K-34733/31502 - UK / IRELAND - (BASE) - PAGE 2
(UK only) The (COSHH) Control of Substances Hazardous
to Health Regulations may apply to the use of this product
at work.
SAFETY INFORMATION
STEWARD®
Insecticide – contains 300 g/kg indoxacarb
Contains Indoxacarb. May produce an allergic reaction
PCS No 02603,
MAPP No 13149
FOR PROFESSIONAL USE ONLY
SP
Harmful if swallowed.
May cause damage to organs (nervous system).
Very toxic to aquatic life with long lasting effects
Do not breathe vapours/spray.
Wash hands and face thoroughly after handling.
Do not eat, drink or smoke when using this product.
IF exposed or if you feel unwell: Call a POISON Centre or
doctor/physician.
Collect spillage.
Dispose of contents / container to a licensed hazardous-waste
disposal contractor or collection site except for triple rinsed empty
clean containers which can be disposed of as non-hazardous waste.
Do not contaminate water with the product or its container (Do
not clean application equipment near surface water/Avoid
contamination via drains from farmyards and roads).
To avoid risks to human health and the environment, comply with
the instructions for use
PCS No 02603, MAPP No 13149
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WARNING
Du Pont (UK) Limited, Crop Protection Products
Wedgwood Way, Stevenage. Herts. SG1 4QN
Tel: (01438) 734450 or [email protected]
Emergency 24-hour contact:
Telephone: UK 0870 820 0418, Ireland 01 901 4670
England and Wales - National Poisons Information Service
111
Scotland - National Poisons Information Service 08454
24 24 24
Ireland: National Poisons Information Centre (01) 809 2166
(UK only) This label is
compliant with the CPA
Voluntary Initiative Guidance
A water dispersible granule containing 300 g/kg indoxacarb for the
control of caterpillars in cabbage,
cauliflower, broccoli, apples, pears
and various protected fruiting ve getables and pollen beetle in Winter
and Spring oilseed rape.
® DuPont’s
registered trademark
250 g ℮
K-34733/31502 - UK / IRELAND
NOIR
K-34733/31502 - UK / IRELAND - PAGE 3
IMPORTANT INFORMATION
FIELD OF USE: For use only as an agricultural/horticultural insecticide
FOR PROFESSIONAL USE ONLY
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Crops
Cabbage, cauliflower, broccoli
Max. Individual dose Max.
(g product / ha
number of
or 100 l water)
treatments
Latest time of
application
85 g/ha
3 per crop
1 day before harvest
6 per year
1 day before harvest
Protected cucumber, courgette,
marrow, winter squash,
12.5 g/100 l water
pumpkin, melon, aubergine,
tomato and pepper
PCS No 02603, MAPP No 13149
Apples, pears
250 g/ha
3 per year
7 days before harvest
Winter and Spring oilseed rape
85 g/ha
1 per crop
Before GS 60 (first
flowers open stage)
OTHER SPECIFIC RESTRICTIONS
When applying to protected crops the maximum spray concentration must not exceed 12.5 g
product/100 litres of water
(UK only) The (COSHH) Control of Substances Hazardous to Health Regulations may apply
to the use of this product at work.
(UK only) This product qualifies for inclusion within the Local Environment Risk Assessment for
Pesticides (LERAP) scheme for broadcast air-assisted sprayers only. Before each spraying operation from a broadcast air-assisted sprayer, either a LERAP must be carried out in accordance with CRD’s published guidance or the statutory buffer zone must be maintained. The
results of the LERAP must be recorded and kept available for three years
SP
A water dispersible granule containing 300 g/kg indoxacarb for the control of caterpillars
in cabbage, cauliflower, broccoli, apples, pears and various protected fruiting vegetables
and pollen beetle in Winter and Spring oilseed rape.
Du Pont (UK) Limited, Crop Protection Products
Wedgwood Way, Stevenage. Herts. SG1 4QN
Tel: (01438) 734450 or [email protected]
Emergency 24-hour contact:
Telephone: UK 0870 820 0418, Ireland 01 901 4670
England and Wales - National Poisons Information Service 111
Scotland - National Poisons Information Service 08454 24 24 24
Ireland: National Poisons Information Centre (01) 809 2166
(IRL only) – Method of application: Tractor mounted sprayer, Knapsack and Orchard blast sprayer
(UK only) This label is
compliant with the CPA
Voluntary Initiative Guidance
READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING
PLANT PROTECTION PRODUCTS
NOIR
K-34733/31502 - UK / IRELAND - PAGE 4
(Ireland only) Broadcast air-assisted sprayers - To protect aquatic organisms respect
an unsprayed buffer zone of 15m to surface water bodies.
