Review Practice Problems Part #1: Topics 1-6 2 Who were the 10 scientists that were covered in class that contributed to the development of different Sketch and name the fouratomic atomic models models? did in they each that wereWhat covered class. contribute? 3 Describe Rutherford’s Gold Foil experiment and what it proved. 1 4 5 6 7 8 9 10 11 12 Bohr Rutherford observed how an alpha particle beam was scattered when it stroke a thin gold foil. It proved the existence of a small massive center to atoms, which would later be known as the nucleus of an atom. What does the Quantum model say about Orbital quantum numbers tell you what energy level the electron is in, and the types of orbital tell the nature of electrons in an atom? you shapes of orbitals (sometimes called electron clouds), volumes of space in which there is likely to be an electron. Put 0.00345 in scientific notation 3.45×10-3 Put 29800000 in scientific notation 2.98×107 What is wrong with the following number that was supposed to be put in sci. notation? 24.6 x 103 What is wrong with the following number that was supposed to be put in sci. notation? 0.54 x 102 What is the definition of atomic mass? 24.6 is greater than 10. It should be 2.46×104 How many neutrons does an atom of silver-108 have? How many protons, neutrons, and electrons does each atom have? Cl-35 Ba-137 C-12 Ne-20 When mass number is 108, there are 61 neutrons because the proton number is 47. 108-47=61 Cl Ba C Ne p 17 56 6 10 n 18 81 6 10 e 17 56 6 10 each of two or more atoms of the same element that contain equal numbers of protons but different numbers of neutrons in their nuclei. Carbon-12 has 6 neutrons, Carbon-13 has 7 neutrons, and Carbon-14 has 8 neutrons 14 What is the difference between Carbon12, Carbon-13, and Carbon-14? How many protons, neutrons, electrons does Bromine-80 have compared to Bromine-83? Which version of Bromine above is the more common isotope? How do you know? 17 What is a mole? 18 Why do we use “the mole” in chemistry class? What’s the difference between observation and interpretation? Qualitative observation vs quantitative observation? 19 the mass of an atom of an element expressed in atomic mass units (amu) Number of protons of the atom What is an isotope? 16 0.54 is lower than 1 It should be 5.4×101 What does the atomic number tell you? 13 15 Aristotle, Democritus, John Dalton, J. J. Thomson, Rutherford, Neils Bohr, de Broglie, Heisenberg, SchrÖdinger, Chadwick Dalton Bromine-80 has 35 protons, 45 neutrons, and 35 electrons Bromine-83 has 35 protons, 48 neutrons, and 35 electrons Bromine-80 is the more common isotope because the average atomic mass for Bromine is 79.90 amu, which is closer to 80 amu. A mole is the quantity of anything that has the same number of particles, which is which is roughly 6.02×1023 Moles give us a consistent method to convert between atoms/molecules (too small and too many to be counted) and grams (easily be measured). An observation is any report from your 5 senses. It does not involve an explanation. An observation can also involve measurements. Such an observation is a quantitative one, as opposed to a qualitative one (no measurements). On the other hand, an interpretation is an attempt to figure out what has been observed. 20 What is density? How do you calculate it? What is its unit? The density of a substance is the relationship between the mass of the substance and how much space it takes up (volume). Density equals the mass of the substance divided by its volume: D = m/v. The unit is g/cm3 or g/mL 21 How do you read a phase diagram and what a phase diagram can tell you? The phase diagram shows, in pressure–temperature, the lines of equilibrium or phase boundaries between the three phases of solid, liquid, and gas. Single phase regions are separated by lines where phase transitions occur, which are called phase boundaries. Triple point is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist. 22 What are the differences between chemical and physical changes? A physical change in a substance doesn't change what the substance is. In a chemical change where there is a chemical reaction, a new substance is formed and energy is either given off or absorbed. Physical changes can be reversed, but chemical changes cannot. 