MSDS TOC
(Note: Italicized prefixes are not considered for the alphabetization of names)
Acetamide
1
4-Acetamidobenzenesulfonamide
2
4-Acetamidobenzenesulfonyl Chloride
3
Acetaminophen
197
Acetanilide
4
Acetic Acid (glacial)
5
Acetic Anhydride
6
Acetone
7
p-Acetophenetidide
8
Acetophenone
9
Acetylsalicylic Acid
10
Adipic Acid
11
L-Alanine
12
Allyl Bromide
13
Alumina
16
Aluminum
14
Aluminum Chloride (anhydrous)
15
Aluminum Oxide
16
4-Aminobenzoic Acid
17
2-Aminobenzenesulfonic Acid
18
3-Aminobenzenesulfonic acid
19
4-Aminobenzenesulfonic Acid
20
3-(4-Aminophenyl)propanoic acid
21
3-Aminophthalhydrazide
22
Ammonium 8-Anilino-1-naphthalenesulfonate
23
Ammonium Formate
24
Ammonium Hydroxide
25
i
Aniline
26
trans-p-Anisalacetophenone
27
p-Anisaldehyde
28
p-Anisic acid
29
Anisole
30
Aspirin
10
Azobenzene
31
1,1’–Azo-bis-(cyclohexanecarbonitrile)
32
Baker’s Yeast
33
Basic Fuchsin
299
Benzaldehyde
34
Benzamide
355
Benzanilide
36
Benzenesulfonyl Chloride
37
Benzilic Acid
38
Benzocaine
168
Benzoic Acid
39
Benzoyl Chloride
40
Benzyl Bromide
41
Benzyl Cinnamate
42
Benzyl 3-Phenylpropanoate
43
Benzyltriphenylphosphonium Chloride
44
exo-Bicyclo[2.2.1]heptane-2-ol
261
Bicyclo[2.2.1]hept-2-ene
260
cis-Bicyclo[2.2.1]hept-5-ene-endo-2,3-dicarboxylic Acid
45
cis-Bicyclo[2.2.1]hept-5-ene-endo-2,3-dicarboxylic Anhydride
46
2,2-Bipyridyl
47
Bleach
48
Boileezer
16
ii
Borane-THF Solution
49
Brine
50
Bromine
51
Bromobenzene
52
Bromocyclohexane
53
2-Bromoacetanilide
54
4-Bromoacetanilide
55
2-Bromoanisole
56
4-Bromoanisole
57
4-Bromobenzyl Alcohol
58
1-Bromobutane
59
1-Bromoethylbenzene
60
2-Bromohexane
61
2-Bromonitrobenzene
62
4-Bromonitrobenzene
63
2-Bromophenol
64
4-Bromophenol
65
1-Bromopropane
66
4-Bromo-2-chloroacetanilide
67
4-Bromo-2-chloroaniline
68
4-Bromo-2-chloro-6-iodoaniline
69
1-Bromo-3-chloro-5-iodobenzene
70
1-Bromo-2,4-dinitrobenzene
71
2-Bromo-2-methylbutane
72
1-Bromo-2-naphthol
73
Butanedioic Acid
334
1-Butanol
74
2-Butanol
75
2-Butanone
76
iii
3-Buten-2-one
77
N-tert-Butoxycarbonyl- L-alanine
78
1-Butyl Benzoate
80
1-Butyl Ethanoate
79
n-Butyl Acetate
79
n-Butyl Benzoate
80
tert-Butyl Peroxybenzoate
81
1-Butyl Propanoate
82
n-Butyl Propionate
82
n-Butylbenzene
83
sec-Butylbenzene
84
tert-Butylbenzene
85
Calcium Chloride
86
Calcium Hypochlorite
87
Caraway Seed Oil
88
Carbon (decolorizing)
89
Carbon Dioxide, solid
163
Carborundum
304
Carvone
90
Celite
91
Ceric Ammonium Nitrate
92
4-Chloroacetanilide
93
Chloroacetyl Chloride
94
4-Chlorobenzaldehyde
95
Chlorobenzene
96
2-Chlorobenzoic Acid
97
4-Chlorobenzoic Acid
98
4-Chlorobenzyl Alcohol
99
1-Chlorobutane
100
iv
4-Chlorocinnamic Acid
101
α-Chloro-2,6-dimethylacetanilide
102
Chloroform
103
Chloroform-d
104
2-Chloro-2-methylbutane
105
3-(4-Chlorophenyl)propanoic Acid
106
Chloroplatinic Acid
107
Chlorosulfonic Acid
108
Chromic Anhydride
109
Cinnamaldehyde
110
(E)-Cinnamic Acid
111
N-Cinnamyl-m-nitroaniline
112
N-Cinnamylidene-m-nitroaniline
113
Citral
114
Copper
115
Cupric Acetate
116
Cupric Sulfate (pentahydrate)
117
Cuprous Bromide
118
Cyclododecanol
119
Cyclododecanone
120
Cyclohexane
121
Cyclohexane-cis-1,2-dicarboxylic Acid
122
cis-1,2-Cyclohexanediol
123
trans-1,2-Cyclohexanediol
124
Cyclohexanol
125
Cyclohexanone
126
Cyclohexanone Semicarbazone
127
Cyclohexyl Bromide
53
Cyclohexene
128
v
4-Cyclohexene-cis-1,2-dicarboxylic Acid
129
1,3-Cyclopentadiene
130
Decanedioyl Dichloride
131
DEET
146
DMF
153
Deuteriochloroform
104
Dibasic Potassium Phosphate
132
Di-tert-butyl Dicarbonate
133
m-Dichlorobenzene
134
o-Dichlorobenzene
135
1,2-Dichlorobutane
136
1,3-Dichlorobutane
137
1,4-Dichlorobutane
138
Dichloromethane
139
Dicyclopentadiene
140
Diethyl Benzylphosphonate
141
Diethyl Ether (anhydrous and technical/solvent grades)
142
Diethylamine
143
N,N-Diethyl-2,6-dimethylacetanilide
144
Diethylene Glycol
145
N,N-Diethyl-m-toluamide
146
Dimethyl Fumarate
147
Dimethyl Maleate
148
Dimethyl Sulfoxide
149
2,6-Dimethylaniline
150
2-(2,4-Dimethylbenzoyl)benzoic Acid
151
4,4-Dimethyl-2-cyclohexen-1-one
152
N,N-Dimethylformamide
153
2,6-Dimethylnitrobenzene
154
vi
1,3-Dinitrobenzene
155
3,5-Dinitrobenzoic Acid
156
3,5-Dinitrobenzoyl Chloride
157
3,5-Dinitrophenylhydrazine
158
1,4-Dioxane
159
Diphenyl Ether
160
Diphenylacetylene
161
Disodium Hydrogen Phosphate
162
DMSO
149
Dry Ice
163
DMF
153
Ethanol (anhydrous)
164
Ethanol (95%)
165
Ethyl Acetate
166
Ethyl Acetoacetate
167
Ethyl 4-Aminobenzoate
168
Ethyl Benzoate
169
Ethyl Ethanoate
166
Ethyl p-Hydroxybenzoate
170
Ethyl 6-Methyl-2-oxo-4-phenyl-1,2,3,4-tetrahydropyrimidine-5-carboxylate
171
Ethyl Propanoate
172
Ethyl Propionate
172
Ethylbenzene
173
Ferric Bromide
174
Ferric Chloride
175
Ferrous Ammonium Sulfate
176
Filter Aid
91
Fluorene
177
9-Fluorenone
178
vii
Fluorescein
179
4-Fluorocinnamic Acid
180
3-(4-Fluorophenyl)propanoic Acid
181
Formic Acid
182
D-Fructose
183
2-Furaldehyde
184
2-Furaldehyde Semicarbazone
185
Furfural
184
Glass Wool
186
D-Glucose
17
tris-[3-(Heptafluoropropylhydroxymethylene)-(+)-camphorato]europium
188
Heptane
189
Hexane
190
1,6-Hexanediamine
191
Hexamethylenediamine
191
1-Hexene
192
Hydrazine (8%)
193
Hydrobromic Acid (concentrated)
194
Hydrochloric Acid (solutions, 9-37%)
195
Hydrogen Peroxide (solutions, 3–30%)
196
4-Hydroxyacetanilide
197
Hydroxylamine Hydrochloride
198
3-Hydroxy-3-methyl-2-butanone
199
Iodine
200
Iodine Monochloride
201
Isobutyl Chloroformate
202
Isobutylbenzene
203
Isobutyraldehyde
228
(-)-Isopinocampheol
204
viii
Isopropyl Alcohol
291
Isopropylbenzene
205
Isopropylxylenes
206
Lead Acetate
207
Lemongrass Oil
208
Luminol
22
Magnesium
209
Magnesium Sulfate (anhydrous)
210
Maleic Anhydride
211
Mercuric Oxide
212
Metanilic Acid
19
Methanol
213
Methyl Acetoacetate
214
Methyl L-Alanyl-L-phenylalaninate Tetrafluoroacetate
215
Methyl Alcohol
213
Methyl Benzoate
216
Methyl N-tert-Butoxycarbonyl-L-alanyl-L-phenylalaninate
217
Methyl Iodide
218
Methyl Isobutyrate
219
Methyl 2-Methylpropanoate
219
Methyl L-Phenylalaninate.Hydrochloride
220
Methyl Propanoate
221
Methyl Propionate
221
3-Methylbenzoic Acid
222
(+/-)-α-Methylbenzylamine
223
Methylcyclohexane
224
Methylene Chloride
139
N-Methylimidazole
225
N-Methylmorpholine
226
ix
4-Methylphenylboronic acid
227
2-Methylpropanal
228
Methyltrioctylammonium Chloride
229
4'-Methyl-(1,1’-biphenyl)-4-methanol
