CHEM 4 DENSITY PROBLEMS Show your work. Each number in your calculation should be accompanied by an appropriate unit. The final answer should be recorded with the correct number of significant digits. 1. Use the handout “Densities of Some Common materials at 25ºC” to complete the table below. Classified as: Material Element carbon dioxide Homogeneous Mixture X X air X olive oil X cement Heterogeneous Mixture X water aluminum Compound X 2. Below is a graph showing the relationship between the mass and volume for water. Within the same coordinate plane draw a graph showing the relationship between the mass and volume for: (i) aluminum; (ii) ethyl alcohol. (Please use a ruler to draw the graphs.) 3. Below is a cube that approximately corresponds to one gram of water. Next to it draw (approximately to the scale) two cubes: a cube of one gram of iron and a cube of one gram of air. 4. Fill the blanks in the following. 1 mL H2O (at 4°C) = 1.000 g H2O 1 cm3 H2O (at 4°C) = 1.000 g H2O 1L H2O (at 4°C) = 1000 g H2O 1L H2O (at 4°C) = 1.000 kg H2O 1000 L H2O (at 4°C) = 1000 kg H2O 1 m3 1000 kg H2O H2O (at 4°C) = 5. Find the density of ethyl alcohol if 80.0 cm3 weighs 63.3 g. Ans.: 0.791 g/cm3 Mass Density = 63.3 g = Volume 80.0 cm 3 = 0.791 g/cm3 6. A piece of metal weighs 79.432 g. When the metal was placed into a graduated cylinder partially filled with water the level of water went up from its original 35.5 mL to 46.5 mL. What is the density of the metal in g/cm3? Ans.: 7.22 g/cm3 Volume = 46.5 mL – 35.5 mL = 11.0 mL = 11.0 cm3 Mass 79.432 g Density = = Volume 11.0 cm = 7.22 g/cm3 3 7. Find the volume in liters of 40 kg of carbon tetrachloride, CCl4. (Density = 1.60 g/cm3.) Ans.: 25 L 1 cm3 1000 g 40 kg × 1 mL × × 1 kg 1 cm3 1.60 g 1L × = 25 L 1000 mL 8. The mass of fuel in an airplane must be carefully accounted for before a takeoff. If a 747 contains 155,211 L of fuel, what is the mass of the fuel in kilograms? Assume the density of the fuel to be 0.768 g/cm3? (N.J. Tro, page 51, problem 111). Ans.: 119,000 kg 1000 cm3 155211 L 0.768 g × × 1L 1 cm 3 1 kg × = 119000 kg 1000 g 9. Osmium, element 76, is the densest natural element, with a density of 22.59 g/cm3 (twice that of lead). What is its density in pounds per cubic inch? Ans.: 0.8161 lb/in3 22.59 g 1 cm 3 (2.54 cm)3 1 lb × × 453.6 g 3 1 in = 0.8161 lb/in3 10. An electrolytic tin-coating process gives the coating 30 millionths of an inch thick. How many square meters can be coated with one kilogram of tin, density 7.30 g/cm3? Ans.: 180 m2 2.54 cm Thickness = 30×10-6 in × = 7.62×10-5 cm 1 in Volume = Area × Thickness = Area × 7.62×10-5 cm Volume = Area = Mass Density 1000 g 7.30 g/cm3 = Volume Thickness = = 137 cm3 137 cm3 -5 7.62×10 cm = 1.8×106 cm2 = 1.8×102 m2 11. An 56.1 cm3 sample of nickel weighs 0.500 kg. The density of lead is 11.3 g/cm3. How many grams of nickel metal would occupy the same volume as 215 g of lead? Ans.: 170. g or 1.70×102 g Mass 0.500 kg Density of Ni = = = 8.91 g/cm3 3 Volume 56.1 cm Volume of Pb = Mass of Ni = Mass Density = 215 g 11.3 g/cm3 19.0 cm3 × 8.91 g/cm3 = 19.0 cm3 = 170. cm3 12. A quick method of determining density utilizes Archimedes' principle, which states that the buoyant force on an immersed object is equal to the weight of the liquid displaced. A bar of magnesium metal attached to a balance by a fine thread weighed 31.13 g in air and 19.35 g when completely immersed in hexane (density 0.659 g/cm3). Calculate the density of this sample of magnesium. Ans.: 1.74 g/cm3 31.13 g – 19.35 g = 11.78 g = Archimedes’ Force = Weight of Hexane Displaced Volume of Mg = Volume of Hexane Displaced = Density of Mg = Mass of Mg Volume of Mg = Mass of Hexane Density of Hexane 11.78 g 17.9 cm3g = 11.78 g 0.659 g/cm3 = 1.74 g/cm3 = 17.9 cm3
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