A2 Physics Unit 9 Radioactivity Mr D Powell Chapter Map Common Issues Take care not to mix units when calculating. For instance, you may encounter activities given in Becquerel's and count rates stated in counts per minute; half lives are often quoted in reference works using the most relevant time unit, be it seconds or years. Mr Powell 2008 Index 9.1 Radioactivity 1. How big is the nucleus? 2. How was the nucleus discovered? 3. Why was it not discovered earlier? Mr Powell 2008 Index Alpha Decay.... Alpha particles tracks Mr Powell 2008 Index Probing the Nucleus – Rutherford Scattering 3 1 By firing alpha particles at a heavy gold nucleus Rutherford could easily see that atoms were mostly space with a large positive nucleus in the Rutherford alpha particle scattering experiment centre. lead block to select narrow beam of alpha particles thin gold foil microscope to view zinc sulphide screen, and count alpha particles 4 2 nucleus 2 90 1 135 3 50 4 30 vary angle of scattering observed radium source of alpha particles alpha particle beam zinc sulphide screen, tiny dots of scattered alpha light where struck particles by alpha particle 5 Mr Powell 2008 Index 5 20 Mr Powell 2008 Index Scattering Formulae (extension) There are complex formulae that we can use to work out the distance of closest approach. You will not have to learn these but should appreciate Rutherford’s picture of alpha scattering some of the maths involved. At the very least the idea of the forces For involved calculations force F = alpha particle scattered 2Ze2 40d2 charge +2e ‘aiming error’ b scattering angle d Assumptions: alpha particle is the He nucleus, charge +2e gold nucleus has charge + Ze, and is much more massive than alpha particles scattering force is inverse square electrical repulsion gold nucleus charge + Ze equal force F but nucleus is massive, so little recoil Mr Powell 2008 Index Distance of Closest Approach (extension) Mr Powell 2008 Index Distance of Closest Approach (extension) Mr Powell 2008 Index Mr Powell 2008 Index Summary Question... For an alpha particle with an initial KE of 6MeV fired at a gold nucleus find the distance of closest approach of the alpha and the nucleus... Mr Powell 2008 Index 9.2 Alpha / Beta / Gamma 1. What are alpha, beta, gamma 2. Why is it dangerous 3. What are the properties of alpha, beta, gamma Mr Powell 2008 Index Link them up? Mr Powell 2008 Index Mr Powell 2008 Index Guess the field? Mr Powell 2008 Index Particle Tracks Mr Powell 2008 Index Mr Powell 2008 Index Calibration plateau p.d... Mr Powell 2008 Index 9.3 More on Alpha / Beta / Gamma 1. What happens to the nucleus in a radioactive change 2. How does the intensity spread out 3. How do we represent the changes in the nucleus in alpha, beta, gamma. Mr Powell 2008 Index How does the intensity spread out Mr Powell 2008 Index Lines of stability... Mr Powell 2008 Index Emitters.... Mr Powell 2008 Index Mr Powell 2008 Index Mr Powell 2008 Index Mr Powell 2008 Index Corrected count rates & distances.... We must find the source centre for inverse sq law to work correctly. d0 d k C C0 2 d d 0 Mr Powell 2008 Index 9.4 The Dangers of Radioactivity 1. Why is ionising radiation 2. What factors determine whether , , are the most dangerous 3. How can exposure to ionising radiation be reduced Mr Powell 2008 Index Background Radiation Mr Powell 2008 Index Mr Powell 2008 Index Sievert The sievert (symbol: Sv) is the SI derived unit of dose equivalent. It attempts to reflect the biological effects of radiation as opposed to the physical aspects, which are characterised by the absorbed dose, measured in gray. It is named after Rolf Sievert, a Swedish medical physicist famous for work on radiation dosage measurement and research into the biological effects of radiation. 