230
2-Methyl-2-butanol
231
2-Methyl-1-butene
232
2-Methyl-2-butene
233
2-Methyl-3-butyn-2-ol
234
2-Methyl-3-heptanol
235
4-Methyl-2-pentanol
236
2-Methyl-1-pentene
237
2-Methyl-2-pentene
238
4-Methyl-1-pentene
239
cis- and trans-4-Methyl-2-pentene
240
2-Methyl-1-propanol
241
2-Methyl-2-propanol
242
Mineral Oil
243
Naphthalene
244
2-Naphthalenesulfonic Acid
245
αNaphthol
246
1-Naphthol
246
Naphthol
247
2-Naphthol
247
1-Naphthyl Isocyanate
248
Nitric Acid (concentrated)
249
Nitric Acid (fuming)
250
3-Nitroaniline
251
4-Nitroaniline
252
Nitrobenzene
253
x
3-Nitrobenzyl Alcohol
254
4-Nitrobenzyl Alcohol
255
4-Nitrocinnamic Acid
256
3-(4-Nitrophenyl)propanoic acid
257
3-Nitrophthalhydrazide
258
3-Nitrophthalic Acid
259
Norbornene
260
exo-Norborneol
261
Nujol
243
Nutmeg
262
Nylon-6,10
263
Orthanilic Acid
18
Palladium on Carbon (10%)
264
Pentane
265
3-Pentanone
266
Petroleum Ether (30–60 °C)
267
Petroleum Ether (60–90 °C)
268
Phenacetin
8
Phenol
269
Phenolphthalein
270
3-Phenylpropanoic Acid
271
L-Phenylalanine
272
Phenylhydrazine
273
Phenylhydrazine Hydrochloride
274
Phenylmagnesium Bromide (1 M in THF)
275
p-Phenylphenol
276
Phthalic Anhydride
277
Picric Acid
278
(+)--Pinene
279
xi
Polystyrene
280
Potassium Bromide
281
Potassium tert-Butoxide
282
Potassium Carbonate
283
Potassium Chloride
284
Potassium Ferricyanide
285
Potassium Fluoride
286
Potassium Hydroxide
387
Potassium Iodide
288
Potassium Permanganate
289
1,3-Propanediol
295
Propanoic Acid
292
1-Propanol
290
2-Propanol
291
Propionic Acid
292
n-Propyl Alcohol
290
1-Propyl Benzoate
293
n-Propyl Benzoate
293
1-Propyl Propanoate
294
n-Propyl Propionate
294
Propylene Glycol
295
Pyridine
296
Pyridinium Tribromide
297
Resorcinol
298
p-Rosaniline Hydrochloride
299
Salicylamide
300
Salicylic Acid
301
Sand
305
Semicarbazide Hydrochloride
302
xii
Silica Gel (70-230 mesh)
303
Silicon Carbide
304
Silicon Dioxide [Sand]
305
Silver Nitrate
306
Sodium
307
Sodium Acetate (anhydrous)
308
Sodium Acetate (trihydrate)
309
Sodium Bicarbonate
310
Sodium Bisulfite
311
Sodium Borohydride
312
Sodium Bromide
313
Sodium Carbonate (anhydrous)
314
Sodium Chlorate
315
Sodium Chloride
316
Sodium Citrate (dihydrate)
317
Sodium Dichromate (dihydrate)
318
Sodium Hydrosulfite
319
Sodium Hydroxide
320
Sodium Hydroxide (50% solution)
321
Sodium Hypochlorite
322
Sodium Iodide
323
Sodium Lead Alloy
324
Sodium Nitrite
325
Sodium Nitroprusside
326
Sodium Sulfate (anhydrous)
327
Spearmint Oil
328
(E)-Stilbene
329
(Z)-Stilbene
330
d,l-Stilbene Dibromide
331
xiii
meso-Stilbene Dibromide
332
Styrene
333
Succinic Acid
334
Sucrose
335
Sulfanilamide
336
Sulfanilic Acid
21
3-Sulfolene
337
Sulfuric Acid (fuming)
338
Sulfuric Acid (solutions)
339
Sulfuryl Chloride
340
D-Tartaric Acid
341
L-Tartaric acid
342
TEMPO
345
Tetrachloroethylene
343
Tetrahydrofuran (anhydrous and solvent grades)
344
(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl
345
THF
344
Thionyl Chloride
346
Tin
347
Tin (II) Chloride
348
Tin(II) Chloride (dihydrate)
349
Toluene
350
p-Toluenesulfonic Acid
351
p-Toluic acid
352
p-Toluidine
353
Triethylene Glycol
354
Trifluoroacetic Acid
355
Trimyristin
356
Triphenylmethanol
357
xiv
Urea
358
m-Xylene
359
p-Xylene
360
Xylenes (mixture)
361
Zinc Chloride (anhydrous)
362
Zinc Oxide
363
xv
Acetamide
C2H5NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
60-35-5
Solid
Colorless
Distinct
174
221
80–82
1.159
10 @ 105
N/A
2
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Slight fire hazard.
Inhalation
Irritation, drowsiness, nausea, acidosis Ventilation, local
and skin eruptions. Irritating to
exhaust.
mucous membranes and upper
respiratory tract.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and may be absorbed through Protective gloves and
skin.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, corneal damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Drowsiness, fatigue, nausea, acidosis
and skin eruptions.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Avoid heat, sparks,
and flames.
First Aid/Fire
Suspected carcinogen.
Mutagenicity
Dry chemical powder,
carbon dioxide, water,
regular foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
1
4-Acetamidobenzenesulfonamide
C8H10N2O3S
CAS No.
121-61-9
PS
Solid
Types of
Hazard/Exposure
Color
Odor
FP
BP
MP
d
VP
VD
Sol
Off-white
N/A
N/A
N/A
219
N/A
N/A
N/A
Slightly
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under fire
conditions.
No open flames or Water spray, carbon
sparks.
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be irritating to the skin.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Dust, vapor, or mist may be irritating to the Safety goggles.
eyes.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Do not eat or
drink in the
laboratory.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100mL) at 25 °C unless otherwise state; N/A =
not available or not applicable.
2
4-Acetamidobenzenesulfonyl Chloride
C8H8ClNO3S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
121-60-8
Solid
Tan
Acetic acid-like
N/A
N/A
145–148
N/A
N/A
8.1
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks, Carbon dioxide, dry
no contact with hot
chemical powder, or foam.
surfaces.
Inhalation
Corrosive material, chemical burns,
coughing, wheezing, laryngitis,
headache, and vomiting.
Ventilation, local
exhaust.
Skin
Corrosive material, chemical burns.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Corrosive material, chemical burns.
Safety goggles.
Ingestion
Corrosive material, convulsions, muscle Do not eat or drink in Wash out mouth with
weakness, and symptoms as described in the laboratory.
water; if vomiting occurs,
acute ingestion.
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
3
Acetanilide
C8H9NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
103-84-4
Solid
White
Odorless
169
304
114
1.219
1 @ 114
4.7
0.5
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
Irritation, eczematous skin eruptions,
poisoning as in ingestion.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, contact dermatitis, skin
eruptions due to systemic poisoning.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, vomiting, sweating, gastric
irritation, chills.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
4
Acetic Acid (glacial)
C2H4O2
CAS No.
