CHEMISTRY WKST SIGNIFICANT DIGITS / METRIC SYSTEM REVIEW NAME: __________JMS_________________________ 1) Tell how many significant digits are in each of the following quantities. a) 3200 g 2 f) b) 106 mL 3 c) 12.006 g 5 4 k) 3.240 g g) 0.450 ns 3 l) h) 0.0610 L 3 m) 312.000 s 6 d) 10.204 mL 5 i) 0.00308 g 3 n) 0.1006 cm 4 e) 47000 m j) 70000 km 1 o) 5.0040 mL 5 2 227.0 g 2.00 x 108 m 4 3 2) The following data readings were taken from a balance reading in hundredths of a gram, a meter stick reading in thousandths of a meter and a graduated cylinder in tenths of a milliliter. However, some of the readings are wrong in the way they were recorded. It is your task to look at each reading and decide what the reading should have been and correct it and then tell how many significant digits are in the new reading. If the reading is correct, write “OK” in the first blank, but still tell how many significant digits are in the measurement. a) 12.6731 g 12.67 g 4 e) 0.0741 m 0.074 m 2 i) 50 mL 50.0 mL 3 b) 42.006 m OK 5 f) 3.399 mL 3.4 mL 2 j) 18.00 g OK 4 c) 7.423 mL 7.4 mL 2 g) 0.00274 g 0.00 g 1 k) 78421.0062 g 78421.01 g 7 d) 127 mL 127.0 mL 4 h) 200 m 200.000 m 6 l) 0.22 mL 1 0.2 mL 3) In chemistry, rounding numbers correctly is a must. If the digit to the right of the one to be rounded is higher than 5, round up. If it is less than 5, round down. If it is 5 and there are numbers after it, round up. If it is exactly 5 with no numbers after it, round to the nearest even number—if this is not done, then when taking large numbers of readings that are always rounded up, the mean (average) data is higher than is accurate. Round the following numbers to 3 significant digits. a) 5.344 x 107 5.34 x 107 d) 7.278278 7.28 g) 5,555,555 5,560,000 b) 6.6888 x 10−4 6.69 x 10−4 e) 4.997997 5.00 h) 6.9851 6.99 c) 6.675 f) 3.88 i) 0.00833 6.68 3.885 0.0083294 4) Write the following decimal numbers in scientific notation. Keep the same number of significant digits as already in the number. a) 4490000 4.49 x 106 b) 0.0002200 2.200 x 10−4 c) 3000000 3 x 106 5) Write the following scientific notation numbers in decimal form. Keep the same number of significant digits as already in the number. a) 3.2 x 10−5 0.000032 b) 9.254 x 10−3 0.009254 c) 2.95 x 106 2950000 6) What are the 5 fundamental measurements, and their base unit, that you are responsible for? MEASUREMENT BASE UNIT length meter mass kilogram time second temperature Kelvin amount of substance mole -27) Indicate what metric prefix is used for the following powers of 10. d) 103 kilo g) 10−6 micro b) 10−3 milli e) 109 giga h) 10−2 centi c) 10−9 nano f) a) 106 mega 10−1 deci i) 10−12 pico 8) Give the abbreviation for the following metric units. a) kilometer km d) milligram mg g) megaliter ML b) gigasecond Gs e) decimeter dm h) nanosecond ns c) micrometer μm f) cg i) pm centigram picometer 9) Compute the following addition and subtraction calculations. Round off answers to the correct number of significant digits and label the answer with the correct unit. a) 5.432 cm 2.52 cm + 1.6 cm 9.552 cm 9.6 cm b) d) 5000 cm + 0.123 cm + 2.1 cm = 5002.223 cm 5000 cm 7.136 mL 0.02 mL + 0.0032 mL 7.1592 mL 7.16 mL e) 125.7 g ─ 32.62 g = 93.08 g c) 47.892 m ─ 4.2 m 43.692 m 