( Springer-Verlag 1999 Climate Dynamics (1999) 15 : 29—42 T. Goslar · B. Wohlfarth · S. Björck · G. Possnert J. Björck 14 Variations of atmospheric Dryas transition C concentrations over the Allero/ d-Younger Received: 15 April 1998/Accepted: 9 July 1998 Abstract Highly variable atmospheric radiocarbon concentrations are a distinct feature during the last deglaciation. The synchronisation of two high-resolution AMS 14C-dated records, Lake Gościa9 z5 , and a floating Late Weichselian glacial varve chronology at the Aller+d-Younger Dryas transition allowed us to assess in detail atmospheric *14C changes between late Aller+d and early Preboreal. The combined data set shows a drastic rise in *14C during the first 200 years or so of Younger Dryas and the two following about 500 year- long 14C plateaux. Model experiments which included variations in the geomagnetic field, atmospheric CO variations and a drastic reduction in 2 North Atlantic Deep Water flux at the onset of Younger Dryas allowed to reproduce the distinct rise in *14C during the first 200 years of Younger Dryas fairly well. Also the drop in *14C at the Younger Dryas/Holocene boundary seems reasonably explained by changes in North Atlantic Deep Water circulation. However, the reason behind the anomalous behaviour of the *14C signal in the middle of Younger Dryas remains an open question. T. Goslar ( ) Radiocarbon Laboratory, Institute of Physics, Silesian Technical University, Krzywoustego 2 PL- 44 100 Gliwice, Poland E-mail: [email protected] B. Wohlfarth Department of Quaternary Geology, Lund University, Tornavägen 13, S-223 63 Lund, Sweden S. Björck Geological Institute, University of Copenhagen, "ster Voldgade 10, DK-1350 Copenhagen K, Denmark G. Possnert Tandem Laboratory, Uppsala University, Box 533, S-75121 Uppsala, Sweden J. Björck Department of Quaternary Research, Stockholm University, S-106 91 Stockholm 1 Introduction The transition period between the Last Glacial Maximum and the present Interglacial was characterised by highly variable atmospheric radiocarbon (14C) concentrations. These are expressed by several long-lasting radiocarbon plateaux, sudden drops in radiocarbon ages (e.g. Hughen et al. 1998; Björck et al. 1996; Goslar et al. 1995a) and by a large offset between radiocarbon and calendar years (Kitagawa and van der Plicht 1998; Bard et al. 1993). A radiocarbon calibration curve based on U/Th-dated corals has been proposed to extend the Holocene dendro-calibration curve back in time (Stuiver and Reimer 1993). Unfortunately, the U/Th data points published so far (Bard et al. 1993, 1996; Edwards et al. 1993) still seem too scarce to reveal atmospheric *14C variations in great detail. These problems might, however, be overcome with AMS 14C dating of laminated sediment records. The new data sets from the Cariaco basin and Lake Suigetsu provide now, e.g. possibilities to assess radiocarbon variations more in detail (Hughen et al. 1998) and as far back as 35 14C ky BP or 38.0 cal ky BP (Kitagawa and van der Plicht 1998). Lacustrine terrestrial sequences have the advantage that radiocarbon and varve ages can directly be related to interstadial and stadial vegetation changes. One of these records is the laminated sediment sequence from Lake Gościaz5 in Poland, which covers a time period from late Aller+d up to the middle Holocene (Goslar et al. 1995a). The most unequivocal way of matching different radiocarbon-dated terrestrial chronologies to each other is to use the beginning and/or end of a radiocarbon plateau as a time-synchronous marker horizon. Since variations in past atmospheric 14C/12C ratios can be regarded as time-synchronous world wide, the rapid changes in radiocarbon ages at the end/beginning of a radiocarbon plateau are ideal markers for correlating 30 between densely 14C-dated records. Here, we combine three different high-resolution (AMS 14C) dated terrestrial data sets, which all show a distinct drop in radiocarbon ages at the Aller+d (AL) — Younger Dryas (YD) boundary: the laminated lake record from Lake Gościa9 z5 (LG) in Poland (Goslar et al. 1995a), the nonlaminated, but high-resolution AMS 14C-dated lake sediment sequence from lake Madtjärn (LM) in SW Sweden (Björck et al. 1996) and, a floating late Weichselian glacial varve chronology, which forms part of the Swedish Time Scale (STS) (Fig. 1). The synchronisation between two of these different types of high-resolution dated terrestrial chronologies (LG and the STS) at the AL—YD boundary, allows the possibility of assigning calendar-year ages to the floating varve chronology and makes it feasible to reconstruct and discuss variations in atmospheric *14C (*14C!5.) over this transition. Wiggles in the radiocarbon calibration curve are equivalent to variations of past atmospheric 14C concentrations. Rapid drops in 14C age and plateaux of constant 14C age reflect, respectively, increases and decreases of atmospheric 14C. Following models by e.g. Hughen et al. (1998), Stocker and Wright (1996), Björck et al. (1996) and Goslar et al. (1995a), the maximum in atmospheric 14C concentration around the Aller+d- Fig. 1A Location of Lake Gościa9 z5 (¸G) in Poland, Lake Madtjärn (¸M) and the Swedish Time Scale. B The different regional varve chronologies which form part of the STS are shown by striped bars; those of Cato (1987), Lidén and Cato (in preparation) and Strömberg (1985, 1989) cover the Holocene part, while those of Brunnberg (1995), Strömberg (1994), Kristiansson (1986) and Ringberg (1991) make up the Late Weichselian part. Mullsjön (MS) and the 770-y long varvedclay chronology (open rectangle) discussed in the text are indicated Goslar et al.: Variations of atmospheric 14C concentrations Younger Dryas transition could be interpreted as a manifestation of a drastic weakening of the North Atlantic thermohaline circulation (THC). Such a change in THC in turn may be a plausible mechanism of rapid global climatic changes (Broecker 1991). Goslar et al.’s (1995) and Björck et al.’s (1996) conclusions were based on a few 14C dates only. By combining the three records from LG, LM and the STS and by synchronising the data sets from LG and the STS, we are here able to document the large maximum in *14C during the early YD by a more extensive set of dates. 