KS2 SCIENCE Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Particle Theory and Chemical Reactions Scheme of Work Chemical Reactions Lesson Particle Theory and Chemical Reactions. Key Stage and Year Group KS2 A Brief Aside Unfortunately, for many people, their experience of high school chemistry is that it was not as fun as it should have been. In fact, it may even have left them deeply cynical of the whole subject! We hope that through this scheme, we manage to reignite a real ‘flame (safely of course!) of enthusiasm’. The following anecdote is from a real chemist and should provide a flavour of the kind of zeal for the science we hope to induce: A Historical Sidelight: Ira Remsen on Copper and Nitric Acid Ira Remsen (1846-1927) founded the chemistry department at Johns Hopkins University, and founded one of the first centers for chemical research in the United States; saccharin was discovered in his research lab in 1879. Like many chemists, he had a vivid “learning experience,” which led to a heightened interest in laboratory work: While reading a textbook of chemistry I came upon the statement, “nitric acid acts upon copper.” I was getting tired of reading such absurd stuff and I was determined to see what this meant. Copper was more or less familiar to me, for copper cents were then in use. I had seen a bottle marked nitric acid on a table in the doctor’s office where I was then “doing time.” I did not know its peculiarities, but the spirit of adventure was upon me. Having nitric acid and copper, I had only to learn what the words “act upon” meant. The statement “nitric acid acts upon copper” would be something more than mere words. All was still. In the interest of knowledge I was even willing to sacrifice one of the few copper cents then in my possession. I put one of them on the table, opened the bottle marked nitric acid, poured some of the liquid on the copper and prepared to make an observation. But what was this wonderful thing which I beheld? The cent was already changed and it was no small change either. A green-blue liquid foamed and fumed over the cent and over the table. The air in the neighborhood of the performance became colored dark red. A great colored cloud arose. This was disagreeable and suffocating. How should I stop this? I tried to get rid of the objectionable mess by picking it up and throwing it out of the window. I learned another fact. Nitric acid not only acts upon copper, but it acts upon fingers. The pain led to another unpremeditated experiment. I drew my fingers across my trousers and another fact was discovered. Nitric acid acts upon trousers. Taking everything into consideration, that was the most impressive experiment and relatively probably the most costly experiment I have ever performed. . . . It was a revelation to me. It resulted in a desire on my part to learn more about that remarkable kind of action. Plainly, the only way to learn about it was to see its results, to experiment, to work in a laboratory. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 2 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Introduction From ancient Greece to the present day, mankind has puzzled over the nature of matter and why materials behave the way they do. Particle theory states that all matter consists of many, very small particles which are in a continual state of motion. This is why it is also referred to as kinetic theory. The degree to which the particles move is determined by the amount of energy they have and their relationship to other particles. We have the ability to change the energy of such particles by subjecting them to various processes. Particles might be atoms, molecules or ions (simply atoms with more or less electrons). In an element, the particles will be atoms of that element. In a pure compound, the particles will be molecules or ions of that compound. Solutions and some compounds contain ions. Of course, some substances might contain mixtures of all three! Use of the general term ‘particle’ means the precise nature of the particles does not have to be specified. Particle theory helps to explain properties and behaviour of materials by providing a model which enables us to visualise what is happening on a very small scale inside those materials. As a model it is useful because it appears to explain many phenomena. For example, metals expand when they are heated because the particles vibrate to a greater degree when energy is introduced to the system. On cooling, the vibrations decrease and the metal returns to its original size. Like all models however, it does have its limitations. The scheme of work is split into 2 parts: Particle Theory itself, and an introduction to simple chemical reactions. See below for further details. The Scheme has been designed to conform to and in some instances, go beyond the requirements of the National Curriculum. Useful links are as follows: New National Curriculum Link: https://www.gov.uk/government/publications/national-curriculum-in-england-science-programmes-of-study/nationalcurriculum-in-england-science-programmes-of-study Links to Relevant Sections from Old NC UNITs 4D, 5C, 5D , 6C and 6D http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci4d/?view=get http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci5c/?view=get http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci5d/?view=get http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci6c/?view=get http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci6d/?view=get Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 3 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions The Empiribox System This is the term we give to how we believe science should be undertaken in the class room. It involves much use of practical investigation to understand scientific theories and encourages pupils to think for themselves by asking their own questions and devising their own methods. The way science is taught using this method can be broken down into the following stages: 1. Define the question and form a hypothesis 2. Conduct research and make a prediction 3. Write a