SAFETY PRECAUTIONS
STORAGE AND DISPOSAL
KEEP AWAY FROM FOOD DRINK AND ANIMAL FEEDING STUFFS
KEEP OUT OF REACH OF CHILDREN
KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place
DO NOT RE-USE CONTAINER FOR ANY OTHER PURPOSE
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OPERATOR PROTECTION
Engineering control of operator exposure must be used where reasonably practicable in
addition to the following personal protective equipment:
WEAR SUITABLE PROTECTIVE GLOVES AND SUITABLE PROTECTIVE RESPIRATORY
PROTECTIVE EQUIPMENT (disposable filtering facepiece to EN 149 FFP2, or equivalent)
when handling the product
WEAR SUITABLE PROTECTIVE GLOVES when during application by broadcast air-assisted sprayer.
However, engineering controls may replace personal protective equipment if a COSHH
assessment shows that they provide an equal or higher standard of protection.
TAKE OFF IMMEDIATELY all contaminated clothing
WHEN USING DO NOT EAT, DRINK OR SMOKE.
IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible).
SP
ENVIRONMENTAL PROTECTION
(UK only) DO NOT ALLOW DIRECT SPRAY from broadcast air-assisted sprayers to fall within
15 m of the top of the bank of a static or flowing water body, unless a Local Environment Risk
Assessment for Pesticides (LERAP) permits a narrower buffer zone, or within 5 m of the top
of a ditch which is dry at the time of application. Aim spray away from water.
(UK only) This product qualifies for inclusion within the Local Environment
Risk Assessment for Pesticides (LERAP) scheme for broadcast air-assisted
sprayers only. Before each spraying operation from a broadcast air-assisted
sprayer, either a LERAP must be carried out in accordance with CRD’s
published guidance or the statutory buffer zone must be maintained. The
results of the LERAP must be recorded and kept available for three years.
DO NOT CONTAMINATE WATER WITH THE PRODUCT OR ITS CONTAINER. Do not clean application
equipment near surface water/ Avoid contamination via drains from farmyards and roads.
DIRECTIONS FOR USE
IMPORTANT: This information is approved as part of the Product Label. All instructions
within this section must be read carefully in order to obtain safe and successful use of
this product.
RESTRICTIONS
Steward must not be applied to any crop suffering from stress as a result of drought,
waterlogging, low temperatures, pest or disease attack, nutrient or lime deficiency or other
factors reducing crop growth.
Good agricultural practice suggests that Steward should be used when bees are less
active (i.e. early morning or late evening).
INSECT CONTROL
Steward is an oxadiazine (IRAC group 22) insecticide used for the moderate control of
pollen beetle (Meligethes spp.) and the larvae of various Lepidopteran (caterpillar) species.
Activity is by ingestion and contact. The product also shows ovicidal efficacy against some
species. Paralysis of the pest occurs within a few hours of exposure and results in
cessation of movement and feeding. Optimal effectiveness takes 6-7 days.
K-34733/31502 - UK / IRELAND - PAGE 5
It is important that the grower considers the following:
• Alternate the use of Steward with products with a different mode of action than indoxacarb.
• Monitor insect populations and apply Steward when locally determined economic
thresholds are reached. More than one application may be necessary for any infestation.
• Follow the directions for use as mentioned on this label, regarding dose, interval and
optimum application timing.
Cabbage, cauliflower and broccoli
Pests controlled:
Dose:
Timing:
SP
Growers should consult the IRAG website for further information on the current resistance
management strategy for pollen beetle.
CROPS
Steward may be applied to the following crops:
Protected cucumber (gherkin), courgette (zucchini), marrow, winter squash, pumpkin,
melon, aubergine, tomato and pepper
Pests controlled: Golden twin-spot moth (Chrysodeixis chalcites), Beet armyworm
(Spodoptera exigua), Cabbage moth (Mamestra brassicae), Tomato moth
(Lacanobia oleracea), Silver y-moth (Autographa gamma) and other
Plusia species and leafrollers.
Dose:
0.0125% w/v (12.5 g/100 L of water)
Timing:
Treat as soon as the first caterpillars (damage) are detected. Subsequent
treatments may be applied at 8 –14 day intervals as required.