2 The data set 2.1 Lake Gościa9 z5 (LG) Lake Gościa9 z5 is situated in central Poland (Fig. 1A) and has a sequence of annually laminated sediments deposited between about 3 and 12.8 cal ky BP (Goslar et al. 1995a, b; Ralska-Jasiewiczowa et al. 1992). The large set of proxy climate data allows a detailed correlation to the major European pollen zones and to the Greenland ice core record (GRIP). By ‘wiggle-matching’ the densely spaced AMS 14C measurements on terrestrial macrofossils to the Holocene calibration curve, it was possible to tie the floating varve chronology from LG to calendar years (Goslar et al. 1995b). Combined pollenstratigraphic investigations and stable 18O analyses allowed defining the transitions between AL and YD to Goslar et al.: Variations of atmospheric 14C concentrations 31 12580$130 cal y BP, and between YD and Preboreal (PB) to 11440$120 cal y BP (Goslar et al. 1995a). Recently, Goslar and Ma9 dry (1998) presented an improvement of the wiggle-matching technique, and updated the calendar-year age of the LG chronology, through the match to the revised oak chronology (Björck et al. 1996). Accordingly, the ages of the AL/YD and YD/PB transitions have been adjusted to 12 650$60 cal y BP and 11 510$40 cal y BP. 2.2 Lake Madtjärn (LM) Madtjärn is a small lake situated in southwest Sweden (Fig. 1A). Pollen stratigraphy, macrofossil and stable isotope analyses allow an assignment to the Scandinavian Late Weichselian and early Holocene climatic and vegetational development (Björck and Digerfeldt 1991; Wohlfarth et al. in preparation). LM became deglaciated during AL and the marine isolation occurred slightly before the AL-YD boundary. Late AL sediments comprise a succession from marine clays to gyttja clay, clayey gyttja and moss-rich clayey gyttja. The transition from clay gyttja to clayey fine detritus gyttja marks the boundary between YD and PB as a distinct lithological change. The densely spaced AMS 14C dates performed on terrestrial macrofossils give a high-resolution 14 °C stratigraphy for the AL-YD-PB pollen zones (Björck et al. 1996, 1997). 2.3 The Swedish Time Scale (STS) Glacial and postglacial varved clays are a common feature in lakes and peat bogs along the Swedish east coast, in the estuaries of the large rivers in northern Sweden and in the Baltic Sea. The glacial varved clays deposited during the Late Weichselian and Early Holocene retreat of the Scandinavian inland ice and reflect the seasonal melting of the ice sheet with their silty summer and clayey winter laminae (Björck et al. 1992). The postglacial varved clays cover the Holocene time period up to present and are mainly delta sediments deposited in the estuaries of the large rivers in northern Sweden (Widerlund and Roos 1994; Cato 1987). Already early this century varved clays were used to create a time scale for the ice recession from southern to northern Sweden, by correlating successively younger varve diagrams with each other (De Geer 1912). This time scale has later been revised and many more varve diagrams were added to strengthen the Holocene (Lidén and Cato in preparation; Cato 1987; Strömberg 1985) and the Late Weichselian part of the chronology (Brunnberg 1995; Strömberg 1994, 1989; Ringberg 1991; Kristiansson 1986) (Fig. 2A, B). Based on these revisions and on the correlations presented by Lidén and Cato (in preparation), Brunnberg (1995), Strömberg (1994, 1989, 1985), Björck and Möller (1987), Cato (1987) and Kristiansson (1986), the STS had been regarded as a continuous calendar year chronology covering the last about 13300 varve years (Wohlfarth et al. 1995). Accordingly, earlier AMS 14C dates obtained on terrestrial macrofossils from the Late Weichselian varves were related to varve years BP by assuming that the STS is a correct, calendar-year time scale (Wohlfarth et al. 1995, 1993). Recently, however, several pieces of evidence have been put forward, which clearly indicate errors in the STS. 1. The calibrated age of an AMS 14C date obtained on terrestrial macrofossils from the Holocene varves differs by several hundred years compared to the corresponding varve age and indicates an error between approximately 2000—5000 varve y BP (Wohlfarth et al. 1997). 2. A discrepancy of several hundred years exists between the varve age BP and the calibrated age BP for one of the most widely spread marker horizons in varved and non-varved sequences along the Swedish east coast, the Yoldia ingression (Björck et al. 1996). This ingression which is synchronous with the Preboreal Oscillation (11300—11150 cal y BP) (Björck et al. 1997) is dated to Fig. 2 A The linkage of the different regional varve chronologies of the Swedish Time Scale according to Björck et al. (1992), Strömberg (1994), Brunnberg (1995) and Björck and Möller (1987). The connection between Strömberg’s (1989) and Lidén and Cato’s (in preparation) chronologies is based on drainage varves. Brunnberg’s chronology (1995) is in turn linked to Strömberg’s (1989) chronology by overlapping varve diagrams and the marker varves of the Yoldia ingression (marked by a striped bar). The match between Brunnberg’s (1995) and Kristiansson’s chronology (1986) is based on a colour change visible in both chronologies and on overlapping varve diagrams. The connection between Kristiansson’s (1986) and Ringberg’s (Ringberg 1991) chronology is a tentative link, suggested by Björck and Möller (1987). B Location of errors within the regional varve chronologies: '300 y in the middle Holocene and possibly about 300 y in the early Holocene (Wohlfarth et al. 1997; Björck et al. 1996), #47 y within Kristiansson’s (1986) chronology and about # 1400 y in the early Late Weichselian (Wohlfarth in preparation). The addition of 47 y could be confirmed through the new 770-year long varve chronology, while the prolongation by 1400 y is still tentative and has to be evaluated by further investigations. Pollenstratigraphic investigations on the varves in south easternmost Sweden (Ringberg 1991) by Ising (in preparation) show that these varves were deposited during the B+lling and Older Dryas pollen zone. In comparison with the GRIP ice core (Johnsen et al. 1992), Ringberg’s (1991) chronology is, therefore, placed between about 14000 and 14600 calendar y BP about 10430—10310 varve y BP (Brunnberg 1995) (Fig. 2A), which indicates an offset of 870 y. 3. The AL-YD transition, which had been estimated in the varved clays to about 12 varve ky BP is 600 years younger, when Goslar et al.: Variations of atmospheric 14C concentrations 32 compared to the LG record (about 12.65 cal ky BP) (Goslar et al. 1995a; Wohlfarth et al. 1995). 4. An additional offset is visible during the older part of the STS, i. e. the B+lling to early AL varves, when the varve ages BP of the corresponding AMS 14C dates are compared to the 14C-U/Th coral record (Wohlfarth 1996). These pieces of evidence show beyond doubt, that the present-day STS can not be regarded as a continuous calendar-year chronology and that the critical parts have to be revised (Fig. 2B) before the Late Weichselian AMS 14C dates can unequivocally be tied to varve years BP. All AMS 14C dates obtained so far can be divided into three parts (Table 1, Fig. 1B). A. The youngest 14C dates were obtained from the site Mullsjön, which is situated in south-central Sweden. The varve diagram could be correlated to the oldest part of Strömberg’s (1994) varve chronology. The varve ages assigned here to the 14C dates were set 800 y older than Strömberg’s (1994) varve years, according to the discrepancy outlined already. B. The local varve ages attributed to the AMS 14C dates from the sites Nedre Emmaren, Tynn, Gummetorpasjön, Hargsjön, Adlerskogssjön and Glottern are based on an independent 770-year long varve chronology, which has been established in southeastern Sweden by cross correlating 26 varve diagrams (Wohlfarth et al. in print) (Figs. 1B, 2B). In order to avoid the introduction of a new set of