #4? ________________________________________________________________________ 6. What other uses of water, not included in the survey, may affect your actual per capita use of water and caused the difference you noticed in question #5? ________________________________________________________________________ ________________________________________________________________________ Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 3: The Water Cycle The water cycle describes the existence and movement of water on, in, and above the Earth. Earth's water is always in movement and is always changing states, from liquid to vapor to ice and back again. The water cycle has been working for billions of years and all life on Earth depends on it continuing to work. Examine the water cycle diagram below. Put the letter from the diagram in front of the term that is being depicted. You may need to look some of the terms up in the text or on the internet. [ [ [ [ [ [ [ [ [ ] Condensation ] Evapotranspiration ] Groundwater discharge ] Infiltration ] Snowmelt runoff to streams ] Streamflow ] Surface runoff ] Water storage in ice and snow ] Desublimation [ [ [ [ [ [ [ [ [ ] Evaporation ] Freshwater storage ] Groundwater storage ] Precipitation ] Spring ] Sublimation ] Water storage in the atmosphere ] Water storage in oceans ] Plant uptake Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 4. Phase Diagram. Examine the diagram below and then answer the questions that follow. 1. Define the following terms based on what you see in the diagram above. a. Melting ____________________________________________________________ b. Freezing ____________________________________________________________ c. Condensation ____________________________________________________________ d. Vaporization ____________________________________________________________ e. Sublimation ____________________________________________________________ f. Deposition ____________________________________________________________ 2. Which phase(s) of the water cycle is represented by vaporization? ___________________________________________________________________________ 3. Which phase above occurs directly prior to precipitation? _____________________________ 4. The “white cloud or fog” you see when dry ice is set out at room temperature represents which phase in the water cycle? ___________________________________________________ Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 5: The Structure of Water- Chemical and Molecular Formulas 1. What is a chemical formula? ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 2. What is the chemical formula for water? 3. Build the molecular model of water using the molecular model kit provided. Sketch the model in the space provided below. Color your sketch- use the same colors as in the molecular modeling kit. 4. What does the molecular formula for water reveal that the chemical formula does not? ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 5. Based on the water molecule you’ve constructed, what is the shape of water molecule? Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 6: Water- Bonding & Polarity 1. Define an ionic compound. Give an example. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 2. Define a covalent compound. Give an example. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 3. Is water an ionic or covalent compound? _________________________________________ 4. What is meant by the term “polar” or “polarity”? ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 5. Is water a polar molecule? Explain your reasoning. ___________________________________________________________________________ ___________________________________________________________________________ 6. What is a hydrogen bond? ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ Hon Env Sci Ms. Sipe Name _________________________ Period _____ Date _____________ 7. Draw four water molecules and use dashed lines between them to represent hydrogen bonding that exists. Use solid lines to represent covalent bonds. Show the S+ and Scharges on the correct atoms. 8. How does the polarity of water and hydrogen bonding account for properties that sustain life? ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ Hon Env Sci Ms. Sipe Name _________________________ Period _____ Date _____________ Station 7: Water- The Universal Solvent Water is capable of dissolving a variety of different substances, which is why it is such a good solvent. In fact, water is called the "universal solvent" because it dissolves more substances than any other liquid. This is important to every living thing on earth. It means that wherever water goes, either through the air, the ground, or through our bodies, it takes along valuable chemicals, minerals, and nutrients. It is water's chemical composition and physical attributes that make it such an excellent solvent. Water molecules have a polar arrangement of oxygen and hydrogen atoms—one side (hydrogen) has a positive electrical charge and the other side (oxygen) had a negative charge. This allows the water molecule to become attracted to many other different types of molecules. Water can become so heavily attracted to a different molecule, like salt (NaCl), that it can disrupt the attractive forces that hold the sodium and chloride in the salt molecule together and, thus, dissolves it. At the molecular level, salt dissolves in water due to electrical charges and due to the fact that both water and salt molecules are polar, with positive and negative charges on opposite sides in the molecule. A salt molecule consists of a sodium and chloride atom, and they are called ions because they both have an electrical charge—the chloride ion is negatively charged and the sodium ion is positively charged. Likewise, a water molecule is ionic in nature, but the bond is called covalent, with two hydrogen atoms both situating themselves with their positive charge on one side of the oxygen atom, which has a negative charge. When salt is mixed with water, the salt dissolves because the covalent bonds of water are stronger than the ionic bonds in the salt molecules. The positively-charged side of the water molecules are attracted to the negatively-charged chloride ions and the negatively-charged side of the water molecules are attracted to the positively-charged sodium ions. Essentially, a tug-of-war ensues with the water molecules winning the match. Water molecules pull the sodium and chloride ions apart, breaking the ionic bond that held them together. After the salt molecules are pulled apart, the sodium and chloride atoms are surrounded by water molecules, as the diagram above shows. Once this happens, the salt is dissolved, resulting in a homogeneous solution. Hon Env Sci Ms. Sipe Name _________________________ Period _____ Date _____________ Part A. Define the following terms. 