T EC HNI CA L DATA SH E E T PRODUCT OVERVIEW Vecalloy 600 is a revolutionary new material specifically designed as a chromium free and heat-treatable hardfacing. It provides the best performance in aggressive environments where impact and abrasive wear are critical sources of material failure. By eliminating chromium as an alloying addition, Vecalloy 600 eliminates liability from the highly carcinogenic hexavalent chromium fumes generated when welding chromium bearing materials. In terms of wear resistance, the high density of complex borides and vanadium carbides in a martensitic matrix allow it to compete with the wear performance of WC/Ni overlays at a lower price point. The extremely fine lamellar structure of the complex borides and the spherical morphology of the vanadium carbides allow for impact performance 20X that of WC/Ni, and more than 4X compared to both chromium carbide overlays (CCO) and nanostructure forming steels. Vecalloy 600 is heat-treatable, meaning it preserves excellent performance before and after standard quench and temper heat treatments. Vecalloy 600 is patent pending. DESIGN APPROACH The design process for Vecalloy 600 and all SCOPERTA materials involves a proprietary high throughput computational metallurgical process to evaluate millions of candidate alloy compositions. Potential candidates are then experimentally evaluated using an advanced screening process where both properties and alloy microstructure are measured. The combined computational and experimental approach allows SCOPERTA to rapidly design the final material with a much better accuracy than conventional experiment-based methodologies. VECALLOY 600 PERFORMANCE ‣ ‣ ‣ ‣ ASTM G65A: 0.04 – 0.09 grams lost (5 mm3 – 11 mm3 ) (low stress abrasion) Hardness: 64.5-68 HRC Impact Resistance: >10,000 20J Impacts to Failure Hard Boride/Carbide Fraction: ~33% Vecalloy 600 at 1,000X Double-layer welding of Vecalloy 600 WIRE is NOT recommended. 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 1 of 8 T EC HNI CA L DATA SH E E T VECALLOY 600 OUTPERFORMS CONVENTIONAL HARDFACING Vecalloy 600 uniquely pairs the toughness required for high impact applications with high wear resistance to rival the best coatings available. It achieves these typically discordant properties by forming a high fraction of tough, lamellar complex borides while avoiding long needle-like particles known to cause problematic embrittlement in chromium carbide type overlays and many nanostructured steel alloys. WHY VECALLOY 600 OUTPERFORMS WC/Ni PTA & CHROMIUM CARBIDE 1. Homogeneity: WC/Ni PTA coatings involve depositing two separate materials simultaneously; a Ni matrix and tungsten carbide (WC) particles. This results in poor performance due to undesirable settling and dissolution during welding. In contrast, Vecalloy 600 is deposited as a single alloy with carbides and borides thermodynamically driven to precipitate homogeneously throughout the weld thickness. 2. Fine-Scale Microstructure: WC/Ni PTA and chromium carbide coatings contain carbide particles on the order of 50 to >250 microns in size. In contrast, the carbides and borides in Vecalloy 600 range in size from 1 to 10 microns. Computational metallurgy allows us to design these phases to grow from the liquid at a small and consistent size, shape, and distribution. This fine scale microstructure has many beneficial effects such as preventing small sand particles from attacking the matrix directly and distributing thermal stresses more evenly upon cooling. However, perhaps the most important benefit of the Vecalloy 600 microstructure is the ability to withstand impact and high stresses. Almost every application which is commonly understood to be an abrasive environment is also an environment containing high stress and significant levels of impact. Vecalloy 600 provides the best performance of any hardfacing in high impact, high abrasion applications. 