local varve years, this new chronology was connected to Kristiansson’s (1986) varve chronology at the local varve year 1940. Following this match the new chronology covers the local varve years 1701—2475. C. The sequences from Toregöl and Lillsjön are beyond the range of the 770-year long chronology. Therefore, no local varve ages could be attributed to the radiocarbon dates obtained from these two sites. Table 1 AMS 14C dates from the glacial varves and their estimated calendar year age BP. The calendar-year ages assigned to group A were obtained by adding 800 years to Strömberg’s (1994) chronology and those in group B by synchronising the records with the data set from Lake Gościa9 z5 (see text for further explanation). The calendar-year ages assigned to group C are only tentative. L"leaves, Lf"leaf fragment, F"flower, S"seeds, UP"unidentified plant remains, *"plant remains possibly reworked, d"uncertain age caused by fungi (see Wohlfarth et al. 1995). Samples marked with * and d and are not included in Figs. 3 and 4 Lab. No. Locality Local varve years Macrofossils submitted for AMS measurement AMS 14C yr BP Estimated cal yr BP A Ua-4212 Ua-2741 Ua-4214 Mullsjön Mullsjön Mullsjön 11010$10 11027$54 11115$11 10,160$115 9,640$190 10,170$195 11,810 11,827 11,915 Ua-4215 Mullsjön 11178$50 10,140$155 11,978 Ua-2742 Ua-4216 Ua-4217 Mullsjön Mullsjön Mullsjön 11356$25 11437$19 11471$14 Salix herbacea (Lf ), Salix indet. (Lf ) ?Dryas oct. (Lf ) Salix indet.. (Lf; B), Salix/Betula (Lf ), Betula nana (Lf ) Salix indt. (Lf ) , Salix herbacea (Lf ), Betula nana (Lf ) Salix/Betula (Lf ), Oxyria (S), Caryophyllaceae (S) Betula/Salix (Lf ), brown mosses (L, F, stems) Salix indet. (Lf ), Betula nana (Lf ), Oxyria (S) Salix herbacea (Lf ) 9,945$115 10,620$155 10,330$175 12,156 12,237 12,271 B Ua-4496 Ua-10180 Glottern Glottern 1856$50 1872$66 10,585$465 11,550$300* 12,506 12,522 Ua-10187 Ua-2544 Ua-10186 Ua-4359 Ua-11527 Ua-4493 Ua-10185 Gummetorpasjön Hargsjön Gummetorpasjön Hargsjön Hargsjön Adlerskogssjön Gummetorpasjön 1938$4 1938$2 1968$25 1973$31 1990$24 2003$59 2009$16 10,420$220 11,405$145* 11,040$110 10,610$110 10,384$130d 10,830$165 11,230$100 12,588 12,588 12,618 12,623 12,640 12,650 12,659 Ua-2753 Ua-10184 Ua-4358 Ua-10183 Ua-11518 Ua-3131 Ua-10182 Ua-11234 Hargsjön Gummetorpasjon. Hargsjön Gummetorpasjon Tynn Tynn Gummetorpasjön Nedre Emmaren 2010$45 2044$16 2055$50 2090$18 2125$35 2125$35 2138$30 2146$23 10,480$150 10,970$90 10,980$100 11,030$120 10,511$130d 10,890$120 11,470$130 10,885$250 12,660 12,694 12,705 12,740 12,775 12,775 12,788 12,796 Ua-10181 Ua-11233 Gummetorpasjön Nedre Emmaren 2199$32 2221$52 11,450$240 10,745$240 12,849 12,871 C Ua-4635 Ua-4634 Ua-2750 Ua-2752 Ua-4945 Lillsjön Lillsjön Toregöl Toregöl Lillsjön 11,895$860* 12,320$470* 11,520$225 11,820$150 11,530$130 ? ? 13,557? 13,557? 13,563? ? ? ? ? ? Salix/Betula (Lf ) Empetrum (L), Salix indet (Lf ), Salix/Betula (Lf ), Dryas oct. (L), Arenaria (S), insects Dryas oct. (L), Salix/Betula (Lf ) Dryas oct. (Lf, stem), ¸eguminosa (S) Dryas oct. (L), Salix/Betula (Lf ) Dryas oct. (¸), Salix polaris (L) Salix indet. (Lf ) Salix polaris (L), Dryas oct. (L, F) Salix reticulata (L), Salix polaris (L), Salix indet, (Lf ), Ericaceae (L), Dryas oct. (L) Betula/Salix (Lf ), UP Salix/Betula (Lf ), Dryas oct. (L) Salix polaris (L) Dryas oct. (L), Betula/Salix (Lf ) Salix/Betula (Lf ), Dryas oct. (Lf, F) Salix indet. (Lf ), Dryas oct. (L, F), insects, UP Ericacea (L, F), Salix/Betula (Lf ), Dryas oct. (L) Salix indet. (Lf ), Dryas oct. (L, S), Arenaria (L), Salix polaris (L) Saxifraga (F), Salix indet. (Lf ), Silene (L) Salix indet. (Lf ), Salis polaris (L), Dryas oct. (L, F), Betula nana (L) Salix polaris (L), Salix/Betula (L), Dryas oct. (L) Salix polaris (L), Armeria, Dryas oct. (L) Dryas oct. (Lf ), Betula/Salix (Lf ), UP Dryas oct. (Lf ), Betula/Salix (Lf ), UP Salix/Betula (Lf ) Goslar et al.: Variations of atmospheric 14C concentrations 33 The only possibility to relate the floating AMS 14C-dated varve chronologies of the STS to an absolute time scale, is by synchronising the data set with other, well-dated absolute records at certain marker horizons, such as the end or beginning of a 14C plateau. 3 Synchronisation of the data set In the pollen record from LG the AL-YD transition is marked by a decrease in tree pollen, an increase in Artemisia and Juniperus, and by a drastic decline in the algae ¹etraedron minimum, which in turn gives indications for declining summer temperatures (Goslar et al. 1993; Ralska-Jasiewiczowa et al. 1992). A similar interpretation can be derived from the decrease in the d18O record of authigenic carbonates, which coincides with the vegetational changes at 12650$60 cal y BP (Goslar and Ma9 dry 1998; Goslar et al. 1995a). At LM the boundary between AL and YD is marked by a decrease in tree pollen (Betula alba, Pinus), an increase in shrubs (Betula nana, Juniperus), herbs (Artemisia) and decreasing pollen concentrations (Björck et al. 1996). A significant feature in both, the LG and the LM record is the rapid drop in radiocarbon ages at the transition from AL to YD, which is followed by a long radiocarbon plateau (Fig. 3 and inset figure). The same marked drop in 14C ages from 11—10.8 14C ky BP to 10.6—10.4 14C ky BP is also visible in the AMS 14C dated 770-y long sequence of the Swedish varves at around the local varve year 2000. Based on the assumption that the atmospheric 14C/12C content was the same worldwide, we can use this rapid decrease in radiocarbon ages as a basis for correlating the floating varve sequence to LG (Fig. 3). Indirect support for this correlation is given by pollen stratigraphic investigations performed on the 770-y long local varve chronology which show a distinct YD pollen signal starting between the local varve years 1850—2000 (J. Björck submitted). The AMS 14C dates obtained on the varved sequence from Lake Mullsjön, show indications for a transition between the first and second YD plateau (Björck et al. 1996; Goslar et al. 1995a), i.e. the drop in 14C ages from about 10.6—10.4 14C ky BP to about 10.1—10 14C ky BP. By fitting the 14C ages from Mullsjön to the LG curve a difference of about 800 y is apparent when compared to the varve ages BP in Strömberg’s (1994) chronology. Based on this fit and based on the apparent offset of 870 y (Björck et al. 1996, 1997), we tentatively added a minimum of 800 varve years to Strömberg’s (1994) chronology in order to account for the difference in the younger part of the STS. The calendar-year assignment of the 14C ages obtained from Lillsjön and Toregöl, i.e. from the non-revised part of Kristiansson’s (1986) chronology remains, however, tentative until the new 770-y long chronology has been extended. Fig. 3 Radiocarbon ages versus calendar-year ages during the Late Weichselian and early Holocene. The records of Lake Gościa9 z5 (solid circles) (Goslar et al. 1995a) and the Swedish varved clays (open diamonds) were synchronised by the method described in the text. Open triangles represent the 14C-U/Th dates on corals from Barbados and Mururoa Atoll (the calculated