Journal of Hydrology (2006) 329, 140– 153 available at www.sciencedirect.com journal homepage: www.elsevier.com/locate/jhydrol Stream–air temperature relations to classify stream–ground water interactions in a karst setting, central Pennsylvania, USA Michael A. O’Driscoll a,* , David R. DeWalle b a Geology Department, East Carolina University, 204 Graham Building, Greenville, NC 27858, United States School of Forest Resources, The Pennsylvania State University, 107 Land & Water Research Building, University Park, PA 16802, United States b Received 3 January 2005; received in revised form 23 January 2006; accepted 6 February 2006 KEYWORDS Summary Stream–ground water interactions in karst vary from complete losses through swallow holes, to reemergences from springs. Our study objective was to compare stream–air temperature and energy exchange relationships across various stream–ground water relationships in a carbonate watershed. It was hypothesized that ground water-fed stream segments could be distinguished from perched/losing segments using stream–air temperature relationships. Two types of computations were conducted: (1) comparisons of stream–air temperature relationships for the period of October 1999–September 2002 at 12 sites in the Spring Creek drainage and (2) detailed energy budget computations for the same period for ground water-dominated Thompson Run and Lower Buffalo Run, a stream with negligible ground water inputs. Weekly average air temperatures and stream temperatures were highly correlated, but slopes and intercepts of the relationship varied for the 12 sites. Slopes ranged from 0.19 to 0.67 and intercepts ranged from 3.23 to 9.07 C. A twocomponent mixing model with end members of ground water and actual stream temperatures indicated that the slope and intercept of the stream–air temperature relationship was controlled by ground water inputs. Streams with large ground water inputs had greater intercepts and lesser slopes than streams that were seasonally losing, perched, and/or distant from ground water inputs. Energy fluxes across the air–water interface were greatest for the ground water-fed stream due to increased longwave, latent, and sensible heat losses from the stream in winter when large temperature and vapor pressure differences existed between the stream and air. Advection of ground water was an important source and sink for heat in the ground water-fed stream, depending on season. In contrast, along the seasonally losing stream reach, advection was of minimal importance and stream temperatures were dominated by energy exchange across the air- water Water–air temperature relationships; Stream temperature; Stream–ground water interactions; Karst hydrology; Air–water interface; Energy exchange * Corresponding author. Tel.: +1 252 328 5578; fax: +1 252 328 4391. E-mail address: [email protected] (M.A. O’Driscoll). 0022-1694/$ - see front matter c 2006 Elsevier B.V. All rights reserved. doi:10.1016/j.jhydrol.2006.02.010 Stream–air temperature relations to classify stream–ground water interactions in a karst setting 141 interface. Overall, results showed that stream temperatures and energy exchange in this carbonate watershed were strongly related to stream–ground water interactions. c 2006 Elsevier B.V. All rights reserved. Introduction The degree to which a stream interacts with the underlying ground water system is important for a variety of scientific, practical, and legal reasons, such as wellhead protection (Nnadi and Sharek, 1999), bank filtration (Sheets et al., 2002), stream ecology (Brunke and Gonser, 1997), and non-point source pollution from adjacent lands (Hill et al., 1998). Stream temperature fluctuations are related to the nature of stream–ground water interactions and have been used as signals to trace exchanges between surface and ground waters (Stonestrom and Constantz, 2004). In karstic terrains, surface water drainage basins often differ from ground water basins and it may be difficult to clearly distinguish between surface water and ground water (White, 1988). Streams in carbonate settings exhibit a wide variety of relations with respect to the underlying ground water system ranging from complete losses due to swallow holes, to reemergences from discrete springs (Brahana and Hollyday, 1988; Brown and Patton, 1996). Carbonate aquifers have been characterized based on annual temperature fluctuations from spring discharges. Seasonal water temperature patterns were found to be good indicators of the carbonate aquifer type, with conduit-fed springs showing large seasonal temperature variations and diffuse-fed springs showing little to no seasonal variation in water temperature (Shuster and White, 1971). This approach characterizes springs based on the rate of movement of recharge waters through the underlying carbonate aquifer based on spring water temperatures. Spatial variations in ground water inputs to streams may also be detected using in-stream water temperatures (O’Driscoll, 2004). A variety of approaches have been used to predict stream water temperatures. Investigators have found that air temperature is a good index of stream temperature at timescales of greater than one week (Mohseni and Stefan, 1999; Ozaki et al., 2003). A common approach to stream temperature predictive modeling is to use the equilibrium temperature concept (Edinger et al., 1968). Equilibrium temperature is the hypothetical temperature that water reaches under constant atmospheric heating/cooling where no more heat is transferred at the air/water interface. The net energy exchange across the air–water interface can be estimated from the following equation (modified from Mohseni and Stefan, 1999): Q n ¼ Hns þ Hla Hls Hle Hc where Qn is the net heat flux across the air–water interface, Hns is the net solar radiation at the stream surface, Hla is the longwave radiation downwelling to the surface water body, Hls is the longwave radiation emitted from the surface water body, Hle is the latent heat loss due to evaporation, and Hc is the sensible heat or convective heat exchange. Equilibrium temperature is the temperature at which the net heat flux across the air–water interface (Qn) is equal to zero. Mohseni and Stefan (1999) found that the equilibrium temperature–air temperature relationship is similar to the