CHEMISTRY 30 – Course Outline A. Prerequisite: A minimum pre-requisite mark of 50% is required. But in order to experience success in Chemistry 30, a recommended mark of 60% in Chemistry 20 is advised. B. Textbook: Nelson Chemistry Replacement cost is $126.00 C. Course Outline: Review from Chemistry 20 will be done as required. Unit 7: Electrochemistry (approximately 25 periods) Chapter 13: Redox Reactions Chapter 14: Electrochemical Cells Unit 8: Chemical Equilibrium – Focusing on Acid-Base Systems (approximately 25 periods) Chapter 15: Equilibrium Systems Chapter 16: Equilibrium in Acid-Base Systems Unit 6: Chemical Energy (approximately 15 periods) Chapter 11: Enthalpy Change Chapter 12: Catalysis Unit 5: Organic Chemistry (approximately 15 periods) Chapter 9: Hydrocarbons from Petroleum Chapter 10: Organic Reactions 1 D. Mark Breakdown Unit 7 (Chapters 13 and 14) Electrochemistry 31 % Chapter 13 Exam Chapter 14 Exam Unit 8 (Chapters 15 and 16) Acid-base Equilibrium 31 % Chapter 15 Exam Chapter 16 Exam Unit 6 (Chapters 11 and 12) Chemical Energy 19 % Unit Exam Unit 5 (Chapters 9 and 10) Organic Chemistry 19 % Unit Exam The final Chemistry 30 mark is a blended mark of the teacher based mark and the diploma exam mark. The final mark in Chemistry 30 must be 50% or over to receive credits. A mark of 70% or better is suggested for Post-Secondary. Chemistry 30 Diploma: Monday, June 24, 2013 9:00 a.m. – 11:00 a.m. (Multiple Choice / Numerical Response ONLY) Students are permitted an additional ½ hour to complete their examination. Chemistry 30 Diploma Exam 44 multiple choice questions 16 numerical response questions You have 2.0 hours (120 minutes) – 2.5 hours (150 minutes) to do 60 questions 120 minutes / 60 questions = 2 minutes per question 80 minutes / 2.0 minutes/question = 40 questions 150 minutes / 60 questions = 2 ½ minutes per question 80 minutes / 2.5 minutes/question = 32 questions 29 multiple choice 23 multiple choice 11 numerical response 9 numerical response 2 TENTATIVE COURSE OUTLINE BY CHAPTER Unit 7 - Electrochemisty Chapter 13 – Redox Reactions 13.1 Oxidation and Reduction (page 558) Reduction / Oxidation Half-reactions Oxidized species / Reduced species Oxidizing agent / Reducing agent Redox equations Lab / Demo: Single Replacement Reactions between metals and aqueous solutions Writing Complex Half-Reaction Equations 13.2 Predicting Redox Reactions (page 568) Introduction to Reduction Half-reaction table Spontaneity Rule (spontaneous /non-spontaneous reactions) Predicting Redox reactions using the data book Constructing Redox Tables - making a redox table from lab results or using the spontaneity rules Predicting Redox Reactions by Constructing Half-Reactions 13.3 Oxidation States (page 583) Rules for determining the oxidation number(state) of atoms Making up ½ reactions in acidic or basic solutions Balancing using oxidation numbers 13.4 Redox Stoichiometry (page 596) Redox Titration Lab / Demo Redox Titration Stoichiometry Questions Chapter 13 Exam 3 Unit 7 - Electrochemisty Chapter 14 – Electrochemical Cells – Voltaic and Electrolytic Cells 14.1 Technology of Cells and Batteries (page 612) 14.2 Voltaic Cells (page 622) Voltaic Cell Demo Voltaic Cells Standard ½ cell Eo (V) values – calculating 14.3 Electrolysis / Electrolytic Cells (page 639) Electrolytic cells - Demo Electrolytic cells Electroplating – Demo 14.4 Cell Stoichiometry (page 652) Corrosion Prevention Cathodic protection Sacrificial