1 Sv = 1 J/kg = 1 m2/s2 = 1 m2·s–2 Frequently used SI multiples are the millisievert (1 mSv = 10–3 Sv) and microsievert (1 μSv = 10–6 Sv). The millisievert is commonly used to measure the effective dose in diagnostic medical procedures (e.g., X-rays, nuclear medicine, positron emission tomography, and computed tomography). The natural background effective dose rate varies considerably from place to place, but typically is around 2.4 mSv/year. For acute (that is, received in a relatively short time, up to about one hour) full body equivalent dose, 1 Sv causes nausea, 2-5 Sv causes epilation or hair loss, hemorrhage and will cause death in many cases. More than 3 Sv will lead to LD 50/30 or death in 50% of cases within 30 days, and over 6 Sv survival is unlikely. (For more details, see radiation poisoning.) The collective dose that a population is exposed to is measured in "man-sieverts" (man·Sv). Mr Powell 2008 Index 9.5 Radioactive Decay What do we mean by the activity of an isotope Activity A = λN. or Energy Transfer per second = AE What is the half-life of an isotope t1/2 = 0.69/λ Does anything affect radioactive decay Mr Powell 2008 Index Rate of Decay is the decay constant... Mr Powell 2008 Index Dice Results - 300 Number of sample 350 300 Number of Atoms Left 250 y = 288.79e-0.164x R² = 0.9922 200 150 100 50 0 0 5 10 15 20 25 Time elaspsed arbitrary Mr Powell 2008 Index Gamma 1.... Villard Paul Villard, a French physicist, is credited with discovering gamma rays in 1900. Villard recognised them as different from X-rays (discovered in 1896 by Roentgen) because the gamma rays had a much greater penetrating depth. It wasn't until 1914 that Rutherford showed that they were a form of light with a much shorter wavelength than X-rays. Roentgen High-energy photons emitted as one of the three types of radiation resulting from natural radioactivity are the most energetic form of electromagnetic radiation, with a very short wavelength (high frequency). Wavelengths of the longest gamma radiation are less than 10 -10 m, with frequencies greater than 10 18 hertz (cycles per sec). Gamma Emission occurs primarily after the emission of a decay particle. Gamma is a form of high energy electromagnetic radiation. After a particle is ejected from a nucleus the system may have some slight excess of energy, or exist in a metastable state. This slight excess of energy is released as gamma. Gamma emission will not change the isotope or the element. The wavelength of the emitted gamma radiation will be unique to each isotope. Gamma emission is a significant health risk. Mr Powell 2008 Rutherford Index Gamma 2 Villard After a decay reaction, the nucleus is often in an “excited” state. This means that the decay has resulted in producing a nucleus which still has excess energy to get rid of. Rather than emitting another beta or alpha particle, this energy is lost by emitting a pulse of electromagnetic radiation called a gamma ray. Roentgen The gamma ray is identical in nature to light or microwaves, but of very high energy. Like all forms of electromagnetic radiation, the gamma ray has no mass and no charge. Gamma rays interact with material by colliding with the electrons in the shells of atoms. They lose their energy slowly in material, being able to travel significant distances before stopping. Depending on their initial energy, gamma rays can travel from 1 to hundreds of meters in air and can easily go right through people. Rutherford Mr Powell 2008 Index Gamma Emission Mr Powell 2008 Index Gamma Emission 1. Gamma is a process which often happens in addition to a beta decay 2. It can often have different energies attached from differing transitions. Mr Powell 2008 Index Alpha Decay The nucleus is initially in an unstable energy state. An internal change takes place in the unstable nucleus and an alpha particle is ejected leaving a decay product. Alpha particles have a velocity in air of approximately one-twentieth the speed of light, depending upon the individual particle's energy. Since the number of protons in the nucleus of an atom determines the element, the loss of an alpha particle actually changes the atom to a different element. For example, polonium-210 