PS
64-19-7
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Vinegary
FP
BP
MP
d
VP
VD
Sol
39
118
N/A
1.049
11.8 @ 20
2.07
Soluble
Acute Hazards/Symptoms
Prevention
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam, alcoholresistant foam
Inhalation
Irritation, pharyngeal edema, chronic
bronchitis, coughing, shortness of
breath, laryngitis, pulmonary edema,
and hypotension.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, pain, blisters, burns and
superficial destruction of the skin;
readily absorbed through the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
water and 5% aqueous
sodium bicarbonate, and
seek medical advice.
Eyes
Irritation, lacrimation, corneal erosion, Safety goggles.
opacification, iritis, and possibly loss
of sight.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Severe ulceronecrotic lesions, stricture Do not eat or drink in
of the esophagus, diarrhea, shock,
the laboratory.
vomiting, abdominal spasms.
Seek medical advice. Give
large amounts of water
and allow vomiting to
occur; when vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
First Aid/Fire
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
5
Acetic Anhydride
C4H6O3
CAS No.
PS
108-24-7
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Vinegary
FP
BP
MP
54
138–140
-73
Acute Hazards/Symptoms
d
VP
1.0820 10 @ 36
Prevention
Sol
3.52
Reacts
First Aid/Fire
Fire
Moderate fire hazard. Vapors or
gases may ignite at distant ignition
sources, contact with water or moist
air may generate flammable and/or
toxic gases.
Inhalation
Severe irritation, cough, choking,
Ventilation, local
wheezing, chest pain, and pulmonary exhaust.
edema, which may be fatal.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, white, wrinkled skin,
blisters, and severe burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Pain, lacrimation, photophobia, and
blurred vision. Corneal and
conjunctival edema, iritis, corneal
erosion, and opacity may be delayed
effects.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Severe burns of the mouth,
esophagus, and stomach with pain,
difficulty swallowing, nausea,
vomiting, and diarrhea.
Do not eat or drink in
the laboratory.
Seek medical advice. Give
large amounts of water or
milk, and allow vomiting
to occur; when vomiting
occurs keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks,
no contact with hot
surfaces.
VD
Mutagenicity
Carbon dioxide, dry
chemical powder, alcoholresistant foam
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
6
Acetone
C3H6O
CAS No.
67-64-1
PS
Color
Odor
Liquid Colorless Paint thinner- like
Types of
Hazard/Exposure
FP
BP
MP
d
VP
VD
Sol
-17
56
-94
0.791
180 @ 20
2.0
Soluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors or gases may
ignite at distant ignition sources.
Inhalation
Irritation, dryness of the mouth and throat,
Ventilation, local
central nervous system depression, headache. exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, cellular damage to the outer layers Protective gloves
of the epithelium with edema and hyperemia, and clothing.
small amounts may be absorbed through
intact skin.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, corneal epithelial, conjunctival,
stinging sensation, and damage to eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Fruity odor of the breath and mucous
membrane, gastroenteric irritation, diarrhea,
nausea and vomiting.
Do not eat or
drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
No flames, no
Alcohol-resistant foam,
sparks, no contact carbon dioxide, dry
with hot sources. chemical powder, water.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
7
p-Acetophenetidide [Phenacetin]
C10H13NO2
CAS No.
PS
62-44-2
Solid
Types of
Hazard/Exposure
Color
Odor
FP
White Odorless N/A
BP
Decomposes
Acute Hazards/Symptoms
MP
d
134–135 N/A
VP
VD
Sol
N/A
N/A
0.0763
Prevention
First Aid/Fire
Fire
Slightly flammable.
No flames, no
sparks, no contact
with hot sources.
Inhalation
Cyanosis, dizziness, respiratory
depression.
Local exhaust or
Remove from exposure
breathing protection. immediately and seek
medical advice.
Skin
Possibly a mild irritant.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Possibly irritating to eye tissues.
Safety goggles, or
eye protection in
combination with
breathing protection.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Moderately toxic, causes cyanosis,
Do not eat or drink
dizziness, respiratory depression.
in the laboratory.
Cardiac arrest may occur. May result in
liver and kidney damage.
Induce vomiting
immediately and keep
head lower than hips.
Seek medical advice
immediately.
Possible carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
Water spray, dry chemical
powder, alcohol foam, or
carbon dioxide.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
8
Acetophenone
C8H8O
CAS No.
PS
Color
Odor
FP
BP
MP
98-86-2
Liquid
Colorless
Floral
82
203
19–20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
1.030 1 @ 15 4.14
Prevention
Sol
0.55 @ 20
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam
Inhalation
Irritation, coughing and central
nervous system depression with
headache, dizziness, and narcosis.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, pain, and mild
burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Severe reaction with only transient
optical irregularity of the corneal
epithelium.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, abdominal pain, nausea
Do not eat or drink in
and central nervous system depression the laboratory.
with headache, dizziness, and narcosis.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
9
Acetylsalicylic Acid [Aspirin]
C9H8O4
CAS No.
50-78-2
PS
Color
Solid
White
Types of
Hazard/Exposure
Odor
Odorless
FP
250
BP
N/A
N/A
Causes serious eye irritation.
Eyes
Harmful if swallowed.
Ingestion
Carcinogenicity
VD
Sol
N/A 3.3 g/L
First Aid/Fire
Dry chemical powder,
carbon dioxide, water,
alcohol-resistant foam.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Causes skin irritation.
Skin
VP
Prevention
May cause respiratory irritation.
Inhalation
d
134–136 1.340 3 x 10-6 @ 25
Acute Hazards/Symptoms
N/A
Fire
MP
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry.
Thoroughly wash skin
with soap and water, and
seek medical advice
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
If swallowed wash out
Do not eat or drink in the
mouth with water. Seek
laboratory.
medial advice.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
10
Adipic Acid
C6H10O4
CAS No.
PS
Color
124-04-9
Solid
White
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
Odorless 196
337
150–152
1.360
1 @ 159.5
5.04
1.4
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible.
No flames, no sparks,
no contact with hot
sources.
Dry chemical powder,
water spray, foam, carbon
dioxide.
Inhalation
Cough, labored breathing, sore
throat.
Local exhaust or
breathing protection.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
water and 5% aqueous
sodium bicarbonate, and
seek medical advice.
Eyes
Redness and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Slightly toxic.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
11
L-Alanine
C3H7NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
56-41-7
Solid
White
N/A
N/A
N/A
315–316
N/A
N/A
N/A
9
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks, no
contact with hot surfaces.
Carbon dioxide, water, dry
chemical powder, or
appropriate foam.
Inhalation
Irritation, sore throat, and
coughing.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, gastric pain, nausea, Do not eat or drink in the
vomiting, and allergic reactions. laboratory.
Do not induce vomiting.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
12
Allyl Bromide
C5H5Br
CAS No.
PS
106-95-6
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Unpleasant
FP
BP
MP
d
VP
VD
Sol
-1
70
-119
1.39
NA
NA
0.38
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable liquid and vapor.
No open flames or
sparks.
Dry chemical powder,
alcohol-resistant foam or
carbon dioxide. Water
may be ineffective.
Inhalation
Causes irritation to the respiratory
tract. Symptoms may include
coughing, shortness of breath. A
central nervous system depressant.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation to skin. Symptoms
include redness, itching, and pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Causes irritation to the gastrointestinal Do not eat or drink in
tract. Symptoms may include nausea, the laboratory.
vomiting and diarrhea.
Give water; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Possible carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
13
Aluminum
Al
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7429-90-5
Solid
N/A
N/A
N/A
N/A
660
2.7
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable. Emits toxic fumes Do not use near
under fire conditions.
ignition sources.
Water spray, carbon dioxide,
dry chemical powder or
appropriate foam.
Inhalation
May be harmful if inhaled.
Material may be irritating to
mucous membranes and upper
respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek medical
advice.
Skin
May be harmful if absorbed
through the skin. May cause skin
irritation.
Protective clothing and Remove contaminated
gloves.
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with water;
if vomiting occurs, keep head
lower than hips. Seek
medical advice immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
14
Aluminum Chloride (anhydrous)
AlCl3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7446-70-0
Solid
White
Pungent
N/A
N/A
190 @ 1900
2.44 @ 25
1 @ 100
4.5
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Carbon dioxide, dry
chemical powder.
