FUNGICIDE Superior Sulfur Protection Micronized Wettable Sulfur Formulation Micro Sulf® Nufarm Agriculture Division Sulfur – Improving With Age S ulfur is one of the oldest pesticides known to man. As early as 1000 B.C. Homer recommended what he called “the pest-averting sulfur.” In 1845, sulfur was recommended for control of powdery mildew in grapes. And in the 1920s, sulfur was registered for pesticidal use in the United States. Sulfur is also one of the most effective pesticides known to man. In fact, sulfur is now even more effective for treatment and prevention of such pests as Powdery Mildew, Mites and Phomopsis, thanks in large part to the discovery and production of better formulations. Among the best is the micronized formulation from Nufarm – Micro Sulf®. Micro Sulf provides excellent coverage and exceptional disease and mite control for a wide range of crops, from fruits such as grapes, apples, peaches and cherries to vegetables such as spinach, cucumbers and carrots. Micro Sulf is made from the highest quality ingredients for easy mixing and spraying. And Micro Sulf has a 2 lower phytotoxicity than other forms of sulfur. • Clingstone peaches have a pit to which the fruit 'clings' • Freestone peaches have a pit from which the fruit easily pulls away • The peach is the state fruit of Georgia and South Carolina • The peach blossom is the official state flower of Delaware • Georgia is the largest producer of peaches in the U.S. • Johnston, South Carolina is known as the Peach Capital of the World . Sulfur has historically been a leading weapon in the war against fungi and mites. Now it’s easier than ever before to use the power of sulfur for your crops … because now you have Micro Sulf from Nufarm. Nufarm’s Micro Sulf – the proven performance of sulfur enhanced for today’s growers. FUNGICIDE A Brief History of Sulfur Sulfur Formulations Through the Ages 1000 B.C. Homer recommends “the pest-averting sulfur.” Homer was probably referring to Flowers of Sulfur. Formed when raw sulfur is purified through sublimation, Flowers of Sulfur is supposed to deter insect infestations. Of any sulfur formulation, it has been in use the longest. 1850 Dusting sulfur was invented and used on dew-dampened foliage. Dusting sulfur is usually mixed with clay to facilitate dry grinding. This affects the size of the sulfur particle for an average size of 20 to 25 microns. Dusting sulfur is applied dry onto crops for dew to activate its pesticidal power. 1852 A French gardener, Grison, boiled a mixture of lime and sulfur to protect his grapes from mildew. He called it “Eau Grison.” Lime sulfur is water soluble and more potent than insoluble elemental sulfur. In fact, it is one of the most powerful of all sulfur fungicides. Unfortunately, it is also the most phytotoxic. 1884 Sulfatine dust, a combination of Bordeaux and sulfur, was developed. The Bordeaux Mixture, invented by Millardet, combines copper sulfate with lime for a messy, yet effective fungicide used to combat downy mildew on French grapes. This mixture was apparently added to sulfur and boiled to form a dry formulation. 1923 The first wettable sulfur was proposed. Wettable sulfurs are a blend of sulfur, dispersants and surfactants that are milled to a fine particle size. They can be applied dry or as a spray. 1970 Flowable sulfurs are introduced for pesticidal use. Flowable sulfurs are homogenized and suspended in water using dispersants and thickeners. They are easy to measure and apply. 1990s Micronized sulfurs are developed. Micronized sulfur particles are extremely fine. The active sulfur content in micronized sulfurs is lower than other types of sulfur formulations, yet they are more effective. Micro Sulf, a highly effective micronized sulfur from Nufarm, becomes available in 2000. • Spinach was the first frozen crop to be sold • Spinach is an excellent source of Vitamin A and folacin, and is also a source of fibre, potassium and Vitamin C • California is the leading spinach producer in the U.S. • Persian Arabs first brought spinach to Spain in the early 9th century, calling it “aspanakh” 3 The Power of Sulfur Why sulfur? Why a sulfur product to protect your grapes, apples and other crops from mites and disease? There are a number of products available in the marketplace today that