stream temperature–air temperature relationship over the range of 0–20 C for streams that do not have significant ground water inputs. If all heat input to a stream is from the atmosphere, weekly stream temperature should be close to weekly equilibrium temperature. In stream reaches with significant ground water inputs, the stream temperature–air temperature relationship should have a smaller slope and larger intercept than that of the equilibrium temperature–air temperature relationship. Bogan et al. (2003) found that for 596 streams in the central and eastern United States, a median stream temperature-equilibrium temperature linear relationship existed with a slope of 0.82 and intercept of 2.8 C when comparing stream temperature to equilibrium temperature on a weekly basis. Streams with ground water inputs had slopes less than the median and intercepts greater than the median. Since the stream temperature–equilibrium temperature relationship is linearly related to the stream temperature–air temperature relationship, these results indicate that the stream–air temperature relationship should provide a good indicator of ground water inputs along streams. Stream temperature ranges from an upstream temperature to equilibrium temperature over a distance from the upstream location. The difference between actual stream temperature and equilibrium temperature is related to the temperature difference between the source (i.e., ground water spring or seep) and the air temperature at the source. Stream temperature will become closer to air temperature with distance from the source. Flow rate influences the upstream temperatures and affects the stream response to equilibrium temperature. The greater the flow rates the farther downstream the influence of upstream temperatures will be present (Mohseni and Stefan, 1999). In a recent study in the Exe basin, Devon, UK, Webb et al. (2003) found that stream water temperatures were more sensitive to air temperatures during low flows (below median levels) and water temperature was inversely related to discharge, indicating the importance of ground water inputs to stream temperatures. The inverse relationship between water temperature and discharge is also related to meteorological conditions and the relationship between discharge and thermal mass. In a study of losing and gaining stream reaches along alpine streams in the western US, it was found that diurnal variations in stream temperature and discharge were greater in losing streams when compared to gaining streams, indicating that stream–ground water relations have a strong influence on stream temperatures (Constantz, 1998). Study objectives The goal of this study was to compare stream–air temperature and energy exchange relations across a variety of catchment areas and stream–ground water relations in a 142 karst basin. It was hypothesized that ground water-fed stream segments could be distinguished from perched or losing streams using the surface water temperature versus air temperature relationship. Spring and seep ground water inputs are typically close to the regional average annual air temperature year-round and ground water temperatures are only slightly affected by meteorological conditions (particularly from diffuse-fed aquifers). Waters from spring-fed streams will have temperatures that are more influenced by the advection of ground water than the energy exchange across the air–water interface. In this study, two types of computations were conducted to characterize stream temperature regimes: (1) comparisons of stream–air temperature relations for 12 sites in the Spring Creek drainage and (2) detailed energy budget computations for two streams: ground water-dominated Thompson Run and Lower Buffalo Run, with negligible ground water influence. The objectives of this study were: 1. To analyze the differences in energy exchange processes occurring between a stream dominated by ground water inputs and one with minimal ground water inputs. 2. To illustrate how the stream versus air temperature relations are affected by ground water inputs at 12 stations within the Spring Creek drainage basin. M.A. O’Driscoll, D.R. DeWalle Study site and hydrology The Spring Creek watershed The study sites were located in the Spring Creek watershed, Centre County, Pennsylvania (see Fig. 1). The watershed is present in a complex hydrogeological setting of the karstunderdrained, Nittany Valley in the Valley and Ridge Province of the Appalachian region of central Pennsylvania. The drainage basin consists of a broad carbonate valley containing a variety of solutional features associated with karst development. Ridges underlain by shale, sandstone, and quartzite bound the valley (Parizek and White, 1985). The geologic factors that control the occurrence and movement of ground water in the bedrock and indirectly in the soil mantle are: topography, joints, fracture concentrations, bedding planes, variations in rock type, rock texture, primary porosity, permeability, and solutional features (Krothe, 1976). In the valley, stream reaches are underlain predominantly by carbonate rocks and both surface and subsurface drainage exist. Perched and losing streams are common in carbonate uplands for most of the year. Streams in the watershed are fed by mountain runoff or ground water seeps or springs. Springs are connected to a diffuse and extensive underground conduit system that carries ground water flow for up to 23 km (Giddings, 1974). Water table elevations and ground water Figure 1 Water table map and surface water monitoring stations (white boxes) for the Spring Creek Watershed (modified from Wood, 1980). Ground water head contour interval is 30 m. Locations of water temperature and streamflow monitoring sites are described in Table 1. Stream–air temperature relations to classify stream–ground water interactions in a karst setting 143 Figure 2 Geological map depicting major aquifer types and fault zones underlying the Spring Creek Watershed (modified from Fulton et al., 2005). Major springs are indicated by gray circles. Water monitoring sites as labeled in Fig. 1 are indicated by white boxes. flowpaths are significantly influenced by the nature of the underlying carbonate geology (Wood, 1980). The underlying formations can be classified into four main aquifer types: diffuse-flow dominated carbonates, fracture-dominated carbonates, conduit-dominated carbonates, and fracture dominated siliclastics (see Fig. 2 – modified from Fulton et al., 2005). An extensive ground water trough is located in the valley center, which indicates that a large amount of drainage bypasses streams in the upper sections of the watershed and later emerges possibly along stream channel segments and at springs in the Bellefonte area (see Fig. 1 – modified from Wood, 1980). Numerous large springs are present within the Spring Creek watershed (see Fig. 2), a detailed listing of major springs is provided by Wood (1980) and more recently by Fulton et al. (2005). Springs are frequently found at bedrock contacts. The largest of the springs, Big Spring, located along Spring Creek in Bellefonte, discharges approximately 0.5 m3/s. The most extensive soil association within the carbonate valley is the Hagerstown (Typic Hapludalf)–Opequon (Lithic Hapludalf)–Hublersburg (Typic Hapludalf) association formed as residuum from limestone and dolomite bedrock (Ciolkosz and Dobos, 1992). The surface water drainage basin is approximately 378 km2, whereas the ground water drainage basin drains a considerably larger area, approximately 453 km2 (Giddings, 1974). At the mouth of the Spring Creek watershed average discharge, as measured at the US Geological Survey gage at Milesburg, is 7.2 m3/s for the record of 1968–2002. The Spring Creek surface watershed is comprised of 36% agricultural, 37% forested, 17% urban/suburban, and 10% other land-uses (Sengle, 2002). Typically land-use associated with the carbonate valley consists of agricultural and urban land, whereas the siliclastic ridges are usually forested. Meteorological and hydrological conditions Central Pennsylvania has a humid northeastern continental type climate. Mean annual precipitation in the Spring Creek watershed is approximately 99 cm based on 76 years of data (1926–2002) measured at State College. Evapotranspiration is approximately 43 cm/year or 43% of precipitation based on precipitation minus long-term discharge data from 1968 to 2002. Mild to extreme drought conditions were present in central Pennsylvania beginning in the fall of 1998 and continuing until the spring of 2003 (Pennsylvania State Climatologist, 2003). 144 M.A. O’Driscoll, D.R. DeWalle two wastewater treatment plants along Spring Creek, and a fish hatchery, a metal products factory, and mining operations along Logan Branch. Water temperatures were not logged at these sites during this study. In addition, ground water withdrawals at the State College Water Authority well fields remove approximately 3800 million liters per year (Walsh, 2002) of ground water from the subsurface. The well fields are located within floodplain sediments adjacent to Upper Slab Cabin Run and may induce streambed infiltration along segments of Slab Cabin Run for portions of the year. Linear regressions were performed between weekly moving average stream temperatures versus weekly moving average air temperatures for all 12 study locations for the period of October 1, 1999 through September 30, 2002 (see Table 2). The weekly moving average was calculated daily for the three-year period and each daily value represents the weekly average preceding that date. Stream temperature–air temperature relations were compared for the 12 stream locations using linear regressions between weekly average stream temperatures versus weekly average air temperatures. Hourly air and stream temperature were summarized as weekly moving average data for regression analyses. Methods Streamflow and water temperature Twelve sites were used for water temperature and streamflow data collection. Data were collected on an hourly basis by the Water Resources Monitoring Committee of the Spring Creek Watershed Community, administered by the ClearWater Conservancy, a local watershed conservation group (State College, Pennsylvania) from October 1, 1999 until September 30, 2002 (sites noted in Fig. 1) (ClearWater Conservancy, 2003). Hourly air temperatures were obtained from the Pennsylvania State Climatologist Station at the University Park Campus (Pennsylvania State Climatologist, 2003). A summary of the sites, catchment areas, average streamflows for the period of October 1999–September 2002, and average hydrological yields (streamflow/catchment area) for that period are presented in Table 1 (modified from Sengle, 2002). In addition to ground water discharge as springs and seeps, several point source discharges are present along streams within the basin, including two fish hatcheries and Table 1 Summary of monitoring station locations, basin areas, average streamflow and hydrologic yield (average streamflow/ catchment area) for the three-year study period Monitoring Station Station ID Latitude Longitude Basin area (ha) Streamflow (m3/s) Hydrologic yield (m3/s/ha) Spring Creek Upper – Linden Hall Road Bridge Cedar Run – Brush Valley Road Bridge Slab Cabin Run – Millbrook Marsh Thompson Run – Millbrook Marsh Spring Creek Houserville – Trout Road Bridge Spring Creek Axemann – Spring Creek Road Bridge Logan Branch Lower – State Route-150 Bridge Buffalo Run Lower – Lower Coleville Road Bridge Spring Creek Milesburg – McCoy Dam Logan Branch Upper – Odd Fellows-SR 144 Buffalo Run Upper – SR550 at Filmore Slab Cabin Run Upper – South Atherton Street SPU CEL SLL TR SPH SPA LOL BUL SPM LOU BUU SLU 40/47/34 40/47/40 40/48/44 40/48/47 40/50/02 40/53/24 40/54/27 40/54/35 40/55/54 40/52/30 40/51/30 40/47/05 77/47/54 77/47/50 77/49/54 77/50/09 77/49/38 77/47/39 77/46/54 77/47/38 77/47/11 77/45/45 77/53/00 77/50/15 3403 4526 4328 1021 15,058 22,236 5832 6941 45,300 3324 3262 3795 0.40 0.30 0.20 0.27 1.29 1.27 1.76 0.30 4.91 0.67 0.16 0.12 1.19E 04 6.63E 05 4.69E 05 2.69E 04 8.57E 05 5.71E 05 3.02E 04 4.33E 05 1.08E 04 2.04E 04 4.80E 05 3.29E 05 Table 2 Summary of the linear regression equations for weekly average stream–air temperature relationships for all 12 locations for the three-year study period Location Slope (B0) Intercept (B1) R2 S B0se (±) B1se (±) N Lower Logan Branch Upper Logan Branch Lower Cedar Run Lower Slab Cabin Run Upper Slab Cabin Run Spring Creek at Axemann Spring Creek at Houserville Spring Creek at Milesburg Upper Spring Creek Upper Buffalo Run Lower Buffalo