CHEM 3: Midterm Exam 1: Spring 2016 (100 points) Name: ___________________________________ INSTRUCTIONS: On the FRONT and BACK of the scantron, fill out your name and 7-digit student ID. Fill in this information from left to right in the provided fields, and BUBBLE IN the values on the scantron. 1 point will be deducted from your exam grade for incomplete or erroneous filling of the scantron. Please read each question carefully. Where the question specifies “MARK ALL THAT APPLY”, you may need to select more than one answer on the scantron. 1. MARK ALL THAT APPLY: How does neutral cabon-14 differ from neutral oxygen-16? Be sure to consider each answer carefully. Remember, you can select as many answers as are correct. a. Oxygen-16 has more protons than carbon-14. b. Oxygen-16 has more neutrons than carbon-14. c. Oxygen-16 has more electrons than carbon-14. d. Oxygen-16 has a larger mass than carbon-14. e. None of the above. 2. How many electrons are in a carbide anion (C4-)? a. 2 b. 4 c. 6 d. 10 e. 12 3. Naturally occurring Tungsten (W) consists of the four isotopes below, and has an average atomic mass of 183.85 amu. Using ONLY this information, is it possible to determine which isotope is most abundant in nature? If so, which one? If this information alone isn’t sufficient to identify the most abundant isotope, select E. Tungsten Isotope Isotopic Mass (amu) a.) Tungsten-182 181.948 b.) Tungsten-183 182.950 c.) Tungsten-184 183.950 d.) Tungsten-186 185.954 e.) Cannot be determined from information provided. Mass spectrometry data would have to be collected and analyzed. 4. How many significant figures are in this measurement: 0.09010 g? a. 2 b. 3 c. 4 d. 5 e. 6 5. How would you round the number 3,951 to two significant figures? a. 3 b. 39 c. 40 d. 4,000 e. 4.0 x 103 6. Using the rule for multiplication & division with significant figures, what is the answer to the calculation below? (45.90 g) ÷ (2.70 g/mL) = ________ a. 20 mL b. 20. mL c. 17 mL d. 17.0 mL e. 17.00 mL 7. Using the rule for addition & subtraction with significant figures, what is the answer to the calculation below? (9.71 mL) + (0.592 mL) = _______ a. 10 mL b. 10.3 mL c. 10.30 mL d. 10.302 mL e. 10.3020 mL 8. Using rules for significant figures, what is the answer to the calculation below? (10.3 g + 0.19 g) ÷ (19.81 mL) = _________ a. 0.529531 g/mL b. 0.5295 g/mL c. 0.530 g/mL d. 0.53 g/mL e. 0.5 g/mL 9. Convert this number to PROPER scientific notation: 0.0078 x 107 a. 7.8 x 107 b. 7.8 x 1010 c. 7.8 x 104 d. 7.8 x 109 e. 7.8 x 105 10. Convert this number to standard notation: 13.9 x 10-5 a. 0.00139 b. 0.000139 c. 0.0000139 d. 1390000 e. 13900000 11. Convert 295 ng to g. a. b. c. d. e. 2.95 x 109 g 2.95 x 107 g 2.95 x 10-7 g 2.95 x 10-9 g 2.95 x 10-11 g 12. Convert 4.2 x 10-4 mg to µg. a. b. c. d. e. 4.2 x 10-13 µg 4.2 x 10-7 µg 4.2 x 10-1 µg 4.2 x 105 µg 4.2 x 1013 µg 13. Convert 8.78 g/cm3 to kg/L. a. b. c. d. e. Hint: 1 cm3 = 1 mL 8.78 x 106 kg/L 8.78 x 103 kg/L 8.78 kg/L 8.78 x 10-3 kg/L 8.78 x 10-6 kg/L 14. Convert 7.74 x 10-8 m3 to cm3. a. b. c. d. e. 7.74 x 10-14 cm3 7.74 x 