provide effective control for fungi and mites – but, unfortunately, many of them can lead to resistance issues. What is the best protection for resistance issues? Sulfur. All other products come and go, but sulfur is the bedrock foundation every effective disease management program rests upon. There is another reason growers need sulfur for their crops – it works. In fact, it works extremely well. How does sulfur work? Properly applied, sulfur forms a protective barrier on the plant surface. This barrier kills fungi by interfering with cellular respiration, inhibiting the electron movement within the fungi and 4 preventing it from accumulating the materials and energy it needs to survive and thrive. This protective barrier also acts as a stomach toxin for the control of mites. • Emperor Tiberius of Rome grew cucumbers in carts, using slaves to wheel them around to catch the sun • Cucumbers have been cultivated since about 8,000 B.C. • Columbus brought cucumbers to America • Cucumbers are about 95% water • A cucumber can actually be up to 20 degrees F cooler on the inside than the outside What’s the difference among sulfurs? After all, every sulfur pesticide on the market will kill fungi and mites, right? That’s correct, but there are some significant differences. One difference is that micronized sulfurs are less phytotoxic than other types of sulfurs, resulting in fewer instances of crop damage. In addition, micronized sulfurs have a lower dust content – dust-free in many cases. But the biggest difference is one of quality, efficiency and effectiveness. Some sulfur formulations simply need more active sulfur to be effective. As a general rule, the active sulfur content for wettable powders must be as high as 92%. The active sulfur content for micronized sulfurs can typically be far lower at 80%. How can they have less sulfur and still be effective? It’s a matter of size – particle size. Although particle sizes for wettable powders appear tiny, compared to micronized sulfur, they’re much larger … and heavier too. FUNGICIDE In fact, these sulfur particles are heavier than water molecules. Without extreme agitation, much of the sulfur content sinks to the bottom. Upon application, the grower is left with a slurry of sulfur and crops sprayed with yellow water of very little sulfur content. Plus, the sulfur that makes it to the crop’s surface doesn’t get far. Because the droplets flatten without spreading far, the sulfur in the water tends to fall to the bottom of the droplet instead of spreading out to form the protective barrier crops need for disease and mite control. Micronized sulfur particles, on the other hand, are extremely fine. These particles are very buoyant and disperse quickly to suspend in the water. This micronized sulfur mixture won’t clog spray application nozzles, and so it can be applied quickly and easily. Upon application, the droplets spread to form a protective barrier that is more volatile, and effective, than other sulfur formulations. Why should I use Micro Sulf? For one thing, Micro Sulf is a micronized sulfur product. Everything that makes micronized sulfurs efficient and effective – including consistently finer particle sizes, dustless • More than 40 million tons of apples are produced worldwide each year • There are more than 7,000 varieties of apples formulation and high suspensibility – also makes Micro Sulf efficient and effective. • The U.S. grows 100 varieties commercially Micro Sulf also compares very favorably with other micronized sulfurs on the market, • The average American eats almost 20 pounds demonstrating as good, if not superior, characteristics. of fresh apples each year Micronized Sulfurs Comparison Chart (%) Analysis Type Sulfur Content Insolubles Suspension Moist Mesh Dustiness Micro Sulf® 80.6 .02 85.9 .2 .04 (dust-free) Kumulus® 81.4 .54 88.7 .34 .16 (dust) Thiolux® 82.4 2.0 80.8 .46 .05 (little dust) Microthiol® DF 82.3 0.1 84.1 .07 .01 (dust-free) Micro Sulf is produced using technologically advanced processes from some of the purest sulfur sources in the world. This ensures a consistent particle size from batch to batch for high suspensibility and a dust-free formulation. And Micro Sulf has just the right amount of sulfur to make it extremely effective. Its unique formulation optimizes