MATERIAL Safety Data Sheet (MSDS) NITROUS OXIDE N2O SUPPLIER DETAILS OTHER PROPERTIES Supplier Name: Renegade Gas (Pty) Ltd T/A Supagas (NSW) & Supagas (QLD) Head Office Address: 5 Benson Road, Ingleburn, 2565 Telephone: (02) 8788 4444 Fax: (02) 8788 4445 Emergency: 24hr EMERGENCY TELEPHONE No. 1300 651 106 EMERGENCY SERVICES: DIAL 000 Website: www.supagas.net.au Strong Oxidising Agent. Will support and enhance combustion. May react violently with Organic Materials, combustible materials and reducing agents. Above 300C Nitrous Oxide Can thermally decompose to form corrosive & toxic products. Nitrous Oxide decomposition liberates heat and is not reversible and leads to a large pressure increase within the cylinder. Liquid Nitrous oxide is very cold and its low temperature may cause metals to become brittle if spilt. MANUFACTURER’S CODE INGREDIENTS UN Number: 1070 Nitrous Oxide, compressed DG Class: 2.2 Non - flammable gas, non-toxic gas Packaging Group: Not applicable Subsidiary Risk(s): 5.1 Oxidiser Note: Cylinders of compressed Nitrous Oxide may be labelled with an “Oxidising gas” label instead of class 2.2 and subsidiary risk 5.1 Labels. Hazchem Code: 2 (S) EPG No: 2C8 Poisons Schedule: Clasified as Schedule 4 (S4) Uses: This product is supplied for Scientific Applications .e.g as an oxidant for detectors for flame atomic absorption spectrometers. PHYSICAL DESCRIPTION & PROPERTIES Appearance: Colourless gas, slightly soluble in water Boiling Point: -88 ∞C Melting point: -90.8∞C Vapour Pressure: 5100kPa Volatiles: 100% Evaporation Rate: Very Rapid if Cylinder Valve Open Odour: Odourless Vapour Density: 1.5 @ 20∞C (Air=1) Weight per ml: 1.2 (water =1) Flash Point: None Flammability Limits: None Auto-Ignition Temperature: Not Applicable MSDS061 Name CAS No Proportion Nitrous Oxide 10024-97-2 > 99.5% HEALTH EFFECTS Acute: Swallowed: An unlikely route, unless as a cryogenic liquid. Skin: No effects reported from the gas. Contact with liquefied Nitrous Oxide will cause moderate to severe frostbite. Eyes: No effects reported from the gas Inhaled: Nitrous Oxide is a simple asphyxiant. May replace oxygen in the atmosphere. Symptoms of approaching asphyxia include accelerated pulse rate, increase in the rate and volume of respiration,decreased ability to think clearly, inattention and loss of muscle coordination. At only 10-14%, there may be nausea and vomiting, and an inability to move. Below 6% oxygen, breathing is likely to be in gasps, with risk of convulsions. Breathing a pure Nitrous Oxide atmosphere may result in immediate loss of consciousness and death within a few minutes. Chronic: Breathing and repeated exposure to high levels of Nitrous Oxide at atmospheric pressure may lead to thickening and/or scarring of exposed tissues, including the lungs. TLV/TWA: 50ppm LD50: No data found If poisoning occurs, contact a doctor or Poisons Information Centre Ph: 13 11 26 MATERIAL Safety Data Sheet (MSDS) NITROUS OXIDE continued Swallowed: Not applicable. Skin: If skin contact occurs with liquid Nitrous Oxide, remove contaminated clothing and flush skin thoroughly with water. Eyes: If in eyes, hold eyes open, flood with water for at least 15 minutes and see a doctor. Inhaled: Remove from exposure, rest and keep warm. If unconscious, assist breathing and seek medical assistance immediately FIRST AID FACILITIES Recommended: None Advice to Doctor: Product is Nitrous Oxide, compressed. Overexposure to high concentrations of Nitrous Oxide at elevated pressures may lead to delayed onset of pulmonary oedema. Contact Poisons Information Centre if ingested on 131 126. EXPOSURE LIMITS National Occupational Health & Safety Commission (NOHSC) – (Worksafe Australia) TLV-TWA: 50ppm TLV-STEL: None assigned Engineering Controls: Prevent contact with grease and oils. Do not use combustible materials for construction. Always use with a regulator, and pressurise systems slowly. Secure cylinders at all times. Ensure adequate ventilation (same as outdoors) at all times. Personal Protection: Avoid exposure to high concentrations of Nitrous Oxide during pregnancy. Personal protection to be selected from those recommended below, as appropriate to mode of use, quantity handled and degree of hazard: Safety Glasses Safety Shoes Rubber Gloves Flammability: Not Flammable. Will support combustion. Contact with combustible materials may cause fire. Combustible materials, such as grease and oils, in contact with Nitrous Oxide under pressure may cause explosion. STORAGE AND TRANSPORT Storage Temperature: Room Temperature UN Class: 2.2 Compressed gas Packaging Group: 5.1 Oxidiser MSDS061 UN Number: 1070 Nitrous Oxide, compressed EPG No: 2C8 Correct Shipping Name: Nitrous Oxide, compressed Observe requirements of The Australian Code for the Transport of Dangerous Goods by Road and Rail. Observe the requirements of State Dangerous Goods (Storage and Handling) Regulations. STORAGE ADVICE Store cylinders securely in a cool, well-ventilated area, out of direct sunlight. Keep valves closed, even on empty cylinders. Keep upright. Keep away from naked flames and other sources of heat. No Smoking. Keep away from flammable or combustible material. Keep away from the oils and grease. Prevent gas from collecting in enclosed or low-lying places. Rotate cylinders in storage to ensure that they are not stored for excessive periods. Protect from physical damage, particularly valves and regulators. Store away from heavy traffic and emergency exits SPILLS AND DISPOSAL Disposal of small spillage only CAUTION: Before dealing with spillage take the necessary protective measures, inform others to keep at a safe distance and shut off all possible sources of ignition. Extinguish all naked flames. Switch off all non-flameproof equipment. Shut off pressure regulator or cylinder valve if safe to do so. Isolate cylinder if safe to do so. Relieve system pressure. Disconnect cylinder and remove to a safe, open area. Allow venting to atmosphere. Inform cylinder supplier or emergency services as appropriate. Do not attempt to repair damaged valve or regulators. FIRE/EXPLOSION HAZARD Not flammable. Will violently support combustion. Contact with combustible materials may cause fire. Combustible materials, such as grease and oils, in contact with Nitrous Oxide under pressure may cause explosion. Compressed gas: exposure to high temperatures, as in a fire, may lead to explosion. Do not approach cylinders suspected of being hot. Cool cylinders exposed to fire with water from a safe location. MATERIAL Safety Data Sheet (MSDS) NITROUS OXIDE continued Above 300C Nitrous Oxide Can thermally decompose to form corrosive & toxic products. Nitrous Oxide decomposition liberates heat and is not reversible and leads to a large pressure increase within the cylinder. In case of small fire/explosion use: Water In case of major emergency: Hazchem Code: 2 (S) Extinguishant: Water fog or fine water spray Danger of violent reaction or explosion? Yes Protective Clothing: Breathing apparatus and protective gloves for fire only. Appropriate Measures: Dilute Evacuate? Yes, if cylinders near, or in path of, fire OTHER INFORMATION Prevent leaking gas from entering drains or sewers. Report Reviewed: 6 June 2014 MSDS061
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