Department of Natural Resources and Mines Geological Survey of Queensland Rhenium opportunities in Queensland What is rhenium? Rhenium (Re) is one of several strategic elements that have not been exploited in significant quantities, but which are now attracting interest because of likely new sources and their potential use in new technologies. • Rhenium is a silver-white very dense metal with the atomic number of 75. • Rhenium was the last stable element in nature to be discovered; it was found in 1925 by a team of German scientists. • With an estimated average crustal concentration of 1 part per billion (1ppb), rhenium is one of the rarest elements in the earth’s crust. • Rhenium has a melting point of 3186°C, the third highest melting point of all elements apart from carbon and tungsten. It has the highest boiling point of any element at 5596°C. • At 21.0 g/cm3, rhenium is one of the densest of all elements—a 1 m3 block weighs 21 tonnes). • Rhenium is rigid under stress and remains ductile from 0° Kelvin to its melting point without fracturing, making for easy machining. • Rhenium is one of a group of refractory metals, including niobium, molybdenum, tantalum and wolfram that have very high resistance to heat and wear. • Rhenium is probably not found free in nature, but only in the mineral molybdenite which is the major commercial ore. How do we use rhenium? Rhenium’s low production levels have restricted its usefulness, but possible future increased production will lead to more research and wider use. Regular supply, such as that predicted to come from Queensland (see ‘Where is rhenium found in Queensland?’), will see rhenium use increase and become more common. Currently, rhenium is used in: • Jet engines. Super alloys of rhenium and nickel are used in high temperature turbine engine components by jet engine manufacturers such as General Electric, Rolls-Royce and Pratt & Whitney. Compared to standard engines, rhenium turbines operate at much higher temperatures, produce more power and thrust, are more fuel efficient and have lower emissions. The use of rhenium alloys in all new turbines will raise the strategic importance of the metal. • Catalysts in fuels. Platinum–rhenium catalysts are used in making lead-free high octane petrol. Great state. Great opportunity. September 2014 • Thermometers. Tungsten–rhenium alloys, which are ductile and easier to machine are used as thermocouples to measure temperatures up to 2200°C. • X-ray sources. Tungsten–rhenium alloys are also used as X-ray sources. The high melting points of both compounds, and high atomic mass, make them stable under prolonged electron impact. • Lighting. Rhenium is widely used in filaments in mass spectrographs and also as an electrical contact material. Where is rhenium found in Queensland? Chile has the world’s largest rhenium reserves in molybdenite as a minor constituent of its porphyry copper deposits, and was the leading global producer in 2005. However, the Merlin deposit is the world’s highest grade molybdenum and rhenium deposit and is hosted by the metasedimentary rocks of the Kuridala Group in the Mount Isa Eastern Succession. Very high-grade molybdenum mineralisation close to the surface also occurs at its southern end in the subsidiary Little Wizard deposit. The origin of the mineralisation is unclear, but there are closely related copper–gold deposits in the region, which are classified as iron-oxide–copper–gold (IOCG) and are probably related to Proterozoic granitoids. The molybdenum–rhenium mineralisation is overlain by discrete copper and zinc-rich polymetallic sulphide zones of the Mount Dore ore body (Australian Mines Atlas, 2014). Published Probable Reserves at Merlin are 7.1 million tonnes (Mt) at 1.1% molybdenum and 18.1 grams per tonne (g/t) rhenium for a contained 78 thousand tonnes (kt) molybdenum and 129 tonnes rhenium. Inova (formerly Ivanhoe Australia and now Chinova Resources following a takeover by Shanxi Doughui Coal Coking& Chemicals Group Co. Limited) commenced construction of a decline at Merlin in late 2010 and reported that phase 1 was completed in early 2012. Phase 2 of the decline development is awaiting project approval (Australian Mines Atlas, 2014). Rhenium is also present at the Kalman copper–gold– molybdenum deposit 62 km southeast of Mount Isa. This molybdenum also contains high concentrations of rhenium. The deposit is still being explored. The deposit has Inferred Resources of 60.8 Mt at 0.05% molybdenum, 1.19 g/t rhenium, 0.32% copper and 0.15g/t gold, with a contained 30.4 kt of molybdenum (Australian Mines Atlas, 2014). The distribution of rhenium in Queensland was tested during a recent regional national geochemical survey. The survey showed several drainage systems in Queensland with anomalous rhenium concentrations in the sediments. Currently there has been no testing to determine their source. Further reading Further information http://minerals.usgs.gov/minerals/pubs/commodity/rhenium/ index.html#mcs GSQ hotline Email: [email protected] Telephone: +61 7 3006 4666 Geological Survey of Queensland Level 12, 61 Mary St Brisbane Qld 4000 www.dnrm.qld.gov.au 140° 145° 150° Queensland Molybdenum and Rhenium 10° Molybdenum & Rhenium occurrence Very Small Small " Medium Weipa Large Giant " Town Railway Road Permian-Triassic Granitoids " 15° Kennedy Igneous Association Cooktown Mesozoic basins Permian Triassic basins Devonian-Carboniferous basins VICTORIA MUNGANA RED DOME " " Cairns New England Orogen WOLFRAM CAMP TUNGSTEN PROSPECT Karumba Mossman Orogen Thomson Orogen MAUREEN Georgina Basin North Australian Craton COCKIE CREEK COPPER PROSPECT " BEN LOMOND Townsville 20° JULIA CREEK VANADIUM-MOLYBDENUM PROSPECT - ALISONA-RICHMOND LINFIELD ERNEST HENRY " N o r th er n Te r r i t o r y Mount Isa " MILO KALMAN Cloncurry LILYVALE JULIVON CREEK PROSPECT JULIA CREEK VANADIUM-MOLYBDENUM PROSPECT - ST ELMO-BURWOOD " 0 50 100 Hughenden " 200 Kilometres Mackay MERLIN/MOUNT DORE " ANTHONY Winton " " Clermont " Marlborough " Longreach " Emerald Rockhampton " Gladstone KAUFFMANS PROSPECT WHITEWASH " Bundaberg 25° CHINAMAN CREEK PROSPECT Maryborough " Produced by Publication Graphics SGS, Geological Survey of Queensland September 2014. © State of Queensland (Department of Natural Resources and Mines) 2014. http://creativecommons.org/licenses/by/3.0/au/deed.en Produced by Spatial and Graphic Services, Geological Survey of Queensland © The State of Queensland (Department of Natural Resources and Mines) 2014 http://creativecommons.org/licenses/by/3.0/au/deed.en MOUNT BIGGENDEN " " Charleville " Roma " Chinchilla Dalby ANDURAMBA PROSPECT " Toowoomba " N e w S o u th Wa l e s Gympie " Brisbane Ipswich " 14B\Factsheets\critical_elements So u t h A u s tr a l i a GSQ\14B\MG\CE\CrititcalElementWeb.mxd COALSTOUN LAKES PORPHYRY COPPER PROSPECT
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