anode STS Connections with regard to cells Chapter 14 Exam 4 Unit 8 – Chemical Equilibrium Focusing on Acid-Base Systems Chapter 15- Equilibrium Systems 15.1 Explaining Equilibrium Systems (page 676) What is Equilibrium? Equilibrium Law Expression based upon balanced equations Equilibrium constant, (K / Kc), value calculations Equilibrium concentrations of reactants or products ICE Tables 15.2 Qualitative Change in Equilibrium Systems (page 690) Manipulating Equilibrium systems Le Chatelier’s Principle: changes in concentration, temperature, volume, catalyst, and inhibitors Chapter 15 Exam 5 Unit 8 – Chemical Equilibrium Focusing on Acid-Base Systems Chapter 16 – Equilibrium in Acid-Base Systems Arrhenius Definition of Acids and Bases Revised (Modified) Arrhenius Definition of Acids and Base 16.1 Water Ionization and Acid-Base Strength (page 712) Water Equilibrium Systems Calculations of [H3O1+(aq)] and [OH1-(aq)] Calculations of pH, and pOH Strong Acids vs. Weak Acids % reaction of acids 16.2 Bronsted-Lowry Theory of Acid-Base Concept (page 722) Predicting Bronsted-Lowry Acid/Base Reactions (using the data book) Building Acid-Base Tables 16.3 Acid-Base Strength and the Equilibrium Law (page 737) Acid Ionization Constant, Ka, for weak acids Approximate rule for determining [H3O1+(aq)] Base Strength and the Ionization Constant, Kb Approximate rule for determining [OH1-(aq)] 16.4 Interpreting pH Curves (page 751) Buffering regions Endpoints / equivalence point Acid-base indicators Polyprotic species / polybasic entities Buffer solutions Chapter 16 Exam 6 Unit 6 – Chemical Energy Chapter 11 – Enthalpy Change 11.1 Energy Demands and Sources (page 480) 11.2 Calorimetry (page 486) Q = m c t = rH Heat Transfer and Enthalpy Change Molar Enthalpies and Calorimetry rH = n rHm Law of Heat Exchange (total enthalpy lost = total enthalpy gained) 11.3 Communicating Enthalpy Changes (page 495) Method 1: Molar Enthalpies of Reaction, rHm Method 2: Enthalpy Changes, rH Method 3: Energy Terms in Balanced Equations (thermochemical equations) Method 4: Chemical Potential Energy Diagrams 11.4 Hess’s Law (page 502) Predicting rH: Hess’s Law 11.5 Molar Enthalpies of Formation (page 510) Molar Enthalpies of Formation Molar Enthalpies of Decomposition Molar Enthalpies of Combustion Unit 6 – Chemical Energy Chapter 12 – Explaining Chemical Changes 12.1 Activation Energy (page 524) 12.2 Bond Energy and Reactions (page 532) 12.3 Catalysts and Reaction Rates (page 535) Chapter 11 / 12 Exam 7 Unit 5 – Organic Chemistry Chapter 9 – Hydrocarbons from Petroleum 9.1 Fossil Fuels (page 358) 9.2 Alkanes from Natural Gas (page 362) Straight Chain Hydrocarbons alkanes alkenes alkynes 9.3 Alkenes and Alkynes – Cracking Natural Gas Branched Hydrocarbons alkanes alkenes alkynes Cyclic Hydrocarbons cycloalkanes cycloalkenes cycloalkynes 9.4 Aromatics (page 381) benzene 9.5 Crude Oil Refining (page 386) Reactions of Hydrocarbons 9.6 Complete and Incomplete Combustion Reactions (page 398) 8 Unit 5 – Organic Chemistry Chapter 10 - Hydrocarbon Derivatives, Organic Reactions, and Petrochemicals 10.1 Petrochemicals in Alberta (page 412) 10.2 Organic Halides and Addition and Substitution Reactions (page 417) 10.3 Alcohols and Elimination Reactions (page 425) 10.4 Carboxylic Acids, Esters, and Esterification Reactions (page 436) 10.5 Polymerization Reactions – Monomers and Polymers (page 445) Chapter 9 / 10 Exam 9
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