23 What are the signs of a chemical reaction? Change in color, change in temperature, formation of gas bubbles, and formation of a solid (precipitate) Review Practice Problems Part #2: Topics 7-12 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 What is an electron orbital? Sketch pictures of an “s” orbital and a “p” orbital. How many electrons can an orbital hold? How many electrons can a set of s orbitals hold? A set of p orbitals? A set of d orbitals? A set of f orbitals? Sketch what the orbital diagram should look like for sulfur. Write a short paragraph explaining how to fill an orbital diagram. What element is represented by the econfiguration of: 1s22s22p63s23p64s23d104p2 ? What element is represented by the electron configuration of: 1s22s22p63s23p64s1 Write the electron configuration for phosphorus s-2, p-6, d-10, f-14 S Mg fill the lowest energy level first, maximum of 2 electrons with opposite spin may be placed in each orbital, and 1 electron is added to each sub energy level before double up Germanium (Ge) Potassium (K) 1s22s22p63s23p3 Write the electron configuration for 1s22s22p63s23p64s23d104p65s14d10 silver Draw a picture of what happens during atomic absorption. Write 3 sentences describing what happens. Electrons in an atom absorb energy, get excited and jump from a ground state up to higher energy levels (excited state). Energy is released when electrons in an atom Draw a picture of what happens come back down from an excited state of higher during atomic emission. Write 3 energy level to a ground state of lower energy sentences describing what happens. level What does ground state mean? Excited A ground state atom possesses electrons in its lowest energy orbitals. Excited state means state? a valence electron absorbs energy and jumps up to a higher energy level. List the three main types of radiation, Alpha, α, 42α, 42He, a piece of paper what their symbols are (including the Beta, β, 0-1β, 0-1e, a piece of thin metal little numbers on top and bottom of Gamma, γ, 00γ, a thick layer of heavy metal like lead. the symbol), and what stops them. 18 19 Finish the following nuclear equation: 238 234 U Th + 20 Write the nuclear equation for Samarium undergoing beta emission 17 2 Sketch what the orbital diagram should look like for Mg Which type of radiation is pure energy? Which type is a high energy electron? Which type is a helium nucleus? What is the charge on the three main types of radiation & what type of charge would they be attracted to? Finish the following nuclear equation: 99 + 0-1e 43Tc → _ 16 Electronic orbitals are regions within the atom in which electrons have the highest probability of being found. Gamma is pure energy, beta is a high energy electron and alpha is a helium nucleus. Alpha, +2, attracted to negative charge Beta, -1, attracted to positive charge Gamma, 0, attracted to neither. 99 99 + +0 10e-1e 43Tc → 44Ru 4 3 238 234 4 92U → 90Th + 2α 9 2 9 0 146 146 0 62Sm → 63Eu + -1β Review Practice Problems Part #3: Topics 13-19 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 What charge do alkali metals, alkaline earth metals, halogens, oxygen group like to have? (example, alkalimany metalsvalence like to electrons have +1 charge) How does each of the following have: Na, Cs, Be, F, O, S, C, B Alkali: +1; Alkaline earth metals: +2; Halogens: -1; Oxygen group: -2 Na (1), Cs (1), Be (2), F (7), O (6), S (6), C (4), B (3) Write the symbol for a particle with 17 protons, 18 neutrons, and 18 electrons List two of each type of atom: metals, nonmetals, metalloid, and transition metals Draw a sketch of a periodic table and draw an arrow pointing from lowest ionization energy towards the highest. 