43.7 m f) 6000. mL ─ 0.2 mL = 5999.8 mL 93.1 g 6000. mL 10) Compute the following multiplication and division calculations. Round off answers to the correct number of significant digits and label the answer with the correct unit. a) (0.063 cm)(0.063 cm) = 0.003969 cm2 = 0.0040 cm2 b) (32.31 m)(0.043 m) = 1.38933 m2 = 1.4 m2 c) (270 cm)(3.04 cm) = 820.8 cm2 = 820 cm2 d) (121 m)(0.32 m)(2 m) = 77.44 m3 = 80 m3 e) g) 54.2 g 61.21 mL 200. cm 20 s g g = 0.885476229 mL = 0.885 mL = 10 cm s f) h) 7.85 g 200.4 mL g g = 0.039171656 mL = 0.0392 mL (32.0 m)(14 kg) 0.005689 h = 78748.46194 m∙kg = 79000 m∙kg h h 11) Compute the following and give the answer in the correct number of significant digits and unit label. a) 321.0 cm + 40 cm 25.00 s = 360 cm 25.00 s = 14.4 cm = 14 cm s s b) (35.0 g)(261.00 g + 0.255 g) (150 mL + 37.5 mL) = 48.12684211 g2 mL g2 = 48 mL = (35.0 g)(261.26 g) 190 mL -312) Perform the given metric conversions. Keep the number of significant digits the same for the answer as the original quantity. a) 150 g = 0.15 kg i) 0.003450 L = 3.450 mL b) 422.5 mL = 0.4225 L j) 4.256 x 10−4 dg = 4.256 x 10−3 cg or 0.004256 cg c) 0.0035 km = 3.5 m k) 350,000,000 m = 0.35 Gm d) 6.25 x 105 μg = 0.625 g or 6.25 x 10−1 g l) e) 2.50 m = 250. cm m) 180 ps = 0.18 ns f) 32.10 ns = 0.03210 μs 15 mmol = 0.015 mol n) 4205000 cm = 42.05 km g) 0.0150 Mm = 15.0 km o) 86.000 dg = 8.6000 g h) 55.35 cg = 553.5 mg p) 0.54202 ks = 542020000 μs 13) Perform the following calculations using the rules for significant digits. 20̅ 0 b) + 185.41 ̅̅̅̅̅̅̅̅̅̅̅̅̅̅ 385.41 390 4000 40̅ 00 d) - 40.4 ̅̅̅̅̅̅̅̅̅̅̅̅ 3959.6 40̅ 00 = 4.0 x 103 3960. f) 16.748 4.2 a) + 3.06 ̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅ 24.008 24.0 c) 4000 - 40.4 ̅̅̅̅̅̅̅̅̅̅̅̅ 3959.6 e) 4000̅ - 40.4 ̅̅̅̅̅̅̅̅̅̅̅̅ 3959.6 g) (4100)(40.4) = 165640 = 170000 i) 45.0 90.0 = 0.5 = 0.500 4000.0 - 40.4 ̅̅̅̅̅̅̅̅̅̅̅̅̅ 3959.6 3959.6 h) (4100.0)(40.4) = 165640 = 166000 j) (20.20)(0.004)(150) 3030 = 0.004 14) Perform the following calculations and give your answers in scientific notation using significant digits. a) (4.52 x 109) + (6.23 x 1010) = 6.682 x 1010 b) (8.3 x 108) – (7.34 x 107) = 7.566 x 108 = 7.6 x 108 = 6.68 x 1010 c) (5.320 x 106)(4.23 x 10−3) = 2.25036 x 104 = 2.25 x 104 d) (9.090 x 108) ÷ (4.1 x 10−10) = 2.21707317 x 1018 = 2.2 x 1018 15) Calculate the density of an object having a mass of 32.56 g and a volume of 12.4 cm 3. 𝑑𝑒𝑛𝑠𝑖𝑡𝑦 = 𝑚𝑎𝑠𝑠 32.56 𝑔 𝑔 𝒈 = = 2.625806452𝑐𝑚3 = 𝟐. 𝟔𝟑 𝟑 𝒄𝒎 𝑣𝑜𝑙𝑢𝑚𝑒 12.4 𝑐𝑚3 16) What property of water and hexane was utilized in the bromide/iodide lab? Solubility. 17) What color was the hexane layer if the following ion was present in the original solution? a) iodide pink (purple) b) bromide gold (orange) c) chloride clear d) iodide and bromide pink (purple) 18) What are the 3 steps of the chloride test? Tell what happens for each step is chloride is present. -add AgNO3 → precipitate forms -add NH4OH → precipitate clears -add HNO3 → precipitate forms 19) What is the precipitate in the chloride test when AgNO3 is added to a solution containing chloride? silver chloride (AgCl) 20) What ion gives off a gas when acid was added in the chloride test? carbonate ion (CO32−)
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