575 Series Selection Guide VOC Chek 575 Series Selection Guide On-worker ppm Level Sampling of Organic Vapors SKC VOC Chek 575 Series Passive Samplers are available with sorbents such as activated carbon and Anasorb 747 that strongly retain the collected compounds and require solvent extraction for laboratory analysis. Use the following guide to locate target compounds and get an overview of critical sampling parameters along with the SKC catalog number of the recommended SKC VOC Chek 575 Series Passive Sampler. Visit www.skcinc.com and download our free SKC Sampling Guide app to access this information on your Android or Apple device. Validation Levels See the Validation Level column in this guide to determine the level of scientific testing. Go to www.skcinc.com and search the number in the Research Report column to access online research reports. Full – Stringent NIOSH testing protocol has been applied to verify sampler desorption efficiency, sampling rate, capacity, and the effects of relative humidity, temperature, concentration, reverse diffusion, and storage on accuracy. Bi-level – NIOSH testing protocol has been applied to the most volatile member of a related (homologous) series of chemicals; therefore, related less volatile series members require only partial validation (described below) to achieve the same level of sampling accuracy. See Guild et al. (http://doi.org/cjzqd7) or request a copy from SKC. Partial – NIOSH testing protocol has been applied to verify sampling rate, desorption efficiency, and storage stability. Calculated – This calculation of a sampling or uptake rate uses the diffusion coefficient of a specific chemical (D) and the cross-sectional area (A) and length (L) of the sampler’s diffusion path (based on sampler geometry). OSHA – Sampler has been validated by OSHA and is referenced in a published OSHA method. OSHA PELs ∆ Chemical Hazard Validation Research Level Report Acetic acid Acetic acid Acetoin (acetyl methyl carbinol) Acetone Acetone Acetonitrile Acetonitrile Acetyl methyl carbinol (acetoin) Acrylonitrile Allyl alcohol Allyl alcohol Allyl chloride Allyl chloride n-Amyl acetate n-Amyl acetate sec-Amyl acetate (2-pentyl acetate) n-Amyl alcohol n-Amyl alcohol t-Amyl methyl ether (methyl tert-amyl ether) Aniline Benzene Benzene Benzotrifluoride (trifluoromethyl benzene; OXSOL 2000) Benzotrifluoride (trifluoromethyl benzene; OXSOL 2000) Benzyl acetate Benzyl chloride Benzyl chloride Bromobenzene Bromodichloromethane (dichlorobromomethane) Bromoethane (ethyl bromide) Bromoform Bromomethane (methyl bromide) 1-Bromopropane (propyl bromide) 1-Bromopropane (propyl bromide) 1,3-Butadiene n-Butane n-Butanol (n-butyl alcohol) Calculated Calculated Calculated Full Full Calculated Calculated Calculated Full Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Bilevel Calculated Full OSHA 1005 Bilevel Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Full Full Calculated Calculated Calculated TWA (ppm) 10 10 1303 1303 15 # 15 # 1000 1000 40 40 2 2 2 1 1 100 100 125 10 C 4# 4# 2# 2# 1355 1312 5 1 1 100 100 10 1 1 200 0.5 5 5 1C 1C 250 # 20 C 1740 1740 Sampling Time CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 0.1 0.1 1 5 100 50 # 19.6 19.6 14.9 20.3 √ 15.2 ≈ 22.4 22.4 14.9 20.4 18.4 18.4 17.8 17.8 11.7 11.7 11.8 13.9 13.9 13.1 14.2 16 17.1 13.3 13.3 11.3 12.9 12.9 13.8 16.1 18.5 15.2 22.1 14.4 14.7 19.6 18.1 15.5 15 240 15 30 15 15 15 15 30 30 Max (hrs) Analytical DE % Method § GC-FID GC-FID GC-FID 4 GC-FID 8 ≈ GC-FID GC-FID GC-FID GC-FID 8 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 8 GC-FID GC-FID 8 GC-FID 8 GC-FID 8 GC-FID 8 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 8 GC-FID 8 GC-FID GC-FID GC-FID GC-FID SKC VOC Chek 575 Cat. No. 99.2 575-001 107.9 575-002 575-001 90.2 575-002 90.2 575-002 103 575-001 108 575-002 575-001 81 575-002 64 575-001 76 575-002 95.1 575-001 101.3 575-002 93.5 575-001 96 575-002 575-001 87.3 575-001 100.6 575-002 99 575-001 575-001 93.5 575-001 93.6 575-002 106 575-001 107 575-002 91.2 575-002 98.7 575-001 98.9 575-002 575-001 575-001 575-001 575-001 575-001 100 575-001 107 575-002 575-001 575-001 94 575-001 or 575-002 or 575-002 See page 212 for abbreviations. 