Chemistry 1010 Handout 1: Chemical substance and Measurements 1. A can of Campbell’s tomato soup indicates a suggested serving of 10 fluid ounces or 274 mL. (a) How many servings can be obtained from 1.00 litres of the soup? Servings = 1.00 L x 1000 mL L −1 274 mL = 3.6 servings (b) How many fluid ounces are there in 1.00 litre of the soup? Fluid ounces in 1 L = 1.00 L x 1000 mL L −1 x 10 fluid ounces serving −1 274 mL serving −1 = 36 fluid ounces (c) If the density of the soup is 0.9800 g mL–1, what is the mass in grams of a serving? Mass of one serving = 274 mL x 0.9800 g mL−1 = 269 g 2. Convert: (a) 1.75 metres to centimetres. 1 (b) 30.15 inches to metres. According to the data book that I have 1 in = 2.54 % 10 −2 m. The number of metres should be less than the number of inches. So, 30.15 in x 2.54 % 10 −2 m in −1 = 0.76581 m. To the correct number of significant digits the answer is = 0.766 m. (c) 256 mL to L. = 2.56 % 10 −1 L Ans: 2.56 % 10 −1 L 256 mL 1000 mL L −1 (d) 3.61 L to mL 1 L = 1000 mL so there must be more mL that L! Ans: 3.61 % 10 3 mL (e) 683.4 cm3 to dm3. 1 dm = 10 cm so 1 dm3 = (10 cm)3 = 1000 cm3. So, 683.4 cm3 683.4 cm3 = 1000 cm3 dm−3 :Ans = 6.834 % 10 −1 dm3 3. Recording tape in a cassette player travels at 1 7/8 inches per second. What is the length of the tape in a cassette if it is measured in metres and plays for 45 min per side (C-90)? Length of tape in inches = 15 8 in s −1 x 60 s min -1 x 45min = 5062.5 in Length of tape in metres = 5062.5 in x 2.54 cm in-1 x 1 1000 cm m −1 Volume in litres = 250 imperial_gallon x 4.545 L imperial_gallon-1 = 1.13625 x 103 L (b) What is the internal length of the sides of the cube in cm? Volume of the cube = 1.13625 x 103 L x 1000 cm3 L-1 = 1.13625 x 106 cm3 The volume of a cube = (length of side)3 Length of side = 3 1.13625 x 10 6 cm3 = 104.3497 cm (c) What is the total area of the steel sheet needed to make the cube? Each face has an area = (side)2. There are 6 faces so the total area = 6 x (104.3497 cm)2 = 6.53 x 104 cm2 5. Evaluate the following expressions giving your answer to the There are 1 centimetre is 100 metre so there are 100 cm in one metre and the number of centimetres will be greater than the number of metres. 1.75 m x 1000 cm m−1= 1750 cm but this leaves the number of significant digits in doubt. It is better to quote the answer in scientific notation so the answer becomes (3 significant digits) Ans : 1.75 x 10 3 cm There are 1000 mL in 1 litre so 256 mL = (a) What is the required volume in litres? = 12.86 m Ans: 13 m 4. A company wishes to make fuel tanks in the shape of a regular cube (all sides have same length) to hold 250 imperial gallons when completely filled. (Note: 1 imperial gallon = 4.545 L). correct number of significant digits. (a) 2.673 - 1.71 x 10–3 + 3.3216 x 102 334.83 (b) 232.81 + 2.221 + 0.0335 + 0.000044 235.06 (c) 12.226 x (1.312 + 1.35 x 10 2 ) (273.412 − 101.3) x 1.732 5.59 6. In a kitchen you will usually find a few pure substances. Calculate the formula weight and the molar mass of each of the following: (a) 'Common salt': sodium chloride, NaCl 58.4425 u; 58.44245 g.mol–1 (b) 'Baking soda': sodium hydrogen carbonate, NaHCO3 84.007 u; 84.007 g.mol–1 (c) 'Lye': sodium hydroxide, NaOH 39.9971; 39.9971 g.mol–1 (d) 'Sugar': sucrose, C12H22O11 39.99707; 39.99707 g.mol–1 (e) 'Bleach': sodium hypochlorite, NaOCl 74.4418; 74.4418 g.mol–1 (f) 'Washing soda': sodium carbonate decahydrate, Na2CO3·10 H2O 286.141; 286.141 g.mol–1 (g) 'Vinegar': ethanoic acid (as an aqueous solution), C2H4O2. 60.052; 60.052 g.mol–1 7. Balance the following equations: (a) 2 C(s) + O2(g) → CO(g) (b) 2 Na(s) + 2 H2O(l) → 2 NaOH(aq) + H2(g) (c) CaCO3(s) + 2 HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l) (d) WO2(s) + 2 H2(g) → W(s) + 2 H2O(g) 8. How many grams of the named substance is contained in the stated number of moles? (a) 0.50 mol of Ag(s) Ans: 54 g (b) 5.032 mol Ca(NO3)2 (c) 1.01 x 10–3 mol CuSO4·5 H2O Ans: 825.7 g Ans: 0.252 g 9. How many moles of the named substance is contained in the stated mass? (a) 50.0 g of S(s) Ans: 1.56 mol (b) 0.05000 g of NaCl (c) 22.26 g of (NH4)2SO4 Ans: 0.0008555 mol Ans: 0.1951 mol
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