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Insect resistance
When insecticides with the same mode of action are used repeatedly over several years
to control the same species in the same field, naturally-occurring resistant strains may
survive a correctly applied treatment, propagate, and become dominant in that field. An
insect can be resistant if the product applied under recommended conditions does not
work well. Some insects (e.g. Cydia pomonella) have developed resistance to commercially
available products. When resistance occurs, recommended rates fail to suppress the pest
population below economic thresholds.
Cabbage whites (Pieris spp.), Cabbage moth (Mamestra brassicae),
Garden pebble moth (Evergestis forficalis), Cabbage leafroller
(Clepsis spectrana) and Diamondback moth (Plutella xylostella).
85 g/ha in 200 l/ha using boom sprayer.
Treat when first caterpillars are detected or 7-10 days after trapping
of the first adults in pheromone traps. Subsequent treatments may be
applied at 8 –14 day intervals as required.
Apples and pears
Pests controlled: Steward will provide moderate control of Marbled orchard tortrix (Hedya
nubiferana), Large fruit tree tortrix (Archips podana), Rose tortrix
(Archips rosana), Straw-coloured tortrix (Clepsis spectrana), Dark fruit
tree tortrix (Pandemis heparana), Bud moth (Spilonota ocellana),
Summer fruit tortrix (Adoxyphyes orana), Codling moth (Cydia
pomonella), Winter moth (Operopthtera brumata) and Orthosia spp.
Dose:
A rate of 250 g/ha should be used for trees of 3.75 m height in a single row
system, 3.25 m height in a 2 or 3 row system and 2.25 m in a 5 row system.
Where tree height and/or canopy density is reduced, the dose (and
water volume) should be adjusted in accordance with an appropriate
dose adjustment scheme, for example PACE. However, if reducing the
dose according to tree height or canopy density, do not use less than
170 g/ha. Consult your specialist advisor for further information. Further
information on the PACE scheme is available from HDC, or see the HDC
fact sheet available from HSE’s website
http://www.pesticides.gov.uk/HDC.pdf
Timing:
Apply at egg-hatch. Subsequent treatments may be applied at 10 –14
day intervals.
K-34733/31502 - UK / IRELAND - PAGE 6
Winter and Spring oilseed rape
Pest controlled: Steward offers moderate control of Pollen beetle (Meligethes spp.)
Dose
85 g/ha in 200 l/ha using boom sprayer.
Timing
Apply when pollen beetles are present and reaching threshold levels.
Application may be made before GS 60 first flowers open growth stage.
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MIXING
Before using Steward, make sure that the spraying equipment is clean. Steward mixes
easily with water, but the following mixing procedure should be followed:
Quarter fill the spray tank with clean water, start the agitation and add the required quantity
of Steward directly to the tank without prior creaming. Continue agitation while topping up
the tank and while spraying. (IRL only) Follow the Good practice guide for empty pesticide
containers.
SP
SPRAY TANK CLEAN-OUT
Immediately after application, completely drain spray equipment. Thoroughly rinse sprayer
and flush the hoses, boom and nozzles with clean water. Loosen and physically remove
visible deposits. Remove and clean nozzles, screens and strainers. Flush the entire system
with clean water. Take all necessary safety precautions when cleaning equipment. Do
not clean near wells or water sources. Consult label tank cleanup procedures for all tank
mix partners and be sure to use the most rigorous procedure recommended.
NOTICE TO BUYER
All goods supplied by us are of a high grade and we believe them to be suitable for any
purpose for which we expressly supply them, but as we cannot exercise control over their
mixing or use, all conditions and warranties, statutory or otherwise, as to the quality or
fitness for any purpose of our goods are excluded and no responsibility will be accepted
by us for any damage or injury whatsoever arising from their storage, handling, application
or use.
K-34733/31502 - UK / IRELAND - PAGE 7
SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 and 453/2010
Telephone:
+44 (0) 1438 734 000
STEWARD®
E-mail address:
[email protected]
1.4. Emergency telephone number
Version 5.0 (replaces: Version 4.0)
Emergency telephone number: UK 0870 820 0418, Ireland 01 901 4670
Ref. 130000000325
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Revision Date 28.04.2014
SECTION 2: Hazards identification
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Chronic aquatic toxicity, Category 1:
H410: Very toxic to aquatic life with long lasting effects.