76 SKC Ltd. www.skcltd.com • SKC South Africa www.skcsouthafrica.co.za 575 Series Selection Guide OSHA PELs ∆ Validation Research Level Report Chemical Hazard n-Butanol (n-butyl alcohol) 2-Butanol (sec-butyl alcohol) 2-Butanol (sec-butyl alcohol) 2-Butanone (methyl ethyl ketone, MEK) 2-Butanone (methyl ethyl ketone, MEK) 2-Butoxyethanol (butyl CELLOSOLVE solvent) n-Butyl acetate n-Butyl acetate n-Butyl acetate sec-Butyl acetate sec-Butyl acetate sec-Butyl acetate t-Butyl acetate t-Butyl acetate t-Butyl acetate Butyl acrylate t-Butyl alcohol n-Butyl alcohol (1-butanol) n-Butyl alcohol (1-butanol) sec-Butyl alcohol (2-butanol) sec-Butyl alcohol (2-butanol) t-Butyl benzene Butyl CELLOSOLVE acetate (ethylene glycol monobutyl ether acetate) t-Butyl ethyl ether (ethyl tert-butyl ether) n-Butyl glycidyl ether t-Butyl methyl ether (methyl t-butyl ether, MTBE) p-tert-Butyl toluene n-Butylbenzene sec-Butylbenzene gamma-Butyrolactone Camphor Camphor Carbolic acid (phenol) Carbon disulfide Carbon tetrachloride 2-CELLOSOLVE acetate (2-ethoxyethyl acetate) 1-Chloro-2-methyl benzene (monochlorotoluene; OXSOL 10) 1-Chloro-2-methyl benzene (monochlorotoluene; OXSOL 10) 1-Chloro-4-(trifluoromethyl)benzene (parachlorobenzotrifluoride; OXSOL 100) 1-Chloro-4-(trifluoromethyl)benzene (parachlorobenzotrifluoride; OXSOL 100) Chlorobenzene Chlorobenzene Chlorobromomethane Chloroethane (ethyl chloride) Chloroform Chloromethane (methylchloride) o-Chlorostyrene 4-Chlorotoluene Cumene (isopropyl benzene) Cumene (isopropyl benzene) Cyclohexane Cyclohexane Cyclohexanol Cyclohexanol Cyclohexene Cyclohexene Cyclopentane p-Cymene (4-isopropyltoluene) Decamethylcyclopentasiloxane (D5) Decamethyltetrasiloxane n-Decane 1-Decanol (decyl alcohol) Decyl alcohol (1-decanol) Desflurane Diacetone alcohol 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (ethylene dibromide) Calculated Calculated Calculated Bilevel OSHA 1004 Calculated OSHA 1009 Partial Partial Calculated Calculated OSHA 1009 Calculated Calculated OSHA 1009 Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Calculated Bilevel Calculated Full Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Calculated Bilevel Calculated Bilevel Bilevel Bilevel 1306 1894 1894 100 150 150 200 200 50 150 150 150 200 200 200 200 200 200 10 ‡ 100 100 100 150 150 CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 50 # 150 # 150 # 200 # 200 # 200 # 150 50 # 50 # 150 # 150 # 5 1356 50 5.6 ‡ 1352 10 2 mg/m3 2 mg/m3 5 20 10 100 50 ‡ 50 ‡ 25 ◊ Bilevel Partial Partial Calculated Calculated Bilevel Calculated Bilevel Calculated Bilevel Bilevel Bilevel Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Partial Calculated Partial Calculated Calculated Partial Calculated Calculated Calculated Calculated TWA (ppm) 1838 1374 15.6 C 30 25 C 15.5 15.6 15.6 17.1 16.88 12 13.07 12.3 13.2 12.8 12.8 12.74 12.7 12.7 13.09 11.7 15.8 15.5 15.5 15.6 15.6 11.3 10.4 13.1 11.6 13.6 10.4 11.23 11.3 16.6 10.8 10.8 14.5 19.54 14.1 12.1 13 13 11.8 Max (hrs) Analytical DE % Method § 30 8 15 15 15 8 8 8 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 15 12 8 15 30 30 8 8 8 15 8 15 30 8 8 15 8 8.5 15 8 8 98.3 95.4 91.8 91 102 575-002 575-001 575-002 575-002 575-002 575-002 575-002 575-001 575-002 575-001 575-002 575-002 575-001 575-002 575-002 575-002 575-002 575-001 575-002 575-001 575-002 575-002 575-002 575-001 575-002 575-001 575-001 575-002 575-002 575-002 575-001 575-002 575-001 575-001 575-001 575-002 575-001 575-002 575-001 575-002 