Inhalation
Forms corrosive hydrochloric
acid on contact with moisture
and burns of the mucous
membranes.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, pain, and
possibly burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
water and 5% aqueous
sodium bicarbonate, and
seek medical advice.
Eyes
Redness, pain, blurred vision,
and corneal burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning pain in the mouth and
throat, severe burns of the
mucous membranes,
discoloration of the tissues,
vomiting, diarrhea, hemolysis,
kidney damage, and liver
damage with jaundice.
Do not eat or drink in the
laboratory.
Give water or milk; if
vomiting occurs, keep
head lower than hips; get
medical attention
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
15
Aluminum Oxide [Alumina, Boileezer]
Al2O3
CAS No.
PS
Color
1344-28-1
Solid
White
Types of
Hazard/Exposure
Odor
FP
BP
MP
Odorless N/A 2980
d
2053–2072
Acute Hazards/Symptoms
VP
VD
3.965 @ 25 1 @ 2158
Prevention
Sol
N/A Insoluble
First Aid/Fire
Fire
Not flammable.
N/A
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be harmful if inhaled.
Material may be irritating to
mucous membranes and upper
respiratory tract.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation. May
be harmful is adsorbed through
the skin.
Protective clothing and
gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
16
4-Aminobenzoic Acid
C7H7NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
150-13-0
Solid
White
N/A
N/A
N/A
188–189
1.374
N/A
N/A
0.539
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
No open flames or
sparks.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be harmful if inhaled. Irritating
to respiratory system. Do not breathe
in dust.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation. May cause
sensitization by skin contact.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
17
2-Aminobenzenesulfonic Acid [Orthanilic acid]
C6H7NO3S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
88-21-1
Solid
N/A
N/A
N/A
N/A
>300
N/A
N/A
N/A
19 g/L
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
N/A
N/A
Inhalation
Material is extremely destructive to the Ventilation, local
tissue of the mucous membranes and
exhaust.
upper respiratory tract.
Skin
May be harmful if absorbed through
skin. Causes skin burns
Eyes
Causes eye irritation. Causes eye
burns
Ingestion
May be harmful if swallowed
Carcinogenicity
Not a known carcinogen
First Aid/Fire
N/A
Remove from exposure
immediately and seek
medical advice.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
Do not eat or drink in If swallowed wash out
the laboratory.
mouth with water. Seek
medial advice.
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
18
3-Aminobenzenesulfonic acid [Metanilic acid]
C6H7NO3S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
121-47-1
Solid
White
N/A
N/A
N/A
>300
1.69
N/A
N/A
21 g/L
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
N/A
Inhalation
May be harmful if inhaled. Causes
respiratory tract irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed through
skin. Causes skin irritation
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice
Eyes
Causes eye irritation
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
Ingestion
May be harmful if swallowed
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medial advice.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
19
4-Aminobenzenesulfonic Acid [Sulfanilic Acid]
C6H7NO3S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
121-57-3
Solid
Colorless
N/A
N/A
N/A
>300
1.485
N/A
N/A
21 g/L
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
N/A
Inhalation
May be harmful if inhaled. Causes
respiratory tract irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed through skin. Protective gloves and
Causes skin irritation
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice
Eyes
Causes eye irritation
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
Ingestion
May be harmful if swallowed
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medial advice.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
20
3-(4-Aminophenyl)propanoic Acid
C9H11NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2393-17-1
Solid
Offwhite
N/A
166
351
133–137
1.217
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Forms oxides of carbon and nitrogen
upon combustion.
No open flames or
sparks.
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
May cause respiratory irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
Causes skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
Causes serious eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
21
3-Aminophthalhydrazide [Luminol]
C8H7N3O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
521-31-3
Solid
Yellow
N/A
N/A
N/A
319–320
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks, no Carbon dioxide, dry
contact with hot
chemical power, or
surfaces.
appropriate foam.
Inhalation
Irritation of the respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract,
vomiting, and diarrhea.
Do not eat or drink in the Do not induce vomiting.
laboratory.
Wash out mouth with
water. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
22
Ammonium 8-Anilino-1-naphthalenesulfonate
C116H16NO3S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
28836-03-5
Solid
N/A
N/A
N/A
N/A
242 °C
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
May cause respiratory tract irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice
Eyes
Causes serious eye irritation
Ingestion
May be harmful if swallowed
Carcinogenicity
Not a known carcinogen
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
Do not eat or drink in If swallowed wash out
the laboratory.
mouth with water. Seek
medial advice.
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
23
Ammonium Formate
CH5NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
540-69-2
Solid
White
Odorless
N/A
N/A
119–121
1.26
N/A
N/A 63.1 g/l at 20 °C
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Sol
First Aid/Fire
Fire
N/A
No flames, no, sparks, Use water spray, alcoholno contact with hot
resistant foam, dry
surfaces.
chemical or carbon
dioxide
Inhalation
May cause respiratory irritation.
Ventilation, local
exhaust
Remove from exposure
immediately and seek
medical advice
Skin
Causes skin irritation
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
Causes serious eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
24
Ammonium Hydroxide
H5NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1336-21-6
Liquid
Colorless
Pungent,
sharp
N/A
36
N/A
0.90
115 @ 20
1.2
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, headache, salivation,
nausea, vomiting, difficulty in
speaking, decreased respiratory
function, and inflammation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe pain, stinging sensation,
severe burns and vesiculation, and
possibly brownish stains.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Severe pain, loss of corneal
Safety goggles.
epithelium despite irrigation,
swelling of the eyelids, and increased
intraocular pressure.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate pain, circumoral burns,
Do not eat or drink in
corrosion of the mucous membranes, the laboratory.
profuse salivation, inability to
swallow or speak. Shock with
marked hypotension, weak and rapid
pulse, shallow respiration, and
clammy skin may occur.
Do not induce vomiting;
give large amounts of
water or milk; if vomiting
occurs keep head lower
than hips; get medical
attention immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
25
Aniline
C6H7N
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
62-53-3
Liquid
Colorless
Fish-like
70
184
N/A
1.0217
0.6 @ 20
3.2
3.5
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, regular
foam, alcohol-resistant
foam.
Inhalation
May cause effects as described under
ingestion.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, sensitization dermatitis,
Protective gloves and
readily absorbed through the skin, and clothing.
a small amount absorbed from clothes
or shoes may cause toxic symptoms as
described in acute ingestion.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and possible corneal
damage.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Headache, nausea, vomiting, chest or Do not eat or drink in
abdominal pain, dryness of the throat, the laboratory.
cyanosis, lips, tongue and mucous
membranes may be navy blue to black
and the skin may appear slate gray.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Possible carcinogen.
Possible mutagen.
Carcinogenicity
Safety goggles.
Mutagenicity
First Aid/Fire
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
26
trans-p-Anisalacetophenone
C16H14O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
959-33-1
Solid
Yellow
N/A
N/A
N/A
73–76
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
sources.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Irritant, may be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritatant, may be harmful to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice. Remove
contaminated clothing.
Eyes
Vapor or mist is irritating to the eyes,
may be harmful.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
27
p-Anisaldehyde
C8H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
123-11-5 Liquid Colorless Floral
116
118–121
-1
1.119– 1.123
133.5 @ 73
4.7
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, flames,
sparks.
Inhalation
N/A
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if ingested.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Dry chemical powder,
carbon dioxide, water,
regular foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
28
p-Anisic acid
C8H8O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
100-09-4
Solid
Beige
N/A
185
275–280
182–185
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Fire
Inhalation
Skin
Eyes
Ingestion
Carcinogenicity
Acute Hazards/Symptoms
Negligible fire hazard. Forms oxides
of carbon upon combustion.
May cause respiratory irritation.
Causes skin irritation.
Causes serious eye irritation.
Harmful if swallowed.
Not a known carcinogen.
Prevention
First Aid/Fire
No flames, no,
Carbon dioxide, water, dry
sparks, no contact chemical powder, or
with hot surfaces. appropriate foam.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek medical
advice.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with soap and water,
and seek medical advice
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice
Do not eat or
drink in the
laboratory.
If swallowed wash out mouth
with water. Seek medial
advice.
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
29
Anisole
C7H8O
CAS No.