10-11 cm3 7.74 x 10-10 cm3 7.74 x 10-6 cm3 7.74 x 10-2 cm3 15. What is the volume of 28.9 g of gold (Au)? Information that MIGHT be useful: Gold has a density of 19.3 g/cm3, and a molar mass of 196.96 g/mol. a. b. c. d. e. 0.147 cm3 0.668 cm3 1.50 cm3 2.83 cm3 558 cm3 16. How many moles of iron (Fe) are in 3.1 x 1022 atoms of iron? Information that MIGHT be useful: Iron has a density of 7.870 g/mL, and a molar mass of 55.845 g/mol. a. b. c. d. e. 0.051 mol 0.405 mol 2.8 mol 19.4 mol 5.1 x 1044 mol 17. What is the molar mass of Mg(NO3)2 to 3 significant figures? a. 54.3 g/mol b. 68.3 g/mol c. 118 g/mol d. 134 g/mol e. 148 g/mol 18. How many moles are in 22.0 g of CO2? a. b. c. d. e. 2.00 mol 0.500 mol 0.786 mol 22.0 mol 968 mol 19. How many atoms are present in 32.7 g of Nickel (Ni)? Information that MIGHT be useful: Nickel has a density of 8.908 g/cm3, and a molar mass of 58.693 g/mol. a. 3.36 x 1023 atoms b. 2.98 x 1022 atoms c. 1.08 x 1024 atoms d. 9.25 x 1021 atoms e. 1.97 x 1025 atoms 20. The correct name for Co2S is: a. cobalt sulfide b. cobalt sulfate c. cobalt sulfite d. cobalt (II) sulfide e. cobalt (I) sulfide 21. The correct name for Cl3O6 is: a. trichlorine hexoxide b. chlorine (IV) oxide c. chlorine (VI) oxide d. chlorine (I) oxide e. dichlorine heptoxide 22. The correct name for FeN is: a. iron nitrate b. iron nitride c. iron nitrite d. iron (I) nitride e. iron (III) nitride 23. The formula for iron (II) phosphate is: a. Fe3P2 b. FePO4 c. Fe2(PO4)3 d. Fe3(PO4)2 e. FePO3 24. MARK ALL THAT APPLY: Which formulas below are INCORRECT with improperly balanced charges? Be sure to consider each answer carefully. Remember, you can select as many answers as are correct. a. MgO b. CaPO4 c. NaClO3 d. NH4SO4 e. AlP 25. MARK ALL THAT APPLY: Which acids below are named incorrectly? Be sure to consider each answer carefully. Remember, you can select as many answers as are correct. a. H2SO3 is sulfurous acid b. H2SO4 is hydrosulfuric acid c. HCl is hydrochloric acid d. HNO2 is hydronitric acid e. HClO3 is chloric acid 26. MARK ALL THAT APPLY: Which substances below are covalent compounds? Be sure to consider each answer carefully. Remember, you can select as many answers as are correct. a. NH4OH b. CS2 c. Na2O d. P2O5 e. FeCl3 EXTRA CREDIT: Challenge Problem: NO PARTIAL CREDIT--Attempt after finishing the exam and checking your work 1. (5 points) Verify the following statement: ”There are more atoms within the smallest speck of matter visible to the naked eye, than there are stars in the whole of our Milky Way galaxy.” FOR THIS COMPARISON: Determine the total number of atoms in a spherical drop of water with a diameter of 0.05 mm. Compare this number to the number of stars in our galaxy (approximately 1 x 10 11). Which is larger? By how much? Hints: Water has a density of 0.998 g/mL Volume of a Sphere = 4/3∙π∙r3 diameter = 2 x radius REFERENCE EQUATIONS: 𝑴𝒂𝒔𝒔 Density = 𝑽𝒐𝒍𝒖𝒎𝒆 Average atomic mass = (isotopic mass)∙(isotopic abundance) 1 mole = 6.022 x 1023 particles 1 cm3 = 1mL Summing over all isotopes.
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