Run Lower Thompson Run Average slope and intercept 0.185 0.428 0.487 0.615 0.625 0.585 0.528 0.426 0.207 0.640 0.672 0.272 0.47 9.07 7.66 5.58 5.04 4.58 5.94 5.32 7.08 8.18 3.23 3.61 8.44 6.14 96.0 92.4 95.2 92.2 88.4 97.7 97.6 98.0 86.5 96.3 95.3 97.1 0.3478 1.102 0.9833 1.183 1.566 0.8079 0.7569 0.5447 0.7379 1.120 1.346 0.4239 0.0013 0.0037 0.0033 0.0076 0.0101 0.0027 0.0027 0.0018 0.0024 0.0044 0.0045 0.0014 0.0195 0.0532 0.0457 0.1244 0.1663 0.0376 0.0359 0.0254 0.0345 0.0759 0.0627 0.0197 843 605 1096 557 502 1096 1096 1096 1096 787 1079 1096 Stream–air temperature relations to classify stream–ground water interactions in a karst setting Energy fluxes at the air–water interface from meteorological and radiation data Energy fluxes at the air–water interface for Thompson Run (TR) and Lower Buffalo Run (BUL) were calculated using site-specific hourly stream temperature data for the period of October 1, 1999 through September 30, 2002. These streams were chosen because they had the most complete records and had similar flow rates but differed in their relationship with the ground water system (Thompson Run, spring-fed/Buffalo Run, seasonally losing). Meteorological and radiation data were obtained from the Rock Springs Agricultural Research Station (Latitude: 40.72 North, Longitude: 77.93 West, Elevation: 376 m, approximately 4.5 miles west of Slab Cabin Run) as part of the SURFRAD network (SURFRAD, 2004). Short-wave and long-wave radiation, relative humidity, wind speed, barometric pressure and air temperature data were collected at the Rock Springs site and used in this study in the form of weekly moving averages. These data were paired with site-specific stream temperature data collected at each site. Meteorological and radiation data processing A detailed description of net heat flux calculations is provided in O’Driscoll (2004). Net solar (Hns) was calculated as (1 albedo) · shading factor · measured downwelling solar. Where albedo was estimated as 0.07 (DeWalle, 1974; Brutsaert, 1982) and shading factors were calculated from field canopy estimations as 0.93 for Thompson Run and 0.84 for Lower Buffalo Run (DeWalle, 1974) and average shading factors for direct and diffuse incoming solar fluxes combined were calculated. Atmospheric downwelling longwave radiation (Lopen) was measured at the weather station at Rock Springs. The open site downwelling longwave radiation was corrected for the effects of shading using view factors developed in DeWalle (1974). For Thompson Run, the fraction of longwave that would make it to the stream was 0.84, and for Lower Buffalo Run the factor was 0.76. The longwave emitted from terrestrial vegetation (Lt) and slopes to the stream was estimated from the following equation (DeWalle, 1974): Lt ¼ 2erT 4surface F sv where e is the emissivity of vegetation and slopes and is estimated at 1, r is the Stefan–Boltzmann constant (4.899 · 106 kJ/m2 K4), Tsurface is estimated by air temperature in K, and Fsv is the view factor from the streams to terrestrial objects along one bank. View factors were estimated from those derived by DeWalle (1974). The view factor to the vegetation cover along each bank for Lower Buffalo Run was 0.12 and for Thompson Run 0.08. The total longwave radiation arriving at the stream was calculated from (DeWalle, 1974): Hla ¼ Lt þ ð1 2 F sv ÞLopen Longwave radiation emitted by the streams was calculated using the following equation (DeWalle, 1974): Hls ¼ ew rðTwÞ4 145 where ew is the emissivity of the water surface, taken to be 0.97 (Brutsaert, 1982), r is the Stefan–Boltzmann constant (4.899 · 106 kJ/m2 dK4), and Tw is the water temperature (K). Net longwave radiation was estimated as open longwave radiation (multiplied by the view factor correction) plus terrestrial longwave radiation emitted to the stream minus the longwave radiation emitted by the stream. Latent heat flux (Hle) was estimated using the method based on Shulyakovskiy (1969) and modified by Ryan et al. (1974). This method was chosen because it accounts for free convection effects. Ground water inputs can cause stream temperature to deviate significantly from air temperature, when large temperature gradients exist between the stream and overlying air mass, free convection may affect evaporative losses for these streams (DeWalle, 1976). The modified Ryan et al. (1974) equation for evaporative energy losses is: Hle ¼ 0:00451 U2 þ 0:00379ðT wv T av Þ1=3 ðew ea Þ where U2 is wind speed at 2 m elevation, Twv is virtual temperature for saturated air at the water temperature in C, Tav is virtual temperature for air at 2 m height in C, ew is the saturation vapor pressure at the water temperature, and ea is the vapor pressure of the air at 2 m height. For this equation positive values indicate energy losses from the stream to the atmosphere. For the purposes of stream evaporation calculations, wind speed data were corrected for elevation to 2-m. Elevation corrections for wind speed were performed using the power law approximation (Brutsaert, 1982, p. 63), where U2 m = U10 m/(10 m/2 m)1/7 for a wind speed correction of 80% of the 10 m wind speed. Radiation and meteorological data collected at the Rock Springs station along with water temperature data measured at the stream sites were used to estimate energy fluxes to and from Thompson Run and Lower Buffalo Run. Wind speed (U) and relative humidity (e) data were measured at 10 m elevation. For the purposes of stream evaporation calculations, these data were corrected for elevation to 2-m; a depth commonly used in stream and lake evaporation studies (i.e., Lee and Swancar, 1996). A correction for vapor pressure profiles was adapted from DeWalle (1976) to convert vapor pressure estimates from 10 m elevation to 2 m elevation at the stream sites; the subscript w indicates measurements at the water surface. The following equation was used e2 m = ew + (e10 m ew) · 0.80. A similar approach was used to correct air temperature measurements. With T2 m = Tw + (T10 m Tw) · 0.80. To account for the sheltering effects at streams due to vegetation and topography a constant coefficient of 0.6 was multiplied by the wind speed previously corrected to 2 m height for all stream sites. Open wind speed varies with distance from vegetation and density of vegetation. The riparian vegetation