1.1. Product identifier
Harmful
Dangerous for the environment
Product name:
STEWARD®
Synonyms:
DPX-MP062 30WG
SP
This Safety Data Sheet adheres to the standards and regulatory requirements
of Great Britain and may not meet the regulatory requirements in other
countries. This Safety Data Sheet adheres to the standards and regulatory
requirements of the Republic of Ireland and may not meet the regulatory
requirements of other countries.
2.1. Classification of the substance or mixture
Acute toxicity, Category 4: H302: Harmful if swallowed.
Specific target organ toxicity - single exposure, Category 2:
H371: May cause damage to organs. (Nervous system)
R22: Harmful if swallowed.
R51/53: Toxic to aquatic organisms, may cause longterm adverse effects in the aquatic environment.
2.2. Label elements
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture:
Insecticide
1.3. Details of the supplier of the safety data sheet
Company:
Du Pont (UK) Limited
Wedgwood Way
Stevenage, Herts. SG1 4QN
United Kingdom
Exclamation mark
Health hazard
Environment
K-34733/31502 - UK / IRELAND - PAGE 8
Warning
H302
H371
H410
SECTION 3: Composition/information on ingredients
Harmful if swallowed.
May cause damage to organs. (Nervous system)
Very toxic to aquatic life with long lasting effects.
3.1. Substances
not applicable
Do not breathe vapours.
Do not breathe spray.
Wash hands and face thoroughly after handling.
Do not eat, drink or smoke when using this product.
IF exposed or if you feel unwell: Call a POISON CENTER or doctor/ physician.
Collect spillage.
Dispose of contents/ container to a licensed hazardous-waste disposal
contractor or collection site except for empty clean containers which can be
disposed of as non-hazardous waste.
Special labelling of certain substances and mixtures:
Restricted to professional users
SP 1
SP
P260
P260
P264
P270
P309 + P311
P391
P501
3.2. Mixtures
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Special labelling of certain substances and mixtures:
EUH401
To avoid risks to human health and the environment, comply with the
instructions for use.
Contains: Indoxacarb / EUH208: May produce an allergic reaction.
Do not contaminate water with the product or its container (Do not clean
application equipment near surface water/Avoid contamination via drains
from farmyards and roads).
2.3. Other hazards
Indoxacarb (CAS-No.173584-44-6)
T; R25
R48/25
Xi; R43
N; R50/53
Xn; R20
Acute Tox. 3; H301
Acute Tox. 4; H332
Skin Sens. 1B; H317
STOT RE 1; H372
Aquatic Acute 1; H400
Aquatic Chronic 1; H410
30 %
The above products are REACH compliant; Registration number(s) may not be provided
because substance(s) are exempted, not yet registered under REACH or are registered
under another regulatory process (biocide uses, plant protection products), etc.
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).
This mixture contains no substance considered to be very persistent nor very
bioaccumulating (vPvB).
4.1. Description of first aid measures
General advice: Never give anything by mouth to an unconscious person.
K-34733/31502 - UK / IRELAND - PAGE 9
Extinguishing media which shall not be used for safety reasons: High volume water jet,
(contamination risk)
5.2. Special hazards arising from the substance or mixture
Specific hazards during firefighting: Hazardous decomposition products formed under fire
conditions. Carbon dioxide (CO2) Nitrogen oxides (NOx)
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For specialist advice physicians should contact the National Poisons
Information Service: Tel. 111 for England and Wales and Tel. 08454 24 24 24
for Scotland.
For specialist advice contact the National Poisons Information Service:
Tel. (01) 837 9964 (Healthcare Professionals) or (01) 809 2166 (Public Poisons
Information Line - 8am-10pm).
Inhalation: Move to fresh air. Oxygen or artificial respiration if needed. Consult a physician.
Skin contact: Take off contaminated clothing and shoes immediately. Wash off immediately
with soap and plenty of water. In the case of skin irritation or allergic
reactions see a physician. Wash contaminated clothing before re-use.
Eye contact: If easy to do, remove contact lens, if worn. Hold eye open and rinse slowly
and gently with water for 15-20 minutes. If eye irritation persists, consult a
specialist.
Ingestion:
Obtain medical attention. DO NOT induce vomiting unless directed to do so
by a physician or poison control center. If victim is conscious: Rinse mouth
with water.
5.3. Advice for firefighters
Special protective equipment for firefighters: Wear self-contained breathing apparatus
and protective suit.
Further information: Prevent fire extinguishing water from contaminating surface water or
the ground water system. Collect contaminated fire extinguishing water separately. This
must not be discharged into drains. Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local regulations.
