Available online at http://www.urpjournals.com International Journal of Inorganic and Bioinorganic Chemistry Universal Research Publications. All rights reserved ISSN 2249-8540 Original Article A COMPARATIVE ANALYSIS OF FUNCTIONAL ELEMENTS IN TOOTH POWDER, GEL AND PASTE 1 DR.D.GOPALA KRISHNA*, 2 MARYAM MOHAMED ALRASHDI, &3 EMAN ALI ALGHAFIR Department of Applied Sciences, Section-Chemistry, Higher College of Technology, Muscat-Post box no 74, PIN-133, Sultanate of Oman [email protected] Received 25 June 2015; accepted 08 July 2015 Abstract Commercial toothpastes, Powder and Gel, randomly sampled from the open market were analyzed for fluoride, phosphate, Nitrate, calcium, sodium, potassium, magnesium, moisture content, Alkalinity, Ash, Benzoic Acid and pH. Moisture content was 20-39%, with 85% of the samples having water levels > 29 wt %. The pH of the toothpastes ranged from 4-8, with 60% of them having a neutral pH. The levels of constituents depend on the method of solubilization of toothpaste, with concentrated nitric acid digestion giving the best results. The health implications for tooth care and of assimilation of the elements during the mouth cleansing process, especially when present at unacceptable levels, was discussed. © 2015 Universal Research Publications. All rights reserved Key words: Fluoride, Phosphate, Mouth Cleaning, Toothpaste. Introduction: Toothpaste is a preparation for cleaning and polishing the surfaces of teeth. Dentifrices Dental decay, a common human (toothpastes & toothpowders) usually contain mild disorder affecting more than 95 per cent population of abrasives for polishing, binding agents, sudsier, is caused by the formation of acid by (foaming agents), flavourings and humectants to certain mouth bacteria. It is directly related to the prevent hardening on exposure to air. Some eating of sweet or starchy foods. Foods articles that toothpastes, especially for children, contain remain in the mouth are acted on by bacteria to fluorides to prevent dental decay. Ingredients of Toothpaste Water: Toothpaste contain between 20–42 % water to help keep it from drying out. Abrasives: Abrasives constitute at least 50% of typical toothpaste. These insoluble particles help remove plaque from the teeth. The removal of plaque and calculus helps minimize cavities and periodontal disease. Fluorides: Fluoride in various forms is the most popular active ingredient in toothpaste to prevent cavities. The fluoride in toothpaste has beneficial effects on the formation of dental enamel and bones. Sodium fluoride (NaF) is the most often type of fluoride used in toothpaste. Stannous fluoride (SnF2). This type may stain the tooth surface yellow. Mono fluoro phosphate (Na2PO3F). 65 Surfactants: Typically sodium lauryl sulfate (SLS) is used as the surfactant. This is a detergent that also acts as the foaming agent in the toothpaste. It is a harsh ingredient and it's better to find and use SLS free toothpaste. Antibacterial agents: Triclosan is one of the antibacterial medications used in toothpaste. Long-term use of any antibacterial ingredient may cause more problems than benefits by promoting antibiotic resistant bacteria. Flavorants: Toothpaste comes in a variety of colors, and flavors intended to encourage use of the product. Three most common flavorants are peppermint, spearmint, and wintergreen. Toothpaste flavored with peppermint-anise oil is popular in the Mediterranean region. These flavors are provided by the respective oils, e.g. peppermint oil Remineralization: some toothpaste is formulated to help strengthen enamel (outer surface of the tooth). Calcium phosphate is typically the ingredient used. Preservatives: to help prevent microorganisms from growing in toothpaste, certain preservatives are added. These may include sodium benzoate, methyl paraben, and ethyl paraben. Between the three common preservatives, sodium benzoate is the safest. Some “natural” toothpaste use citric acid. Sweeteners: to improve the taste of toothpaste, the best form is xylitol, since it does have many benefits for a healthy mouth, as stated earlier. International Journal of Inorganic and Bioinorganic Chemistry 2015; 5(3): 65-66 Coloring agents: Titanium dioxide may also be used to make toothpaste white. It’s best to avoid toothpaste with artificial dyes and coloring. Table 1: Results of Inorganic constituents Tooth Parameter Gel powder pH 6.72 9.62 Paste 6.63 EC (µs/cm) 210.5 72.9 52.95 Ash (%) Alkalinity (ppm) K (ppm) Benzoic Acid (ppm) Phosphate (ppm) Nitrate (ppm) Na (ppm) Ca (ppm) Fluoride (mg/g) Magnesium (mg/g) 9.96 14.25 3.47 7.415 3.81 15.01 8.36 10.6 1.0 1.2 14.6 14.87 6.79 6.245 3.28 8.99 6.047 17.91 1.55 2.3 5.85 12.05 9.23 5.026 2.06 5.26 7.37 11.90 2.03 2.50 Fig.1: Physico-Chemical parameters Conclusion 1. The investigated toothpastes help to increase the level of oral hygiene significantly, in case of regular use. 2. Due to its ability to inhibit growth of dental plaque, the dentifrice ROCS allows to achieve good hygiene level in a week. 3. As a result of this study, the dentifrice ROCS with calcium, phosphorus, magnesium, and without fluoride, can increase caries-resistance at least such effectively. 4. The toothpaste ROCS can significantly increase the rate of remineralization after acidic exposure. Acknowledgements: Authors thank to Higher College of Technology, Muscat, and Ministry of man power Sultanate of Oman, for providing research facilities to the research scholar. References 1. Kunin A.A.,( 2005) Individual'naja profilaktika kariesa u vzroslyh. Voronezh –; 178. 2. Fedorov Ju.A.,( 2001) Sto sem' voprosov k stomatologu. SPb: «Nevskij prospekt» –; 128. 3. Borovskij E.V.,(2001) Leont'ev V.K.; Biologija polosti rta. N.Novgorod: Izdatel'stvo NGMA. 4. Budavari S, O’Neil (1989) M J, Smith A & Heckelman F, The for incorporating fluoride, phosphates and other Merck Index, 11th edn (Merck and Co. Inc., New Jersey) additives. Presence of sodium (12-38 mg/g) in 70 per, 1602-1603. 5. Grolier, (1995) The Encyclopedia AmericanaInternational Edition cent samples is within 15-20 mg/g (Fig. 3). Potassium (Grolier incorporated, Connecticut, USA), 14, 547; 20, is present at 0.01-0.99 mg/g (Fig. 4), while 567, 573; 21, 113-114, 23: 516; 26, 382, 846, 1995. 6. Safra J E, Constantine S Y & Goulka J E, (1998) The New potassium are reported as associated elements because Encyclopedia Britannica, 15th edn (Britannica, London), 2, 356; 7, 678; 10, 931; 14, 547; 17, 293, 259; 20, 513; their role in body metabolism tends to complement Source of support: Nil; Conflict of interest: None declared 66 International Journal of Inorganic and Bioinorganic Chemistry 2015; 5(3): 65-66
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