method and produce equipment lists 4. Perform experiments, collecting data (observations and measurements) and presenting results 5. Interpret data, draw conclusions and explain observations 6. Evaluate the experiment and suggest further investigations 7. Publish results + ‘Pupil Peer Review’ (so pupils in other schools can see them and compare them with their own results) 8. Retest (this can be done by other pupils) We can however condense the stages into four parts: Stage Planning Activities Asking a question(s) that can be tested. Determining Independent and Dependent Variables Making and justifying Prediction Writing a Method Deciding which equipment to use and using it correctly. Recording Data and Analysis Collecting and presenting scientific observations in a way that can be analysed . Creating graphs and charts of the data Analysing data the data obtained from the experiment, writing a conclusion and determining whether or not it proves the hypothesis. Evaluation Critically deciding how well the experiment went Deciding how to improve the investigation to obtain better and more valid results. Make suggestions for further areas of study. Once pupils become used to the planning process, they will be able to undertake their own investigations with reduced input from teachers. They can call themselves proper scientists at this point! Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 4 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions What should students being doing in a science lesson? Having lots of fun Asking questions Identifying variables Obtaining valid results by controlling some factors Testing ideas and models Helping each other Making mistakes and understanding why they happen Recording data Drawing and interpreting graphs Developing the skill of thinking for themselves NEVER accepting received wisdom Particle Theory – a synopsis All matter consists of particles which move to a certain degree Particles may be atoms, molecules or ions. (They may be mixed!) There are 3 states of matter – solid, liquid and gas The particles for each state of matter are arranged as follows: Pupils could be asked what these diagrams tell them about each state of matter. Their answer could look like this: Particles in Solids are held tightly and packed fairly close together - they are strongly attracted to each other are in fixed positions but they do vibrate Particles in Liquids are fairly close together with some attraction between them are able to move around in all directions but movement is limited by attractions between particles Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 5 Particles in Gases have little attraction between them are free to move in all directions and collide with each other and with the walls of a container and are widely spaced out Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Once the pupils have these ideas, they can use the model to help explain (they will be given several substances to investigate): 1. The properties of matter 2. What happens during physical changes such as melting, boiling and evaporating The properties of matter Solids have a definite shape maintain that shape are difficult to compress as the particles are already packed closely together are often dense as there are many particles packed closely together Liquids do not have a definite shape flow and fill the bottom of a container maintain the same volume unless the temperature changes are difficult to compress because there are quite a lot of particles in a small volume are often dense because there are quite a lot of particles in a small volume Gases do not have a definite shape expand to fill any container are easily compressed because there are only a few particles in a large volume are often low density as there are not many particles in a large space Changing States Solids have the lowest kinetic energy particles as they just vibrate around their fixed points. Gases on the other hand have high kinetic energy as they are free to move wherever. Therefore, substances can change their state of matter by introducing energy, usually in the form of heat. For example, if we heat ice, it changes rapidly to water and finally when the temperature is high enough, to steam. There are some keywords associated with changing states that pupils should know. This is best shown by the following diagram (some important definitions follow): IMPORTANT DEFINITIONS: Boiling Point – the temperature at which a liquid turns to a gas Melting Point – the temperature at which a solid turns to a liquid Freezing Point – the temperature at which a liquid turns to a solid Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 6 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Famous Scientists who contributed to Particle Theory These scientists had a dramatic effect on the history of science with their theories and discoveries: Democritus http://en.wikipedia.org/wiki/Democritus Robert Boyle http://en.wikipedia.org/wiki/Robert_Boyle John Dalton http://en.wikipedia.org/wiki/John_Dalton Antoine Lavoisier http://en.wikipedia.org/wiki/Lavoisier Dmitri Mendeleev http://en.wikipedia.org/wiki/Dmitri_Mendeleev Robert Brown http://en.wikipedia.org/wiki/Robert_Brown_(botanist) Albert Einstein http://en.wikipedia.org/wiki/Albert_Einstein JJ Thomson http://en.wikipedia.org/wiki/J._J._Thomson Ernest Rutherford http://en.wikipedia.org/wiki/Ernest_Rutherford Chemical Reactions – A synopsis A chemical reaction is a process that leads to the change of one set of chemical substances to another (by rearrangement of atoms). Chemical reactions can be either spontaneous, requiring no input of energy, or non-spontaneous, often coming about only after the input of some type of energy, such as heat, light or electricity. Changes of state often result from reactions. A slightly more complex definition is that chemical reactions involve the movement of electrons in the forming and breaking of chemical bonds. The substance/substances initially involved in a chemical reaction are called reactants. Chemical reactions produce one or more products, which usually have properties different from the reactants. Chemical Equations A chemical equation can be written if a chemical reaction takes place. They can either be a symbol equation or simpler word equations. They always have the following format: Reactant(s) Product(s) Eg. A + C B + D NOTE: If you are to attempt to ask pupils to write some equations, never allow an ‘equals sign’ to be used instead of an arrow! Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 7 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Science enquiry and investigation skills The skill of being able to do science requires continuous practise. At its heart, the Empiribox Method enables pupils the opportunity to develop their science skills on an ongoing basis, week after week, year after year. Lesson time is an opportunity for pupils to improve their planning, analytical and evaluative ability. They need to become proficient at handling equipment and chemicals and eventually be able to use a number of methods to answer their questions. As a simple example, if you asked a pupil how to find the boiling point of water, they will need to know that a thermometer is required to answer this question. It is difficult to complete whole investigations each time so we suggest you focus on one of the four skill areas each half term. By the end of the final term, pupils should have gained enough experience to complete whole investigations. A science investigation often begins with an observation leading to a question or the need to solve a problem. Examples of these can be seen below. Observation followed by a question Robert Brown was a botanist who observed pollen grains in a drop of water moving in a random and jerky manner using a microscope in 1827. He repeated his observation with boiled pollen grains and found the same result and so knew it was because the pollen grains were ‘alive’. He was unable to explain his observation. It was eventually explained by Albert Einstein 1905 but named Brownian motion after Robert Brown. Brownian motion is caused by water molecules colliding with the pollen grains. Einstein explained it using mathematics. Problem to solve When NASA scientists were developing the Space Shuttle, they knew that the heat generated on reentry would burn up the shuttle unless they could insulate it. The problem was that most insulation materials were not robust enough to stand the forces of take-off. The problem was solved by developing ceramic foam tiles made from sand. These were developed and tested and found to be the best solution to the problem Planning Scientists must plan investigations in detail in order to answer questions or solve problems. In this way, they can ensure the highest probability of gathering sufficient, accurate, reliable and reproducible data. Any plan should be as detailed as necessary so it could be used by other individuals who may wish to investigate similar scientific questions. The 8 step process described previously provides a good ‘template’ for how an investigation plan should look. Hypotheses A hypothesis is a statement that can be proven by scientific investigation as true or false. An example would be: ‘Solid Fuels contain more energy than liquid fuels.’ ‘Usually, pupils are given the hypothesis. From this, they can do research, make a prediction, identify variables, write a method, gather the equipment they will need and work out how they will present their experimental results. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 8 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Terms regarding scientific data Data obtained from scientific investigations can take many forms, but it is typically either an observation, a measurement or both. There are some keywords which pupils should become familiar with as they improve their proficiency. Primary evidence Primary evidence is original evidence that the scientist collects his or herself. This evidence may be measurements, observations or survey results. In terms of school-based science, this means the pupils doing an investigation and making observations and/or measurements.. Secondary evidence Secondary evidence is evidence that the scientist collects from other sources. These sources may be directly from other scientists or from scientific journals. This evidence may be measurements, observations or survey results. In terms of school-based science, this means the pupils getting results from other groups of pupils or researching for information on the internet or reference books. Valid A valid measurement is one that measures what you want to measure. A valid way to measure the height of a person is with a ruler or tape measure. Using bathroom scales is not a valid way to measure the height of a person. Reliable A good measure of how reliable results are is by repeating measurements or observations. If the measurements or observations are about the same each time, we can say they are reliable. To improve the reliability of our evidence, we discount outlier results and take an average of our measurements. Sufficient We have sufficient evidence if we have enough to establish a pattern. For example, if we want to find out if there is a pattern between the weight we hang on a spring and its length, using five or so values of weight may well be sufficient. To find out if there is a pattern between the height of a person and the length of their stride, many more measurements would be needed before we have sufficient evidence. Accurate An accurate measurement is one which is close to the true value. In science, it is often difficult to be sure of the true value for a measurement. We often need to make a judgement of what the true value is based on how we have made the measurement. For instance, using a 30 cm rule to measure the width of a piece of paper is likely to give us an accurate measurement. We would have more evidence the result was accurate because repeated readings would give the same value. We would judge this to be the true value for the width of the paper. Measuring the true height of a tall tree would be more difficult to measure accurately. We might need to make several different measurements using different methods. We would judge the accuracy of our result from the methods we used and the reliability of our results. Reproducible This refers to the methodology of scientific investigations. Using the same method and equipment as one scientist has used to obtain data, can another individual observe similar results? Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 9 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Variables Variables are factors which do not have fixed values and can be kept the same, changed or measured by scientists. Variables can be independent or dependent. Independent and dependent variables can be continuous, discrete or categoric. Variable Type . Independent An independent variable is one which the scientist changes in the investigation. For example, in an investigation to measure how the length of a spring varies with weight, the independent variable is the weight the scientist changes to put on the spring. He can then make different measurements of the length of the spring. It is important to note that independent variables are always plotted on the x-axis of graphs. To help pupils remember this the word ‘Exchange’ can be used as an aide-memoire. Dependent A dependent variable is one where the value depends on the value of another variable. In the case of the spring investigation, the length of the spring depends on the weight the scientist puts on the spring. In other words, it is the variable that is measured by the scientist. This would be plotted on the y-axis of graphs.. Continuous A continuous variable is one which can have any value e.g. length. The length of a piece of string can be any value; 15 cm, 27.3567 cm 25.345 km etc. Quantities such as weight, length, speed, temperature can have any value and are continuous variables.. Discrete A discrete variable can only have whole number values. For example, number of people (not to be confused with the average number of people which is continuous. This is why we can have a family with 2.4 children!). Categoric A categoric variable is one which has values which are described by labels; it does not have number values e.g. type of metal, colour of eyes, country etc. Control A control variable is a condition which is kept the same throughout the experiment in order to ensure a fair test. It is only by having control variables do we achieve valid results. For example, the distance between the bunsen burner and test tube when heating water, using the same thermometer etc In an investigation of the density of metals, the metal would be the independent categoric variable. The density of the metal would be the dependent continuous variable. Key points to remember Pupils need to be given planned opportunities to ask questions that can be investigated scientifically and decide how to find answers. They should consider what sources of information, including first-hand experience and a range of other sources, they will use to answer these questions. Pupils must think about what might happen, or try things out, when deciding what to do, what kind of evidence to collect, and what equipment and materials to use. Using the Sc1 Planning sheets for each investigation students will develop the skill of identifying variables to control, measure and change in addition to making and testing PREDICTIONS or HYPOTHESES, Try and use the right terminology with pupils and get them to use it in their discussions about science investigations Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 10 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Observing and recording evidence Observing and measuring Observation is a really important skill for the scientist. The ability to see what is really happening rather than seeing what you expect to see can be difficult. It’s a good idea to give pupils observation exercises to help them to improve this skill. A good example of an observation exercise is to get them to describe what happens when a match is struck. The first time they see it, they will see the flare of the flame as it is struck, the yellow flame and the match turns to black. If you repeat it, asking them to observe every little detail including sounds and smells, the list they come up with is enormous Pupils should be able to choose and use simple scientific equipment and materials appropriately and take action to the control risks involved in their use. They need to make systematic observations and accurate measurements using appropriate equipment, including the use of ICT for data logging. In their investigations, pupils should check their observations and measurements by repeating them where appropriate to ensure that they are reliable. Recording data Pupils should demonstrate their ability to use a wide range of methods, including diagrams, drawings, tables, bar charts, photographs, video clips, voice recordings, line graphs and ICT, to communicate data in an appropriate and systematic manner. Pupils will need explicit skill teaching in order to construct tables, charts and graphs well. They also need practise in choosing the most appropriate method to show their results to analyse and evaluate their evidence. The way data is recorded often depends on the type of data. Measurements are often tabulated before they are put on a graph, pie chart or bar-chart. A bar chart or pie chart is used to show categoric and discrete variables. Continuous variables are shown by line graphs. Measurements and observations can be written in simple tables which are arranged to show the independent variable (left hand column) and the dependent variable (right hand column). Tables should always state the units being used in the experiment. Observations which are made can be recorded by photograph, picture or diagram. Events may be recorded using video or sound recording. Examples of recording data Line graph: continuous variable (heating time) continuous variable (water temperature) Bar chart: categoric variable (favourite food) discrete variable (number of pupils) Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 11 Pie chart: categoric variable (employment sector) discrete variable (percentage) Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Table of Results: Independent variable (temperature) Dependent variable (rate of solubility) Photograph (of a model virus) Drawing (of a heart) Analysing Most scientific data is presented in one form of graph such as a Line graph, Bar graph, Pictographs or Pie Charts. When analysing scientific data a decision needs to be made as to which particular type of graph best reveals the ‘trends’ or patterns in the data. As a general rule, line graphs are only used where both the variables are continuous. The key part of every analysis is of course to state clearly what the data ‘appears’ to suggest i.e. ‘it appears* that there is a correlation between Force and Mass’ etc. *Always remember there are NO DEFINITES in science! Two key skills in analysing data are 1.Learning that (for most graphs) the Independent Variable data goes on the X axis and the Dependent Variable data goes on the Y axis 2.Drawing ‘Lines of best Fit’ – this is defined simply as ‘A line on a scatter plot which can be drawn near the points to more clearly show the trend between two sets of data’ e.g. a ‘strong positive correlation’. A good rule of thumb for lines of best fit is that the number of points above your line should be the same as those below the line, and the line drawn should bisect as many points as possible. Lines of best fit can show strong positive and negative correlations or weak positive and negative correlations. A positive correlation is one where the dependent variable increases as the independent variable increases (as with the example above). A negative correlation is where the dependent variable decreases as the independent variable increases’. A strong correlation is where all the points are clustered closely to the line of best fit. A weak correlation is where the points on the graph are more scattered. In the weakest correlation, no line of best fit can be drawn. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 12 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions There are lots of different types of Lines of best fit and care needs to be taken to determine which the best one to use is. The most common line of best fit is a straight line but the graphs below show some common shapes of curve. e.g. How speed increases with time e.g. How the time for one swing of a e.g. How the temperature of a cup of e.g. ow the number of bacteria in a for something you drop pendulum changes with length coffee decreases with time colony increase with time Writing conclusions The type of conclusion being written depends very much on the type of variables used in the investigation. When writing conclusions for experiments which contain independent and dependent variables, pupils should always refer to both variables and the results they have obtained. For example a model conclusion would be ‘I can conclude that the longer I heat the water, the higher the temperature of the water. At 1 minute, the temperature of the water was 30oC and at 10 minutes the temperature was 100oC. Where ‘categoric’ investigations are conducted, a conclusion could be more definite. For example ‘In my class, most pupils have brown hair’ etc. Evaluating In using the Sc1 Analysis and Evaluation sheet to support investigation work, students will develop the skill of analysing data from each of their experiments and suggesting ways in which they could improve them to increase the validity and reliability of the data. Evaluation involves critically considering the reliability of the data and discussing how it can be improved. Pupils explain whether their evidence is robust enough to support a firm conclusion. They also suggest ideas to enable their investigation to provide additional relevant evidence. Prompt questions to support evaluation of quality of data To prompt pupils to identify inconsistencies/anomalies in evidence:• Are there any results/observations which don’t seem to match others? • Are there any results/observations that you were not expecting? • How reliable are your results? To prompt pupils to explain inconsistencies/anomalies in evidence:• How would you explain any results/observations which don’t seem to match others? • How would you explain any results/observations that you were not expecting? • How reliable are your results and how can you tell? To prompt pupils to explain inconsistencies/anomalies in evidence using science:• How would you use science to explain any results/observations which don’t seem to match others? • How would you use science to explain any results/observations that you were not expecting? Prompt questions to support evaluation of quality of procedure To prompt pupils to suggest improvements to working methods:• What could you do to make your method better? • What could you do to get more reliable results? • How could you get more accurate measurements? • Is that the best way of doing that • Is there a better piece of equipment you could use? • Is there any part of your method you could change to get better results? To prompt pupils to explain improvements to working methods:• Why would doing X make your method better? • Why would doing X give you more reliable results? • Why would doing X give you more accurate measurements? • Explain why doing X would be a better way of doing that • Explain why X would be a better piece of equipment to use? Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 13 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Evaluating In using the Sc1 Analysis and Evaluation sheet to support investigation work, students will develop the skill of analysing data from each of their experiments and suggesting ways in which they could improve them to increase the validity and reliability of the data. Evaluation involves critically considering the reliability of the data and discussing how it can be improved. Pupils explain whether their evidence is robust enough to support a firm conclusion. They also suggest ideas to enable their investigation to provide additional relevant evidence. Particle Theory and Chemical Reactions KEY VOCABULARY Diffuses Particles Particle theory Atoms Molecules Elements React Reactant Products Flame Flammable Melt Mixture Proportion Properties Residue Solution Dissolves Evaporate Condense Vapour Vaporize Crystal Solidify Thixotropic Temperature Endothermic Exothermic Valid Reliable Prediction Hypothesis Line of best fit Line graph Bar graph Pictograph Surface area Rate of Reaction Oxidation Asphyxiate Carbon dioxide Hydrogen Hydrochloric acid Sulfuric acid Ethanoic acid Nitric Acid Magnesium Zinc Iron Combine Celsius Thermometer KEY FACTS AND DEFINITIONS Particles – The name given by scientists to atoms and molecules that make up all solids, liquids and gases. Atoms – the smallest unit of mass that has all the unique properties of the element to which it belongs. Molecules – 2 or more atoms chemically combined – i.e. cannot be separated by physical means. Element – a pure substance containing only one type of atom. There are currently about 108 of them and are the basic building blocks of all matter Chemical reaction – a process where one set of substances is transformed into another. Reversible change – A reversible chemical reaction is one where the products can change back into the reactants. Irreversible change – An irreversible chemical reaction is one where the products cannot change back into the reactants. Exothermic reaction – A chemical reaction in which thermal energy is emitted into the surroundings and the temperature increases. Endothermic reaction – A chemical reaction in which thermal energy is absorbed from the surroundings and the temperature drops. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 14 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Understanding the assessment focuses for science The AFs for science describe the key elements of performance. They are linked to the National Curriculum programmes of study and the level descriptions, and are designed give a detailed, analytic view of pupils’ attainment across all the key stages and in all areas of science. AF1 Thinking scientifically AF1 contains the main criteria related to how pupils work with scientific ideas, models and evidence to understand and handle knowledge of the subject. It includes criteria which recognise how scientific ideas and models develop through further evidence, recognising the tentative nature of science as a discipline. Pupils work with scientific ideas, models and evidence themselves to further their understanding, and recognise how scientific understanding as a whole develops in such a way. AF2 Understanding the applications and implications of science The focus of AF2 is linking specific scientific ideas to particular applications and scientific and technological developments, and exploring how these developments can affect individuals, society and the world. It includes criteria related to the understanding of various issues surrounding such developments, such as ethical or moral arguments, and also criteria related to the understanding of the factors that can influence the development of science and technology. In addition there are criteria which relate to the application of science in roles or jobs. AF3 Communicating and collaborating in science AF3 contains the main criteria related to how pupils construct and present evidence-based responses and arguments for particular audiences, drawing on appropriate scientific language, mathematics, and scientific conventions and terminology. It also contains the main criteria related to how pupils use and develop collaborative approaches to their own work, and understand and recognise the advantages of the collaborative work of scientists. AF4 Using investigative approaches The focus of AF4 is how pupils ask questions, hypothesise, and develop appropriate and safe strategies and methodologies to collect scientific evidence, through experimental or other means. AF5 Working critically with evidence AF5 involves criteria based on how pupils interpret and analyse data and other scientific evidence to identify outcomes and draw conclusions using scientific knowledge and understanding. It also considers their ability to evaluate evidence, recognise limitations and develop methodologies or other strategies to improve data or provide further evidence. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 15 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions APP (ASSESSING PUPIL PROGRESS) Opportunities for APP in this Unit Assessment Foci Explanation and Level Descriptors AF 1 Thinking scientifically AF 2 Understanding the applications and implications of science AF 3 Communicating and collaborating in science AF 4 Using investigative approaches AF 5 Working critically with evidence Can use simple models to describe the difference between solids, liquids and gases. 2 Can use simple notation to represent basic chemical reactions. 4 Can make abstract ideas or models when describing processes 6 Can suggest a simple application of some of the experiments 2 Can identify aspects of chemistry used in specific jobs 4 Can explain in detail the applications of chemical reactions 6 Can represent data in a simple table 2 Can present data in more than one way 4 Can use appropriate graph / table to present and discuss data for specific experiment 6 Can follow instructions and handle basic equipment to complete investigation 2 Can use scientific terms to describe chemical reactions 4 Can make and record detailed sets of scientific measurements 6 Can suggest problems with some of the experimental procedure 2 Can identify ways of making the investigations fairer 4 Can suggest detailed ways of improving the data obtained from the experiments 6 PARTICLE THEORY– WEEK BY WEEK SUMMARY OF KEY CONCEPTS, OBJECTIVES, INVESTIGATIONS AND EQUIPMENT LIST OF THEORY LESSONS AND DEMONSTRATIONS QCA UNIT REFERENCES & LINKS 4D: Solids, liquids and how they can be separated http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci4d/?view=get Unit 5C: Gases around us http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci5c/?view=get Unit 5D: Changing state http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci5d/?view=get