mean) (Bard et al. 1993), Huon Peninsula (Edwards et al. 1993) and Tahiti (Bard et al. 1996). Crosses denote 14C dates derived from varved sediments from the Cariaco Basin (Hughen et al. 1998). All data sets are presented with a double standard deviation. The smooth line represents a spline function fitted to all the data, except to those from the Cariaco Basin. The inset figure shows the radiocarbon-depth record from Lake Madtjärn (open circles) (Björck et al. 1996) and the rapid drop in 14C ages at the Aller+d/Younger Dryas boundary The synchronised records, LG and the STS, (Fig. 3) are rather consistent with the 14C-U/Th coral data (Bard et al. 1993, 1996; Edwards et al. 1993). A generally good agreement exists also between the combined set of the Swedish, Polish and coral data, the recently published 14C dates from varved marine sediments from the Cariaco Basin (Hughen et al. 1998) as well as the record from Lake Suigetsu (Kitagawa and van der Plicht 1998). All records indicate a marked drop in 14C age from 11—10.9 to 10.6—10.4 14C ky BP, completed within 100—200 y and followed by two distinct, about 500 y long plateaux at approximately 10.4 and 10 14C ky BP. The indication of a long radiocarbon plateau at 10 14C ky BP, which is followed by a shorter plateau at 9.5 14C ky BP and by a gradual decrease of radiocarbon ages after 10.8 cal ky BP, is in excellent agreement with the (not shown in Fig. 3) results of the high-precision dated German pine chronology (Björck et al. 1996; Kromer and Becker 1993). Although the dates are rather sparse and reveal a fairly large scatter between 13 and 12.7 cal ky BP, there are indications in our data set for a short 14C plateau 200 y before the end of AL. A similar radiocarbon plateau of 200—300 y is 34 also visible in the Cariaco basin and Lake Suigetsu data sets (Hughen et al. 1998; Kitagawa and van der Plicht 1998). The drop in 14C ages at 12.65 cal ky BP, which coincides in LG (Goslar and Ma9 dry 1998; Goslar et al. 1995a) and LM (Björck et al. 1996) with the transition from AL to YD occurs in Lake Suigetsu at approximately the same time, i.e. around 12.7 cal ky BP (Kitagawa and van der Plicht). An age of 12.65 cal ky BP for this transition agrees also well with the estimate of about 12.7 ky BP indicated by the GRIP ice core (Johnsen et al. 1992). The recently published records from the Cariaco basin (Hughen et al. 1998) suggest, however, a distinctly older placement for the AL/YD transition and for the drop in radiocarbon ages (12.9—13.0 ky BP). In this data set, the duration of the YD period of 1330 y is around 200 y longer than the 1150 y consistently indicated by European sites (Goslar et al. 1995a, b; Hajdas et al. 1995, 1993) and the GRIP ice core (Björck et al. 1996; Johnsen et al. 1992). On the other hand, the timing of the YD in the Cariaco basin agrees with that recorded in the GISP2 ice core (Hughen et al. 1998). It remains to be solved whether the apparent non-synchronism of the AL/YD transition in different sites is an artefact of inadequate calendar-year chronologies or whether it reflects the real dynamic behaviour of the global climate system. At any rate, a delay between climatic changes at the two nearby sites on the Greenland summit (GISP and GRIP) seems fairly unlikely. Independently of the meaning of the Cariaco AL-YD boundary, our records indicate that the AL-YD transition occurred in Europe at around 12.65 cal ky BP, just at the marked drop in 14C age. 4 Possible causes of atmospheric D 14C variations Natural radiocarbon is one of the most robust tracers of oceanic and atmospheric circulation, because it is produced by cosmic rays in the atmosphere only (Lal 1992) and then distributed to other reservoirs involved in the global carbon cycle, i.e. the oceans and the biosphere. The total amount of 14C on Earth is thus controlled by the balance between 14C production and its radioactive decay in all reservoirs. The concentration in particular reservoirs depends, on the other hand, on reservoir size and rate of carbon exchange between them. 14C concentration in the atmosphere is higher than in any other reservoir, since the source of radiocarbon is in the atmosphere itself. It is obvious that a weakening of the carbon exchange between other reservoirs will produce an increase in *14C!5.. As demonstrated by Stuiver et al. (1991) and Stuiver and Braziunas (1993), the major features of the *14C!5. curve in the Holocene may be explained by variations in the 14C-production rate alone, controlled by the strength Goslar et al.: Variations of atmospheric 14C concentrations of the geomagnetic field and by solar activity. In fact, there are no clear indications for significant changes in the global carbon cycle during the Holocene. Another situation concerns the Late Weichselian. During this period, changes in carbon circulation are manifested by a distinct rise of atmospheric CO content, as evid2 enced in studies of Antarctic and Greenland ice cores (Anklin et al. 1997; Jouzel et al. 1992; Leuenberger et al. 1992; Barnola et al. 1991, 1987; Neftel et al. 1988). Also, firm evidence exists for a drastic change in the intensity of the vertical mixing of oceanic water between the Late Glacial Maximum (LGM) and the Holocene. The ventilation of the modern deep oceans is driven mostly through sinking of large surface water masses in the North Atlantic, where North Atlantic Deep Water (NADW) is formed and in the belt around Antarctica, where formation of Antarctic Bottom Water (AABW) occurs. As shown by many paleoceanographic studies (e.g. Sarnthein et al. 1995, 1994; Keigwin and Lehman 1994; Charles and Fairbanks 1992; Keigwin et al. 1991; Jansen and Veum 1990; Boyle 1988; Duplessy et al. 1988; Boyle and Keigwin 1987), the formation of NADW was much weaker during the LGM than today. Changes in the carbon cycle, implied by Antarctic and Greenland ice cores and marine studies, should have a distinct imprint on the pattern of *14C!5. variations during the Late Weichselian. Indeed, the amplitude of the *14C!5. change observed during early YD (Fig. 4) is much larger (50—70 per mille) and longer (500—700 y) than any *14C!5. fluctuation during the following 12500 calendar years (see inset in Fig. 4). This *14C!5. maximum could be plausibly explained by a cessation of NADW flux. According to general circulation models (GCM), shutting down NADW formation and reducing northward heat transport from equatorial regions would have a profound effect on North Atlantic regional and perhaps global climate (Manabe and Stouffer 1997, 1995, 1988; Rahmstorf 1995). While a much weakened NADW flux during the LGM is indeed evidenced by paleoceanographic studies, the question of reduced NADW formation during the YD is, on the other hand, still under discussion (e.g. Keigwin and Lehman 1994; Keigwin et al. 1991; Charles and Fairbanks 1992; Jansen and Veum 1990). However, there is growing evidence that the sinking of water masses in the North Atlantic proceeded also during YD, but to shallower depths than today (Sarnthein et al. 1994; Lehman and Keigwin 1992). The possible connection between reduced