sulfur’s activity to destroy fungal spores and mites quickly and efficiently. Add it all together, and using Micro Sulf for your fungicide and miticide needs isn’t just a good idea – it’s a great idea. Why sulfur? Because it works! Why Micro Sulf? Because it works better! • The U.S. is the world’s second largest apple producer; China is first • Washington state produces more apples than any other state 5 Micro Sulf® Active Ingredient: Sulfur Micro Sulf, a premium sulfur fungicide and miticide with preventative action, is a micronized wettable formulation specifically designed to provide superior disease and mite control. Micro Sulf’s consistently fine particle size, dust-free formulation and high suspensibility make it the perfect sulfur product for any spray application – offering dependable, uniform plant coverage for your crops. Features and Benefits Effective Control • Powdery Mildew 6 • Grape growing is the largest food industry in the world • Mites • There are more than Consistent Fine Particle Sizes 8,000 varieties of grapes • Phomopsis • Better surface area coverage • The average person eats eight pounds of grapes a year • Lower risk of phytotoxicity • The best selling table grape in the U.S. is the Thompson Seedless • Easy to mix and spray • Botanically, grapes are berries Highly Suspensible Micro Sulf is a dust-free micronized formulation that provides highly effective disease and mite control. • More sulfur on plant • Less sulfur left in tank Widespread Compatibility • There are about 25 million acres of grapes worldwide • Copper fungicides • The world production of grapes is over 72 million tons • Organic fungicides, insecticides, • Liquid fertilizers acaricides and herbicides Dust-free Formulation • Easy suspension • Improved handling The raw material for Micro Sulf is elemental sulfur refined from the "Klaus" process. The Klause process recovers sulfur from the residual gas of oil refining. This sulfur's purity exceeds 99.9%. FUNGICIDE Application Methods Micro Sulf may be applied through any type of handheld, knapsack, mechanical or pneumatic spray equipment. The volume per acre will differ depending on the crop and the equipment used. Micro Sulf can also be employed through aerial application methods. In addition, Micro Sulf can be applied through chemigation systems, except in California. Please consult label for specific ratios. Crops Protected * Micro Sulf offers excellent disease and mite protection for the following crops: • Grapes – Powdery Mildew, Bud Mite, Blister Mite, Red Spider Mite • Carrots – Powdery Mildew, Petrobia Mite • Citrus – Broad Mite, Citrus Rust Mite, Flat Mite, Silver Mite, Bud Mite, Red Spider Mite, Six Spotted Mite • Cucumbers – Powdery Mildew • Apples – Powdery Mildew, Scab, Blisters and Silver Mites, Two Spotted Mite, Red Spider Mite • Spinach – Powdery Mildew, Rust • Peaches – Powdery Mildew, Blossom Blight, Brown Rot, Leaf Spot, Silver Mite, Flat Mite, Red Spider Mite • Tomatoes – Two-Spotted Mite, Russet Mite, Powdery Mildew • Cherries – Powdery Mildew, Blossom Blight, Brown Rot, Leaf Spot, Silver Mite, Flat Mite, Red Spider Mite * Consult label for a complete list of diseases and mites Micro Sulf controls and the crops they affect. • Of the more than 1,000 varieties of cherries in the United States, fewer than 10 are commercially produced • Broadway in New York shifts west at East 10th Street because a cherry tree once stood there • In his work “History of Plants,” Theophrastus (372272 B.C.) mentions that cherries had been cultivated for hundreds of years in Greece • Michigan has over 35,000 acres of tart cherry trees and grows almost 75% of the tart cherries produced in the United States • The cherry is the state fruit of Utah • Kane, Pennsylvania, is the Black Cherry Capital of the World 7 MS.1202.056 © 2002 Nufarm Americas Inc. Nufarm Americas Inc. 1333 Burr Ridge Parkway • Suite 125A Burr Ridge, IL 60527-0866 Phone: 708.754.3330 • Fax: 708.754.0314 E-Mail: www.nufarm.com Micro Sulf® is a registered trademark of Nufarm Americas Inc. Kumulus® is a registered trademark of BASF Aktiengesellschaft. Microthiol® is a registered trademark of Les Raffineries de Soufre Reunies. Thiolux® is a registered trademark of Sandoz-Wander, Inc.
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