(on small fires) If area is heavily exposed to fire and if conditions permit, let fire burn itself out
since water may increase the area contaminated. Cool containers/tanks with water spray.
Symptoms:
SP
4.2. Most important symptoms and effects, both acute and delayed
No cases of human intoxication are known and the symptoms of experimental
intoxication are not known.
SECTION 6: Accidental release measures
4.3. Indication of any immediate medical attention and special treatment needed
6.1. Personal precautions, protective equipment and emergency procedures
Treatment:
Personal precautions: Control access to area. Keep people away from and upwind of
spill/leak. Avoid dust formation. Avoid breathing dust. Use personal protective equipment.
Refer to protective measures listed in sections 7 and 8.
Treat symptomatically.
SECTION 5: Firefighting measures
6.2. Environmental precautions
5.1. Extinguishing media
Suitable extinguishing media: Water spray, Foam, Dry chemical, Carbon dioxide (CO2)
Environmental precautions: Prevent further leakage or spillage if safe to do so. Use appropriate
container to avoid environmental contamination. Do not flush into surface water or sanitary
K-34733/31502 - UK / IRELAND - PAGE 10
sewer system. Do not allow material to contaminate ground water system. Local authorities
should be advised if significant spillages cannot be contained. If the spill area is porous,
the contaminated material must be collected for subsequent treatment or disposal. If the
product contaminates rivers and lakes or drains inform respective authorities.
working solution as soon as possible - Do not store. Provide appropriate exhaust ventilation
at places where dust is formed. Wash hands before breaks and immediately after handling
the product. Remove and wash contaminated clothing before re-use. Avoid exceeding of
the given occupational exposure limits (see section 8).
6.3. Methods and materials for containment and cleaning up
Advice on protection against fire and explosion: Keep away from heat and sources of
ignition. Avoid dust formation in confined areas. During processing, dust may form
explosive mixture in air.
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Methods for cleaning up: Clean-up methods - small spillage Soak up with inert absorbent
material.
Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean-up
methods - large spillage Avoid dust formation. Contain spillage, pick up with an electrically
protected vacuum cleaner or by wet-brushing and transfer to a container for disposal
according to local regulations (see section 13). Large spills should be collected
mechanically (remove by pumping) for disposal.
Collect leaking liquid in sealable (metal/plastic) containers. Collect and contain contaminated
absorbent and dike material for disposal.
Other information: Never return spills in original containers for re-use. Dispose of in
accordance with local regulations.
For personal protection see section 8., For disposal instructions see section 13.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Requirements for storage areas and containers: Store in original container. Keep in
properly labelled containers. Keep containers tightly closed in a dry, cool and wellventilated place. Store in a place accessible by authorized persons only. Keep out of the
reach of children. Keep away from food, drink and animal feedingstuffs.
Advice on common storage: No special restrictions on storage with other products.
Other data: Stable under recommended storage conditions.
7.3. Specific end use(s)
SP
6.4. Reference to other sections
7.2. Conditions for safe storage, including any incompatibilities
Advice on safe handling: Use only according to our recommendations. Use only clean
equipment. Avoid contact with skin, eyes and clothing. Do not breathe dust or spray mist.
Wear personal protective equipment. For personal protection see section 8. Prepare the
working solution as given on the label(s) and/or the user instructions. Use prepared
Plant protection products subject to Regulation (EC) No 1107/2009.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
If sub-section is empty then no values are applicable.
8.2. Exposure controls
Engineering measures:
Ensure adequate ventilation, especially in confined areas.
K-34733/31502 - UK / IRELAND - PAGE 11
Provide for appropriate exhaust ventilation and dust collection
at machinery.
Spray application - outdoor: Tractor / sprayer with hood: No
personal body protection normally required.
Contains no substances with occupational exposure limit values.
Tractor / sprayer without hood: Full protective clothing Type 4
(EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO 20345).
Safety glasses with side-shields conforming to EN166
Hand protection:
Material: Nitrile rubber
Glove thickness: 0.3 mm
Glove length: Standard glove type.
Protection index: Class 6
Wearing time: > 480 min
The selected protective gloves have to satisfy the specifications
of EU Directive 89/686/EEC and the standard EN 374 derived from
it. Please observe the instructions regarding permeability and
breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local conditions
under which the product is used, such as the danger of cuts,
abrasion, and the contact time. The suitability for a specific
workplace should be discussed with the producers of the
protective gloves. Gloves must be inspected prior to use. Gloves
should be discarded and replaced if there is any indication of
degradation or chemical breakthrough. Gauntlets shorter than
35 cm long shall be worn under the combination sleeve. Before
removing gloves clean them with soap and water.