NADW formation and an increase of *14C!5. during early YD has already been discussed (Hughen et al. 1998; Stocker and Wright 1996; Björck et al. 1996; Goslar et al. 1995a). The residual *14C, obtained after removal of the long-term trend from the observed record, was compared in these works with a *14C!5. simulated using several simple models of the carbon cycle (Bard et al. 1994; Broecker et al. 1990; Keir 1988; Oeschger et al. 1975) or in a model including a more realistic, Goslar et al.: Variations of atmospheric 14C concentrations Fig. 4 Atmospheric radiocarbon concentrations versus calendar-year ages during the Late Weichselian and early Holocene. The concentrations are expressed as per mil deviation (*14C) from the standard. The symbols correspond to those in Fig. 3. Some of the outlying data from those shown in Fig. 3 have been omitted. The maximum of *14C during the early Younger Dryas is striking. The smoothed line represents a spline function fitted to all data, except to some outlying data. For comparison, some of the largest fluctuations of *14C during the Holocene are shown in the inset on the same scale. These fluctuations correspond to the periods: (a) 9.6—9.25 cal ky BP (Kromer and Becker 1993); (b) 7.3—7.05 cal ky BP (Stuiver and Reimer 1993) and (c) 2.8—2.2 cal ky BP (Pearson et al. 1993) zonally averaged ocean circulation (Stocker and Wright 1996). In most of those simulations the *14C wiggles were calculated for several scenarios of oceanic ventilation changes while other parameters of the carbon cycle and the 14C-production rate were kept constant. Here, we present another approach, which simultaneously takes into account a few factors that could influence the varying atmospheric radiocarbon concentration during YD: (1) long-term variations of the 14C production rate, driven by the well-reconstructed changes of the geomagnetic field; (2) terrestrial and oceanic mechanisms of the observed changes of atmospheric CO content and, (3) possible fluctuations of 2 the NADW flux. 5 Model simulations of observed D 14C 5.1 Model description As a basis for the simulations we used the PANDORA model (Broecker et al. 1990) of the global carbon cycle. Oceanic circulation of carbon in this model is represented through the fluxes of water, organic matter and 35 Fig. 5 A Schematic representation of oceanic water circulation in the PANDORA model of the global carbon cycle (after Broecker et al. 1990). In the steady-state of pre-industrial ocean the fluxes of individual loops are as follows: L1, 6 Sv; L2, 13.5 Sv; L3, 10.5 Sv; L4, 4 Sv; L5. 3 Sv; L6, 15 Sv; L7, 20 Sv; L8, 100 Sv. The additional loop L9 (0 Sv in the pre-industrial steady-state) has been introduced to represent the upper part of the NAIW flux. B Variations of fluxes of individual loops of oceanic water circulation, assumed in the scenarios S2, S3 and S4 of the model simulations discussed in the text. The variations of loops L1 and L2 were the same in all scenarios. The scenarios for loops L3 and L9 are distinguished by line thickness (S2: thin line, S3: medium line, S4: thick line) carbonates between particular well-mixed boxes. The circulation of water (Fig. 5A) has the form of a few loops (L1—8), which connect the surface boxes with the deep oceans. All paraeters of oceanic circulation have been adopted from Broecker et al. (1990). The atmosphere (600 Gt C) exchanges carbon with the oceans (total 37000 Gt C in the pre-industrial steady state, 1 Gt C"1012 kg of carbon) and the terrestrial biosphere (2150 Gt C). The carbon fluxes between the surface oceanic boxes and the atmosphere are proportional to the partial pressures of CO in the surface water and in 2 the air. The standard flux (for pCO "280 latm) is 2 equal to 15 mol/m2y. The atmosphere-biosphere fluxes are proportional to the mass of carbon stored in appropriate reservoirs. The formation of NADW is represented in the model by the sum of the fluxes L1, L2 and L3 (30 Sv altogether, 1 Sv"106 m3/s). This is distinctly higher than the NADW flux of about 20 Sv in the real ocean (Schmitz and McCartney 1993). The model fluxes have been set (Broecker et al. 1990) to reproduce 36 correctly the distribution of 14C in the pre-industrial ocean. In fact, when no transport of organic matter and carbonates exists, 14C is transported to the deep ocean due to both the large scale advective circulation (such as NADW) and the turbulent diffusion. Therefore, the exchange of carbon between reservoirs is always stronger than that attributed to water currents only. The PANDORA model includes parameters, which control and potentially could be responsible for Late Weichselian changes of atmospheric CO content. 2 These are (1) the alkalinity of the surface water, (2) the strength of the biological pump, which depends on the residence time of phosphorus in the surface reservoirs and, (3) the mass of the terrestrial biosphere. Calculations of *14C!5. during the period 15—10 14C cal ky BP (Fig. 6) were made in a few runs: (1) with all model parameters kept constant, except for the 14C production rate dependent on the geomagnetic field; (2) with the 14C production as in (1), but combined with the parameters controlling atmospheric CO to reproduce the observed variations of CO ; (3) 2 2 with all parameters as in (2) and a variable flux of NADW. Goslar et al.: Variations of atmospheric 14C concentrations 5.2 14C production rate Variations of the 14C-production rate were derived from paleomagnetic data of Tric et al. (1992) and McElhinny and Senanayake (1982), using the relations of Lal (1988). As pointed out by Goslar et al. (1995a), calculated 14C concentrations depend on the initial value of *14C and on the model adjustment of the absolute value of 14C production. In the standard model, the 14C production, which corresponds to the current geomagnetic field, maintains the steady state *14C!5."0&. However, using such a production and initiating the run from the actual *14C level at 15 cal ky BP, we obtain too high *14C!5. values over the whole Holocene. The best fit of the simulated to the observed Holocene *14C!5. curve is obtained when the 14C production is systematically lowered by 2% (Goslar 1996). With such an adjustment, variations of the geomagnetic field almost completely explain the general decline of *14C!5. between 15 and 10 cal ky BP (Fig. 6), but they are too weak to produce the large *14C maximum during the early YD. 5.3 Size of the atmospheric carbon reservoir and carbon exchange between atmosphere and ocean Fig. 6 Results of modelling the atmospheric 14C concentrations during the late Weichselian and early Holocene. The crosses represent the same data set as in Fig. 4. The results of the model simulations are shown by the following lines: dashed line, *14C variations driven only by fluctuations of the geomagnetic field; dotted line, *14C variations driven by fluctuations of the geomagnetic field and including the mechanisms responsible for changes of atmospheric CO ; dashed-dotted line, the scenario as mentioned plus a reduced 2 NADW flux to 7 Sv during the whole YD (scenario S1); solid line, the same