35 Rank the atoms from lowest to highest ionization energy: Na, F, Fr, Ca, Fe, S Draw a sketch of a periodic table and draw an arrow pointing from lowest electronegativity towards the highest. Fr, Na, Ca, Fe, S, F Rank the following atoms from lowest to highest electronegativity: Na, F, Fr, Ca, Fe, S Draw a sketch of a periodic table and draw an arrow pointing from smallest to largest atomic radius. Fr, Na, Ca, Fe, S, F Rank the following atoms from smallest to largest atomic radius: Na, F, Fr, Ca, Fe, S Describe how to name ionic compounds vs covalent molecules Name the following: N4O10 P4S10 MgCl2 CCl4 C5I Al2O3 SrSO4 NH4Cl Ca(NO3)2 F, S, Fe, Na, Ca, Fr Write the formula for the following: Gallium Oxide, Calcium Chloride, Ammonium Chloride, Calcium Fluoride Write the formula for diphosphorus monoxide, tetrasulfur trifluoride, nitrogen tetrahydride What types of elements make up ionic bonds? Covalent bonds? How do you decide a covalent bond as polar or nonpolar? What is happening during an ionic bond? A covalent bond? Why do things bond in the first place??? 17 Identify the following as ionic, or covalent: NaF KOH CS2 NO H2 18 What is the definition of the octet rule? 19 20 What are the main exceptions to the octet rule? 21 22 23 24 25 F2 Draw Lewis Structures for CO2, N2, O2, H2, H2O, NH3 For the Lewis Structures you drew above identify which have single bonds, double bonds, triple bonds. Calculate the average atomic mass of sulfur if 95.00% of all sulfur atoms have a mass of 31.972 amu, 0.76% has a mass of 32.971amu and 4.22% have a mass of 33.967amu. How to calculate %yield and %error in the copper cycle lab? What are the 5 types of chemical reactions? Write a generic equation for each type of reactions. Explain the role of bond breaking and bond forming in a chemical reaction and overall absorption or production of heat energy (endothermic or exothermic reaction). 17Cl - List any two of each. The following are just examples. Metals: Na, Ca; Nonmetals: O, Cl; Metalloid: Si, Ge; Zn Transition metals: Cu, Ionic compounds: name cation first, then anion (finish with –ide). DO NOT use prefix Covalent molecules: use prefix except when the first element is one. N4O10-tetranitrogen pentoxide; P4S10-tetraphosphorus decasulfide; MgCl2-magnesium chloride; CCl4-carbon tetrachloride; C5I-pentacarbon monoiodide; Al2O3-aluminum oxide; SrSO4-strongtium sulfate; NH4Cl-ammonium chloride; Ca(NO3)2-calcium nitrate Gallium Oxide: Ga2O3, Calcium Chloride: CaCl2, Ammonium Chloride: NH4Cl, Calcium Fluoride: CaF2 diphosphorus monoxide: P2O , tetrasulfur trifluoride: S4F3, nitrogen tetrahydride: NH4 Metal & nonmetal make up ionic bonds. Nonmetal & nonmetal make covalent bonds. When electronegativity difference of the 2 nonmetals is very small (<0.4), the covalent bond is nonpolar; If the difference is between 0.4-1.6(roughly) it’s polar. Electrons are transferred from metal to nonmetal in an ionic bond; electrons are shared between 2 nonmetals in a covalent bond. Things bond because they have an attraction force between them. Ionic: NaF KOH Covalent: CS2 NO H2 F2 When atoms combine to form compounds they generally each lose, gain, or share valence electrons to attain an electron configuration of the nearest noble gas (8 valence electrons). Hydrogen only needs 2 valence electrons to be stable. H-H CO2 has 2 double bonds, N2 has 1 triple bond, O2 has 1 double bond, H2 has 1single bond, H2O has 2 single bonds, NH3 has 3 single bonds. Average mass = (31.972×0.95) + (32.971×0.0076) + (33.967×0.0422) = 32.06 amu %yield = recovered Cu mass/initial Cu mass × 100 %error = (initial Cu mass-recovered Cu mass)/initial Cu mass ×100 = 100-%yield Synthesis A+B→AB; Decomposition ABC→AB + C; Single replacement A+BX→AX+B; Double replacement AX+BY→AY+BX; Combustion CxHy+O2→CO2+H2O energy is absorbed to break bonds in reactants, and released when new bonds are formed in products. If overall total energy is positive, meaning energy absorbed is higher than energy released, it’s an endothermic reaction. If overall total energy is negative, meaning energy released is higher than energy absorbed, it’s an exothermic reaction.
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