SP
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Eye protection:
Skin and body protection: Manufacturing and processing work: Full protective clothing
Type 5 (EN 13982-2)
Mixer and loaders must wear: Full protective clothing Type 5 + 6
(EN ISO 13982-2/ EN 13034) Rubber apron Nitrile rubber boots
(EN 13832-3 / EN ISO 20345).
Backpack / knapsack sprayer: Full protective clothing Type 4
(EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO 20345).
Spray application - indoor: Motorized greenhouse sprayer: Full
protective clothing
Type 4 (EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO
20345).
Backpack / knapsack sprayer: Full protective clothing Type 4
(EN 14605) Nitrile rubber boots (EN 13832-3 / EN ISO 20345).
Mechanical automatized spray application in closed tunnel: No
personal body protection normally required.
When exceptional circumstances would require an access to
the treated area before the end of re-entry periods, wear full
protective clothing Type 6 (EN 13034), nitrile rubber gloves class
2 (EN 374) and nitrile rubber boots (EN 13832-3 / EN ISO 20345).
To optimize the ergonomy it may be recommended to use cotton
underwear when wearing some fabrics. Take advice from
supplier. Garment materials that are resistant to both water
vapour and air will maximise wearing comfort. Materials should
be robust to maintain the integrity and barrier in use. The
permeation resistance of the fabric must be verified
independently of the « type » protection recommended, to
ensure an appropriate performance level of the material
adequate to the corresponding agent and type of exposure.
K-34733/31502 - UK / IRELAND - PAGE 12
Spray application - indoor: Motorized greenhouse sprayer: Half
mask with a particle filter P1 (EN 143).
Mechanical automatized spray application in closed tunnel: No
personal respiratory protective equipment normally required.
SECTION 9: Physical and chemical properties
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Hygiene measures:
The type of protective equipment must be selected according to
the concentration and amount of the dangerous substance at the
specific workplace. All chemical protective clothing should be
visually inspected prior to use. Clothing and gloves should be
replaced in case of chemical or physical damage or if contaminated.
Only protected handlers may be in the area during application.
Handle in accordance with good industrial hygiene and safety
practice. Regular cleaning of equipment, work area and clothing.
Keep working clothes separately. Contaminated work clothing
should not be allowed out of the workplace. Wash hands and face
before breaks and immediately after handling the product. When
using do not eat, drink or smoke. Keep away from food, drink and
animal feedingstuffs. Remove clothing/PPE immediately if material
gets inside. For environmental protection remove and wash all
contaminated protective equipment before re-use. Wash
thoroughly and put on clean clothing. Dispose of rinse water in
accordance with local and national regulations.
SP
Protective measures:
Respiratory protection: Manufacturing and processing work: Half mask with a particle
filter FFP1 (EN149)
Mixer and loaders must wear: Half mask with a particle filter FFP1
(EN149)
Spray application - outdoor: Tractor / sprayer with hood: No
personal respiratory protective equipment normally required.
Tractor / sprayer without hood: Half mask with a particle filter FFP1
(EN149)
Backpack / knapsack sprayer: Half mask with a particle filter P1
(EN 143).
9.1. Information on basic physical and chemical properties
Form:
Colour:
Odour:
Odour Threshold:
pH:
Melting point/range:
Flash point:
Flammability (solid, gas):
dry, free flowing granules
dark brown
mild, woody
not determined
7.5 at 10 g/l (20 °C)
Not available for this mixture.
not applicable
Does not sustain combustion., Method:
Flammability (solids)
Thermal decomposition:
Not available for this mixture.
Auto-ignition temperature:
not auto-flammable
Oxidizing properties:
The product is not oxidizing. Method:
Directive 67/548/EEC, Annex V, A.17.
Explosive properties:
Not explosive
Lower explosion limit/ lower flammability limit: Not available for this mixture.
Upper explosion limit/ upper flammability limit: Not available for this mixture.
Vapour pressure:
Not available for this mixture.
Relative density:
0.8
K-34733/31502 - UK / IRELAND - PAGE 13
800 kg/m3
not determined
not applicable
not determined
Not available for this mixture.
Not available for this mixture.
