Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
44400 - Malachite
Revised edition: 24.11.2008
printed: 25.11.2008
1. Identification of the Substance/Preparation and of the Company/Undertaking
Identification of the Product
Product Name:
Article No.:
Use of the Substance/Preparation:
Malachite
44400
Artists´ and Restoration Material
Company
Company:
Address:
Tel/Fax:
Internet:
Emergency No.:
Kremer Pigmente GmbH & Co. KG
Hauptstrasse 41-47, D 88317 Aichstetten
Tel +49 7565 914480, Fax +49 7565 1606
www.kremer-pigmente.de, [email protected]
+49 7565 914480, Mon-Fri 8:00 - 17:00
2. Hazard Identification
Hazard designation:
Risk Phrases:
Xn Harmful
R22 Harmful if swallowed.
3. Composition/Information on Ingredients
Chemical Characterization:
Hazardous Ingredients:
CuCO3*Cu(OH)2 (basic copper carbonate with approx. 55 % Cu)
Copper(II)-hydroxide carbonate (Xn; R22)
CAS-Nr: 12069-69-1 EINECS-Nr: 235-113-6 EC-Nr:
4. First Aid Measures
After inhalation:
After skin contact:
After eye contact:
After ingestion:
Move to fresh air.
Remove contaminated clothing.
Wash with soap and rinse with plenty of water.
Rinse open eyes with plenty of water. In case of discomfort seek
medical help.
Get medical help.
5. Fire-Fighting Measures
Suitable extinguishing media:
Special hazards:
Product itself does not burn.
Use extinguishing media for surrounding fire.
In case of fire: formation of carbon monoxide and dioxide.
6. Accidental Release Measures
Personal precautions:
Environmental precautions:
Methods of cleaning/absorption:
Avoid dust formation, wear protective clothing.
Prevent contamination of soil, drains and surface waters.
Clean up mechanically. Transfer liquids and solid diking material to
separate suitable containers for recovery or disposal.
7. Handling and Storage
Handling
Page
1
of
3
Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
44400 - Malachite
Revised edition: 24.11.2008
Instructions on safe handling:
Information on fire and explosion
protection:
Storage
Storage conditions:
Storage compatibility:
Storage class (VCI):
printed: 25.11.2008
The usual precautionary measures are to be adhered to when
handling chemicals.
Product is not ignitable.
Store in tightly sealed containers in a dry room.
Do not store above 30°C.
Do not store together with: acids.
13; Non combustible solids.
8. Exposure Controls/Personal Protection
Additional information about
design of technical systems:
Personal protective equipment
General protective measures:
Respiratory protection:
Hand protection::
Eye protection:
Body protection:
Adequate ventilation.
Keep away from food, drink and animal feeding stuffs.
Wash hands before breaks and after work.
Dust mask.
Chemical protective gloves (EN 374).
Safety glasses
Protective clothing.
9. Physical and Chemical Properties
Form:
Color:
Odor:
Flash point:
Ignition temperature:
Explosion risk:
Density:
Solubility in water:
powder
green
odorless
not applicable
not applicable
not applicable
4.0 g/cm3 (20°C)
practically insoluble
10. Stability and Reactivity
Thermal
decomposition/Conditions to be
avoided:
Products to be avoided:
Hazardous decomposition
products:
> 200°C
Acids
Carbon monoxide and dioxide.
11. Toxicological Information
Acute toxicity
LD50, oral:
1350 mg/kg (rat)
12. Ecological Information
Page
2
of
3
Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
44400 - Malachite
Revised edition: 24.11.2008
printed: 25.11.2008
Elimination (Persistency and
Degradability):
Inorganic product, not very soluble in water.
Further ecological effects:
The product contains copper as copper(II)-hydroxide carbonate (List
II).
Further information
Water hazard class:
2
13. Disposal Considerations
Product:
Dispose of according to official national and local regulations.
Uncleaned packaging:
Dispose of according to official local regulations.
14. Transport Information
Further information:
Not classified as a dangerous good under transport regulations.
15. Regulatory Information
Designation according to EC
guidelines:
Hazard designation:
The material is subject to classification according to EC lists.
Risk Phrases:
R22 Harmful if swallowed.
Water hazard class:
2, hazardous for water
Xn Harmful
16. Other Information
This product should be stored, handled and used in accordance with good hygiene practices and in
conformity with any legal regulations.
This information contained herein is based on the present state of knowledge and is intended to describe
our product from the point of view of safety requirements. It should be therefore not be construed as
guaranteeing specific properties.
Page
3
of
3