Department of Natural Resources and Mines Geological Survey of Queensland Lithium opportunities in Queensland October 2015 What is lithium? Lithium (Li) is the lightest of all metals with an atomic number of 3. It is an alkali metal together with elements such as Na and K. It has a metallic lustre but only occurs in nature in compounds. The main sources of lithium are from pegmatites (spodumene, petalite, amblygonite, lepidolite and zinnwaldite), continental brines, geothermal brines, oilfield brines and the clay mineral hectorite. Is lithium considered ‘critical’? Lithium is listed as critical by Geoscience Australia because of its rapidly expanding use in battery technology. Although lithium is not rare globally, rapid expansion in the demand for lithium makes the development of new resources important to maintain supply. Photograph of lepidolite (mauve mineral) from Buchanans Creek/ Grants Gully area, Queensland. Where is lithium found? • Globally, lithium is not particularly rare. How do we use lithium? • A major application for lithium is for production of ceramics and glasses, including heat-resistant glass and ceramics such as those used in oven wear and cook tops. It is also used in fluxes and glazes. Lithium is used in alloys to increase strength-to-weight ratios, taking advantage of lithium’s strength and light weight (low-density) characteristics. Aluminium–lithium alloys, for example, are used in the aerospace and motorsport industries. • Lithium is used in the manufacture of computers, communication devices and electronics, as well as medical applications, lubricants, fuel cells and nuclear technology. • Its use in lithium-ion batteries is seen as a growth area for the coming years. • New Scientist reports that lithium-ion batteries are critical to the development of electric cars in order to make them competitive with petrol engine vehicles. They predict an increase in production of lithium carbonate (the compound used in lithium-ion batteries) from 129,000 tonnes in 2011 to 499,000 tonnes in 2025 (the Tesla electric car being developed in the US is predicted to require 40 kg of lithium). • Lithium is a light metal with abundant charge-carrying ions for its weight making it ideal for charge storage in batteries. • While new battery technologies are being developed, they are unlikely to be commercially available in the short term making lithium-ion batteries the most advanced currently available. • Low cost abundant lithium occurs in salt flats in Chile and Bolivia (together they hold ~40% of the world’s known lithium). Brines are also known from China and the USA. Extraction of lithium from brines is in the form of lithium chloride which then needs to be converted to lithium carbonate for use in batteries—an energy intensive process. • In Australia, lithium is mostly recovered from lithium minerals, specifically the mineral spodumene (Li2O.Al2O3.4SiO2), found mostly in several deposits associated with pegmatites in Western Australia. The largest is the Greenbushes deposit south of Perth. • Recent technological advances have identified a process for the low-cost extraction of lithium from the mineral lepidolite, which occurs in pegmatites. This process extracts the lithium as lithium carbonate which is used directly in Li-ion batteries. Globally, the mineral lepidolite has not been readily recorded making the resources of the mineral uncertain. Where is there potential for lithium resources in Queensland? • The mineral lepidolite has been known in Queensland for some time but its distribution has been uncertain. • Recently lepidolite has been the focus of exploration in the Georgetown region in north Queensland. • Significant quantities have been found at Buchanans Creek and the adjacent Grants Gully south of Georgetown. Exploration of this deposit is continuing and drilling to define a resource is expected later this year. • Minor lepidolite and zinnwaldite (another Li-bearing mica) has been reported from Lord Nolan and Swipers Gully tin deposits in the Stanthorpe area. POWER TO THE PEOPLE, 2015: New Scientist, 227(3031), 21–24. SKIRROW, R.G., HUSTON, D.L., MERNAGH, T.P., THORNE, J.P., DULFER, H. & SENIOR, A.B., 2013: Critical commodities for a high-tech world: Australia’s potential to supply global demand. Geoscience Australia Report. • Lithium has been reported from the Bitumen and Cobree prospects in a resedimented Tertiary sandstone in the Broken River area in northeast Queensland • Recently, lepidolite has been identified at Gingeralla west of Mount Garnet south west of Cairns. Further information GSQ hotline Email: [email protected] Telephone: +61 7 3006 4666 Further reading AUSTRALIAN MINES ATLAS: (http://www.australianminesatlas. gov.au/aimr/commodity/lithium.html). Geological Survey of Queensland Level 12, 61 Mary St Brisbane Qld 4000 JELL, P.A. (Editor) 2013: Geology of Queensland. Geological Survey of Queensland, Department of Natural Resources and Mines, Brisbane. 140° www.dnrm.qld.gov.au 145° 150° Lithium deposits in Queensland 10° 10° ( ! Lithium occurrence " Town Rail Road Permian-Triassic Granitoids Kennedy Igneous Association " Weipa Mesozoic basins Permian Triassic basins Devonian-Carboniferous basins New England Orogen Mossman Orogen 15° 15° Thomson Orogen " Cooktown Georgina Basin North Australian Craton " Cairns " Karumba 0 BUCHANAN'S CREEK 100 200 Kilometres ( ! BITUMEN COBREE ( ! ( ! " Townsville " 20° 20° No rt her n Ter rit o ry " Cloncurry " Hughenden " Mackay " Winton " Clermont " Longreach " Rockhampton " Emerald " Gladstone " Bundaberg 25° 25° Maryborough " GSQ\15B\MG\NTL\NioTanLit.mxd " Gympie " Roma " Chinchilla " Dalby Toowoomba " " " Brisbane Ipswich SWIPERS GULLY ! ( LORD NOLAN ( ! Produced by Publication Graphics SGS, Geological Survey of Queensland September 2014. © State of Queensland (Department of Natural Resources and Mines) 2014. http://creativecommons.org/licenses/by/3.0/au/deed.en 140° Produced by Spatial and Graphic Services, Geological Survey of Queensland © The State of Queensland (Department of Natural Resources and Mines) 2015 http://creativecommons.org/licenses/by/3.0/au/deed.en New S ou th Wal es 145° 150° 15B\Factsheets\critical_elements South Aust rali a " Charleville
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