found along the valley streams of the Spring Creek watershed is typically low density and ranges in elevation from 1 to 30 m. Sheltering due to forest vegetation may cause wind speed to drop by as much as 40% of open wind speed (Oke, 1987 p. 244). More recently, Bogan et al. (2003) found that for 156 streams in the eastern and central US the median sheltering effect was approximately a 20% reduction of open wind speed. Since the streams they studied were larger than those found in the Spring Creek 146 M.A. O’Driscoll, D.R. DeWalle watershed it is likely that the sheltering coefficient for these streams reduces wind speed by more than 20% because of the lower ratio of stream width to vegetation height in the Spring Creek watershed. It was assumed that shelter effects fell between 60% and 20% reduction of open wind speed and for this study a 40% reduction of open wind speed at 2 m elevation was used. A combined coefficient accounting for elevation (0.8) and sheltering effects (0.6) on wind speed was 0.48 times the open wind speed measured at 10 m. Virtual temperatures were used to calculate the evaporative energy losses as laid out in Brutsaert (1982, p. 37– 38). The virtual temperature is defined as the temperature dry air should have in order to have the same density as moist air at a given specific humidity, temperature, and total air pressure. Saturation vapor pressure at the water surface was estimated from the following equation from Richards (1971): ew = 1013.25exp(13.3185 · tr 1.976 · tr2 0.6445tr3 0.1299tr4) where tr = 1 (373.15/T) in which T is the temperature at the water surface in Kelvin. Vapor pressure in the air was calculated by calculating saturation vapor pressure from air temperature and multiplying by relative humidity/100. The Bowen ratio (b) is the ratio between sensible heat flux (Hc) and latent heat flux (Hle). The Bowen ratio was calculated from the following equation: b = (0.61 · P(Tw Ta)/(ew ea))/1000 where P is barometric pressure in mbar, Tw is water temperature, Ta is air temperature at 2-m height, ew is vapor pressure at the water surface in mbars, ea is vapor pressure of the air at 2-m height in mbars. When the difference between ew and ea is very small, the Bowen ratio becomes excessively large; therefore a minimum value for the vapor pressure difference was set at 0.1 for computations. Sensible heat flux (Hc) was calculated as: Hc = b · Hle. Heat conduction in the channel bottom was assumed negligible. Results Hydrology and energy flux across the air–water interface for a ground water-fed stream segment (Thompson Run) and a seasonally losing stream segment (Lower Buffalo Run) For the stream segments at Thompson Run and Lower Buffalo Run, both streams had similar mean flow rates over the study period (Thompson Run = 0.27 m3/s, Buffalo Run = 0.30 m3/s) but differed in flow variability with Thompson Run behaving more steadily (coefficient of variation of flow = 63%) than Buffalo Run (coefficient of variation of flow = 125%), due to steady spring inputs from Thompson Spring. The temperature regime was far less variable at Thompson Run, with a coefficient of variation for weekly average water temperature of 23% for Thompson Run, versus 60% for Lower Buffalo Run water temperatures over the 3-year period. The weekly average surface water–air temperature relations for the 3-year period differed markedly for Buffalo Run and Thompson Run (see Table 2 and Figs. 3 and 4). Thompson Run surface waters showed much less variability with air temperature and the slope of the water–air temperature relationship was 0.272, compared to a value of 0.672 for Lower Buffalo Run. Thompson Run had a water–air temperature intercept of 8.44 C, whereas Lower Buffalo Run had an intercept of 3.61 C. A deviation from the water–air temperature relationship occurred during the last week of January 2000 along Buffalo Run because of an unseasonably warm period, where daily average air temperatures almost reached 8 C on 1/29/02. The importance of different sources of energy losses from the stream–air interface was similar for both Buffalo Run and Thompson Run, with radiation inputs providing an 30 Temperature (Degrees-C) 25 AIR BUL TR 20 15 10 5 0 -5 -10 Oct- Dec- Mar- Jun- Sep- Dec- Mar- Jun- Sep- Dec- Mar- Jun- Sep99 99 00 00 00 00 01 01 01 01 02 02 02 Figure 3 Seasonal variation of weekly moving average air temperature and stream temperature at Lower Buffalo Run and Thompson Run for the three-year study period (October 1999–September 2002). St ream W ate r T empe rat ure (Degrees- C) Stream–air temperature relations to classify stream–ground water interactions in a karst setting 147 30 25 Lower Buffalo Run 20 15 Thompson Run 10 5 0 -10 -5 0 5 10 15 Air T emperature (Degrees-C) 20 25 30 Figure 4 Weekly average water temperature versus air temperature relationships for Thompson Run and Lower Buffalo Run sites for the three-year study period (October 1999–September 2002). average net input of 99 W/m2 at Thompson Run and 93 W/ m2 at Lower Buffalo Run (see Fig. 5), the difference was due to shading. Longwave energy losses were greater at Thompson Run (average loss of 37 W/m2) and Buffalo Run had an average loss of 30 W/m2 over the study period due to slightly warmer stream waters at Thompson Run (Thompson Run, 3-year average – 11.32 C; Buffalo Run, 3-year average – 10.64 C). Latent heat losses were the next in importance with Thompson Run having greater average latent heat losses (19 W/m2) than Lower Buffalo Run (11 W/ m2). Latent heat losses generally peaked during the winter months due in part to large gradients in temperature and vapor, during this time of year latent heat losses were typically much larger at Thompson Run. Average sensible heat losses were slightly lower than latent heat losses for the 3-year period (17 W/m2 – Thompson Run and 8 W/m2- Buffalo Run). Average net energy exchange for the three-year period was 63 W/m2 for Thompson Run and 74 W/m2 for Lower Buffalo Run. The difference is due to larger longwave radiation, latent, and sensible heat losses from Thompson Run during winter months. Net energy exchange was corrected by dividing by depth to account for different volumes of water underlying the air–water interface for each site. When depth is considered, the net energy exchange across the air–water interface has