DESCRIBING CHEMICAL REACTIONS Reactants: Zn + I2 Product: Zn I2 Chemical Reactions In the course of a chemical reaction, the reacting substances are converted to new substances. Indications of a Chemical Reaction: Changes of Matter • Physical Changes: □ Changes in matter that do not change the composition of a substance. • Changes of state, temperature, volume, etc. • Chemical Changes: □ Changes that result in new substances. • Combustion, oxidation, decomposition, etc. 1.Color change • The visible light absortivity of product molecules is different that that of reactant molecules. 2.Production of a gas • Bubbling of product out of reactant mixture. 3.Change in Temperature • Energy is absorbed or released from reactant mixture. 4.Formation of a Precipitate • A solid is formed and falls out of the reactant mixture. 5.Production of Light • Electromagnetic radiation emanates from the reactant mixture. Chemical Reactions are Represented by: 1. Word Equations Word equations describe a chemical reaction by listing the names of reactant and product molecules on opposite sides of an arrow representing the direction of the reaction Water → Hydrogen + Oxygen When writing word equations, list the reactant particles on the left side of the arrow separated by “+” signs, and product particles on the right side of the arrow, also separated by “+” signs. Write the word equation for the reaction represented below: Reactants: Zn + I2 Product: Zn I2 Word equations are not very descriptive and are only used to explain what reactants and products are involved in the reaction. 1 Anatomy of a Chemical Equation 2. Formula Equations Chemical equations use symbols, subscripts and coefficients to describe the identities and relative amounts of substances undergoing chemical reactions. CH4 (g) + 2 O2 (g) CO2 (g) + 2 H2O (g) 2 H2O (l) → 2 H2(g) + O2(g) Coefficient describing the number of reactant particle reacting Subscript – part of chemical formula of the reactant Subscript symbol denoting the reactant is in the liquid phase Anatomy of a Chemical Equation CH4 (g) + 2 O2 (g) CO2 (g) + 2 H2O (g) Products appear on the right side of the equation. Coefficients are inserted to balance the equation. Anatomy of a Chemical Equation CH4 (g) + 2 O2 (g) CO2 (g) + 2 H2O (g) The states of the reactants and products are written in parentheses to the right of each compound. Anatomy of a Chemical Equation CH4 (g) + 2 O2 (g) Reactants appear on the left side of the equation. Subscripts and Coefficients Give Different Information CO2 (g) + 2 H2O (g) • Subscripts tell the number of atoms of each element in a molecule 2 Subscripts and Coefficients Give Different Information Formula equations are preferred to word equations because they: • Use abbreviated chemical formulas rather than the full names • Include the physical states of reactants and products • Use symbols that describe the reaction environment • Subscripts tell the number of atoms of each element in a molecule • Coefficients tell the number of molecules • Use coefficients to describe the number of particles actually undergoing the reaction When writing formula equations: When writing formula equations: 1.The correct chemical formula must be used for all reactants and products. 2.The physical states must be given for each reactant and product Using the rules of nomenclature, each reactant and product must be defined as an atom, metallic element, alloy, molecular element, molecule or ionic compound and represented accordingly. Physical States at Room Temperature • Elements can exist metallic solids, molecules, and individual atoms. Physical States at Room Temperature Con’t. •Molecules can be (s), (l) or (g); you will just have to learn their natures. 3 Physical States at Room Temperature Con’t. NaCl Crystal Lattice • All natural ionic compounds are solids • However, ionic compounds can sometimes dissolve into solution. Many reactions involve ionic compounds dissolved in water called - aqueous solutions, represented by (aq). When writing formula equations: 3.The correct symbols must be included to describe the environment. When writing formula equations: 4.The law of conservation of mass must be satisfied • In any physical or chemical change, the mass of the reactants must equal the total mass of the products. Or, mass is conserved • Coefficients are added to chemical equations to satisfy the Law of Conservation of Mass. Lavoisier, 1788 4
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