9.2. Other information
Phys.-chem./other information: No other data to be specially mentioned.
SECTION 10: Stability and reactivity
10.1. Reactivity: No hazards to be specially mentioned.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute oral toxicity
LD50 / rat male: 1,876 mg/kg
Method: OECD Test Guideline 401
Information source: Internal study report (Data on the product itself)
LD50 / rat female : 687 mg/kg
Method: OECD Test Guideline 401
Information source: Internal study report (Data on the product itself)
Acute inhalation toxicity
LC50 / 4 h rat : > 5.6 mg/l
Method: OECD Test Guideline 403
Information source: Internal study report (Data on the product itself)
Acute dermal toxicity
LD50 / rat : > 5,000 mg/kg
Method: OECD Test Guideline 402
Information source: Internal study report (Data on the product itself)
Skin irritation
rabbit
Result: No skin irritation
Method: OECD Test Guideline 404
Information source: Internal study report (Data on the product itself)
Eye irritation
rabbit
Result: No eye irritation
Method: OECD Test Guideline 405
Information source: Internal study report (Data on the product itself)
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Bulk density:
Water solubility:
Partition coefficient: n-octanol/water:
Viscosity, kinematic:
Relative vapour density:
Evaporation rate:
SP
10.2. Chemical stability: The product is chemically stable under recommended conditions
of storage, use and temperature.
10.3. Possibility of hazardous reactions: No dangerous reaction known under conditions of
normal use. Polymerization will not occur. No decomposition if stored and applied as directed.
10.4. Conditions to avoid: To avoid thermal decomposition, do not overheat. Under severe
dusting conditions, this material may form explosive mixtures in air.
10.5. Incompatible materials: No materials to be especially mentioned.
10.6. Hazardous decomposition products: Hydrogen fluoride
Hydrogen chloride gas
K-34733/31502 - UK / IRELAND - PAGE 14
Sensitisation
guinea pig Maximisation Test (GPMT)
Result: Animal test did not cause sensitization by skin contact. Method: OECD Test Guideline 406
Information source: Internal study report (Data on the product itself)
Aspiration hazard
Repeated dose toxicity
Oral - feed rat
Exposure time: 90 d
Method: OECD Test Guideline 408
No significant toxicological effects in 90 day studies were found below the recommended
guidance values for classification., Information source: Internal study report
SECTION 12: Ecological information
Mutagenicity assessment
Indoxacarb
Tests on bacterial or mammalian cell cultures did not show mutagenic effects. Animal
testing did not show any mutagenic effects.
Method: OECD Test Guideline 203
Information source: Internal study report (Data on the product itself)
Toxicity to reproduction assessment
Indoxacarb
Animal testing did not show any effects on fertility. No toxicity to reproduction
STOT - single exposure
12.1. Toxicity
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Carcinogenicity assessment
Indoxacarb
Animal testing did not show any carcinogenic effects.
The mixture does not have properties associated with aspiration hazard potential.
Central nervous system
The substance or mixture is classified as specific target organ toxicant, single exposure,
category 2.
STOT - repeated exposure
The substance or mixture is not classified as specific target organ toxicant, repeated
exposure.
Toxicity to fish
LC50 / 96 h / Oncorhynchus mykiss (rainbow trout): 1.8 mg/l
Toxicity to aquatic plants
EbC50 / 72 h / Pseudokirchneriella subcapitata (green algae): > 1.2 mg/l
Method: OECD Test Guideline 201
Information source: Internal study report (Data on the product itself)
Toxicity to aquatic invertebrates
EC50 / 48 h / Daphnia magna (Water flea): 1.7 mg/l
Method: OECD Test Guideline 202
Information source: Internal study report (Data on the product itself)
Toxicity to other organisms
LD50 / Colinus virginianus (Bobwhite quail): 508 mg/kg
Method: US EPA Test Guideline OPP 71-1
Information source: Internal study report (Data on the product itself)
LD50 / 48 h / Apis mellifera (bees): 0.00160 mg/kg
Method: OEPP/EPPO Test Guideline 170
Oral Information given is based on data obtained from similar product.
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K-34733/31502 - UK / IRELAND - PAGE 15
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SP
Product: In accordance with local and national regulations. Must be incinerated in a
suitable incineration plant holding a permit delivered by the competent authorities. The
product should not be allowed to enter drains, water courses or the soil.
Contaminated packaging: Do not re-use empty containers.