101 104 97.4 100 103 80.9 94.2 113 11.8 15 8 GC-FID 108 75 75 200 1000 10 14.41 14.41 18.3 20.02 13 24.6 9.8 12.4 12.8 12.8 15.6 15.6 13.5 13.5 15.4 15.4 16.8 11.3 5.66 7.36 12.2 9.6 9.6 13.8 12.4 12.6 15.6 15.3 15 15 8 8 93.3 87.6 103 60 8 15 8 15 15 15 15 8 8 8 8 15 8 30 4 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 50 C 50 ‡ 5† 1893 2 50 1 ppb 20 30 SKC VOC Chek 575 Cat. No. 100 93 100 100 92.3 89.7 99.2 90.4 98.7 96.2 96.6 98.9 95.1 94.8 98.9 95 84 94 100 93 100 25 ◊ 50 50 300 300 50 50 300 300 1891 Sampling Time or 575-002 575-001 575-002 575-002 575-001 97.3 575-001 575-001 75.2 575-002 575-001 99.3 575-001 106 575-002 105 575-001 109 575-002 98 575-001 105 575-002 102 575-001 106 575-002 575-001 575-001 99 575-001 575-001 103 575-002 97.3 575-002 97.3 575-002 94.3 575-002 92.9 575-002 101.3 575-002 575-001 92.3 575-001 See page 212 for abbreviations. SKC Asia www.skc-asia.com • SKC Inc. www.skcinc.com 77 575 Series Selection Guide OSHA PELs ∆ Chemical Hazard Validation Research Level Report 1,2-Dibromoethane (ethylene dibromide) 1, 6-Dibromohexane (hexamethylene dibromide) o-Dichlorobenzene (1,2-dichlorobenzene) o-Dichlorobenzene (1,2-dichlorobenzene) m-Dichlorobenzene (1,3-dichlorobenzene) m-Dichlorobenzene (1,3-dichlorobenzene) p-Dichlorobenzene (1,4-dichlorobenzene) p-Dichlorobenzene (1,4-dichlorobenzene) 1,3-Dichlorobenzene (m-dichlorobenzene) 1,3-Dichlorobenzene (m-dichlorobenzene) 1,2-Dichlorobenzene (o-dichlorobenzene) 1,2-Dichlorobenzene (o-dichlorobenzene) 1,4-Dichlorobenzene (p-dichlorobenzene) 1,4-Dichlorobenzene (p-dichlorobenzene) Dichlorobromomethane (bromodichloromethane) Dichlorodifluoromethane (Freon 12) 1,1-Dichloroethane 1,2-Dichloroethane (ethylene dichloride) 1,2-Dichloroethene (1,2-dichloroethylene) 1,1-Dichloroethene (vinylidene chloride) Dichloroethyl ether 1,2-Dichloroethylene (1,2-dichloroethene) 1,2-Dichloroethylene (1,2-dichloroethene) Dichloromethane (methylene chloride) Dichloromethane (methylene chloride) 1,2-Dichloropropane (propylene dichloride) 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,2-Dichlorotetrafluoroethane (Freon 114) Dicyclopentadiene Diethyl ether (ethyl ether) Diethyl ketone (3-pentanone) Diethyl ketone (3-pentanone) Diethylene glycol dimethyl ether (2-methoxyethyl ether) Diethylene glycol monobutyl ether Diethylene glycol monoethyl ether Diethylene glycol monoethyl ether acetate Diethylene glycol monomethyl ether (2-[2-methoxyethoxy] ethanol) Diisobutyl ketone (DIBK), (isovalerone) 1,2-Dimethoxyethane (ethylene glycol dimethyl ether) Dimethoxymethane (methylal) Dimethyl adipate Dimethyl disulfide 2,5-Dimethyl hexane 2,2-Dimethyl methane Dimethyl pentanedioate Dimethyl sulfide Dimethyl sulfoxide N,N-Dimethylaniline 2,2-Dimethylbutane (neohexane) trans-1,2-Dimethylcyclohexane N,N-Dimethylformamide (DMF) 2,3-Dimethylpentane 1,4-Dioxane Diphenyl oxide (phenyl ether) Dipropyl ketone (4-heptanone) Dipropyl ketone (4-heptanone) Dipropylene glycol methyl ether Dodecamethylcyclohexasiloxane n-Dodecanol (lauryl alcohol) n-Dodecanol (lauryl alcohol) 1-Dodecene 1-Dodecyl alcohol (lauryl alcohol) 1-Dodecyl alcohol (lauryl alcohol) Dodecyl methacrylate Enflurane (ethrane) Epichlorohydrin 2,3-Epoxy-1-propanol (glycidol) 2,3-Epoxypropyl methacrylate (glycidyl methacrylate) Calculated Calculated Partial Partial Calculated Calculated Calculated Calculated Calculated Calculated Partial Partial Calculated Calculated Calculated Calculated Calculated Bilevel Full Bilevel Calculated Full Full Full Full Bilevel Calculated Partial Partial Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Partial Calculated Calculated Calculated TWA (ppm) 20 CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 30 50 C 50 1875 75 75 50 C 50 C 1875 75 75 1000 100 50 1 5‡ 200 1323 1323 25 25 75 1886 1886 1‡ 100 15 C 125 125 1000 5‡ 400 200 ‡ 200 ‡ 