PS
Color
Odor
FP
BP
MP
100-66-3
Liquid
Colorless
Licorice-like
43
155
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.9961 10 @ 42.2
Prevention
VD
Sol
3.7
Insoluble
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation, dizziness, or suffocation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Moderetely toxic in large amounts. May Do not eat or drink in
cause abdominal pain, nausea, vomiting the laboratory.
and diarrhea
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
30
Azobenzene
C12H10N2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
103-33-3
Solid
Orange
N/A
>143
293
69
1.203
1 @ 103
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and
flames.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Coughing, shortness of breath,
dizziness, dullness, bluish skin, and
faintness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, possibly absorbed through
intact skin with dizziness, dullness,
bluish skin and faintness, all
symptoms of methemoglobenimia.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, dizziness, dullness,
bluish skin, faintness, and
methemoglobinemia.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
31
1,1’–Azo-bis-(cyclohexanecarbonitrile)
C14H20N4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2094-98-6
Solid
White
N/A
N/A
N/A
115–118
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Capable of creating a dust No flames, no, sparks,
explosion. Container explosion may
no contact with hot
occur under fire conditions. Emits
surfaces.
toxic fumes under fire conditions.
Smother with dry sand,
limestone, or clay. A
Class D extinguisher may
be used.
Inhalation
May be harmful if inhaled. Irritating
to respiratory system. Prolonged
exposure can cause nausea, headache,
and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice. Remove
contaminated clothing.
Eyes
Irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
32
Baker’s Yeast
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Solid
Tan
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid heat, sparks and
flames.
Inhalation
Difficulty breathing.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective clothing and
gloves
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if ingested.
Do not eat or drink in the
laboratory
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical or
appropriate foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
33
Benzaldehyde
C7H6O
CAS No.
100-52-7
PS
Color
Odor
Liquid Colorless Almond-like
Types of
Hazard/Exposure
FP
BP
MP
d
VP
VD
Sol
63
178
-26
1.0415 @ 10
1 @ 26.2
3.65
0.29
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or
gases may ignite at distant ignition
sources.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Sore throat, and coughing, central
nervous system depression with
nausea, vomiting, headache,
lightheadedness.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, pain, weak local
anesthesia, possible absorption
through the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, lacrimation, redness, pain,
and eye injury.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, central nervous system
Do not eat or drink in the
depression, nausea, vomiting,
laboratory.
abdominal pain, headache, dizziness,
convulsions, and respiratory failure.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
34
Benzamide
C7H7NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
55-21-0
Solid
Colorless
N/A
180
288
130
1.341
N/A
N/A
1.35
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Headache, shortness of breath,
dullness, drowsiness, nausea,
vomiting, and central nervous system
depression.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
35
Benzanilide
C13H11NO
CAS No.
PS
Color
Odor
FP
93-98-1
Solid
Colorless
N/A
N/A 117–119
Types of
Hazard/Exposure
BP
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
N/A
1.315
N/A
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be absorbed through the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
36
Benzenesulfonyl Chloride
C6H5ClO2S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
98-09-9
Liquid
Colorless
N/A
132
251–252 dec
14.5
1.4
1.3 @ 20
N/A
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Negligible fire hazard. Slight explosion
hazard.
Inhalation
Acidic corrosive action: sore throat,
Ventilation, local
coughing, choking, weakness and labored exhaust.
breathing, tightness in the chest,
dizziness, and low blood pressure.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, and serious burns.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, burns, and permanent corneal
damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Severe burning pain in the mouth, throat Do not eat or drink Give large amounts of
and abdomen, nausea, vomiting, diarrhea, in the laboratory.
water or milk, allow
sudden drop in blood pressure.
vomiting to occur; when
vomiting occurs, keep
head lower than hips.
Seek medical attention
immediately.
Carcinogenicity
Not a known carcinogen.
Strong oxidizing
agents, strong
bases.
First Aid/Fire
Mutagenicity
Dry chemical powder,
regular foam, water.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
37
Benzilic Acid
C14H12O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
65-85-0
Solid
White
N/A
N/A
N/A
150–153
N/A
N/A
N/A
0.1758
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid heat, sparks and Water spray, carbon
flames.
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
38
Benzoic Acid
C7H6O2
CAS No.
PS
Color
Odor
FP
BP
MP
65-85-0
Solid
White
Faint
121
249
122
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.2659 @ 15 1 @ 96
Prevention
VD
Sol
4.2
2.9 @ 20
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, gastric pain, nausea,
vomiting, and allergic reactions.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
39
Benzoyl Chloride
C7H5ClO
CAS No.
PS
98-88-4
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
68
197
N/A
d
VP
VD
1.211 1 @ 32 4.88
Sol
Reacts
Acute Hazards/Symptoms
Prevention
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Inhalation
Irritation, burns, sore throat, coughing, Ventilation, local
labored breathing, pulmonary edema, exhaust.
liver and kidney damage.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, pain, and burns.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, redness, pain, blurred vision, Safety goggles.
and severe eye burns.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate pain and severe burns of
mucous membranes of the mouth and
throat and gastrointestinal tract,
nausea, vomiting, abdominal pain,
diarrhea, and central nervous system
depression.
Do not eat or drink in
the laboratory.
Give water; if vomiting
occurs, keep head lower
than hips; get medical
advice immediately.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Possible carcinogen.
Protective gloves and
clothing.
First Aid/Fire
Carbon dioxide, dry
chemical powder.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
40
Benzyl Bromide
C7H7Br
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1100-88
Liquid
Colorless
N/A
86
198–199
-2 to -1
1.439
0.242 @ 17
5.8
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Hydrolyzed by water, liberating acid
gas that in contact with metal surfaces
can generate hydrogen gas. Emits
toxic fumes under toxic conditions.
Keep away from water
and moistrue. Avoid
heat, sparks and
flames.
Carbon dioxide, dry
chemical powder or
appropriate foam. Do not
use water.
Inhalation
Harmful if inhaled. Extremely
Ventilation, local
destructive to tissues of upper mucous exhaust.
membranes. Symptoms may include
burning sensation, coughing, wheezing
headache, nausea, and vomiting.
Target organ: central nervous system.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, lachrymator.
Safety goggles.
Thoroughly wash eyes
with water for several
minutes, remove contact
lenses if possible, and seek
medical advice.
Ingestion
Harmful if swallowed. Symptoms
may include burning sensation,
coughing, headache, nausea, and
vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
41
Benzyl Cinnamate
C16H14O2
CAS No.
PS
Color
Odor
FP
BP
MP
103-41-3
Solid
Light yellow
N/A
180
195-200
34-37
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.109 @ 20 N/A
Prevention
VD
Sol
N/A
N/A
First Aid/Fire
Fire
Neglible fire hazard.
No flames, no, sparks, Use water spray, alcoholno contact with hot
resistant foam, dry
surfaces.
chemical or carbon
dioxide
Inhalation
N/A
Ventilation, local
exhaust
Remove from exposure
immediately and seek
medical advice
Skin
Causes mild skin irritation
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
42
Benzyl 3-Phenylpropanoate
C16H16O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
22767-96-0
Liquid
Colorless
N/A
N/A
258
N/A
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
No open flames or
sparks.
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
43
Benzyltriphenylphosphonium Chloride
C25H22ClP
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1100-88
Solid
Off-white
N/A
>299
N/A
300
1.18 @ 25
N/A
N/A
Moderately
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks, flames Regular dry chemical,
carbon dioxide, water,
regular foam.
Inhalation
Irritant.
Ventilation, local exhaust Remove from exposure
immediately and seek
medical advice.
Skin
Absorption through skin:
depression, diarrhea or irritability.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, death in animals.
Safety goggles.
Thoroughly wash eyes
with water for several
minutes, remove contact
lenses if possible, and seek
medical advice.
Ingestion
Depression, labored breathing,
diarrhea; kidneys, liver, and lungs
may be affected.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
44
cis-Bicyclo[2.2.1]hept-5-ene-endo-2,3-dicarboxylic Acid
C9H10O4
CAS No.
PS
Color
Odor
FP
BP
3853-88-1
Solid
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms*
MP
d
191–193 N/A
VP
VD
Sol
N/A
N/A
Slightly
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.*
Mutagenicity
Not a known mutagen.*
*Toxicological information for the listed chemical is not available. Information given pertains to cyclohexane-cis1,2-dicarboxylic acid and is intended to be used for comparison of a similar compound. Other effects may result
from contact, inhalation, or ingestion.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
45
cis-Bicyclo[2.2.1]hept-5-ene-endo-2,3-dicarboxylic Anhydride
C9H8O3
CAS No.
PS
Color
Odor
FP
BP
129-64-6
Solid
White
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
MP
D
164–165 1.417
VP
VD
Sol
N/A
N/A
Reacts
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
sand, earth, regular foam.