scenario but with the NADW flux changing gradually at the boundaries of YD (thin line: scenario S2, medium line: scenario S3, thick line: scenario S4). The details of all scenarios are given in the text Another mechanism responsible for *14C!5. variations are changes in atmospheric CO . Studies performed on 2 Antarctic and Greenland ice cores indicate a rather linear, slow increase of CO from about 200 ppm at 17 2 ky BP to about 280 ppm in the Holocene. This change could produce the decrease of *14C!5. by 25—35& (Lal and Revelle 1984; Keir 1983, Siegenthaler et al. 1980). Goslar et al. (1995a) argued that the gradual increase of CO could not be responsible for the rapid variations 2 of *14C!5. during YD. Nevertheless, the incorporation of the CO scenario allowed a better reproduction of 2 the general slope of the *14C curve between 15 and 10 cal ky BP (Fig. 6). The rate of CO exchange between the mixed layer of 2 the oceans and the atmosphere is another parameter affecting *14C!5.. A decrease of the ocean-atmosphere CO flux by 50% rises *14C!5. by about 20& (e.g. 2 Siegenthaler and Beer 1988). Björck et al. (1996) suggested, that during YD this flux might have been 50% weaker than today, possibly caused by abundant cover of sea ice and icebergs as shown from paleoceanographic studies (Haflidason et al. 1995; Koi Karpuz and Jansen 1992). The recent simulations of Stocker and Wright (1996) show, however, that freezing the Atlantic and Pacific oceans north of 45°N would raise the *14C!5.content only by 2&. A distinct increase of *14C!5. (by 20&) would only occur after freezing the Southern Ocean (south of 47.5 °S). Although the question whether this ocean warmed or cooled during YD is partly still under debate (Mabin 1996; Lowell et al. 1995; Manabe and Stouffer 1995; Denton and Hendy Goslar et al.: Variations of atmospheric 14C concentrations 1994), there is growing evidence for an anti-phase relationship between the Southern and Northern Hemispheres during YD (Blunier et al. 1997). Moreover, steeper thermal gradients during the cold YD period may have resulted in stronger trade winds (Hughen et al. 1998; Bard et al. 1994; Mayewski et al. 1993), an effect which could enhance CO exchange even by 2 a few tens of per cent. Having in mind that those opposite mechanisms partly cancel each other, we regard the effect of altered air-sea exchange during the YD as still unknown. 5.4 Including vertical ocean circulation The most probable mechanism of the rapid *14C!5. increase during early YD is the drastic reduction of vertical oceanic circulation. In previous papers several scenarios of circulation were considered. 1. The scenario where NADW flux was reduced from 30 Sv to 10 Sv during the whole YD (Goslar et al. 1995a) gave the highest *14C!5. values at the end of YD, in contradiction to experimental data. A similar peak of *14C!5., accompanying the drastically reduced North Atlantic overturning through the whole length of YD, was also reproduced by Stocker and Wright (1996). 2. Björck et al. (1996) considered a reduced eddy diffusivity of the deep oceanic reservoir by 50% during the first 200 y of YD as an effect of a sudden fresh-water forcing and a gradual recovery to modern values until the onset of the Holocene. Such a scenario reproduces relatively well the observed shape of the YD *14C!5. maximum. GCM models (Rahmstorf 1995; Mikolajewicz and Meier-Reimer 1994), however, predict a gradual decrease of the NADW flux as a response to gradually increased freshwater forcing. The successive decrease of freshwater forcing would then lead to an abrupt switch-on of the NADW circulation, which contradicts with Björck et al.’s (1996) scenario. 3. Another approach (Hughen et al. 1998) assumed that NADW formation ceased completely during YD and was replaced by a gradually increasing flux of North Atlantic Intermediate Water (NAIW). NAIW could serve as an effective sink for 14C!5., but would have heated the North Atlantic region much less than NADW (Rahmstorf 1994). In the simplest scenario presented here (hereinafter denoted as S1), NADW flux instantly reduced at the onset (12650 cal y BP) and restored at the termination (11510 cal y BP) of YD. The 14C concentrations obtained in the later part of that period are too high and the rise of *14C!5. at the beginning of YD seems too slow and slightly delayed with respect to the observed development (Fig. 6). Furthermore, the simulated decline of *14C!5. at the beginning of the Holocene distinctly lags the experimental one. 37 Recent GCM calculations by Manabe and Stouffer (1997) suggest, that NADW flux and sea surface temperatures could change with a phase lag. Manabe and Stouffer (1997, hereinafter denoted MS97) supplied an extra 0.1 Sv of freshwater to the North Atlantic surface during a period of 500 y. They obtained an initial (200 y) rapid decrease of the thermohaline circulation (THC), which was followed by a distinctly slower decrease during the following 300 y. When the freshwater forcing had ceased, the THC re-intensified gradually within about 250 y and reached temporarily even higher values than before the disturbance. The inactive THC appeared thus rather unstable and could restore itself, in contrast to earlier suggestions (Rahmstorf 1995). However, the results obtained by MS97 seem more reliable, since their atmospheric circulation model is more realistic than the highly parametrised model applied by Rahmstorf (1995). Nevertheless the duration of the increase in THC in the MS97 model is a few times shorter than that assumed by Björck et al. (1996). In our scenario (S2) we therefore, used Manabe and Stouffer’s (1997) results for the simulations of *14C!5.. The significant drop in sea surface temperature in the MS97 experiment started about 100 y after the beginning of the decline in THC and the main cooling was completed during the following 100—150 y. The duration of this cooling is similar to that recorded in the sediments of Lake Gościa9 z5 , i.e. 150 y between 12725 and 12575 cal y BP. We, therefore, prescribed the beginning of the MS97 THC decline to the year 12820 cal y BP and adopted the declining part of the MS97 curve (years 0—500) for our scenario of NADW flux changes around the AL/YD boundary. Similarly, we dated the middle part of the main MS97 warming (year 700 in the MS97 time scale) to 11510 cal y BP and used the rising part of the MS97 curve (years 500—1250) for the NADW scenario around the YD/PB boundary. Unfortunately, the period of freshwater supply in the MS97 simulations was significantly shorter than the real duration of YD and the THC curve in the MS97 experiment could not cover the middle part of YD. We, therefore, assumed that NADW flux was constant during this intermediate period (12320—11710 cal y BP). The resulting scenario of the variations in deep water flux (S2), which were used as an input in the PANDORA model, is shown in Fig. 5B (loops L1—2 and L3). As discussed before, the deep ocean water fluxes in the steady-state pre-industrial model are about 50% higher than the large-scale fluxes in the real ocean. Accordingly, the amplitude of the NADW