is an alpha emitter. During radioactive decay, it loses two protons, and becomes a lead-206 atom, which is stable (i.e., nonradioactive). Examples are; Americium-241 , Plutonium-236 , Uranium-238 Thorium-232 , Radium-226 , Radon-222 , Polonium-210 Mr Powell 2008 Index Alpha Decay The positive charge of alpha particles is useful in some industrial processes. For example, radium-226 may be used to treat cancer, by inserting tiny amounts of radium into the tumorous mass. Polonium-210 serves as a static eliminator in paper mills and other industries. The alpha particles, due to their positive charge, attract loose electrons, thus reducing static charge. Some smoke detectors take advantage of alpha emissions from americium-241 to help create an electrical current. The alpha particles strike air molecules within a chamber, knocking electrons loose. The resulting positively charged ions and negatively charged electrons, create a current as they flow between positively and negatively charged plates within the chamber. When smoke particles enter the device, the charged particles attract them, breaking the current and setting off the alarm. Tumors on liver on the top left Mr Powell 2008 Index Alpha Decay Mr Powell 2008 Index Beta Decay Mr Powell 2008 Index Protactinium Generator This experiment uses a 'protactinium generator' to show the exponential decay of protactinium-234, a grand-daughter of uranium. It has a half-life of just over a minute, which allows the chance to measure and analyse the decay in short time. The bottle contains a complex mixture of substances but when you have shaken the bottle the and organic layer separates out which contains the protactinium234. This decays with a half-life of 68 seconds and can be monitored. U 238 Th234 Pa 234 U 234 Th230 U238 T0.5 = 4.47 Billion years Mr Powell 2008 Index Protactinium Generator The Pa234 is a beta emitter 2.3MeV (max) which escapes the tube and leaves U234 which has a very long alpha half life. We can monitor the Pa activity in the top layer and any newly spawned Pa from the bottom layer is prevented from contaminating the top layer. Hence, we have an initial sample of Pa and can see over a period of time the change in activity. 70s years Pa 234 U 234 Th230 Mr Powell 2008 Index Graphical Decay Mr Powell 2008 Index Real Data Now try plotting a graph and prove some formulae 1. Plot one Loge graph or Ln graph 2. Plot one normal graph 3. Show via inspection and mathematically the formulae below. Test each one out and see if it is true! t1/2 = 0.69/λ = ln2/ λ Time in seconds 0 20 40 60 80 100 120 140 160 180 200 Activity Recorded in Bq 210 165 130 110 95 75 65 53 29 28 25 N = N0e-λt A = A0e-λt Activity A = λN Mr Powell 2008 Index Example Results & Proof of Formulae.... Can you now prove any of these relations by drawing a graph and taking some readings? t1/2 = 0.69/λ N = N0e-λt A = A0e-λt Activity A = λN. Mr Powell 2008 Index 250 Counts in 10 seconds 200 150 y = 213.38e-0.011x R² = 0.9791 100 50 0 0 50 100 150 200 250 Time in seconds (s) Mr Powell 2008 Index Dice Exp... 76 dice were taken and thrown and then the number of dice on a 1 were counted and removed. The process continued until there were no dice left. The results were graphed in two different ways by activity and mass Activity Time 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Activity 12 10 8 4 14 6 4 3 5 4 1 1 1 1 1 1 1 Time 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 Mass 76 64 54 46 42 28 22 18 15 10 6 5 4 3 2 1 1 16 14 12 10 8 6 4 2 0 y = 12.379e-0.181x R² = 0.8281 0 5 10 15 20 Mass 120 100 y = 105.9e-0.282x R² = 0.9808 80 60 40 20 0 0 5 10 15 Mr Powell 2008 20 Index Time 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 Number 300 261 218 194 162 133 110 88 65 54 48 43 37 34 31 25 21 19 17 13 11 300 dice were taken and thrown and then the number of dice on a 1 were counted and removed. The process continued until there were no dice left. The results were graphed 50 45 40 35 30 25 20 15 10 