Inhalation
Irritation, runny or stuffy nose,
wheezing, central nervous system
depression, headache, nausea, and
vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, absorption through skin may
cause central nervous system
depression, headache, nausea, and
vomiting.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Symptoms as given in acute skin
contact.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Symptoms as given in acute inhalation.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
46
2,2-Bipyridyl
C10H8N2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
366-18-7
Solid
Colorless
N/A
N/A
273
70–73
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder, foam,
water.
Inhalation
May be harmful. Irritating to respiratory
tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Toxic in contact with skin.
Protective gloves and
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
clothing.
Eyes
May cause irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately. Call a poison
center.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
47
Bleach [Sodium Hypochlorite Solution]
ClONa
CAS No.
PS
N/A
Liquid
Types of
Hazard/Exposure
Color
Odor
Pale yellow Pungent
FP
BP
MP
d
VP
VD
Sol
N/A
102
N/A
1.087
16
19.2
Soluble
Acute Hazards/Symptoms*
Prevention *
First Aid/Fire*
Fire
Not flammable. Emits toxic fumes
under fire conditions.
Inhalation
May be harmful if inhaled. Material
Ventilation, local
may be irritating to mucous membranes exhaust.
and upper respiratory tract.
Skin
Causes skin irritation. May be harmful Protective clothing and Remove contaminated
if absorbed through the skin.
gloves.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Avoid heat, sparks and Water spray, carbon
flames.
dioxide, dry chemical
powder or appropriate
foam.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Not a known mutagen.
*Based on 5% sodium hypochlorite solution.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
48
Borane-THF Solution
BH3 . C4H8O
CAS No.
PS
14044-65-6
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Irritating
FP
BP
MP
d
VP
VD
Sol
-17
>69
N/A
0.898
N/A
N/A
Reacts
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks, no
contact with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, headache, nausea, and
vomiting.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Headache, nausea, and vomiting. Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
49
Brine
(saturated aqueous sodium chloride)
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Liquid
Colorless
None
N/A
107
N/A
1.2
336
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
Use extinguishing agents
appropriate for surrounding
fire.
Inhalation
NA
Ventilation, local
exhaust.
Not expected to require first
aid measures.
Skin
NA
Protective clothing and Remove contaminated
gloves.
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice.
Eyes
Temporary irritation and possible
damage.
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Give water; if vomiting
occurs, keep head lower than
hips. Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
50
Bromine
Br2
CAS No.
7726-95-6
PS
Color
Odor
Liquid Brown to red Irritating
Types of
Hazard/Exposure
FP
BP
MP
d
VP
VD
Sol
N/A
59
N/A
3.12
175 @ 20
7.14
4
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard. May ignite or
explode on contact with combustible
materials.
Avoid contact with
combustible
materials.
Dry chemical powder,
carbon dioxide, regular
foam.
Inhalation
Irritation, copious mucous secretion,
coughing, nosebleeds, and headache.
Delayed symptoms: nausea, diarrhea and
abdominal pains, pulmonary edema,
pneumonitis or pneumonia.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Cooling sensation, burning sensation,
redness, pain, brown discoloration,
blisters, discharging pustules, destructive
burns and deep-seated ulcers.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, blurred vision, burns,
lacrimation, photophobia, loss of vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burns of the mouth, throat and stomach,
brown discoloration and corrosion of the
tongue and mucous membranes, sore
throat, and vomiting.
Do not eat or drink
in the laboratory.
Give large amounts of
water and allow vomiting
to occur; when vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
51
Bromobenzene
C6H5Br
CAS No.
PS
108-86-1
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pleasant
FP
BP
MP
d
51
156
N/A
1.49
Acute Hazards/Symptoms
VP
VD
3 @ 20 5.41
Prevention
Sol
0.045
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases No heat, no flames, no Alcohol-resistant foam,
may ignite at distant ignition sources. sparks.
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation, headache, sore throat,
coughing, shortness of breath, nausea,
vomiting, and dizziness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, abdominal pain,
nausea, vomiting, diarrhea, headache,
dullness, and central nervous system
effects.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Headache, abdominal pain,
gastrointestinal irritation, nausea,
vomiting, diarrhea, dizziness, and
central nervous system effects.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
52
Bromocyclohexane [Cyclohexyl Bromide]
C6H11Br
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-85-0
Liquid
Colorless
N/A
63
48-51@ 10
N/A
1.335
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder, or foam.
Inhalation
May be harmful if inhaled. Exposure
can cause nausea, headache and
vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful by skin absorption.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Exposure can cause nausea, headache
and vomiting.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed. Exposure Do not eat or drink in
can cause nausea, headache and
the laboratory.
vomiting.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
53
2-Bromoacetanilide
C8H8 BrNO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
614-76-6
Solid
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Low fire hazard. Emits toxic fumes
under fire conditions.
Inhalation
May be harmful if inhaled. Irritating Ventilation, local
to mucous membranes and upper
exhaust.
respiratory tract.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation. May be
Protective clothing and
harmful if absorbed through the skin. gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Avoid heat, sparks and
flames.
First Aid/Fire
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
54
4-Bromoacetanilide
C8H8BrNO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
614-76-6
Solid
Off-white
N/A
N/A
N/A
167–169
1.717
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Low fire hazard. Emits toxic
fumes under fire conditions.
Avoid heat, sparks and
flames.
Inhalation
May be harmful if inhaled
Irritating to mucous membranes
and upper respiratory tract.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation. May be
harmful if absorbed through the
skin.
Protective clothing and
gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
55
2-Bromoanisole
C7H7BrO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
578-57-4
Liquid
Pale yellow
N/A
98
215–217
2
1.513
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
Avoid heat, sparks and
flames.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be harmful if inhaled.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful and cause
irritation.
Wear protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
56
4-Bromoanisole
C7H7BrO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
104-92-7
Liquid
Pale yellow
N/A
98
98–99 @ 10
12
1.495
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
Avoid heat, sparks and
flames.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful by skin absorption.
May cause irritation.
Protective clothing and
gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May be harmful. May cause
irritation.
Safety goggles
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
57
4-Bromobenzyl Alcohol
C7H7BrO
CAS No.
PS
Color
Odor
FP
BP
873-75-6
Solid
White
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
MP
d
75-77 N/A
VP
VD
Sol
N/A
N/A
N/A
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no
sparks, no
contact with hot
surfaces.
Inhalation
May be harmful. Irritating to respiratory tract.
Ventilation, local Remove from exposure
exhaust.
immediately and seek
medical advice.
Skin
Irritation; may be harmful if absorbed through
skin.
Protective gloves Remove contaminated
and clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or
drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Carbon dioxide, dry
chemical powder, foam,
water.
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
58
1-Bromobutane
C4H9Br
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
109-65-9
Liquid
Colorless
N/A
22
99–101
N/A
1.3
150 @ 25
4.7
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Emits toxic
fumes under fire conditions.
Inhalation
Irritation of mucous membranes, Ventilation, local exhaust.
narcosis.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and burning.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly wash eyes
with water for several
minutes, remove contact
lenses if possible, and seek
medical attention.
Ingestion
Gastrointestinal disturbances,
possibly narcosis.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
No open flames, no sparks, Dry chemical powder,
no contact with hot surfaces. carbon dioxide, water,
Vapors or gases may ignite regular foam.
at distant ignition sources.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
59
1-Bromoethylbenzene
C8H9Br
CAS No.
PS
Color
Odor
FP
585-71-7
Liquid
Colorless
N/A
81
Types of
Hazard/Exposure
BP
MP
94 @ 16 49.5–50.5
Acute Hazards/Symptoms
d
VP
VD
Sol
1.356
N/A
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No open flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation of mucous membranes and
respiratory tract. Symptoms may
include burning sensation, coughing,
shortness of breath, headache, nausea,
and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
60
2-Bromohexane
C6H13Br
CAS No.
PS
Color
Odor
FP
111-25-1
Liquid
Colorless
N/A
135 154–158
Types of
Hazard/Exposure
BP
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
-85
1.176
<10
5.7
Insoluble
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No open flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam
Inhalation
Irritation of mucous membranes and
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
61
2-Bromonitrobenzene
C6H4BrNO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
577-19-5
Solid
Yellow
Distinct
>110
261
40–42
1.62
N/A
7.0
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard. Emits toxic fumes
under fire conditions.
Avoid heat, flames,
and sparks.
Dry chemical powder,
regular foam, water.