fluxes in our simulations is proportionally higher than that of the THC circulation in MS97. The increase of *14C!5. obtained by the MS97-like scenario S2 occurs earlier and fits the reconstructed maximum in *14C!5. at the YD onset better than the simplified scenario S1 (Fig. 6). In addition, the earlier decline of the calculated *14C!5. values around the 38 YD/PB boundary appears closer to the observed one. This seems to support the indication of MS97, that during the YD cold spell, NADW flux did not change instantly and not exactly in phase with climatic changes. However, *14C!5. values in the S2 simulation remained rather constant after 12.3 cal ky BP, in contradiction to the distinct drop of *14C!5. documented by our reconstructions. The decline of *14C!5. in the mid- and late YD could be reproduced well by Hughen et al. (1998), who allowed for changes in NAIW flux in their simulations. The comprehensive study of d13C distributions in the North Atlantic (Sarnthein et al. 1994) suggests ventilation of the deep Atlantic almost as strong as now during the YD, although North Atlantic surface waters penetrated to shallower depths than today. According to Rahmstorf (1994), NAIW heats the North Atlantic region much less effective than NADW circulation. However, a simple replacement of NADW by NAIW flux produces a very slow increase of *14C!5., which is much weaker than that observed at the AL/YD boundary. Also Manabe and Stouffer (1997) did not obtain a significant increase of NAIW in their studies. One possibility to reconcile these contradictory data is, to assume that NAIW flux was weak during a short period at the beginning of Younger Dryas. Such a short (350 y) break in ventilation might not have had an appreciable influence on deep oceanic d13C. If the water circulation were to cease completely, the present flux of organic matter from the North Atlantic surface (about 1.4 Gt C/y in the PANDORA model) might decrease the deep Atlantic d13C with a rate of 0.3&/ century. However, the biological productivity at the surface rapidly decreases as soon as the circulation has ceased, because it is limited by the availability of nutrients, which are supplied from the deep reservoirs. Indeed, the organic carbon flux integrated through the years 12650—12300 in our S2 run is only 127 Gt C. This amount could not alter the d13C of Atlantic water by more than 0.3&. In fact, the d13C values of deep Atlantic water during the time slice 10.35—10.8 14C ky BP are 0.2—0.3& lower than between 8.35—9.1 ky 14C BP (see e.g. Figs. 16 and 18 in Sarnthein et al. 1994). A strengthening of NAIW a few hundred years after the beginning of YD does neither contradict the results obtained by Manabe and Stouffer (1997), who did not prolong their simulations of inactive THC state beyond the year 500. The scenario of deep Atlantic circulation, particularly weakened during early YD, seems concordant with high-resolution palaeoclimate records from the Greenland ice cores (Johnsen et al. 1992; Alley et al. 1993) and from Lake Gościa9 z5 (Goslar et al. 1995a). It is also in agreement with a number of palaeoclimatic reconstructions of the YD period in Europe, where the coldest climate occurred during the early part of YD (e.g. Isarin 1997; Renssen 1997; Walker 1995; Lowe et al. 1995; Wohlfarth et al. 1994). Furthermore, the data set from core ENAM 93—21 in the Faroe-Shetland Goslar et al.: Variations of atmospheric 14C concentrations Channel (Rasmussen et al. 1996) suggests that a strong freshwater forcing in the North Atlantic occurred only during the earliest 250—400 y after the onset of YD (Björck et al. 1996). Hughen et al. (1998) assumed a complete cessation of both NADW and NAIW at the beginning of YD. We simulated the appearance of a strong NAIW flux after 12300 cal y BP, while at 12200 cal y BP, the sum of NADW and NAIW fluxes is assumed to be equal to the pre-YD and Holocene NADW flux. Around the YD/PB boundary, the NAIW flux gradually decreased, just to keep the sum of NADW and NAIW fluxes constant. Such a scenario is different from that proposed by Hughen et al. (1998), who assumed a slow increase of NAIW through '1000 y. In general, GCM simulations have, up to now, given either almost instantaneous increases of NADW-NAIW fluxes or a gradual increase (e.g. MS97). However, this gradual increase never lasted longer than 250 y. None of the GCM simulations has yet dealt with a 1000 year long period of increasing NADW-NAIW, which renders Hughen et al.’s (1998) scenario unlikely. The NAIW flux was represented first by the additional loop (L9 in Fig. 5A, B), which connects the low- and high-latitude surface boxes of the Atlantic (scenario S3). As the mean depth of the Atlantic surface reservoirs is 1000 m, loop L9 seems too shallow to represent NAIW well. In effect, the drop of *14C!5., after the activation of L9 (Fig. 6), is quickly restrained when all surface Atlantic reservoirs become saturated with atmospheric radiocarbon. In an improved scenario (S4), NAIW was represented by a combination of loops L3 and L9. L3 connects the surface Atlantic reservoirs with the deep Atlantic but, similar to the pattern of shallower NADW flow obtained by Rahmstorf (1994, Fig. 1b), it does not reach the Arctic and Indo-Pacific oceans. We assumed that the L3 flux increased between 12300—12200 cal y BP to the same value as before YD (Fig. 5B). The L9 flux changed accordingly, in order to keep the sum of NADW and NAIW fluxes equal to the pre-YD strength of NADW. This scenario implies that half of the water flowing out from the North Atlantic reservoir penetrated deeper than 1000 m, which is again in reasonable agreement with the pattern obtained by Rahmstorf (1994). Such a scenario reproduces the observed *14C!5. quite well. Nevertheless, it is not easy to distinguish whether the scenario with a gradual NAIW increase (Hughen et al. 1998), or the scenario with a rapid intensification of NAIW (scenario S4, this work), allow reproducing better the decline of *14C!5. during the YD. The decline of *14C!5. around the end of YD can now be explained almost perfectly. This is mainly due to the simulation by Manabe and Stouffer (1997), who showed that the increase of THC flux could be initiated well before the major warming. Although scenario S4 reproduced the *14C!5. drop at the YD/PB transition Goslar et al.: Variations of atmospheric 14C concentrations fairly well, it should be treated with caution, since it is not supported by GCM data. However, if started from a level of about 200 & (which was really the case), this drop is well explained by Manabe and Stouffer’s (1997) THC model, independently of the mechanisms, which lead to the starting level. Some simulations of YD-like changes of NADW circulation were also published earlier by Sakai and Peltier (1996) and Stocker and Wright (1996). In these studies, NADW flux was stopped during the period of meltwater pulses MWP-IA and MWP-IB (Bard et al. 1996; Fairbanks 1989). The *14C!5. maxima produced by these scenarios, however, offset the *14C!5. maximum by about 1000 y. The appearance of a stronger penetration of the deep Atlantic