5 0 y = 43.672e-0.169x R² = 0.8918 0 5 10 15 20 25 Time elaspsed arbitrary Number of sample 350 300 Number of Atoms Left Time Activity 0 39 1 43 2 24 3 32 4 29 5 23 6 22 7 23 8 11 9 6 10 5 11 6 12 3 13 3 14 6 15 4 16 2 17 2 18 4 19 2 20 2 Acticity of Sample Activity 250 y = 288.79e-0.164x R² = 0.9922 200 150 100 50 0 0 5 10 15 Time elaspsed arbitrary 20 25 Write a simple definition for.. T0.5 = = No = N= A= A0 = t = Mr Powell 2008 Index 9.6 Radioactive Decay Theory Can a source decay completely What is an exponential decrease Why is the process random t1/2 = 0.69/λ A = λN N = N0e-λt or A = A0e-λt Mr Powell 2008 Index T1/2 1. The number of radioactive nuclei decaying per second (activity) is proportional to number of nuclei remaining Mr Powell 2008 Index Mr Powell 2008 Index Decay Constant Mr Powell 2008 Index Decay Constant Mr Powell 2008 Index Decay Constant Mr Powell 2008 Index Decay Curves... Mr Powell 2008 Index Decay Curve This curve is an exponential decay It takes the same time for half the sample to decay i.e. Activity reduces over time. Mr Powell 2008 Index Decay Curves... Mr Powell 2008 Index Decay Curves... Mr Powell 2008 Index The Decay Equation 1 Mr Powell 2008 Index Decay Equation 2 Mr Powell 2008 Index Equivalence of Formulae Mr Powell 2008 Index Half - Life The T0.5 time for an isotope is defined as the time taken for half the sample to decay Mr Powell 2008 Index Exam Question... Using the decay equation... Show that 4 marks... Mr Powell 2008 Index Half – Life 2 Mr Powell 2008 Index Example of using Equation Mr Powell 2008 Index T1/2 Examples... TASK Can you work out the decay constant for each isotope of carbon? C9 - 5.457 s-1 C10 – 0.036 s-1 C11 – 5.7 x 10-4 s-1 C12 – 0 s-1 Mr Powell 2008 Index Example Curve Mr Powell 2008 Index 9.7 Isotopes in Use How do we do radioactive dating What are radioactive tracers What do we use radioactivity for in hospitals. Mr Powell 2008 Index Can you plot this data to find out half life? Mr Powell 2008 Index Carbon Dating 14 7 N n C p 14 6 C N e 14 6 beta decay 14 7 Here is a good example of capture of a neutron into the nucleus followed by decay back again via a beta minus process. Mr Powell 2008 Index Maths for Dating? Imagine you start with a blob of a man and want to find out the number of original atoms in the sample which were radioactive. t1/2 = 0.69/λ t1/2 = 5700 years so λ = 1.216 x 10-4 years-1 or work out in seconds N = N0e-λt Now you know No from the mass spectrometer but you don’t know the time it has taken from t = 0 i.e. When it died. You now need to know the activity now (Geiger-Muller tube) and the activity of a sample of man who is living to compare. If in Bq then λ is in seconds Take the ratio of activities & work through to find age, then work back to find N0 of original sample. (see book page 168) Mr Powell 2008 Index Tricks with 2N? T0.5 N Series If you think about the idea of the number of atoms left after a number n of half lives. 1 1/2 21 2 1/4 22 You can then construct a very useful equation. 3 1/8 23 This enables you to predict the number of atoms left if you know the original number of atoms and the T0.5 time. 4 1/16 24 5 1/32 25 Or you can work out the number of T0.5 times it will take to reduce the number of atoms or activity to a certain amount. N N 0 0.5 n N n 0.5 N0 Mr Powell 2008 Index 9.8 More about Decay Modes 1. What can we tell about radioactive isotopes from an N-Z chart 2. Why don’t naturally occurring isotopes emit + radiation? 3. What happens to an unstable nucleus that emits radiation. Mr Powell 2008 Index Mr Powell 2008 Index Technetium Doses... Also, a commonly-used measure of radioactivity is the microcurie: Can you estimate out the activity per second? 