KEY CONCEPTS FROM ST LABS 1. How to Distinguish Between Metals, Metalloids and Nonmetals. • Metals usually react with acid to produce a gas; metalloids and non metals do not. • If a metal reacts with water or oxygen, it will leave behind a base • Non metals are poor conductors; metalloids conduct but usually not as well as most metals. • Metals are malleable; metalloids and non metals are not. • Some nonmetals and metalloids can sparkle but they won’t have that almost mirror-like luster that most metals have. Example: Match column 1 with column 2 COLUMN 1 A solid that conducts electricity__A_ A yellow-gold, shiny crystal____A___ Malleable and bubbles when placed in acid B_ Not malleable___A_ Does not leave a base after being placed in water___A_ 2. Electrolysis of Water 2 H2O a) b) c) d) COLUMN 2 Inconclusive; need more tests Definitely a metal Definitely a metalloid Definitely a non metal. 2 H2 + O2 • Water can be split with electricity and the help of acid or salt • Electrodes connected to a battery are inserted into separate test tubes. Each one will collect a different gas. • When it dissociates, in theory, it should give a 2: 1 ratio of H2 and O2 gases to reflect the balanced equation • But because of competing impurities inthe water, usually less oxygen is produced. 1 Examples: 1. Identify the test tube containing oxygen and find the approximate percent of oxygen in that test tube. Use a ruler. 0.53cm/3.30 cm = 17% Notice that the more meaningful ratio of hydrogen to oxygen can also be measured. 2. A) Water can be split with electricity and the help of ____salt____ or acid or base____ B) Electrodes connected to _____a power source___ are inserted into separate _test tubes_. Each one will collect a different gas. C) When it dissociates, in theory, it should give a ____2:1__ ratio of H2 and O2 gases to reflect the balanced equation D) But because of competing impurities inthe water, usually_less___ oxygen is produced. 3. Preparing a Solution WDTA for a solid after using m = CV and PTA for dilution 2 Examples: 1. a) How would you prepare 5.0 ml of a 3.0 g/L solution? • • • b) What if there was no 5.0 ml volumetric flask. What could you use instead? • c) Weigh 0.005L* 3.0 g/L = 0.015 g of solute Dissolve in a beaker with less than 5.0 ml Transfer to a volumetric flask and top to 5.0 ml mark. (In this case since the volume is so small you could use a 5.0 ml graduated cylinder.) What would you have to do to make the solution 1000 times more dilute? Assume that there is no micropipette in the lab but that there is an IV medicinal drip, which is adjusted to deliver 10 drops from each 1.0 ml. 1000 times more dilute means we want C2 = 3/1000 = 0.0030 g/L V1 =? C1= 3.0 g/L V2 = not mentioned, so we can choose, say, 100.0 ml = 0.100 L C1V1=C2V2 3 V1= 0.0030 g/L(0.100) V1 = 0.00010 L = 0.10 ml Since 1.0ml /10 drops = 0.10 ml/drop, you would need only 0.10 ml/ (0.10ml/drop) = 1 drop of the original solution, and that would have to be diluted to 100.0 ml with water 3 4. Carbon Cycle Lab • By blowing into water or any aqueous solution we represented what happens when carbon dioxide from the atmosphere encounters water: H2O + CO2 H2CO3 • In the presence of base (high pH) and calcium ions, the ions from the H2CO3 react and form calcium carbonate, which is found in shells. • Both vinegar and H2CO3 are acids, so both change the colour of bromothymol blue towards yellow. But since H2CO3 is a weaker acid, it only goes to the in-between colour of green. Example: a) How do you test for the presence of carbon dioxide in breath? Use limewater. It will go cloudy. b) Why does the cloudiness go away if you keep blowing into it? Extra breath introduced more carbon dioxide, which makes the solution eventually acidic and it dissolves the calcium carbonate precipitate that made id cloudy in the first place. 5. How to Build Circuits Case 1: Series Circuit (Note how the voltmeter is connected to each end of the resistor. The ammeter is only connected to one end. 4 Case 2: Parallel Circuit a. Ammeter Positioned to Measure Total Current b. Ammeter Positioned to Measure I2 c. Ammeter Positioned to Measure I1 5 6. A) B) C) Gears: Practical Concepts In order to have a velocity ratio greater than 1, you need to have the larger gear as the input. To further increase the ratio, a gear box can be used. In order to maintain same direction for the output as input, you need: (1) An odd number of gears in a gear train. (2) Or use a chain between two gears (3) Or use a belt between two grooved wheels. 6 Example: Draw a set up in which a pair of 6-toothed gears and a pair of 2-toothed gears are rearranged to create a gear ratio of 9. You need a gear box. 7. Transformation Systems You can transform circular motion to linear motion with (1) (2) (3) Rack and pinion Cam and follower Crank-slider Example: a) Which transformation system is this? Crank and slider. b) What can be attached to make it more practical? A handle 7
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