1305 50 1000 5 10 100 1 50 ‡ 50 ‡ 100 1893 Sampling Time 2 5 50 15.3 10.7 12.5 12.5 12.95 12.95 12.95 12.95 12.95 12.95 12.5 12.5 12.95 12.95 16.1 18.6 16.85 14.2 14.8 12.3 12.5 14.8 14.8 14.7 16 14.3 15.6 13.6 14.4 15.3 11.8 16.4 14.8 14.8 11.5 9.97 9.85 9.88 11.3 10.3 14.7 17.1 10.73 15.4 11.86 21.7 10.8 19 16.3 12 14.2 12.4 16.4 12.8 15.8 10.4 12.1 12.1 10.8 6.75 8.7 8.7 9.29 8.7 8.7 7.6 13.8 16.4 17.8 11.45 Max (hrs) 15 15 8 8 15 15 8 8 60 15 60 8 8 8 15 15 240 15 15 8 8 8π 4 8 15 15 8 8 30 30 8 4 Analytical DE % Method § GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 99.4 79.2 77.1 91.8 92.7 91.1 94.7 91.8 92.7 79.2 77.1 91.1 94.7 95.8 97.1 95.2 97.1 97.1 96 96 97.7 101 99.4 83.9 100.3 98.3 106.1 87.2 91.4 85.3 112 84.3 107.5 103 107.5 103 101 88.2 SKC VOC Chek 575 Cat. No. 575-002 575-001 575-001 575-002 575-001 575-002 575-001 575-002 575-001 575-002 575-001 575-002 575-001 575-002 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-002 575-002 575-001 575-001 575-001 575-001 575-002 575-002 575-002 575-002 575-002 575-002 575-002 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-001 575-002 575-001 575-001 575-001 575-002 575-001 575-002 575-001 575-001 575-002 575-002 575-001 575-001 575-002 575-001 575-001 575-002 575-002 575-002 575-002 575-002 575-002 or 575-002 See page 212 for abbreviations. 78 SKC Ltd. www.skcltd.com • SKC South Africa www.skcsouthafrica.co.za 575 Series Selection Guide OSHA PELs ∆ Validation Research Level Report Chemical Hazard Ethanol (ethyl alcohol) 2-Ethoxyethanol 2-Ethoxyethanol 2-Ethoxyethyl acetate (2-CELLOSOLVE acetate) Ethrane (enflurane) Ethyl acetate Ethyl acetate Ethyl acrylate Ethyl alcohol (ethanol) Ethyl benzene Ethyl benzene Ethyl benzene Ethyl bromide (bromoethane) Ethyl butyl ketone (3-heptanone) Ethyl butyl ketone (3-heptanone) Ethyl chloride (chloroethane) Ethyl cyanide Ethyl ether Ethyl formate 2-Ethyl hexyl acetate Ethyl methacrylate Ethyl methacrylate Ethyl propionate Ethyl tert-butyl ether (tert-butyl ethyl ether) Ethylene dibromide (1,2-dibromoethane) Ethylene dibromide (1,2-dibromoethane) Ethylene dichloride (1,2-dichloroethane) Ethylene glycol Ethylene glycol diethyl ether Ethylene glycol dimethyl ether (1,2-dimethoxyethane) Ethylene glycol monobutyl ether acetate (butyl CELLOSOLVE acetate) Ethylene glycol monohexyl ether Ethylene glycol monomethyl ether acetate (methyl CELLOSOLVE acetate) Ethylene oxide 2-Ethylhexanol 2-Ethyltoluene 3-Ethyltoluene 4-Ethyltoluene Freon 11 (trichlorofluoromethane) Freon 113 (1,1,2-trichloro-1,2,2-trifluoroethane) Freon 114 (1,2-dichlorotetrafluoroethane) Freon 12 (dichlorodifluoromethane) Glutaric acid dimethyl ester Glycidol (2,3-epoxy-1-propanol) Glycidyl methacrylate (2,3-epoxypropyl methacrylate) Halothane n-Heptane n-Heptane 4-Heptanone (dipropyl ketone) 4-Heptanone (dipropyl ketone) 3-Heptanone (ethyl butyl ketone) 3-Heptanone (ethyl butyl ketone) 2-Heptanone (methyl n-amyl ketone) 1-Heptene Hexachlorobutadiene Hexachloroethane Hexadecane Hexamethyldisiloxane (L2) Hexamethylene dibromide (1,6-dibromohexane) n-Hexane n-Hexane Hexanol (hexyl alcohol) 2-Hexanone (methyl butyl ketone MBK) 2-Hexene Hexone (methyl isobutyl ketone [MIBK]) Hexone (methyl isobutyl ketone [MIBK]) sec-Hexyl acetate Hexyl alcohol (hexanol) Hexylene Partial Calculated Calculated Calculated Partial Partial Partial Bilevel Partial Bilevel Bilevel OSHA 1002 Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Full Full Calculated Bilevel Calculated Calculated Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Full Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Full Bilevel Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Partial Calculated Bilevel Bilevel Calculated Partial Calculated Bilevel OSHA 1004 Calculated Calculated Calculated 1876 1893 1894 1894 1876 TWA (ppm) CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 