Inhalation
Irritation. If sufficient amounts are
absorbed, methemoglobinemia may
occur.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation. Skin absorption may occur
Protective gloves and
and may result in methemoglobinemia clothing.
as detailed in ingestion.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea and vomiting, abdominal pain, Do not eat or drink in
coma, and paralysis.
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Safety goggles.
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
62
4-Bromonitrobenzene
C6H4BrNO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
586-78-7
Solid
Off-white
N/A
N/A
255–256
125–127
1.934
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard. Emits toxic fumes
under fire conditions.
Avoid heat, sparks and Dry chemical powder,
flames.
regular foam, water.
Inhalation
Irritation and possibly conditions
detailed in inhalation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, skin absorption may occur
and may result in conditions detailed
in inhalation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea and vomiting, abdominal pain, Do not eat or drink in
confusion, irritability, tremor, memory the laboratory.
loss, anorexia, emaciation, headache,
slurred speech, conjunctivitis.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
63
2-Bromophenol
C6H5BrO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
95-56-7
Liquid
N/A
N/A
42
195–196
3
1.638
N/A
N/A
>10
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
Inhalation
May be harmful if inhaled. Causes
Ventilation, local
irritation of mucous membranes and
exhaust.
upper respiratory tract. Depending on
intensity of exposure, effects may vary
from mild irritation to severe
destruction of tissue.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed through
the skin. Depending on intensity of
exposure, effects may vary from mild
irritation to severe destruction of
tissue.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation. Depending on
Safety goggles.
intensity of exposure, effects may vary
from mild irritation to severe
destruction of tissue.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Depending on Do not eat or drink in
intensity of exposure, effects may vary the laboratory
from mild irritation to severe
destruction of tissue.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Avoid heat, sparks and Water spray, carbon
flames.
dioxide, dry chemical
powder or appropriate
foam.
Wear protective
clothing and gloves
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
64
4-Bromophenol
C6H5BrO
CAS No.
PS
Color
Odor
FP
BP
106-41-2
Solid
White to
off-white
N/A
N/A
235–236
Types of
Hazard/Exposure
Acute Hazards/Symptoms
MP
d
VP
64–68 1.840 @ 15 Negligible
Prevention
VD
Sol
N/A
10
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
May be harmful if inhaled. Causes
irritation of mucous membranes and
upper respiratory tract. Effects may
vary from mild irritation to severe
destruction of tissue.
Ventilation, local
exhaust.
Skin
May cause irritation and May be
Protective gloves and
harmful if absorbed through the skin. clothing.
Depending on intensity of exposure,
effects may vary from mild irritation to
severe destruction of tissue.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation. Depending on
Safety goggles.
intensity of exposure, effects may vary
from mild irritation to severe
destruction of tissue.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible; seek medical
advice.
Ingestion
Harmful if swallowed. Depending on Do not eat or drink in
intensity of exposure, effects may vary the laboratory.
from mild irritation to severe
destruction of tissue.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
65
1-Bromopropane
C3H7Br
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
106-94-5
Liquid
Colorless
N/A
22
71
-110
1.353
100 @18
4.25
0.25
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable liquid and vapor.
No open flames or
sparks.
Dry chemical powder,
alcohol-resistant foam or
carbon dioxide. Water
may be ineffective.
Inhalation
Causes irritation to the respiratory
tract. Symptoms may include
coughing, shortness of breath. A
central nervous system depressant.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation to skin. Symptoms
include redness, itching, and pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Causes irritation to the gastrointestinal Do not eat or drink in
tract. Symptoms may include nausea, the laboratory.
vomiting and diarrhea.
Give water; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
66
4-Bromo-2-chloroacetanilide
C8H7BrClNO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2564-02-05
Solid
Colorless
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. *
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation and may be harmful. *
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and may be harmful if
absorbed through skin. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation, may be harmful. *
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.*
Mutagenicity
Not a known mutagen.*
*Toxicological information for the listed chemical is not available. Information given pertains to 2-chloroacetanilide and is intended to be used for comparison of a similar compound. Other effects may result from
contact, inhalation, or ingestion.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
67
4-Bromo-2-chloroaniline
C6H5BrClN
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
38762-41-3
Solid
Light tan
N/A
N/A
N/A
70–72
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Low fire hazard.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Harmful if inhaled.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if in contact with skin.
Safety goggles.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in the Wash out mouth with
laboratory.
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
68
4-Bromo-2-chloro-6-iodoaniline
C6H4BrClIN
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
147-82-0
Liquid
Beige
N/A
N/A
300
120−122
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions. *
Avoid heat, sparks,
flames.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Highly toxic if inhaled. *
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Toxic if absorbed through skin.
Causes skin irritation. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible; seek medical
advice.
Ingestion
Highly toxic if swallowed. *
Do not eat or drink in
the laboratory.
If swallowed, wash out
mouth with water. Seek
medical advice.
Mutagenicity
Not a known mutagen. *
Carcinogenicity
Carcinogen. *
* Toxicological information for the listed chemical is not available. Information given pertains to 2,4,6tribromoaniline and is intended to be used for comparison of a similar compound. Other effects may result from
contact, inhalation, or ingestion.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
69
1-Bromo-3-chloro-5-iodobenzene
C6H3BrClI
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Solid
N/A
N/A
N/A
N/A
85.8
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Moderate fire hazard.
Inhalation
Respiratory tract effects, central nervous Ventilation, local
system, effects, and possibly corrosion.* exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, possibly corrosion.*
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lacrimation, irritation, and possibly
corrosion.*
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A *
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Not a known carcinogen.*
Mutagenicity
Dry chemical powder,
carbon dioxide, water,
regular foam.
Not a known mutagen.*
*Toxicological information for the listed chemical is not available. Information given pertains to 1,3,5-tribromobenzene and is intended to be used for comparison of a similar compound. Other effects may result from contact,
inhalation, or ingestion.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
70
1-Bromo-2,4-dinitrobenzene
C6H3BrN2O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
584-48-5
Solid
N/A
N/A
N/A
N/A
71–73
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Inhalation
Irritation to mucous membranes and
Ventilation, local
upper respiratory tract. Absorption into exhaust.
the body leads to formation of
methemoglobin, which may cause
cyanosis. Onset may be delayed 2–4
hours or longer.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause allergic skin reaction and
skin irritation. Absorption into the
body leads to the formation of
methemoglobin, which may cause
cyanosis. Onset may be delayed 2–4
hours or longer.
Wear protective
clothing and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation. Absorption into the body
leads to the formation of
methemoglobin, which may cause
cyanosis. Onset may be delayed 2–4
hours or longer.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Absorption into the body leads to the
formation of methemoglobin, which
may cause cyanosis. Onset may be
delayed 2–4 hours or longer.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Avoid heat, sparks and Water spray, carbon
open flames.
dioxide, dry chemical
powder or appropriate
foam.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
71
2-Bromo-2-methylbutane
C5H11Br
CAS No.
507-36-8
PS
Color
Liquid Colorless
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
4
107
N/A
1.182
N/A
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors may ignite No flames, no sparks, no
at distant ignition sources.
contact with hot surfaces.
Inhalation
May be harmful.
Skin
Irritation, may be harmful if absorbed Protective gloves and
through skin.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, may be harmful.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Carbon dioxide, dry
chemical powder, foam,
water.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
72
1-Bromo-2-naphthol
C10H7BrO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
573-97-7
Solid
N/A
N/A
N/A
N/A
78–81
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid heat, sparks and
flames.
Inhalation
May be harmful if inhaled.
Material is irritating to mucous
membranes and upper respiratory
tract.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed
through the skin. Causes skin
irritation.
Protective clothing and
gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
73
1-Butanol
C4H10O
CAS No.
PS
Color
Odor
FP
BP
MP
71-36-3
Liquid
Colorless
Irritating
29
117
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.8098 6.5 @ 25
Prevention
VD
Sol
2.55
7.7
First Aid/Fire
Fire
Severe fire hazard; vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
25 ppm: Irritation. At 50 ppm: Sore
throat, coughing, nausea, and central
nervous system depression with
headache and dizziness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation with redness and dryness
may be absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Moderate temporary injury.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, nausea, vomiting,
and diarrhea. High doses: Complete
paralysis, reduction of body
temperature and respiration.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
74
2-Butanol
C4H10O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
78-92-2
Liquid
Colorless
Strong,
pleasant
24
94
-115
0.81
13 @ 20
2.6
15
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Foam, dry chemical
powder, alcohol-resistant
foam, water spray, carbon
dioxide.
