Science in China Series D: Earth Sciences © 2007 Science in China Press Springer-Verlag Characteristics of petroleum accumulation in syncline of the Songliao basin and discussion on its accumulation mechanism WU HeYong1,2†, LIANG XiaoDong1, XIANG CaiFu3 & WANG YueWen1 1 Daqing Oil Field Exploration and Development Research Institute, Daqing 163712, China; Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China; 3 Basin & Reservoir Research Center of China University of Petroleum, Beijing 102249, China 2 The relation between oil and water in reservoirs with low and ultra-low permeability is very complicated. Gravitational separation of oil and water is not obvious. Normal reservoirs are located in depression and structural high spot, oil and water transitions are located in their middle. Stagnation is the key fact of oil-forming reservoir in the axis of a syncline based on the research of oil, gas and water migration manner, dynamics and non-Darcy flow in the Songliao basin. In low and ultra-low permeable reservoir, gas and water migrate easily through pore throats because their molecules are generally smaller than the pore throats; but the minimum diameter of oil droplets is larger than pore throats and they must be deformed to go through. Thus, gas and water migrate in advance of oil, and oil droplets remain behind. Pressure differential and the buoyancy force in a syncline reservoir are a main fluid driving force; and capillary force is the main resistance to flow. When the dynamics force is less than resistance, oil is immobile. When the buoyancy force is less than the capillary force, a gravitational separation of oil and water does not occur. The reservoir in the mature source rock of a syncline area with the low and ultra-low permeability belongs to an unconventional petroleum reservoir. oil droplet, pore throat, syncline oil reservoir, low to ultra-low permeable reservoir, stagnation, non-Darcy flow The earliest anticlinal reservoir was proposed by T. S. Hunt in 1861[1]. He pointed out that petroleum accumulates in an anticline or a structure high, where gravitational separation occurs, so the hypothesis was called the anticlinal theory. The anticlinal theory is followed by geologists and it directs the decision-making of explora― tion[2 4]. Since then, petroleum geology followed the traditional static analysis of source rock, reservoir, caprock, trap, preservation condition. Furthermore, it emphasizes interrelations between each static factor[5] and dynamic factors and system analysis methods of forming reservoir dynamics[6]. The above petroleum migration and accumulation theories are based on the buoyancy effect and petroleum accumulation in a trap or stratigraphic trap or lithologic trap in the form of discrete accumulation. Law et al. [7] proposed a conceptbasin www.scichina.com www.springerlink.com ― centered accumulation of unconventional petroleum system[7]. They thought that the unconventional petroleum system has no bearing upon a structure, stratigraphic and lithologic traps, owing to having no influence by gravitational separation. There is an oil field belt in a large scale. They took some sorts of the natural gas resources as example, such as coal bed gas[8], deep basin gas[9] and natural gas hydrate[10] and so on, which are unconventional gas resources. Domestic scholars at the beginning of this century took notice of one situation in which an oil seep occurred in the axis of syncline, and called it sag wide oil-bearing theory[11]. The senior author of this paper detected such a situaReceived June 26, 2006; accepted December 6, 2006 doi: 10.1007/s11430-007-0031-y † Corresponding author (email: [email protected]) Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 5 | 702-709 tion in Fuyang oil layers (Fuyu and Yangdachengzi oil layers, Figure 1) in the Sanzhao sag of the Songliao basin in 1986. This is a large petroleum province with highly mature source rocks and high pressure hydrocarbon expulsion. More than 90% of compact layer did not contain water. It is different from structure trap, conventional stratigraphic trap and lithologic trap. Subsequently, similar situations were reported in the Ordos Basin[12] and the Bohai Gulf Basin[13]. We consider that the oil migrates in the low to ultra-low permeable reservoir since the diameter of an oil droplet is larger than that of a pore throat, the oil droplet must be deformed to go through the pore throats (the mean permeability of low permeable reservoir: 50×10−3―10.1×10−3 μm2; the one −3 of especially low permeable reservoir: 10×10 ― 1.1×10−3 μm2; the one of ultra-low permeable reservoir: 1.0×10−3― 0.1×10−3 μm2)[14]. By contrast, gas and water pass easily through pore throats, owing to their smaller diameter; oil stagnation becomes the key of petroleum accumulation in synclines. The study and application to the situation and its accumulation mechanism breaks a conventional exploration idea. The idea that petroleum stagnates in syncline in a large scale will increase greatly the domain of oil exploration. 