1. Solute ________________________________________________________________________ ________________________________________________________________________ 2. Solvent ________________________________________________________________________ ________________________________________________________________________ 3. Solution ________________________________________________________________________ ________________________________________________________________________ 4. Homogeneous Solution ________________________________________________________________________ ________________________________________________________________________ 5. Heterogeneous Solution ________________________________________________________________________ ________________________________________________________________________ 6. Ion ________________________________________________________________________ ________________________________________________________________________ Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Part B. Use the introductory information and internet to answer the following. 1. Why is water called the “Universal Solvent”? Include the important physical attributes and chemical composition in your answer. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 2. Explain how your own kidneys and water's solvent properties make them a great pair in keeping us alive and healthy. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 3. Explain how salts dissolve in water. ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Station 8: Cohesion & Surface Tension Cohesion refers to the tendency of molecules of the same kind to stick to one another. The cohesive forces between similar liquid molecules are responsible for the phenomenon known as surface tension. The molecules at the surface (of a glass of water, for example) do not have other water molecules on all sides of them and so they cohere more strongly to those directly next to and below them, but not above. The stronger cohesion between the water molecules as opposed to the attraction of the water molecules to the air makes it more difficult to move an object through the surface than to move it when it is completely submersed. The cohesive forces between molecules in a liquid are shared with all neighboring molecules. Those on the surface have no neighboring molecules above and, thus, exhibit stronger attractive forces upon their nearest neighbors on and below the surface. Surface tension could be defined as the property of the surface of a liquid that allows it to resist an external force, due to the cohesive nature of the water molecules. Water molecules want to cling to each other. At the surface, however, there are fewer water molecules to cling to since there is air above (thus, no water molecules). This results in a stronger bond between those molecules that actually do come in contact with one another, and a layer of strongly bonded water (see diagram to the left). This surface layer (held together by surface tension) creates a considerable barrier between the atmosphere and the water. In fact, other than mercury, water has the greatest surface tension of any liquid. Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Part A. Define the following terms. 1. Cohesion ___________________________________________________________________________ ___________________________________________________________________________ 2. Surface Tension ___________________________________________________________________________ ___________________________________________________________________________ Part B. Research and provide an explanation for why or how the following are examples of surface tension. Do not just say “due to surface tension”. 1. Why can small insects like the water strider shown at the top of the station handout can walk on water? ___________________________________________________________________________ ___________________________________________________________________________ 2. When camping one night during the summer, it starts to rain. You wake up in the morning relieved that your sleeping bag and belongings are dry. However, when you sit up and accidently bump the side of the tent, water drips through. Why? ___________________________________________________________________________ ___________________________________________________________________________ 3. Washing clothes in cold water may be just as effective as washing with hot water. Why? (Hint: Think about the water temperature and the use of soaps or detergents). ___________________________________________________________________________ ___________________________________________________________________________ 4. Explain why bubbles are round and rain drops are spherical. ___________________________________________________________________________ ___________________________________________________________________________ Hon Env Sci Name _________________________ Period _____ Ms. Sipe Date _____________ Part C. Surface Tension Demonstration. Materials: A penny A pipette A small beaker of water A small beaker with dish soap Paper towels Procedure: 1. Predict how many drops of water will fit on top of a penny. Water Water Soapy 2. Drop water on top of the penny one at a time until it drips over onto the lab table. Observe the water carefully between each subsequent drop. How many drops fit on the penny before it spilled? Water Soapy Water 3. Sketch the penny with the water on top right before it spilled. Water on penny Soapy water on penny 4. Repeat the demonstration with soapy water and discuss your results. Were the results the same or different? Explain. ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________
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