1 μCi = 3.7×104 disintegrations per second = 2.22×106 disintegrations per minute How many Bq? The typical human body contains roughly 0.1 μCi of naturally occurring potassium-40. Mr Powell 2008 Index Mr Powell 2008 Index Stable or Unstable Nuclei e and unstable nuclei: balance of numbers of protons and neutrons stable alpha decay 150 beta decay electron capture positron emission fission 100 N= Z 50 0 0 20 40 60 80 100 proton number Z Mr Powell 2008 Index Pauli cliffs The sides of the valley rise steeply. The Pauli exclusion principle keeps numbers of protons and neutrons approximately equal. Binding is less strong if either are in excess. Positron decay Valley of Stability Free particle plains Z N Z–1 N +1 + Electron decay – Z N proton number Z Binding energy taken as zero for free protons and neutrons. Z+1 N –1 proton number Z Bound nuclei have negative binding energies, down to about –8 MeV per nucleon Binding energy per 0 nucleon/MeV Fusion hill –2.5 Larger numbers of neutrons and protons are bound more strongly than smaller numbers, by the –5.0 strong nuclear interaction. –7.5 These nuclei go down hill by nuclear fusion. 0 Coulomb slope More neutrons than protons are needed to overcome electrical repulsion of many protons. 25 These nuclei go down hill by alpha decay 50 ‘Iron lake’ 75 Nuclei near iron in the Periodic Table are the most strongly bound, and lie in the bottom of the nuclear 100 proton valley. Other nuclei tend to ‘run number Z downhill’ to become like iron. 0 40 80 neutron number N 120 160 Alpha decay Z N Stable nuclei lie along a narrow band of values of numbers of protons and neutrons. The more negative the binding energy, the more stable the nucleus. Z–2 N –2 proton number Z Mr Powell 2008 Index half-life 4.5 109 yr Decay Chains ..... Decay chain from Th-232 146 142 neutron number N Th-232 – Th-228 134 132 Po-216 Pb-212 130 128 Tl-208 – Bi-212 – Rn-220 138 Ra-226 Rn-222 Po-218 Th-230 Main source of naturally occurring radium, half-life 1600 yr. Radium was discovered by Marie Curie and her husband Pierre Curie. Pb-214 – Bi-214 – 130 Po-214 128 Pb-210 – 126 140 132 Po-212 U-234 Radon gas, half-life 56 s, 136 from building materials is an important part of the 134 natural background radiation Marie Curie, discoverer with Pierre Curie of polonium, named the element after her native Poland Pa-234 – Ra-224 – 142 136 Th-234 144 Ac-228 – 138 U-238 Ra-228 140 neutron number N 126 Pb-208 Bi-210 – Po-210 proton number Z 81 82 83 84 85 86 87 88 89 90 Tl Pb Bi Po At Rn Fr Ra Ac Th 124 Pb-206 stable proton number Z 82 83 84 85 86 87 88 89 90 91 92 Pb Bi Po At Rn Fr Ra Ac Th PaIndex U Mr Powell 2008 Review... Why don’t naturally occurring isotopes emit + radiation? 1. they are all manmade by a process of bombarding stable nuclei with protons. 2. Hence, protons need to be fast enough to overcome coulomb repulsion. 3. If elements gain a proton they actually become more unstable and not more stable and move away from line. So Copper for example will never give on + as it would become more unstable. Mr Powell 2008 Index 9.9 Nuclear Radius 1. Are more massive nuclei wider? 2. How does the radius of a nucleus depend on its mass number A? 3. How dense is the nucleus? Mr Powell 2008 Index Small Nucleus.... Nucleons.... Mr Powell 2008 Index Estimate Nuclear Diameter with “Electron Diffraction” Mr Powell 2008 Index Quick Question hc E 1.22 sin d Mr Powell 2008 Index Atomic Scale Can you estimate the distance of the outer shell electron for a gold atom? If you are not sure just pick a figure...... 3.3 miles Mr Powell 2008 Index Atomic Radius.... Various types of scattering experiments suggest that nuclei are roughly spherical and appear to have essentially the same density. The data are summarised in the expression called the Fermi model; r ro A 1 3 r0 = 1.2 x 10-15m = 1.2fm r = atomic radius A = mass number (nucleons) Mr Powell 2008 Index Atomic Radius.... Various types of scattering experiments suggest that nuclei are roughly spherical and appear to have essentially the same density. The data are summarized in the expression called the Fermi model; r ro A 1 3 r0 = 1.2 x 10-15m = 1.2fm r = atomic radius A = mass number (nucleons) Element A A1/3 R in fm Carbon Oxygen Silicon Calcium Vanadium Strontium Indium 12 2.29 