by Antarctic Bottom Water and a gradual weakening of the meridional overturning in the IndoPacific ocean were two additional features of the MS97 simulation. The connection between the deep Antarctic and the Atlantic is in our model represented by the loop L4. Doubling the strength of the loop leads to an increase of *14C!5. of less than 0.5&. The Indo-Pacific overturning (I-PO) in the MS97 simulations gradually decreased, in phase with the decrease of the Atlantic THC flux (between the years 0—500). In fact, the decrease of I-PO during that period was incorporated in our scenarios S2—4 and was represented by the weakened loop L1. However, this decrease continued until the year 800—900, i.e. when Atlantic circulation had already been restored. The decrease of I-PO around the YD/PB boundary produces again a significant (about 200 y) lag between the observed and the simulated drop of atmospheric radiocarbon (not shown in Fig. 6). One can, however, imagine that the minimum of I-PO could still occur during a period of weak Atlantic THC, if the freshwater forcing in the MS97 simulation were kept sufficiently long. 6 Discussion and conclusions The synchronisation of a floating AMS 14C-dated glacial varve chronology with the high-resolution AMS 14C-dated terrestrial data sets from Lake Gościa9 z5 at the AL-YD transition (12.65 cal ky BP), lead to a dense record of *14C!5. changes covering the time period between late AL to early PB. The combined data set shows in general good agreement to other high-resolution chronologies, such as the 14C-U/Th coral series (Bard et al. 1996, 1993; Edwards et al. 1993), the Cariaco and Lake Suigetsu varve record (Hughen et al. 1998; Kitagawa and van der Plicht 1998) and the German pine chronology (Kromer and Becker 1993). A distinct feature evident in our combined records is the drastic rise in *14C!5. during the first 200 y of YD, followed by two about 500 y long 14C plateaux. A less distinct rise in *14C!5. is evidenced some 200 y before the end of AL, which leads into a shorter, around 200 y 39 long 14C plateau. However, since the data set is still too sparse for the time period before 12.7 cal ky BP, we focus here on modelling the marked *14C!5. rise during early YD. While variations in the geomagnetic field explain almost entirely the general decline of *14C!5. between 15 and 10 cal ky BP, they are too weak to reproduce the observed *14C!5. maximum in our model. Including atmospheric CO variations in the model run, the 2 general slope of the *14C!5. curve between 15 and 10 cal ky BP can be simulated better, although the *14C!5. maximum at the onset of YD is not reproduced. The most likely mechanism for drastic changes in *14C!5. is a significant reduction in vertical ocean ventilation (Stocker and Wright 1996; Björck et al. 1996; Goslar et al. 1995a). We, therefore, performed model simulations including the two parameters mentioned and assumed gradual changes of NADW flux near the boundaries of YD, following those obtained in recent GCM simulations by Manabe and Stouffer (1997). Following Manabe and Stouffer’s (1997) and Stocker and Wright’s (1996) model experiments for the YD, the formation of deep water in the North Atlantic is terminated or greatly reduced, when the input of melt water from the decaying ice sheets exceeds 0.1 or 0.2 Sv. This in turn results in a decreased uptake of 14C by the ocean and an increase in *14C!5.. As shown by Bard et al. (1996), the large pulse of melt water from the decaying ice sheets (Fairbanks 1989) occurred as much as 1000 y prior to the YD cooling. The implied long delay in response of the North Atlantic heat conveyor to the freshwater forcing could not yet be successfully modelled. Also the maximum of *14C!5. accompanying the weakening of NADW expected during melt water pulse MWP-IA (Sakai and Peltier 1996; Stocker and Wright 1996), would precede the real maximum by about 1000 y. Alternatively, Björck et al. (1996) proposed that the rapid slow-down of the thermohaline circulation at the AL-YD transition could have been triggered by a sudden drainage of large dammed glacial lakes on both sides of the North Atlantic. This is concordant with reconstructions by Clark et al. (1996), implying that the main source of water for MWP-IA was in Antarctica, which, according to Manabe and Stouffer’s (1997) model, could not effectively disturb the NADW circulation. The magnitude and extent of the early YD *14C!5. maximum clearly exceeds the smaller *14C maximum in our records (about 200 y before the end of AL) and the wiggles seen in LG during YD and PB. The same picture emerges from the record of ice rafted debris (IRD) (Rasmussen et al. 1996; Björck et al. 1996). Clearly minor IRD peaks are associated with smaller *14C!5. maxima, while the large IRD peak during early YD seems synchronous with the large maximum in *14C values. This implies that smaller *14C!5. peaks 40 might be triggered by increased meltwater input into the North Atlantic due to a rapid decay of the ice sheets during warm periods, which lead to a temporary shut-down of deep-water convection and to a cooling (Björck et al. 1996). We conclude that the large *14C!5. maximum during early YD could be reproduced in our model by combining variations in the geomagnetic field, in atmospheric CO and a significant short-term reduction in 2 vertical ocean ventilation. The more than 1000-y long *14C!5. decline during YD and PB, however, could be reproduced only roughly. The almost unrealistic change in atmosphere-ocean flux postulated by Björck et al. (1996) or rather ad-hoc proposed scenarios involving NAIW fluxes (Hughen et al. 1998, and this work) to explain this decline, suggest that the underlying reason for this anomalous behaviour of the *14C!5. signal is still enigmatic. Acknowledgements BW would like to thank Tomas Nilsson, Markus Olsson, Björn Holmquist, Siv Olsson and Dan Hammarlund for their help during field work, Felicia Dobos and Jessica Ademark for sieving the macrofossils from the Swedish varved clays and Gina Hannon for helping with plant macrofossil determinations. Comments by T. Stocker, E. Bard and an anonymous reviewer helped to improve the manuscript. BW’s work was supported by the Swedish Geological Survey (SGU) and the Swedish Natural Science Research Council (NFR) through grants 03—500/92, 03—792/93:9, G-GU 10197—300 and G-AA/GU 10197—301. The work of TG was sponsored by the Polish Committee of Scientific Research through grant 6 P04E 027 10. References Alley RB, Meese DA, Shuman CA, Gow AJ, Taylor KC, Grootes PM, White JWC, Ram M, Waddington ED, Mayewski PA, Zielinski GA (1993) Abrupt increase in Greenland snow accumulation at the end of the Younger Dryas event. Nature 362 : 527—529 Anklin M, Schwander J, Stauffer B, Tschumi J, Fuchs A (1997) CO record between 40 and 8 ky BP from the Greenland Ice Core2 Project ice core. J Geophy Res 102/C12 : 26539—26545 Bard E, Hamelin B, Fairbanks RG, Zindler A (1990) Calibration of the 14C time scale over the past 30000 years using mass spectrometric U-Th ages from Barbados corals. 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