1000 200 200 100 2 400 400 5 1000 100 100 100 200 50 50 1000 250 # 400 100 100 100 1356 20 20 50 30 30 100 C 100 mg/m3 C 5 25 1543 1 5 EL 1000 1000 1000 1250 # 50 1893 500 500 50 ‡ 50 ‡ 50 50 100 0.02 ‡ 1 1892 200 † 500 500 1873 100 1304 100 100 50 Sampling Time 20.3 14.4 14.4 12.1 13.8 13.1 14.1 13.7 20.3 12.9 12.9 13.83 18.5 12.2 12.2 20.2 18.61 16.4 17.8 9.8 13.1 13.1 14 13.1 15.3 15.3 14.2 17.44 12.27 14.7 10.4 10.5 12.9 21.2 10.93 12.1 12.1 12.1 16.65 14.1 15.3 18.6 11.5 17.8 11.45 14.1 13.9 13.9 12.1 12.1 12.2 12.2 12.2 13.1 10.5 11.5 7.7 9.98 10.7 14.3 14.3 12.64 14.3 14.5 13.5 13.62 11.1 12.64 14.5 Max (hrs) 15 8 30 30 30 15 15 15 15 4 8 8 8 8 6 6 8 15 15 8 8 15 8 60 8 15 8 15 15 15 8 8 8 15 8 15 15 8 8 15 8 30 8 8 Analytical DE % Method § GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 99 100.8 111.2 95.4 101 92.8 100 94.2 99 100 104 99.1 GC-ECD GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 102 93.7 106 101 91 SKC VOC Chek 575 Cat. No. 575-002 575-001 575-002 575-002 575-002 575-001 575-002 575-002 575-002 575-001 575-002 575-002 575-001 87.9 575-001 103.4 575-002 575-001 575-001 575-001 575-001 99 575-002 84.7 575-001 104 575-002 575-001 101 575-001 92.3 575-001 99.4 575-002 95.8 575-001 575-002 575-002 575-001 575-002 575-001 92.4 575-002 or 575-002 575-005 575-002 575-002 575-002 575-002 575-001 575-001 575-001 575-001 575-002 575-002 575-002 99.9 575-002 105 575-001 108 575-002 85.3 575-001 112.2 575-002 87.9 575-001 103.4 575-002 99.8 575-002 575-001 575-001 575-001 575-001 102.9 575-001 575-001 100 575-001 112 575-002 92.9 575-002 104 575-002 575-001 94.6 575-002 92.9 575-002 575-002 92.9 575-002 575-001 See page 212 for abbreviations. SKC Asia www.skc-asia.com • SKC Inc. www.skcinc.com 79 575 Series Selection Guide OSHA PELs ∆ Validation Research Level Report Chemical Hazard Hexylene glycol Iodomethane (methyl iodide) Isoamyl acetate Isoamyl acetate Isoamyl alcohol Isobutyl acetate Isobutyl acetate Isobutyl acrylate Isobutyl alcohol Isobutyl alcohol Isoflurane Isooctyl alcohol Isopentane (2-methyl butane) Isophorone Isopropanol (isopropyl alcohol) Isopropyl acetate Isopropyl acetate Isopropyl alcohol (isopropanol) Isopropyl benzene (cumene) Isopropyl benzene (cumene) Isopropyl ether Isopropyl glycidyl ether 4-Isopropyltoluene (p-cymene) Isovalerone (diisobutyl ketone [DIBK]) Lauryl alcohol (1-dodecanol) Lauryl alcohol (1-dodecanol) Limonene Mesityl oxide Mesitylene (1,3,5-trimethylbenzene) Mesitylene (1,3,5-trimethylbenzene) Methanol (methyl alcohol) 2-Methoxy-1-propyl acetate 1-Methoxy-2-propanol (propylene glycol monomethyl ether) 1-Methoxy-2-propanol (propylene glycol monomethyl ether) 1-Methoxy-2-propyl acetate (propylene glycol monomethyl ether acetate) 1-Methoxy-2-propyl acetate (propylene glycol monomethyl ether acetate) 2-Methoxyethanol (methyl CELLOSOLVE) 2-Methoxyethanol (methyl CELLOSOLVE) 2-[2-Methoxyethoxy] ethanol (diethylene glycol monomethyl ether) 2-Methoxyethyl ether (diethylene glycol dimethyl ether) Methoxyflurane Methyl acetate Methyl acrylate Methyl alcohol (Methanol) Methyl amyl alcohol (methyl isobutyl carbinol) Methyl bromide (bromomethane) 2-Methyl butane (isopentane) Methyl butyl ketone (MBK), (2-hexanone) Methyl CELLOSOLVE (2-methoxyethanol) Methyl CELLOSOLVE (2-methoxyethanol) Methyl CELLOSOLVE acetate (ethylene glycol monomethyl ether acetate) Methyl chloroform (1,1,1-trichloroethane) Methyl cyclohexane Methyl ethyl ketone (MEK), (2-butanone) Methyl ethyl ketone (MEK), (2-butanone) Methyl formate Methyl iodide (iodomethane) Methyl isoamyl ketone Methyl isobutyl carbinol (methyl amyl alcohol) Methyl isobutyl ketone (MIBK), (hexone) Methyl isobutyl ketone (MIBK), (hexone) Methyl isopropyl ketone Methyl isothiocyanate Methyl methacrylate (MMA) Methyl n-amyl ketone (2-heptanone) 2-Methyl pentane Methyl