a larger influence on Buffalo Run (see Fig. 6). The influence is most pronounced during the summer months. This explains the greater maximum water temperatures observed during summer at Buffalo Run and greater diurnal variability in water temperatures when compared to Thompson Run. Water temperature–air temperature relations within Spring Creek Watershed Weekly moving average stream temperatures versus weekly moving average air temperatures for all 12 study locations for the period of October 1, 1999 through September 30, Energy Flux (Watts/m2) 160 140 Thompson Run 120 Lower Buffalo Run 100 80 60 40 20 0 -20 -40 -60 Net Solar Net Longwave Net Radiation Net Hle Net Hc Net Heat Flux (Qn) Figure 5 Average net energy flux across the air–water interface for Thompson Run and Lower Buffalo Run for the three-year study period (October 1999–September 2002). M.A. O’Driscoll, D.R. DeWalle Energy Flux/Unit Area*Depth (Watts/m3) 148 3000 Lower Buffalo Run 2500 2000 1500 1000 500 0 Thompson Run -500 -1000 Aug-99 Feb-00 Aug-00 Feb-01 Aug-01 Feb-02 Aug-02 Figure 6 Weekly moving average energy flux/stream depth for Thompson Run and Lower Buffalo Run for the three-year study period (October 1999–September 2002). 2002 are summarized in Table 2. All stream–air temperature relations were linear and R2 values ranged from 86.5% for Upper Spring Creek, to 98.0% for Spring Creek Milesburg. Slopes to the regression lines ranged from 0.185 (Lower Logan Run) to 0.672 (Lower Buffalo Run) with an average slope of 0.472. Intercepts ranged from 9.07 C (Lower Logan Run) to 3.23 C (Upper Buffalo Run) with an average intercept of 6.17 C. All p values for both slopes and intercepts were <0.001. Several of the streams had periods when they ceased to flow and during other periods water temperature data were missed due to technical difficulties. Overall, n values ranged from 502 to 1096. Sites with lower n values were streams that dried up during summer months, the relations at these streams may be seasonally biased because they typically contain fewer warm temperature points. A comparison of intercepts versus slopes for the surface water–air temperature relations for all stream measurement locations revealed that there was an inverse relationship between the slope and intercept of the surface water– air temperature regression lines. The slope of this relationship was 10.306 with a y-intercept of 11.061 C and an R2 value of 89.4% (see Fig. 7). 12 Discharge variations within the spring creek watershed Discharge variations within the watershed were studied to help determine the spatial and temporal variability of ground water inputs in the watershed. Streamflow ceased at several of the stream monitoring locations during the period of October 1999–September 2002. Specifically, the stream dried up at Buffalo Run Upper (BUU) from July 7, 2001 to March 15, 2002 and from August 2, 2002–September 30, 2002 and at Slab Cabin Run Lower (SLL) from September 9, 2000 until January 29, 2001 and again from July 31, 01 until December 31, 2001 with only short periods of runoff occurring within these periods. The stream had zero flow at Slab Cabin Run Upper (SLU) from August 30, 2000 through November 25, 2000, then July 15, 2001–March 19, 2002. Several studies have shown both Buffalo Run and Slab Cabin Run to be seasonally losing or perched (Moorshead, 1975; Krothe and Parizek, 1979; O’Driscoll and Dewalle, 2002; O’Driscoll, 2004). Stream losses between nested gages occurred for brief periods along most streams, with the exception of Logan Intercept (C) = -10.306 (Slope) + 11.061 R2 = 0.8942 Groundwater Control 10 Intercept (C) LOL TR 8 LOU SPU SPA SPM 6 SLL SLU CR SPH 4 BUU BUL Meteorological Control 2 0 0 0.2 0.4 0.6 0.8 1 Slope Figure 7 A summary of slope versus intercept of the weekly air–water temperature relationships (October 1999–September 2002) for the 12 study locations (site locations listed in Table 1). Stream–air temperature relations to classify stream–ground water interactions in a karst setting Difference in Discharge Downstream (m3/s) Branch and the Spring Creek Milesburg reaches. During the period of August 24, 2005–September 16, 2005, no rainfall occurred within the watershed. The differences in runoff between nested gages on September 15, 2005 provided an indication of stream reaches that were receiving the largest ground water inputs (see Fig. 8). Based on this analysis the greatest ground water inputs occurred between Spring Creek Axemann and Spring Creek Milesburg and between Upper and Lower Logan Branch. Ground water inputs were weak or non-existent along Slab Cabin Run, Buffalo Run, and between Upper Spring Creek and Houserville stations. Streamflow-duration curves also reveal the differences in streamflow variability between losing (Buffalo Run and Slab Cabin Run) and gaining streams (Thompson Run and Logan Branch) (see Fig. 9). The nested discharge data and flow 149 duration curves both indicate that of the streams studied Slab Cabin Run and Buffalo Run both exhibited periods of little to no stream gains and did not commonly receive large ground water inputs. Discussion Energy–flux at the air–water interface for Thompson Run and Lower Buffalo Run The one-dimensional heat advection equation describes stream temperature variations in time and space (Mohseni and Stefan, 1999): AoT=ot þ oðQTÞ=ðoxÞ ¼ bS=qw Cpw 3.0 2.5 2.0 1.5 1.0 0.5 0.0 -0.5 Spring CreekUpper to Houserville Slab Cabin Buffalo RunSpring Run- Upper Upper to Creekto Lower Lower Houserville to Axemann Logan Branch Upper to Lower Spring CreekAxemann to Milesburg Figure 8 The differences in streamflow between nested gages (downstream–upstream discharge) on September 15, 2002. Discharge is presumed to be groundwater as rainfall did not occur in the watershed between August 24 and September 16, 2002. Daily discharge (cm/day) 1.E+01 1.E+00 LOL 1.E-01 TR BUL 1.E-02 1.E-03 SLL 1.E-04 1.E-05 BUL LOL TR SLL 1.E-06 0 20 40 60 80 Percent of time daily discharge equalled or exceeded 100 Figure 9 Streamflow-duration curves for Lower Logan Branch, Thompson Run, Lower Buffalo Run, and Lower Slab Cabin Run sites for the period of October 1999–September 2002. 