1 Geological characteristics in the Songliao basin The Songliao basin is located west of the Tanlu fault zone, and occupies three provinces of northeast China and part of Inner Mongolia. Its area is about 26×104 km2. The Daqing oil field, which is one of the biggest nonmarine oil field in the world, is contained within the basin. The basin contains mainly Mesozoic and Cenozoic strata over 10 km thick. The basin is a double-layer model of downside fracture and upside sag. Its fracture stage is pre-Cretaceous involving flysch and pyroclastic strata. Its sag stage is between the Quantou stage and the Nenjiang stage involving three sets of cycles of lake and fluvial facies. Lacustrine mudstone and glutenite are the main source rock and reservoir. The basin began to uplift and be denuded after the Nenjiang stage. It turned into wilt phases and its depocenter migrates unceasingly to the west, with fluvial facies deposits being primary. There are five sets of oil gas combination. Middle and under part combination are primary (Figure 1). 2 The characteristics of syncline oil reservoir in the Songliao basin The Songliao basin is a large-scale nonmarine petroliferous basin. We have discovered more and more geological phenomena which are not explained by conventional petroleum migration and accumulation theory. In the center of syncline in this basin, oil and water in the reservoir are not gravitationally separated. The phenomena cannot be explained with the differential accumulation principle. 2.1 Oil reservoirs exist generally in the center of syncline We discovered large-scale and continue petroleum reserves not only in Daqing placanticline but also in the syncline area. The demonstrated reserves in syncline area surpassed 1200000000 tons, which is important to the stable production and high production of Daqing oil field. Statistics have indicated that syncline oil reservoirs as a result of stagnation accounting for about 87% outside Daqing placanticline. They have no relation with structure and stratigraphic lithologic trap, and the gravitational separation is not obvious (Figure 1), so they belong to unconventional petroleum system. Take the Putaohua oil bed of Talaha-Changjiaweizi syncline in the west of the basin as example, we have already discovered many highly commercial wells, in which the oil production of Gu88 well surpasses 100 m3/day. In recent years, exploration has expanded to the syncline center. The properties of reservoir are different obviously between the conventional oil reservoir and the syncline oil reservoir. The permeability of the former (for example, Daqing placanticline) is bigger than 10×10−3 μm2, but that of the latter is smaller than 10×10−3 μm2. But their sedimentary environment and sedimentary facies are similar, and their percentage of the sand is between 20%―40%. Gas will be on the top and oil on the middle owing to gravitational separation to an identical set of reservoirs, demonstrating that there is a unification oil-water boundary in the reservoir. In the Songliao basin, the syncline oil reservoirs owing to stagnation are in the central part, the oil-water transition zones owing to half stagnation are in both sides, and conventional oil reservoirs are in the anticline (Figure 2). 2.2 Inverted relation between oil and water We have found that 53% oil reservoirs belong to syn- WU HeYong et al. Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 5 | 702-709 703 704 WU HeYong et al. Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 7 | 702-709 Figure 1 Geologic characteristics and syncline oil reservoir of the Songliao basin, northeast China. 1, Primary structural line; 2, secondary structural line; 3, volcanic rock and pyroclastic rocks; 4, conglomerate; 5, glutenite; 6, sandstone; 7, sandy mudstone; 8, mudstone; 9, vitrinite reflectance of Qingshankou Formation source rock; 10, locality of Figure 2; 11, syncline oil reservoir area of Putaohua oil bed; 12, structure and stratigraphic lithologic oil reservoir area of Putaohua oil bed; 13, syncline oil reservoir area of Fuyang oil layers; 14, structure and stratigraphic lithologic oil reservoir area of Fuyang oil layers; 15, permeability of Putaohua oil bed (×10−3 μm2). Figure 2 Oil reservoir profile of Talaha-Changjiaweizi syncline in the Songliao basin, northeast China. 