SECTION 14: Transport information
ADR
14.1. UN number:
14.2. UN proper shipping name:
3077
Environmentally hazardous substance, solid, n.o.s.
(Indoxacarb)
14.3. Transport hazard class(es): 9
14.4. Packing group:
III
14.5. Environmental hazards:
For further information see Section 12.
14.6. Special precautions for user:
Tunnel restriction code:
(E)
K-34733/31502 - UK / IRELAND - PAGE 16
IATA_C
14.1. UN number:
14.2. UN proper shipping name:
IMDG
14.1. UN number:
14.2. UN proper shipping name:
3077
Environmentally hazardous substance, solid, n.o.s.
(Indoxacarb)
14.3. Transport hazard class(es): 9
14.4. Packing group:
III
14.5. Environmental hazards :
Marine pollutant
14.6. Special precautions for user: no data available
SP
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable
SECTION 15: Regulatory information
work of pregnant workers. Take note of Directive 98/24/EC on the
protection of the health and safety of workers from the risks related to
chemical agents at work. Take note of Directive 96/82/EC on the control
of major-accident hazards involving dangerous substances. Take note
of Directive 2000/39/EC establishing a first list of indicative occupational
exposure limit values.
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3077
Environmentally hazardous substance, solid, n.o.s.
(Indoxacarb)
14.3. Transport hazard class(es): 9
14.4. Packing group:
III
14.5. Environmental hazards :
For further information see Section 12.
14.6. Special precautions for user: ICAO / IATA cargo aircraft only
15.1. Safety, health and environmental regulations/legislation specific for the substance
or mixture
Other regulations: The product is classified as dangerous in accordance with Regulation
(EC) No. 1272/2008. Take note of Dir 94/33/EC on the protection of young
people at work. Take note of Dir 92/85/EEC on the safety and health at
15.2. Chemical Safety Assessment
A Chemical Safety Assessment is not required for this/these products
The mixture is registered as a plant protection product under Regulation (EC) No. 1107/2009.
Refer to the label for exposure assessment information.
SECTION 16: Other information
Text of R-phrases mentioned in Section 3
R20
R25
R43
R48/25
R50/53
Harmful by inhalation.
Toxic if swallowed.
May cause sensitisation by skin contact.
Toxic: danger of serious damage to health by prolonged exposure if
swallowed.
Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
Full text of H-Statements referred to under section 3.
H301
H317
H332
H372
Toxic if swallowed.
May cause an allergic skin reaction.
Harmful if inhaled.
Causes damage to organs through prolonged or repeated exposure.
NOIR
K-34733/31502 - UK / IRELAND - PAGE 17
H400
H410
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Other information: professional use
Abbreviations and acronyms
No Observed Effect Concentration
No Observed Effect Level
Organisation for Economic Co-operation and Development
Office of Prevention, Pesticides and Toxic Substances
Persistent, Bioaccumulative and Toxic
Short term exposure limit
time weighted average
very Persistent and very Bioaccumulative
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ATE
CAS-No.
CLP
EbC50
EC50
EN
EPA
ErC50
EyC50
IATA_C
IBC
ICAO
ISO
IMDG
LC50
LD50
LOEC
LOEL
MARPOL
n.o.s.
NOAEC
NOAEL
European Agreement concerning the International Carriage of
Dangerous Goods by Road
Acute toxicity estimate
Chemical Abstracts Service number
Classification, Labelling and Packaging
Concentration at which 50% reduction of biomass is observed
Median effective concentration
European Norm
Environmental Protection Agency
Concentration at which a 50% inhibition of growth rate is observed
Concentration at which 50 % inhibition of yield is observed
International Air Transport Association (Cargo)
International Bulk Chemical Code
International Civil Aviation Organization
International Standard Organization
International Maritime Dangerous Goods
Median Lethal Concentration
Median Lethal Dose
Lowest Observed Effect Concentration
Lowest observable effect level
International Convention for the Prevention of Marine Pollution from Ships
Not Otherwise Specified
No Observed Adverse Effect Concentration
No observed adverse effect level
SP
ADR
NOEC
NOEL
OECD
OPPTS
PBT
STEL
TWA
vPvB
Further information
Before use read DuPont's safety information. Take notice of the directions of use on the label.
® Registered trademark of E.I. du Pont de Nemours and Company
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only
as a guide for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The above information
relates only to the specific material(s) designated herein and may not be valid for such
material(s) used in combination with any other materials or in any process or if the material
is altered or processed, unless specified in the text.
NOIR