2.75 16 2.52 3.02 28 3.04 3.64 40 3.42 4.10 50 3.68 4.42 88 4.45 5.34 115 4.86 5.84 FACT The diameter of the nucleus is in the range of 1.6fm (1.6 × 10−15 m) (for a proton in light hydrogen) to about 15 fm (for the heaviest atoms, such as uranium). Can you plot a graph and show that this formulae is correct and the constant is 1.2fm Mr Powell 2008 Index Finding R0 Nuclear Radius 8.00 7.00 6.00 R in fm 5.00 y = 1.2x + 7E-14 R² = 1 4.00 3.00 2.00 1.00 0.00 0.00 2.00 4.00 6.00 cuberoot of A ( Nucleon Number) Mr Powell 2008 8.00 Index Summary & Question 1. Calculate the radius of an oxygen nucleus which has 16 nucleons.. r=r0A 1/3= 1.4 x 10-15 x (16)1/3 r=3.5 x 10-15m (3.5fm) Mr Powell 2008 Index Nuclear Density – is massive! Mr Powell 2008 Index Reflection high-energy electron diffraction (RHEED) Reflection high-energy electron diffraction (RHEED) is a technique used to characterise the surface of crystalline materials. RHEED systems gather information only from the surface layer of the sample, which distinguishes RHEED from other materials characterization methods that rely also on diffraction of high-energy electrons. Transmission electron microscopy, another common electron diffraction method samples the bulk of the sample due to the geometry of the system. Low energy electron diffraction (LEED) is also surface sensitive, but LEED achieves surface sensitivity through the use of low energy electrons. http://en.wikipedia.o rg/wiki/Reflection_hi gh_energy_electron_ diffraction Mr Powell 2008 Index Reflection high-energy electron diffraction (RHEED) The image shows the setup of the electron gun, sample and detector /CCD components of a RHEED system. Electrons follow the path indicated by the arrow and approach the sample at angle θ. The sample surface diffracts electrons, and some of these diffracted electrons reach the detector and form the RHEED pattern. The reflected (specular) beam follows the path from the sample to the detector. Specular reflection is the mirror-like reflection of light (or of other kinds of wave) from a surface, in which light from a single incoming direction (a ray) is reflected into a single outgoing direction Mr Powell 2008 Index Wave nature of the electron • Louis de Broglie (1892 - 1987) • If light can be modeled as a particle or as a wave, can an electron be modeled as a wave? • The wavelength of a matter wave (1923) is given by: • Everyday objects are too massive to give observable wavelengths; however, electrons are light enough to give observable wavelengths. Diffraction of electrons was observed by two groups in 1927, Davisson & Germer and George Thomson. • The Bohr model could also be explained using standing waves. • Whole numbers (1,2,3,etc.) of de Broglie wavelength give the allowed radii found in the Bohr model. Mr Powell 2008 Index Experiments of GP Thompson Mr Powell 2008 Index Electron Waves Two specific examples supporting the wave nature of electrons as suggested in the DeBroglie hypothesis are the discrete atomic energy levels and the diffraction of electrons from crystal planes in solid materials. In the Bohr model of atomic energy levels, the electron waves can be visualized as "wrapping around" the circumference of an electron orbit in such a way as to experience constructive interference. Bragg diffraction. Two beams with identical wavelength and phase approach a crystalline solid and are scattered off two different atoms within it. The lower beam traverses an extra length of 2dsinθ. Constructive interference occurs when this length is equal to an integer multiple of the wavelength of the radiation. Mr Powell 2008 Index Microstructure of Nickel Superalloys • These pictures are taken using electron diffraction. They are trying to establish the structure and if there are any problems in the structure of Nickel alloys used in aeroplane manufacture. It is important that any micro fissures are detected early on. Mr Powell 2008 Index Experiments of Davisson and Germer 1927 Mr Powell 2008 Index Experiments of Davisson and Germer 1927 Mr Powell 2008 Index De Broglie Summary / Questions Mr Powell 2008 Index Exam Questions Q2 June 07.... The table shows data for some nuclei. 