3. Matrix Hardness: High stress gouging which occurs in many applications such as ground engaging tools is capable of deforming a soft matrix and essentially machining away any carbide particles. WC/Ni is very susceptible to this form of damage due to the soft Nickel matrix. Vecalloy 600, however, is engineered to form a hard martensite matrix and is much more resistant to this form of damage. For additional and more detailed technical information please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 2 of 8 T EC HNI CA L DATA SH E E T WHY VECALLOY 600 OUTPERFORMS WC/Ni PTA & CHROMIUM CARBIDE (cont’d) In the micrograph (right) of WC/Ni PTA, the WC particles are clumped together in some areas of the weld and some sections are free of WC particles. In contrast, the carbide spacing is thermodynamically driven to a very precise spacing in the Vecalloy 600 weld. (below, right) Carbide Depleted Carbide Rich Notice too, large cracks (highlighted by the Crack white arrow) running through the microstructure of the WC/Ni PTA coating. Crack Large carbides can be seen below in the WC/Ni PTA micrograph, but at 500X the hard-phases in Vecalloy 600 are very small. WC/Ni PTA at 25X WC/Ni PTA at 500X Vecalloy 600 at 500X For additional and more detailed technical information please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 3 of 8 T EC HNI CA L DATA SH E E T WHY IMPACT RESISTANCE MATTERS Many people are surprised to see that despite Vecalloy 600’s nearly equal wear resistance compared to WC/Ni PTA coatings, Vecalloy 600 significantly outlasts WC/Ni PTA in actual application. The answer lies in the revolutionary improvement in impact resistance. While WC/Ni PTA is well known as the standard for abrasion resistance under ASTM G65 testing, relatively low levels of impact can generate cracks and significant levels of material loss. When subjected to repeated 20J impacts, Vecalloy 600 lasts 4X as long as the most impact resistant chrome carbide and 30X as long as WC/ N i P TA . T h i s p a r t i c u l a r i m p a c t t e s t i s standardized to 20J of impact energy, the amount of energy developed by dropping a 2 kg rock a distance of 1m. It stands to reason that many more applications should consider the use of coating solutions with better impact resistance. As shown in the diagram below, when subjected to 30 minutes of wear (ASTM G65) Vecalloy 600 c o m p e t e s c l o s e l y w i t h W C / N i P TA a n d outperforms chrome carbide and nanostructured hardfacing. Impact and Abrasion Testing Results of Wear Resistant Coatings ASTM G65 (Volume Loss, mm3) Average Impacts Until Failure @ 20J 6 12,000 13 19 25 32 38 Vecalloy 810 OA Vecalloy 700/710 MIG, OA, SA (Mn Steel Compatible, Non-Magnetic) (Highest Impact Resistance) 10,000 Vecalloy 600 MIG, OA Vecalloy 800 PTA / Laser (Cr-Free, Heat Treat Compatible) (Mn Steel Compatible, Non-Magnetic) 8,000 Vecalloy 600 PTA / Laser Vecalloy 700 PTA / Laser (Cr-Free, Heat Treat Compatible) (Highest Impact Resistance) 6,000 Mass and Volume Scales Equivalent at Vecalloy Density Vecalloy 752 (Proven Gouging Resistance) 4,000 2,000 0 Nanostructured 60/40 Alloys WC/Ni PTA mm3 loss g loss 0.00 0.05 0.10 Chrominum Carbide Overlays 0.15 0.20 0.25 0.30 ASTM G65 (Mass Loss, grams) For additional and more detailed technical information please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 4 of 8 T EC HNI CA L DATA SH E E T VECALLOY 600 COST, PROCESS & PRODUCTIVITY ADVANTAGES Vecalloy 600 delivers WC/Ni PTA performance with the cost and productivity advantages of iron-based alloys and MIG (GMAW) welding. The material properties of Vecalloy 600 allow for unique advantages in cost and productivity that expand the use of extremely abrasion resistant materials into wider markets. Vecalloy 600 is an iron-based alloy resulting in significant material cost savings compared to WC/Ni products. Further, MIG welded Vecalloy 600 has a ~99% deposit efficiency while WC/Ni PTA has a 70% deposit efficiency. This means that 1.4 kg of WC/Ni must be purchased for every 1 kg deposited. Vecalloy 600, because it is iron-based, has a lower density than WC/Ni, this results in further cost savings. Consider the manufacture of a 12” x 12” (300mm x 300mm) wear plate with a ¼” (6mm) overlay. The production of this plate would require half the amount of material by weight when using Vecalloy 600 PTA as opposed to WC/Ni PTA. This immediately results in significant cost savings, in addition to significantly reducing the final weight of the component. In addition to direct material cost, Vecalloy 600 has excellent performance when applied via a wire welding process. This allows a far higher deposition rate than WC/Ni PTA, dramatically improving productivity. For example, WC/Ni PTA is typically deposited at a rate of 11 in3/hr (180 cm3/hr). Vecalloy 600 is typically deposited at a rate of 40 in3/hr (655 cm3/hr), almost 4 times as fast! For additional and more