150 M.A. O’Driscoll, D.R. DeWalle where A is the flow cross-sectional area, oT is water temperature change, ot is time interval, Q is streamflow, T is water temperature, ox is distance downstream, b is average stream width, S is net heat exchange across the air–water interface, qw is density of water, and Cpw is heat capacity of water. Streams receiving significant ground water inputs should have large advective terms (o(QT)/(ox)) that decrease in importance with distance from the ground water source. During the summer, ground water inputs will act as a heat sink along a stream reach. During the winter, ground water inputs will act as a heat source. The importance of the advection of ground water to stream temperatures at Thompson Run and Lower Buffalo Run can be shown directly by a comparison of the advective term of the heat advection equation for the two streams. At Thompson Run large stream temperature gradients exist between Thompson Spring and the Thompson Run temperature measurement station, in contrast to very small temperature gradients from Upper to Lower Buffalo Run stations (see Fig. 10). This indicates that advection of ground water is of little importance to stream temperatures at Lower Buffalo Run, but very important to Thompson Run stream temperatures. Overall, the net energy gains and losses from both streams are dominated by longwave and shortwave radiation fluxes and the latent heat and sensible heat losses were generally of lesser importance. Greater net energy losses in winter and gains in summer were exhibited by Thompson Run when compared to Buffalo Run. Since Thompson Run water temperature variations are subdued annually, periods of extreme air temperatures in winter and summer promote large temperature gradients and greater net energy exchange across the air–water interface. Water temperature–air temperature relations In the Spring Creek watershed, upstream water typically includes mountain runoff, seeps, and spring discharges. The discharges from major springs and their constant temperatures provide large sources of energy during winter and act as energy sinks in the summer. Meteorological energy inputs or losses gain importance with distance from the major ground water inputs. As distance from a spring or seep increases, the meteorological influence on water temperature increases in the absence of additional ground water inputs. In some cases, where losing conditions are present, stream depth may also decrease downstream and thus the meteorological influences may have greater effects on stream temperature. A comparison of the slope and intercept of the stream– air temperature relationship for all 12 locations indicates that the stream–air temperature relationship can reveal information about the nature of the controls on stream water temperatures, with ground water control segments indicated by intercepts closer to the regional ground water temperature and gentle slopes, and streams that are more influenced by meteorological energy inputs having steeper slopes and lower intercepts (see Fig. 7). Stream segments with strong ground water controls on water temperature include Lower Logan Branch, Thompson Run, and Upper Spring Creek. All are located within 2 km of springs and seeps. Buffalo Run and Slab Cabin Run are streams that have water temperatures that are responsive to meteorological conditions, these are generally seasonally losing streams. These streams typically cease to flow along several upland segments during dry periods, particularly in late summer. The Spring Creek Axemann site may have artificially elevated water temperatures due to wastewater and fish hatcheries discharges upstream that counteract the influence of spring inputs, particularly during summer months. In a study of 39 streams in Minnesota, Pilgrim et al. (1998) studied weekly stream–air temperature relations and found an average intercept of 1.7 C and slope of 0.99. In a similar study, for 11 streams within the Mississippi River basin, Stefan and Preud’homme (1993) found an average intercept of 2.9 C and slope of 0.86. These analyses were based on records from US Geological Survey gaging stations, which are likely along larger streams than those within the Spring Creek watershed. Within the Spring Creek watershed the average intercept was 6.14 C and the aver- 0.0003 degrees-C/second 0.0002 Thompson Run 0.0001 0 -0.0001 -0.0002 Lower Buffalo Run -0.0003 -0.0004 -0.0005 Jul99 Nov- Mar99 00 Jul00 Nov- Mar00 01 Jul01 Nov- Mar01 02 Jul02 Oct02 Feb03 Figure 10 The influence of advection on water temperatures as indicated by stream velocity (U) times the downstream temperature gradient (dT/dx). Missing data for Buffalo Run from July 2001–March 2002 is due to the lack of streamflow at Upper Buffalo Run. Stream–air temperature relations to classify stream–ground water interactions in a karst setting age slope was 0.47. The differences in stream–air temperature relations in the Spring Creek watershed are related to the importance of ground water inputs to streamflow. In a recent study by Webb et al. (2003) four streams in the Exe Basin, Devon, UK, were found to have weekly stream–air temperature regression slopes of 0.590–0.946 and intercepts ranging from 1.27 to 4.24 C for ground water-fed stream catchments ranging from 2.1 to 601 km2. To illustrate the importance of ground water inputs to the stream–air temperature relationships within the Spring Creek watershed a two-component mixing model was used with Lower Buffalo Run data to simulate the response of the stream–air temperature relationship to increased ground water inputs. Regional ground water temperature is approximately 10.9 C in the Spring Creek watershed (Langmuir, 1971). Simulations mixed incremental fractions of 10.9 C ground water with stream water of measured temperatures (average for October 1999–September 2002) at Lower Buffalo Run using the following equation: Simulated mixed temperature ¼ ½ð1 fraction of ground water inputÞ measured stream temperature at Lower Buffalo Run þ ½ðfraction of ground water inputÞ ground water temperature ð10:9 CÞ Intercept (degrees-C) Ground water inputs of 10–90% of total streamflow were simulated at 10% increments. The slopes of the simulated stream–air temperature relationship ranged from 0% for 100% ground water, to 0.672% for 100% stream water (see Fig. 11). The relationship of the slope versus intercept was represented by a line with a slope of 11.064 and an intercept of +10.9. This