1, Oil layer; 2, oil and water layer; 3, water layer; 4, empty layer. cline oil reservoirs in the Putaohua oil bed of Gulong sag in the Songliao basin. Water layers are above the oil layer, and there is no edge water and bottom water in the oil reservoir. But the inverted phenomenon does not exist in the anticline and the sandstone lens or the lithological pinchout oil reservoir where the permeability is high. 3 Discussion on mechanism of petroleum accumulation in syncline The phenomenon of an inverted relation between oil and water indicates that the Gulong sag is unconventional oil reservoir. We consider that stagnation is the key to this kind of unconventional oil reservoir forming in a syncline. We discuss the stagnant mechanism in three aspects: difference of migration path ways and rates among oil, gas and water; dynamical condition; and the status of fluid flow through porous medium. 3.1 Difference of migration path ways among oil, gas and water Migration path ways of gas, water and oil through porous media are different. Gas and water flow generally as molecules, and their diameters are generally smaller than the pore throats diameter of low permeable reser- voir (in low to ultra-low permeable reservoir of Putaohua oil bed in the Songliao basin, the average pore throats diameter is: n×10―n×100 nm). But petroleum is some organic macro-molecules and they migrate in the form of oil droplets. The oil droplets diameters are associated with properties of oil (n×100―n×10000 nm)[15]. Generally, they are bigger than the pore throats diameter of this kind of reservoir, so oil droplets are blocked and deformed when they pass through the pore throats. By contrast, gas and water can pass easily. Therefore, the difference of size between oil droplets and water and gas molecules is the main reason that oil droplets are delayed passing through a reservoir with low porosity and permeability. Physical resistance to oil droplet movement is associated with anisotropy of pore structure except properties of oil in the process of migration. The oil droplets are subject to three forces. The first is the result from the change of capillary pore size, and the directions of the force are in agreement with capillary pore size increasing. The second is because of wetting hysteresis of the non-wetting phase (oil in a general way) in the process of movement, and its contact angle between advance and backlash is different which block the non-wetting phase. The direction of third force is vertical to the capillary WU HeYong et al. Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 5 | 702-709 705 pore wall and points to non-wetting phase. It is a kind of pressure to non-wetting phase, and the force is associated with a kinetic friction and deformation of non-wetting phase[16]. The resistance of non-wetting phase would increase when aeolotropism rise of pore throats or the properties of oil become thickness (Figure 3). The third force is zero in Figure 3(a), because the pore size is invariable. The third force in Figure 3(b) is not zero as a result of the pore size changing. The variance of diameter is the same as in Figure 3(c) and (d), but the third force in Figure 3(c) is smaller than in Figure 3(d), because the diameter of Figure 3(c) changes continuously. 3.2 Dynamic conditions of petroleum reservoir formation The buoyancy (F), the internal fluid pressure difference in basin (δp) and the capillary force (PC) control the dynamic process of oil driving water. F and δp are the Figure 3 power of migration, but PC always blocks the movement of the non-wetting phase. The magnitude between drive and resistance determines whether the petroleum is detained. The interrelation among them determines whether gravitational separation of oil and water occurs. The complex dynamics process can be explained by the dynamics model of Berkenpas which is an inversion model of gas and water[17]. It is a process where oil displaces water when oil migrates in a reservoir. Stagnation occurs when the power (interior fluid pressure difference in basin is primary) is insufficient to overcome the resistance (the force makes oil droplets deform). The dynamic condition changes continuously in the process of oil migration. There is hardly any mobile water in the reservoir in the axis of a syncline, and buoyancy does not have an effect. It produces generally pure oil or few emulsified water in the reservoir (Figure 4(a)). Figure 4(a) corresponds to the Oil droplets deform in the process of migration in different pore structures. Figure 4 Theoretical model of the oil reservoir accumulation in syncline by stagnation (modified from Berkenpas[17]). 1, Oil; 2, gas; 3, mobile formation water; 4, boundary layers (immovable irreducible water). 706 WU HeYong et al. Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 7 | 702-709 stagnant area in Figure 2. Oil could migrate up-dip when the fluid pressure difference is larger than the resistance. The fluid pressure difference could diminish gradually along the migration path, simultaneously, the porosity and permeability of a reservoir are improved, and the resistance is reduced gradually. It is the transition zone between oil and water when the power and the resistance balance (Figure 4(b), (c), half stagnant area of Figure 2). Oil is stagnant under the transition zone, migrates up-dip, and conventional petroleum reservoirs are above the transition zone (Figure 4(d), unrestricted flow area in Figure 2). Gravitational separation is the result of interaction of buoyancy and capillary force. The buoyancy which oil droplets receives is smaller by a long way than the capillary resistance in the axis of a syncline, thus gravitational separation does not exist. The mobile water appears gently and begins to surround oil droplets along the up-dip direction where the pores become larger. The capillary resistance which oil droplets receives diminishes gradually, gravitational separation occurs when the buoyancy is bigger than the capillary resistance. 3.3 The state of fluid flowing through porous medium Filtration theory of underground fluid considers that the flow velocity through porous media is proportional to pressure gradient in Darcy flow. But there are nonlinear relations in non-Darcy flow with a low speed, in which there is a starting pressure gradient[18]. Oil droplets migrate only when they overcome resistance in the low to ultra-low permeability reservoir, in which starting pressure gradient exists, so it is a kind of non-Darcy flow. The non-Darcy flow with low speed intensifies stagnation in the low to ultra-low permeability reservoir. The traditional petroleum migration and accumulation theory is based on Darcy flow theory. Petroleum exploration should pay more attention to low porosity and permeable reservoirs, so we should understand in depth the stagnation of fluid flowing at a low speed going through porous medium. Wu Jingchun et al.[19] did a set of experiments about characteristics of single phase low velocity of non-Darcy flow in a low permeable reservoir in the eastern Daqing, with the permeability coefficient being 0―50×10−3 μm2 in the experiments. The experimental results indicate that the reservoirs have the characteristic of low speed non-Darcy flow. 4 Discussions The sphere of application is different between the mechanism of petroleum accumulation in syncline and the traditional petroleum migration and accumulation theory. The former is suitable to the low to ultra-low permeable reservoir. The permeability of a reservoir in syncline areas of the Songliao basin is generally smaller than 50×10−3 μm2. The latter is suitable to medium to high permeable reservoir. Therefore, the former is a supplement to the latter. 4.1 The contrast between the mechanism of petroleum migration and accumulation in syncline and the traditional mechanism of petroleum migration and accumulation The syncline oil reservoir is the unconventional oil reservoir which forms in low to ultra-low permeable reservoir, and the contrast between it and the traditional mechanism of petroleum migration and accumulation is summarized in Table 1. Its mechanism is non-Darcy flow with low to ultra-low speed, and oil accumulates in reservoir by stagnation driven by the fluid pressure difference. The mechanism of traditional petroleum migration and accumulation is Darcy flow with medium to high speed and differential accumulation. Their accumulation spots are different, too. Traditional petroleum accumulation is in the structural high stratigraphic trap where is corresponding to the area with low potential of liquid. But the syncline reservoir accumulates in the axis of syncline. It lies in correspondingly high potential area of liquid, generally, with overpressure phenomenon existing there. Their flow mechanisms are different, so are the development ways. The related mechanism needs to be discussed further. The main difference between a syncline reservoir and stratigraphic lithologic reservoir is the difference between conventional and unconventional oil reservoir. Based on the discussion of reservoir forming mechanisms, conventional stratigraphic lithologic reservoir belongs to Darcy flow. The traditional mechanism emphasizes the cap rock, source rock, reservoir lens wrapped by non-permeable rock layers, and up-dip pinchouts. It also emphasizes the seals in the vertical and lateral directions. But syncline reservoir emphasizes only the stagnation in low to ultra-low permeable reservoir. Only when the fluid pressure difference surpasses the pressure which the low speed non-Darcy flow re- WU HeYong et al. Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 5 | 702-709 707 Comparison of the mechanisms between conventional and unconventional oil reservoir Conventional oil gas reservoir Unconventional oil gas reservoir (Half or non-oil and water gravitational separation) (Oil and water gravitational Classification separation) Traditional petroleum migraMechanism of petroleum accumulation in Deep basin gas tion and accumulation syncline High to medium permeability Applicable scope Low to ultra-low permeable reservoir Low to ultra-low permeable reservoir the reservoir Abnormal pressure differential of natural Power of reservoir Buoyancy, accumulations in Fluid pressure difference, accumulations in gas, concentration difference, accumulaaccumulation relatively low potential area relatively high potential area tions in relatively low potential area Flowing way in which fluid flows through Darcy flow Low speed non-Darcy flow Concentration diffusion porous medium Compact reservoir in the scope of source Low to ultra-low permeable reservoir in the Relations of Source-reservoir-oil reservoir rock discharge. Reservoir and oil reservoir scope of source rock discharge hydrocarbon. source-reservoir connect indirectly connect directly Reservoir and oil reservoir connect directly Displacement ways to From the top downwards From low to high spot From low to high spot primitive water in trap Regional structure low spot or slope, synReservoir structure spots Regional structure high spot Regional structure low spot, syncline area cline area Hydrodynamic trap, stratigraphic lithologic Structure, stratigraphic Low porosity reservoir, oil droplets are stagTrap way trap, structural trap. Dynamic balance of lithologic trap nant or partly stagnant accumulation and diffusion Insufficient gravitational separation of oil Sufficient gravitational sepaand water, edge water and bottom water does Insufficient gravitational separation of gas Distribution of oil and ration of oil and water, edge not exist, emulsified water exists, sometimes and water, there is no obvious bottom water water water and bottom water exist free water exists Bottom water drives, elastic Development way Fluid pressure difference drives, elastic drive Natural gas concentration difference drive drive Injection-production Development by natural gas pressure drop Balanceable water flooding Over balanceable water flooding system (does water flooding) Table 1 quires, would oil flow through porous medium, that is to say, it flows from relatively high potential area to relatively low potential area. 4.2 The contrast between syncline oil reservoirs and deep basin gas Stagnation is the key factor that results in oil accumulation in a syncline. Since the molecular diameter of natural gas is small, gas migrates primarily by concentration diffusion in deep basin gas, and its mechanism is a kind of dynamical equilibrium[20,21]. Two dynamical equilibrium processes exist in deep basin gas. They are between fluid pressure and capillary pressure as well as supply and diffusion of natural gas. There is no syncline reservoir discovered in research to deep basin gas in a syncline of a basin center. It should be the reason that oil had become cracked gas when it is buried to a certain depth. 5 Conclusions First, syncline oil reservoir is the unconventional oil reservoir which forms in a low to ultra-low permeable reservoir by stagnation. 708 Second, the mode of gas, water and oil droplets flowing through porous medium is different. Gas and water flow at the molecular level, and they could pass through the pore smoothly. But the minimum diameter of oil droplets is generally bigger than the pore throats diameter of a low to ultra-low permeable reservoir; thus, they must be deformed to pass through the pore throats. Therefore, water and gas pass through in advance, oil droplets are delayed or stagnate. Third, the main force is the internal fluid pressure difference, the buoyancy and the capillary force in a basin. The former two are the driving force of migration; the latter is the resistance of migration to oil. Oil would be detained when driving force is smaller than resistance. The buoyancy is smaller than the capillary resistance in a syncline reservoir, so normal gravitational separation would not exist. The authors would like to thank academician Jia Chengzao, Professor Li Sitian and Professor Li Mingcheng et al. for their help in researching, and academician Han Dakuang, academician Qiu Zhongjian, Professor Zha Quanheng, Professor Jin Zhijun, Professor Zhao Wenzhi, Professors Pang Xiongqi and Yang Changchun et al. for their amending the paper. WU HeYong et al. Sci China Ser D-Earth Sci | May 2007 | vol. 50 | no. 7 | 702-709 1 North F U. Petroleum Geology (in Chinese). Beijing: Petroleum In- 12 2 3 (in Chinese), 2003, 8(1): 32―40 Schowlter T T. Mechanics of secondary hydrocarbon migration and entrapment. AAPG Bull, 1979. 63: 723―760 13 Sediment Sinica (in Chinese), 2006, 24(1): 148―152 efficient movement of separate, buoyant oil phase along limited 4 14 Magoon L B. The petroleum system―a classification scheme for dustrial Press, 1998. 1―5 15 6 7 16 Wang Z X. Is capillary power a driving force for the primary migra- 17 Berkenpas P G. 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