fl t2-I4cLh&r Section Review 13,1 Part D Questions and Problems Part A Completion 13 NT 15 14. AT 16. AT 22. At the boiling point, particles throughout the liquid have enough kinetic energy to vaporize. 23. Liquid B would evaporate faster because it has a higher vapor pressure, which indicates that it is more volatile 24. Evaporation leads to cooling of a liquid because the particles with the highest kinetic energy tend to escape first. The remaining particles have a lower average kinetic energy and a lower temperature. 21. a Section 1 3.3 1. motion 2. 3. 4. 5. empty space far apart independently random or rapid 6. 7. 8. 9. 10. collisions kinetic energy atmospheric 0°C 101.3 kPa or 1 atm Part B True-False ST 12. AT 11 . . Part C Matching 17. b 19. d 18.c 20.e Part A Completon Part D Questions and Problems 1. compress 101.3 kPa 22. 4,30 tr6 > 43 kPa 1 m1 1 760 4.30 t6>< 3.27 X i0 mm Hg 2. 3. 4. 5. 23. According to the kinetic theory the motion of the particles in a gas is constant and random. Because the particles are relatively far apart, no attractive or repulsive forces exist between the particles. They move independently of each other and travel in straight line paths until they collide with one another or other objects. 24. Odors travel long distances from their sources. Part A CompIeton denser condensed vaporization boiling cooling 6. 7. 8. 9. 10. surface vapor pressure manometer vapor pressure 101.3 kPa or 1 atm Part B True-False 11. ST 13. NT 12. ST 14. AT 19. c 20. d Part B True-False 11. AT 12. ST 13. NT 14. ST 15. AT a c rng ar 16. e 17. c 18. f 22. d 19. a 20. b 21. g 24. When a solid is heated, its particles vibrate more rapidly as their kinetic energy increases. Eventually, the disruptive vibrations of the particles are strong enough to overcome the attractions that hold them in fixed positions. The organization of the particles within the solid breaks down and the solid becomes a liquid. Section 13.4 15. ST 16. AT Part C Matching 17. a 18. e high crystalline lattice unit cell amorphous Part D Questions and Problems Section 1 3.2 1. 2. 3. 4. 5. fixed melts melting point freezing point 6. 7. 8. 9. 10, 21. b Part A Completion 1. 2. 3, 4. sublimation vapor pressure carbon dioxide phase 5. 6. 7. 8. equilibrium triple point 0.016°C 0.61 kPa Part B True-False 9. NT 10. AT 11. NT 13. NT 12. AT 14. NT Part C Matching 15.b 17.d 19.a 16.c 18.e 20.f Part D Questions and Problems 21. Solids that have a vapor pressure that exceeds atmospheric pressure at or near room temperature can change directly to a vapor. This process is called sublimation. 22. The temperature of the system remains constant while the change of state is occurring.
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