1 eV = 1.6 ×10-19 J & speed of electromagnetic radiation = 3.0 × 108 ms-1 (a) (i) Show that these data support the rule that where R0 is a constant; R = R0A(1/3) (ii) The mass of a nucleon is about 1.7 × 10-27 kg. Calculate the density of nuclear matter. (6 marks) (b) (i) Explain what is meant by the binding energy of a nucleus. (ii) Show that the total binding energy of a sodium-23 nucleus is about 3 × 10-11 J. (iii) Calculate the mass-equivalent of this binding energy. (5 marks) Mr Powell 2008 Index Mr Powell 2008 Index Q4 June 05.... Americium-241 ( Am) is a common laboratory source of alpha radiation. It decays spontaneously to neptunium (Np) with a decay constant of 4.8 × 10-11s-1. A school laboratory source has an activity due to the presence of americium of 3.7 × 104Bq when purchased. Avogadro constant = 6.0 × 1023mol-1 one year = 3.2 × 107s (a) (i) Calculate the half-life, in years, of americium-241. (2 marks) (ii) Calculate the number of radioactive americium atoms in the laboratory source when it was purchased. (2 marks) (iii) Calculate the activity of the americium in the laboratory source 50 years after being purchased. (3 marks) (iv) Suggest why the actual activity of the sources is likely to be greater than your answer to part (iii). (1 mark) Mr Powell 2008 Index Q4 June 05.... (answers) (a) (I) half life = 1.44 x 1010 s or half life = 0.69/λ or ln2/λ Or 450 (449) y (or 460(456)y if they use 3.15 x 107 s = 1y) II) A = λN = 7.7 x 1014 III) IV) the decay products/neptunium may also be radioactive Mr Powell 2008 Index Q4 June 05.... (b) (i) Use the following data to deduce the energy released in the decay of one Americium-241 nucleus. mass of americium-241 nucleus = 4.00171 × 10-25kg mass of an alpha particle = 0.06644 × 10-25kg mass of neptunium nucleus = 3.93517 × 10-25kg speed of electromagnetic radiation in free space = 3.00 × 108ms-1 3 marks (ii) Explain what is meant by decays spontaneously and how consideration of the masses of particles involved in a proposed decay helps in deciding whether the decay is possible. 2 marks Mr Powell 2008 Index Q1 June 06.... 1 (a) Radioactive lead-214 changes to lead-206 by a series of decays involving alpha (α) and negative beta (β.) emissions. Explain clearly how many alpha and beta particles are emitted during this change. (4 marks) (b) The half-life of lead.214 is 26.8 minutes. (i) Explain what is meant by half-life. (ii) Show that the decay constant of lead 214 is approximately 0.026 minute-1. (iii) Calculate the percentage of the original number of nuclei of lead-214 left in a sample after a period of 90 minutes. (7 marks) Mr Powell 2008 Index Q2 June 07.... (c) Nuclear structure can be explored by bombarding the nuclei with alpha particles. The de Broglie wavelength of the alpha particle must be similar to the nuclear diameter. Calculate the energy of an alpha particle that could be used to explore the structure of manganese-56. (4 marks) Planck constant = 6.6 × 10-34 J s mass of an alpha particle = 6.8 × 10-27 kg wavelength = nuclear diameter of manganese = 9.2 × 10-15 m momentum = h/λ = 7.17 × 10-20 Js m-1 or (N s) =h/p or h/mv as p = mv so as Ek = ½mv2 we can sub in; Ek = p2/2m or can use = h/mv so v = h/m Using velocity = 1.05-1.06 × 107 ms-1 3.7(4) -3.8(1) × 10-13 J Mr Powell 2008 Index Q2 June 07.... (d) (i) State the proton number and nucleon number of the nucleus formed by the decay of manganese-56. Proton number......... Nucleon number......... (ii) The activity of a sample of manganese 56 varies with time according to the equation A = A0e-λt What value should be used for λ in calculations involving manganese-56 when t is in seconds? (4 marks) Z = 26 A = 56 λ = 0.69/half life or 0.69/2.6 7.37 - 7.41 × 10-5 (s-1) Mr Powell 2008 Index
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