detailed technical information please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 5 of 8 T EC HNI CA L DATA SH E E T SUGGESTED APPLICATIONS Vecalloy 600 coatings are suggested for use in any applications where abrasion resistance is required. The revolutionary improvement in impact resistance and toughness will typically result in an extended lifetime over WC PTA and Chromium Carbide coatings. Specific applications include: ‣ ‣ ‣ ‣ ‣ Shaker Screens Grader Blades and other Ground Engaging Tools Chute Blocks Wear Plate Mill Liners ‣ ‣ ‣ ‣ Slurry Pipe Shovel Wear Packages Communition Other Mining Applications HOW TO USE VECALLOY 600 Vecalloy 600 is currently available as cored wire in 0.045” (1.1 mm), and 0.063” (1.6 mm) for GMAW and in 0.109” (2.8 mm) for open arc welding. Additional welding wire diameters, PTA powder, and laser powder are available upon request. The suggested welding parameters and expected results for Vecalloy 600 are provided on this page and the following page. Please note: for cored wire applications, Vecalloy 600 can be deposited as stringer beads or oscillated beads. However, it is recommended that Vecalloy 600 cored wire only be welded as a single layer deposit. Multiple layer deposits can reduce the impact resistance of the overlay. Preheating Guidelines, Interpass Temperature, and Post Weld Heat Treatment: Preheat temperatures should be done in accordance to the substrate requirements to minimize the heat affected zone. Allow the part to cool below 500°F before welding Vecalloy 600. Vecalloy 600 can be austenitized (850° – 950°C) and water or oil quenched without significant decrease in properties. Vecalloy 600 can also be tempered up to 150°C after quenching. Vecalloy 600 0.045-inch & 0.063-inch GMAW WELDING PARAMETERS Wire Diameter Current Desired Weld Thickness Voltage Amperage Shielding Gas 0.045 in (1.1 mm) DCEP 3 - 6 mm 25 - 27 V ~155A 0.063 in (1.6 mm) DCEP 3 - 8 mm 25.5 - 27 V ~225A Ar 98%/O2 2% Ar 98%/O2 2% Stickout Preheat Interpass Temperature .075 in (19 mm) *see Preheating Guidelines pg. 6 1.125 in (28 mm) *see Preheating Guidelines pg. 6 ≤300°F Torch Drag Angle 5 - 15° Expected Hardness 65 - 68 HRc Expected ASTM G65 mass loss 0.07 - 0.09 g ≤300°F 5 - 15° 65 - 68 HRc 0.07 - 0.09 g Acceptable Dilution 5 - 15% 15 - 20% For application specific guidance on proper welding procedures please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 6 of 8 T EC HNI CA L DATA SH E E T HOW TO USE VECALLOY 600 (cont’d) Vecalloy 600 7/64-inch OPEN ARC WELDING PARAMETERS Wire Diameter 0.109 in (2.8 mm) Current DCEP Desired Weld Thickness 6 - 10 mm Voltage 25 - 26.5 V Amperage ~430 Shielding Gas N/A Stickout 1.5 in (38 mm) Preheat *see Preheating Guidelines pg. 6 Torch Drag Angle 5 - 15° Expected Hardness 64.5 - 68 HRc Expected ASTM G65 mass loss 0.065 - 0.09 g Acceptable Dilution 15 - 40% Vecalloy 600 LASER WELDING PARAMETERS These parameters were developed using a Coherent 4000L & Coherent 8000L. Please note that optimum parameters can be very different with differing laser equipment, and these parameters can only serve as a starting point. Laser welds can be deposited with multiple layers to achieve the desired total thickness. A 24mm wide beam size can be used to deposit a 5-6mm thick single-pass weld. Beam Size 6x6 mm 24x6mm Shielding Gas Argon Argon Power 4kW 7.5kW Powder Feed 35 g / min 80 g / min Expected Hardness ~68 - 70 HRC ~68 - 70 HRC For application specific guidance on proper welding procedures or more detailed technical information please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 7 of 8 T EC HNI CA L DATA SH E E T HOW TO USE VECALLOY 600 (cont’d) Vecalloy 600 PLASMA TRANSFER ARC (PTA) WELDING PARAMETERS Please note that parameters can be very different with differing PTA equipment, and these parameters can only serve as a starting point. PTA welds can be welded with up to (2) layers to achieve the desired total thickness. Powder Size 53-150µm Voltage 28 V Amperage 180 A Expected Thickness ~3 mm Expected Hardness ~66 - 68 HRC Expected ASTM G65A 0.048 - 0.6 grams lost For application specific guidance on proper welding procedures or more detailed technical information please contact: SCOPERTA at [email protected] 11760 Sorrento Valley Road, Suite D, San Diego CA 92121 USA Phone (858) 704-4013 Fax (858) 704-4014 Justin Cheney, PH. D [email protected] 8 of 8
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