propyl ketone (2-pentanone) Calculated Calculated Calculated Calculated Calculated Calculated OSHA 1009 Calculated Calculated Calculated Full Calculated Calculated Calculated Partial Calculated Calculated Partial Bilevel Bilevel Calculated Calculated Calculated Bilevel Calculated Calculated Calculated Calculated Calculated Calculated Partial Calculated Calculated Calculated Calculated TWA (ppm) CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 25 C 100 100 100 150 150 125 # 100 100 1893 1839 1839 50 ‡ 1000 25 400 250 250 400 50 50 500 50 610 # 500 # 500 # 50 # 1308 50 1895 25 25 ¶ 25 ¶ 200 250 100 ‡ 100 ‡ 150 # 150 # Calculated Calculated Calculated Calculated Calculated Calculated Calculated Full Partial Calculated Calculated Calculated Partial Calculated Calculated Calculated Bilevel Bilevel Bilevel OSHA 1004 Calculated Calculated Calculated Calculated Bilevel OSHA 1004 Calculated Calculated Bilevel Calculated Calculated Calculated 0.1 0.1 1895 1873 1306 1304 1308 200 10 200 25 1000 100 0.1 0.1 25 Sampling Time 2 250 # 250 20C 610 # 350 500 200 200 100 11.81 18.7 11.9 11.9 13.9 12.8 13.16 12.2 15.6 15.6 13.2 10.9 15.8 11.3 18.42 14.2 14.2 18.42 12.8 12.8 13.4 12.8 11.3 10.3 8.7 8.7 11.1 13.7 12.1 12.1 1.2 12.1 14.7 14.7 12.2 100 100 200 15 8 15 8 15 8 15 15 15 8 8 8 30 8 15 8 Analytical DE % Method § GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID SKC VOC Chek 575 Cat. No. 575-002 575-001 91.9 575-001 108 575-002 575-002 106 575-002 99.1 575-002 575-002 93 575-001 100 575-002 96 575-002 575-002 575-001 575-002 103.5 575-002 88.5 575-001 101 575-002 103.5 575-002 99.3 575-001 106 575-002 575-001 575-001 575-001 98.3 575-002 107.5 575-001 103 575-002 102 575-002 575-001 93.6 575-001 96 575-002 101 575-007 575-002 82.9 575-001 100 575-002 108 575-001 12.1 GC-FID 103 575-002 16.1 16.1 11.3 11.5 13.3 17.8 15.7 1.2 12.8 22.1 15.8 14.3 16.1 16.1 12.9 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 94.7 91.1 575-001 575-002 575-002 575-002 575-002 575-002 575-002 575-007 575-002 575-002 575-001 575-002 575-001 575-002 575-002 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 99.9 106 100 92.3 14.1 14.2 17.1 16.88 20.58 18.7 12.3 12.8 13.5 13.62 14.8 17.36 13.1 12.2 14.1 14.8 50 25 100 100 Max (hrs) 15 15 8 8 15 8 15 15 15 8 8 12 8 30 8 8 7.5 8 95.7 94.3 101 104 94.7 91.1 92.4 575-001 575-001 575-002 575-002 575-001 575-001 575-002 575-002 94.6 575-002 92.9 575-002 575-002 575-001 100.5 575-002 99.8 575-002 575-001 92.6 575-002 See page 212 for abbreviations. 80 SKC Ltd. www.skcltd.com • SKC South Africa www.skcsouthafrica.co.za 575 Series Selection Guide OSHA PELs ∆ Validation Research Level Report Chemical Hazard 3-Methyl pyrrolidinone Methyl styrene (vinyl toluene) Methyl t-butyl ether (MTBE) Methyl tert-amyl ether (tert-amyl methyl ether) n-Methyl-2-pyrrolidinone 5-Methyl-3-heptanone 5-Methyl-3-heptanone Methylal (dimethoxymethane) Methylchloride (chloromethane) 1-Methylcyclohexanol 1-Methylcyclohexanol Methylcyclopentane Methylene chloride (dichloromethane) Methylene chloride (dichloromethane) 3-Methylhexane alpha-Methylstyrene Mineral spirits Monochlorotoluene (1-chloro-2-methylbenzene; OXSOL 10) Monochlorotoluene (1-chloro-2-methylbenzene; OXSOL 10) Neohexane (2,2-dimethylbutane) Nitrobenzene Nonane Nonyl alcohol Octadecane Octamethylcyclotetrasiloxane (D4) Octamethyltrisiloxane (L3) n-Octane n-Octane Octanol (octyl alcohol) 1-Octene Octyl alcohol (octanol) OXSOL 10 (monochlorotoluene [1-chloro-2-methyl benzene]) OXSOL 10 (monochlorotoluene [1-chloro-2-methyl benzene]) Parachlorobenzotrifluoride (1-chloro-4-[trifluoromethyl]benzene; OXSOL 100) Parachlorobenzotrifluoride (1-chloro-4-[trifluoromethyl]benzene; OXSOL 100) Pentadecane n-Pentane 3-Pentanone (diethyl ketone) 3-Pentanone (diethyl ketone) 2-Pentanone (methyl propyl ketone) 1-Pentene 2-Pentyl acetate (sec-amyl acetate) Perchloroethylene (tetrachloroethylene) Perchloroethylene (tetrachloroethylene) Perfluoromethylcyclohexane Phenol (carbolic acid) Phenyl ether (diphenyl oxide) Phenyl glycidyl ether 4-Phenylcyclohexene alpha-Pinene Propane n-Propanol (propyl alcohol) n-Propanol (propyl alcohol) Propionitrile n-Propyl acetate n-Propyl acetate Propyl alcohol (n-propanol) Propyl alcohol (n-propanol) Propyl bromide (1-bromopropane) Propyl bromide (1-bromopropane) n-Propylbenzene Propylene dichloride (1,2-dichloropropane) Propylene glycol monomethyl ether (1-methoxy-2-propanol) Propylene glycol monomethyl ether (1-methoxy-2-propanol) Propylene glycol monomethyl ether acetate (1-methoxy-2-propyl acetate) Propylene glycol monomethyl ether acetate (1-methoxy-2-propyl acetate) Calculated Calculated Full Bilevel Calculated Calculated Calculated Calculated Calculated Full Full Calculated Full Full Calculated Bilevel Calculated Bilevel Bilevel Calculated Calculated Bilevel Calculated Calculated Partial Partial Bilevel Bilevel Calculated Calculated Calculated Bilevel Bilevel Bilevel CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 50 ‡ 50 ‡ 25 ◊ 13.28 12.3 13.6 13.1 13.97 11.4 11.4 17.1 24.6 12.4 12.4 14.9 16 14.7 12.8 12.6 10.95 13 13 14.2 12.6 10.6 10.2 7.1 6.32 8.47 12.7 12.7 10.86 11.99 10.86 13 13 11.8 25 ◊ 11.8 100 1352 1355 51 25 25 1000 100 100 1323 1323 25 25 1359 125 125 100 C 500 50 ‡ 50 ‡ 1890 1902 Bilevel Calculated Full Calculated Calculated Calculated Calculated Calculated Full OSHA 1001 Partial Calculated Calculated Calculated Calculated Partial Calculated Calculated Calculated Calculated Calculated Calculated Calculated Calculated Full Full Calculated Bilevel Calculated Calculated Calculated TWA (ppm) 1311 1686 10 200 † 500 500 1000 200 ‡ 200 ‡ 200 125 100 100 5 1 10 200 C 200 C 15.6 C 1840 1740 1740 Sampling Time 1000 200 200 6‡ 200 200 200 200 0.1 0.1 75 100 ‡ 100 ‡ Calculated 150 # 150 # 7.93 14.9 14.8 14.8 14.8 16.3 11.8 13.1 13.06 10.2 14.5 10.4 11.6 11.53 11.3 21.73 17.7 17.7 18.61 14.1 14.1 17.7 17.7 14.4 14.7 12.1 14.3 14.7 14.7 12.2 Max (hrs) Analytical DE % Method § 8.5 30 8 8 15 15 8 8 15 240 4 8π 15 12 15 15 8 8 15 8 15 15 15 15 8 8 8 8 15 15 15 8 8 8 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID 15 8 GC-FID 15 8 7.5 5 12 8 15 8 30 30 8 8 15 8 12.1 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID SKC VOC Chek 575 Cat. No. 575-002 575-001 97.4 575-001 99 575-001 575-001 87.5 575-001 110.7 575-002 575-001 575-002 94.7 575-001 108 575-002 575-001 96 575-001 96 575-001 575-001 95.7 575-002 575-001 91.8 575-001 91 575-002 575-001 575-001 103 575-001 96.8 575-002 575-001 97.2 575-001 98.3 575-001 106 575-001 110 575-002 575-002 575-001 575-002 91.8 575-001 91 575-002 102 575-001 108 575-002 575-001 575-001 575-001 575-002 575-002 575-001 575-001 100.8 575-001 95.4 575-002 102 575-002 575-001 575-001 575-001 575-001 108.6 575-002 575-001 87.3 575-001 97.8 575-002 575-001 87.5 575-001 101.1 575-002 87.3 575-001 97.8 575-002 100 575-001 107 575-002 101 575-002 97.7 575-001 82.9 575-001 100 575-002 108 575-001 105.2 83.9 100.3 92.6 103 or 575-002 or 575-002 575-002 See page 212 for abbreviations. SKC Asia www.skc-asia.com • SKC Inc. www.skcinc.com 81 575 Series Selection Guide OSHA PELs ∆ Chemical Hazard Validation Research Level Report Propylene oxide Propylene oxide Pyridine Sevoflurane Solvent naphtha (petroleum) light aromatic Stoddard solvent Styrene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethylene (perchloroethylene) Tetrachloroethylene (perchloroethylene) Tetradecane Tetrahydrofuran 1,2,3,4-Tetramethylbenzene 1,2,3,5-Tetramethylbenzene 1,2,4,5-Tetramethylbenzene Toluene Toluene 1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane 1,1,1-Trichloroethane (methyl chloroform) Trichloroethylene Trichloroethylene Trichlorofluoromethane (Freon 11) 1,2,3-Trichloropropane Tridecane Trifluoromethyl benzene (benzotrifluoride; OXSOL 2000) Trifluoromethyl benzene (benzotrifluoride; OXSOL 2000) 1,2,3-Trimethylbenzene 1,2,3-Trimethylbenzene 1,2,4-Trimethylbenzene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene (mesitylene) 1,3,5-Trimethylbenzene (mesitylene) 2,2,4-Trimethylpentane n-Undecane Vinyl acetate Vinyl bromide Vinyl chloride Vinyl toluene (methyl styrene) n-Vinyl-2-pyrrolidone 4-Vinylcyclohexene Vinylidene chloride (1,1-dichloroethene) m-Xylene m-Xylene m-Xylene o-Xylene o-Xylene p-Xylene p-Xylene p-Xylene Calculated Calculated Calculated Partial Calculated Calculated Full OSHA 1014 Calculated Bilevel Full OSHA 1001 Calculated Partial Calculated Calculated Calculated Bilevel OSHA 111 Calculated Calculated Calculated Bilevel Bilevel Full OSHA 1001 Calculated Bilevel Calculated Bilevel Bilevel Calculated Calculated Partial Partial Calculated Calculated Calculated Calculated Full Calculated Calculated Calculated Calculated Calculated Bilevel Bilevel Bilevel OSHA 1002 Bilevel OSHA 1002 Bilevel Bilevel OSHA 1002 * # ∞ † ‡ ◊ ≈ ∆ Lower than the NIOSH-accepted guideline NIOSH Short Term Exposure Limit (STEL) Depends on detector sensitivity In-house exposure level NIOSH Recommended Exposure Limit (REL) Occidental Chemical corporate exposure limits Valid for PEL samples greater than 4 hours duration. If more than 1000 ppm of other contaminants are present, reduce maximum sample time to 4 hours. Agency standards for OSHA listings represent the OSHA PELs reported in 29 CFR 1910.1000 Part 1910, Section 1000. See page 212 for abbreviations. 82 TWA (ppm) CLG/STEL Sampling Rate Min (ppm) (ml/min) (min) 100 100 5 1893 2 1313 500 100 100 200 C 200 C 1686 5 100 100 200 C 200 C 1841 200 200 200 1000 300 C 300 C 1250 # 5C 10 350 100 100 200 C 200 C 50 1837 100 100 25 ¶ 25 ¶ 25 ¶ 25 ¶ 25 ¶ 25 ¶ 1860 4C# LFC ‡ 1 100 1 100 100 100 100 100 100 100 100 Sampling Time 150 # 150 # 150 # 150 # 150 # 150 # 150 # 150 # 19.9 19.9 16.6 12.8 11.61 10.95 13.7 13.55 13.63 11.8 13.1 13.06 8.3 17.7 11.1 10.8 11.2 14.5 14.89 14.1 11.34 11.4 12.5 14.1 14.9 14.24 16.65 11.9 9.2 13.3 13.3 12 12 13.05 13.05 12.1 12.1 11.89 9.62 16.4 19.6 21.4 12.3 13.9 12.4 12.3 12.5 12.5 13.82 11.9 14.24 12.8 12.8 13.94 Max (hrs) Analytical DE % Method § GC-FID GC-FID GC-FID 30 4 15 15 8 8 480 * 7.5 5 8 12 8 15 8 15 10 8 8 15 15 15 5 8 8 8 8 15 8 15 15 8 8 15 8 15 8 30 8 60 15 15 8 8 8 8 8 8 8 8 8 15 15 15 GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID GC-FID SKC VOC Chek 575 Cat. No. 98 99.7 88.2 100 575-001 575-002 575-002 575-002 575-001 575-001 86.3 575-002 96.7 575-006 98.3 575-002 64.4 ∞ 575-001 100.8 575-001 95.4 575-002 575-001 100.6 575-002 575-001 575-001 86.6 575-002 97.9 575-001 97 575-002 575-001 575-001 575-001 96.7 575-001 99.9 575-001 102 575-001 97.5 575-002 575-001 98.1 575-001 575-001 106 575-001 107 575-002 91.1 575-001 93.8 575-002 88.4 575-001 88.9 575-002 93.6 575-001 96 575-002 575-001 575-001 92 575-002 575-001 575-001 575-001 575-001 575-001 95.2 575-001 96.6 575-001 101 575-002 96.1 575-002 91 575-001 89.4 575-002 95.6 575-001 103 575-002 95.3 575-002 or 575-002 § The values given for the desorption efficiency were obtained in SKC Inc. laboratories. See the online guide at www.skcinc.com for details on the desorption solvent used. ¶ OSHA construction industry standards √ Valid for STEL samples up to 4 hours duration π If more than 1000 ppm contaminants are present, reduce maximum sample time to 4 hours. OARS-WEEL TWA Level (Occupational Alliance for Risk Science - Workplace Environmental Exposure Levels) EL Excursion Limit LFC Lowest feasible concentration More information at www.skcinc.com – search “Passive” SKC Ltd. www.skcltd.com • SKC South Africa www.skcsouthafrica.co.za
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