Unit 6C: More about dissolving http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci6c/?view=get Unit 6D: Reversible and irreversible changes http://webarchive.nationalarchives.gov.uk/20090608182316/http://standards.dfes.gov.uk/schemes2/science/sci6d/?view=get Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 16 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions INVESTIGATION FOCUS & HOW SCIENCE WORKS LEARNING OBJECTIVES All through this term the focus is on recording and analysis of data from scientific investigations, looking specifically at obtaining different types of scientific information, how to record it and ultimately how to analyse it. INVESTIGATION AND DEMONSTRATION EQUIPMENT SHEET Weeks 1 and 2 LESSON DEMONSTRATIONS Introduction to particle theory – atoms, molecules and scientific models INVESTIGATIONS Evaporation and diffusion of essential oils Weeks 1 and 2 Day Period Year Room • Whoosh bottle! KEY QUESTIONS & Investigation Ideas that can be tested. 1. Does the cost of an essential oil determine how quickly it diffuses? 2. What might affect how quickly a vapour / gas particles travel? 3. Were there any problems with this investigation? KEY CONCEPTS and LEARNING OBJECTIVES Everything is made of tiny particles called atoms and molecules. Because these particles are small scientists use models to represent them Solids, liquids and gases have particles which have different separations due to their inherent kinetic energy Be able to draw a particle diagram for a solid, liquid and a gas. HOW SCIENCE WORKS LEARNING OBJECTIVES Liquids turn to gases by evaporation and diffuse away into the atmosphere Using particle theory, explain that diffusion is movement of particles from a high concentration to a low concentration There are often problems with investigations and scientists need to minimise these Enhance the skill of detecting systematic errors from a wide range of contributory factors Practical Equipment Whoosh Bottle – water bottle, safety screen, meter ruler, splint, matches, ethanol (40 ml) Investigation : Evaporation and Diffusion of Perfumes / Aftershaves Class Set (x 15) 4 different essential oils, pipettes, 4 x petri dishes, meter ruler, stopwatches, Sc1 Planning Sheets, access to sink and paper towels. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 17 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Weeks 3 and 4 LESSON DEMONSTRATIONS Introduction to particle theory (II) – solids, liquids and gases. INVESTIGATIONS Materials circus and a thixotropic substance - custard powder. • Sodium ethanoate stalagmite. • Funny putty KEY QUESTIONS & Investigation Ideas that can be tested. 1. 2. Weeks 3 and 4 On what basis are substances classified as solids, liquids and gases? How could you make sure your opinions / analysis are consistent with other evidence? KEY CONCEPTS and LEARNING OBJECTIVES Classify materials in terms of properties of solids, liquids and gases and justify their classification Explain why some materials are difficult to classify Generate descriptions of solids, liquids and gases consistent with the evidence and their scientific knowledge Learn the term thixotropic and give examples. HOW SCIENCE WORKS LEARNING OBJECTIVES That materials can be classified as solid, liquid or gas, but that some are difficult to classify To evaluate their own theory in the light of evidence It is essential to check that scientific results / observations are RELIABLE by checking other identical experiments. Day Practical Equipment Demonstration 1 Funny putty - Science Museum Funny Putty, CD Period Demonstration 2 – Sodium Ethanoate Stalagmite Year Beaker (250 ml) Measuring cylinder (25 ml) Petri dish Stirring rod Bunsen burner, tripod and gauze Access to a top-pan balance (accurate to 0.1 g is sufficient) Sodium ethanoate-3-water (sodium acetate-3-water) (Low hazard), 125 g Room Investigation : Materials Circus + Thixotropic Substances Class Circus Arrangement of the Following Materials - paper, sand, jelly, talc, toothpaste, tomato sauce, blue tack, sponge, small blocks of metal, wood and glass Class Set (x 15) ~ 100 ml custard / corn flour, 50 ml beaker, pipette, plastic washing up bowl, access to water. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 18 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Weeks 5 and 6 LESSON DEMONSTRATIONS Introduction to simple chemical reactions (i) – reactions of metals with acids INVESTIGATIONS Reacting metals with acids • Elephant’s toothpaste • Carbon dioxide trough KEY CONCEPTS and LEARNING OBJECTIVES Learn the simple description of a chemical reaction as REACTANTS reacting to produce PRODUCTS and use this to describe simple every day examples. Learn that metals react with acids to produce hydrogen gas. Learn the squeaky pop test for hydrogen Learn the test for oxygen – relights a glowing splint. Learn that carbon dioxide is a dense gas and ‘suffocates’ flame which is why it is used in fire extinguishers. KEY QUESTIONS & Investigation Ideas that can be tested. 1. Is there a pattern to your observations? How can you tell? 2. Do you think all metals and acids react the same way? 3. How can the data from this experiment be ‘Valid’ 4. How could you investigate your theory / observations further? HOW SCIENCE WORKS LEARNING OBJECTIVES There are often ‘patterns’ in science and these are important for making scientific predictions to test. VALID data is obtained from experiments where only one variable is changed. Identify when chemical reactions are occurring from a number of observations such as colour changes, temperature changes, bubbles, changes of state, light, sound. Weeks 5 and 6 Practical Equipment Day Demonstration 1 – Elephants Toothpaste - latex gloves, hydrogen peroxide (H2O2), 2 x 100 ml measuring cylinders, 1l measuring cylinder, washing up liquid, saturated potassium iodide (KI) solution, bin bag, washing up bowl, food colouring Period Year Room Demonstration 2 – Carbon dioxide trough – sodium hydrogen carbonate (NaHCO3), vinegar, large measuring cylinder / jug, clear-sided sloping candle trough, matches and 4 candles. Investigation : Simple Chemical Reactions – Metals and Acids Class Set (x 15) 4 x test tubes, bottles of 1 M hydrochloric acid (HCl), 1 M sulfuric acid (H2SO4), 0.1 M nitric acid (HNO3) and 1 M ethanoic (acetic) acid (CH3COOH), test tube rack, splints, safety goggles, matches, strips of magnesium (Mg), pieces of zinc (Zn), copper (Cu), granular iron (Fe), sieve Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 19 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Weeks 7 and 8 LESSON DEMONSTRATIONS Foaming endothermic reaction Learn that chemical reactions often involve a Citric acid + Sodium change in temperature. hydrogen carbonate + If the temperature increases the reaction is powdered food dye. EXOTHERMIC and if the temperature decreases it is ENDOTHERMIC. Be able to state and explain a range of exothermic and endothermic reactions. Introduction to simple chemical reactions (ii) - temperature KEY QUESTIONS & Investigation Ideas that can be tested. INVESTIGATIONS Endothermic and exothermic reactions – (possible data logging temperature) Weeks 7 and 8 Day Period Year Room KEY CONCEPTS and LEARNING OBJECTIVES 1. Do chemical reactions involve a change in temperature? How can you tell? 2. How can you make sure data from an investigation is ‘Reliable’. HOW SCIENCE WORKS LEARNING OBJECTIVES You ensure results are RELIABLE by checking data from other identical experiments. Develop the confidence to handle a range of different chemicals in different forms Being able to accurately measure temperature changes in a chemical reaction. Practical Equipment Demonstration 1 – Foaming Endothermic Reaction - Citric Acid (C6H8O7), sodium hydrogen carbonate (NaHCO3), food colouring, 5 litre beaker, large plastic basin, 2 litre jug Investigation : Energy Changes in Chemical Reactions Class Set (x 15) Polystyrene cup (expanded polystyrene) Beaker (250 ml) in which to stand the polystyrene cup for support Thermometer (–10°C to 110°C) Measuring cylinder (10 ml), 2 Spatula Absorbent paper + Access to the following solutions: (all at approx. 0.4 M concentration); Copper(II) sulfate (Low hazard) Hydrochloric acid (Low hazard) Sodium hydrogen carbonate (Low hazard) Sodium hydroxide (Irritant) Sulfuric acid (Low hazard) Access to the following solids Magnesium ribbon (Highly flammable), cut into 3 cm lengths. Magnesium chips (Highly flammable). Citric acid (Irritant). Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 20 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Weeks 9 and 10 LESSON DEMONSTRATIONS Introduction to simple chemical reactions (iii) – speed / rates of reaction INVESTIGATIONS Speed of chemical reactions with rhubarb Weeks 9 and 10 Day Period Year Room Nails and water – rusting Ethanol flame Icing sugar tin explosion KEY QUESTIONS & Investigation Ideas that can be tested. 1. Does the size of a reactant have any effect on the speed of a chemical reaction? 2. How could you repeat this experiment to make it more precise? KEY CONCEPTS and LEARNING OBJECTIVES Chemical reactions occur at a range of different speeds. Give examples of slow, medium and fast reactions e.g. – rusting, growth of organisms, fermentation, and explosions The speed of chemical reactions is affected by ‘surface area’ – the greater the surface area the faster the reaction. HOW SCIENCE WORKS LEARNING OBJECTIVES Appreciate how errors may affect experimental results through experimental procedures that are difficult to undertake Develop the skill of being able to decide an end point in a chemical reaction Develop the skill of handling chemicals safely. Practical Equipment Demonstration 1 – Rusting – Nail, beaker Demonstration 2 –Ethanol fire – Small heat proof mat, methylated spirits, matches, tin lid, low classroom lighting. Demonstration 3 – Icing sugar tin explosion metal tin with lid, small funnel, rubber tubing, icing sugar, tea-light candles, matches, heat proof mat. Investigation : Speed of Chemical Reactions Class Set (x 15) Eye protection Each working group will require: 3 x beakers (100 ml), Measuring cylinder (50 ml) Timer White tile or piece of paper Students will need access to: Rhubarb stalks (frozen rhubarb also works if the pieces are long enough) Knives, 4 to 6 per class (ordinary table knives are probably most appropriate.) Acidified potassium manganate(VII) solution (Irritant) Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 21 Empiribox Chemistry Scheme of Work – Particle Theory and Chemical Reactions Weeks 11 and 12 LESSON DEMONSTRATIONS Introduction to simple chemical reactions • Disappearing plastic (iv) – mass change KEY CONCEPTS and LEARNING OBJECTIVES Learn that the term ‘Combustion’ – involves a reaction with oxygen. Learn that when things react with oxygen the products can be gases, solids or liquids. Some chemical reactions involve an increase in mass and to be able to explain in simple terms why this is using particle theory. INVESTIGATIONS Combustion of iron-wool and paper KEY QUESTIONS & Investigation Ideas that can be tested. 1. When chemicals undergo combustion does their mass change? 2. What happens to the mass of the iron after it is burnt? Why? 3. What happens to the mass of the paper after it is burnt? Why? HOW SCIENCE WORKS LEARNING OBJECTIVES Develop the skill of analysing the data from the experiments Develop the skill of being able to carry out an investigation with precision Develop an understanding about ‘reliability’ in experimentation Develop the skill of being able to carry out a combustion experiment safely. Weeks 11 and 12 Practical Equipment Day Demonstration 1 – Disappearing Plastic – large tea mug, 50 ml acetone, expanded polystyrene chips/blocks Demonstration 2 – Burning Paper – mass balance, heatproof mat, tin lid, A4 paper, matches Period Year Room Investigation : Combustion Class Set (x 15) 3 x 5 g portions of 001 grade fine iron wool, 9 V cell, 2 x small leadswith small crocodile clips, 1 x metal tin lid / combustion tray Class access to 4 x 0.01 g scale electronic mass balances. Empiribox - KS2 Chemistry SOW - Particle Theory SOW1.CO001 V2.1 071015 | Page 22
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