line is very similar to the line representing the range of slope and intercept stream–air temperature relationship values calculated for the 12 points in the Spring Creek watershed (see Fig. 7) with a slope of 10.306 and an intercept of +11.061. These simulations support the importance of advection of ground water as a control on stream temperatures in this valley, assuming that other factors are not contributing to the water temperatures. The link between stream–air temperature relations and hydrology in Spring Creek Basin is more directly shown by 12 100% 11 10 9 8 7 6 5 4 3 0.0 90% 151 comparing average hydrologic yield (streamflow/watershed area) and the slope and intercept of the stream–air temperature relationship (see Fig. 12). Streams with large hydrologic yields have significant ground water inputs that are translated to the gaging stations and damp the effects of meteorological controls on stream temperature. Lower hydrologic yield streams such as Buffalo Run and Slab Cabin Run tend to lose water through their channels, more drainage occurs in the subsurface; therefore they have lower ground water inputs, lower flow rates, and stream depths allowing stream temperatures to be more influenced by meteorological conditions. Based on an equilibrium temperature analyses, Mohseni and Stefan (1999) found that the slope of the air temperature–equilibrium temperature relationship for streams where advective inputs are not significant heat sources is related to the ratio of the emission of thermal radiation from the atmosphere plus the sensible heat loss versus the emission of longwave radiation from the water body plus the sensible heat loss. The intercept is a complicated function that relates solar and longwave radiation inputs, evaporative, and sensible heat losses. In the Spring Creek watershed, large springs and seeps are common and the slope and intercept of the air–stream temperature relationship is related to the magnitude of ground water inputs, the distance from the ground water input source, as well as the meteorological conditions. These results indicate that the slope and intercept of the stream–air temperature relationship are good indexes of the importance of ground water inputs to streams in karst settings. A direct comparison of the importance of the meteorological influence on stream temperatures between two streams can be obtained by the comparison of the slopes of their stream–air temperature relationship. From a watershed management perspective, stream shading would be less effective in moderating stream temperatures in strongly ground water-fed segments (revealed by gentle slopes and large intercepts) but more effective along losing reaches or stream reaches distant from ground water inputs, as indicated by the air–water temperature relationship. Ground water withdrawals that affect springflows also have the potential to affect stream temperatures, the loss in ground water inputs would result in 80% 70% intercept = -11.064(slope) + 10.9 60% 50% 40% 30% 20% 10% 0.1 0.2 0.3 0.4 0.5 0.6 0% 0.7 Slope Figure 11 The computed relationship of slope versus intercept of the weekly air–water temperature relationship for a twocomponent mixing model with end members consisting of 10.9 C ground water and stream temperatures measured at Lower Buffalo Run over the course of the three-year study period. Each fraction indicates a 10% increase in groundwater input. M.A. O’Driscoll, D.R. DeWalle Intercept (degrees-C) and Slope 152 10 9 8 7 6 5 4 3 2 1 0 intercept = 17208(hydrologic yield) + 4.0945 2 R = 0.7273 Intercept Slope 0 0.00005 0.0001 slope= -1529.2(hydrologic yield) + 0.6572 2 R = 0.6634 0.00015 0.0002 0.00025 0.0003 0.00035 3 Hydrologic Y ield (m /s/ha) Figure 12 The relationships between average hydrologic yield (October 1999–September 2002) of the 12 study locations and the associated slope and intercept of the water–air temperature relationship for those locations. greater meteorological controls on stream temperature and greater water temperature variability. For example, using the simple two-component mixing model for Buffalo Run, for a mid-summer week, if ground water flows to the stream dropped 30%, then weekly average stream temperatures would rise more than 3 C. Conclusions Hydrological and water temperature data revealed a large degree of spatial and temporal variability in the stream– ground water interactions in this carbonate watershed. Streams only several kilometers apart showed large differences in streamflow and water temperature regimes, a characteristic of carbonate watersheds. Correction of stream energy fluxes for streams with significant riparian shade are especially problematic and significant due to vegetative impacts on wind speeds and both longwave and shortwave radiative fluxes. Subdued temporal variations in surface water temperature alone can be indicative of ground water inputs, but consideration of the stream–air temperature relationship can help to indicate the strength and proximity of the ground water input signal. Stream settings ranged from strongly ground water-fed to seasonally losing. The nature of the stream–air temperature relationship indicated the importance of ground water advection versus meteorological controls on stream temperatures. The slopes and intercepts of the stream–air temperature relations indicated that an effect of ground water advection is apparent in their range of slopes and intercepts as is evident by the maximum intercept of 9.07 C at Lower Logan Branch. As a management tool, stream–air temperature relations can reveal the importance of ground water inputs, particularly in smaller watersheds where the travel time of surface waters is short enough to allow surface waters to carry thermal evidence of ground water inputs. Records of stream–air temperature relations over time can be indicative of changing hydrological regimes. For instance, if ground water withdrawals were pirating significant amounts of ground water from a stream, the slope and intercept of the air–water temperature relationship at a point along a channel would increase and decrease, respectively. At a lar- ger scale, the spatial and temporal variability of water temperature in a carbonate watershed may be estimated by remote sensing. 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