Fire
Flammable.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Dizziness, drowsiness, headache.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Dry skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, blurred vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Dizziness, drowsiness, headache.
Do not eat or drink in the
laboratory.
Wash out mouth with
water. Give copious
amounts of water to drink.
Seek medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
75
2-Butanone
C4H8O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
78-93-3
Liquid
Colorless
Sharp, mint-like
-9
80
-86
0.805
78 @ 20
2.5
29
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Highly flammable.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
foam, carbon dioxide.
Inhalation
Cough, dizziness, dullness,
headache, nausea, shortness of
breath, vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be absorbed through skin.
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness. Pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Dizziness. Drowsiness. Headache.
Do not eat or drink in
the laboratory.
Wash out mouth with
water and give copious
amounts of water to drink;
if vomiting occurs, keep
head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
76
3-Buten-2-one
C4H6O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
78-94-4
Liquid
Colorless
Irritating
-6
81
N/A
0.842
120 @ 34
1.3
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Coughing, choking, pain, burns,
tightness in the chest, low blood
pressure; central nervous system
depression, headache, nausea, and
vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, pain, burns; absorption
through the skin may cause central
nervous system depression, headache,
dizziness, nausea, vomiting.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, pain, and burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate pain and severe burns,
discoloration of the tissues,
swallowing and speech may be
difficult or impossible, and shock.
Do not eat or drink in
the laboratory.
Give water or milk; if
vomiting occurs, keep
head lower than hips. Seek
medical attention
immediately.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
77
N-tert-Butoxycarbonyl- L-alanine
C8H15NO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
15761-38-3
Solid
White
N/A
N/A
N/A
79–82
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Irritation, sore throat, and
coughing.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness,
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, gastric pain, nausea,
vomiting, and allergic reactions.
Do not eat or drink in the
laboratory.
Do not induce vomiting.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Not a known carcinogen.
Carbon dioxide, dry
chemical power, or
appropriate foam.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
78
n-Butyl Acetate [1-Butyl Ethanoate]
C6H12O2
CAS No.
123-86-4
PS
Color
Liquid Colorless
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
Mild, fruity
26
126
-77
0.883
15 @ 25
4.0
0.7
Acute Hazards/Symptoms
Prevention
Fire
Highly flammable.
Inhalation
Cough. Dizziness. Dullness. Headache. Local exhaust or
Nausea.
breathing protection.
Remove from exposure
immediately and seek
medical advice.
Skin
Dry skin. Redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness. Pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Wash out mouth with
water; do not induce
vomiting. Seek medical
advice immediately.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Not a known carcinogen.
Mutagenicity
Carbon dioxide, dry
chemical power, or
appropriate foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
79
n-Butyl Benzoate [1-Butyl Benzoate]
C11H14O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
136-60-7
Liquid
Colorless
Fruity
106
249
-22
1.01
0.22
6.15
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
80
tert-Butyl Peroxybenzoate
C11H14O3
CAS No.
PS
Color
Odor
FP
BP
MP
614-45-9
Liquid
Colorless to
light yellow
N/A
93
75−76 @ 0.2
8
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.021 3.36 @
50
Prevention
VD
Sol
6.7
Insoluble
First Aid/Fire
Fire
Flammable. Contact may cause fire,
No flames, no sparks, Dry chemical powder,
may accelerate fires. Emits toxic fumes no contact with hot
carbon dioxide,
under fire conditions.
surfaces.
appropriate foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Skin
May be harmful if absorbed through
skin.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May be harmful to the eyes.
Safety goggles.
Ingestion
May be harmful if swallowed.
Do not eat or drink in If swallowed wash out
the laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
81
n-Butyl Propionate [1-Butyl Propanoate]
C7H14O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
590-01-2
Liquid
Colorless
Fruity
38
145
-75
0.875
3
4.5
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
82
n-Butylbenzene
C10H14
CAS No.
PS
104-51-8
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Mild aromatic
FP
BP
MP
d
VP
VD
Sol
54
182−183
-88
0.86
N/A
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible and flammable liquid. Emits
toxic fumes under fire conditions.
No flames, no
sparks, no
contact with hot
surfaces.
Inhalation
May be harmful if inhaled.
Ventilation, local Remove from exposure
exhaust.
immediately and seek
medical advice.
Skin
May be harmful if absorbed through skin.
Protective gloves Remove contaminated
and clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or
drink in the
laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Dry chemical powder,
carbon dioxide,
appropriate foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
83
sec-Butylbenzene
C10H14
CAS No.
PS
135-98-8
Liquid
Types of
Hazard/Exposure
Color
Odor
FP
Colorless Mild aromatic 45
BP
MP
d
VP
VD
Sol
173–174
-75
0.863
4
N/A
Negligible
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under fire No flames, no
conditions.
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Harmful if inhaled. Irritating to
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink If swallowed wash out
in the laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
84
tert-Butylbenzene
C10H14
CAS No.
PS
98-06-6
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Mild aromatic
FP
BP
MP
d
VP
VD
Sol
34
169
-58
0.867
4.79 @
37.7
3.16 @
169
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed through
skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May be harmful to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known caricinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
85
Calcium Chloride
CaCl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
10043-52-4
Solid
White
N/A
N/A
>1600
782
2.15 @ 25
N/A
N/A
74.5 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, coughing, and shortness of
breath.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, erythema, blistering,
exfoliation, and ulceration.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, and superficial Safety goggles.
injury.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal spasms, nausea,
gastrointestinal tract or cardiovascular
irregularities.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Do not eat or drink in
the laboratory.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
86
Calcium Hypochlorite
CaCl2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7778-54-3
Solid
Off-white
N/A
N/A
N/A
100
2.350
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Contact with other material may cause No flames, no sparks,
fire. Contact with combustible
no contact with hot
material may cause fire. Contact with surfaces.
water liberates a toxic gas. Emits toxic
fumes under fire conditions.
Carbon dioxide, dry
chemical powder, or
appropriate foam.
Inhalation
Harmful if inhaled. Irritating to
respiratory system. Symptoms of
exposure may include burning
sensation, coughing, wheezing,
laryngitis, headache, nausea, and
vomiting.
Local exhaust or
breathing protection.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation and burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes severe eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Can produce
nausea, vomiting, coma, respiratory
collapse. Symptoms of exposure may
include burning sensation, coughing,
headache, nausea, and vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
N/A
Mutagenicity
N/A
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
87
Caraway Seed Oil
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
8000-42-8
Liquid
Colorless
to pale
yellow
Fresh
caraway
120
193–231
N/A
0.90–0.91
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Flammable. Vapors may form explosive
mixtures with air. Emits toxic fumes
under fire conditions.
Avoid heat, sparks
and flames.
Water spray, carbon
dioxide, dry chemical or
appropriate foam.
Inhalation
Irritation to respiratory system.
Ventilation local
exhaust.
Remove to fresh air. Get
medical attention.
Skin
Irritation to skin. May cause
sensitization by skin contact.
Protective clothing Wash immediately with
and gloves.
soap and plenty of water.
Eyes
Irritation to eyes.
Safety glasses.
Rinse immediately with
water for at least 15 min.
Seek medical advice
Ingestion
N/A
Do not eat or
drink in the
laboratory.
Rinse mouth with water
only if person conscious.
Seek medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
First Aid/Fire
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
88
Carbon (decolorizing)
C
CAS No.
PS
Color
Odor
FP
BP
7440-44-0
Solid
Black
Odorless
N/A
N/A N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
1.8–2.1
1 @ 3586
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Severe fire hazard; may ignite on
exposure to air.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Mucous membrane irritation.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Dry chemical powder,
sand, earth, regular foam,
water.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
89
Carvone
C10H14O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2244-16-8
Liquid
Colorless
Spicy
98
230
N/A
0.9608
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Erythema; skin absorption may occur.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
90
Celite [Filter Aid]
CAS No.
PS
61790-53-2
Solid
Types of
Hazard/Exposure
Color
Odor
White to Odorless
off-white
FP
BP
MP
d
VP
VD
Sol
N/A
2230
1700
1.9–2.35
N/A
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Physical discomfort of the upper
respiratory tract, coughing, silicosis.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Mechanical irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Mechanical irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Chemically and biologically inert on
ingestion.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
91
Ceric Ammonium Nitrate
CeH8N8O18
CAS No.
PS
16774-21-3
Solid
Types of
Hazard/Exposure
Color
Odor
FP
BP
MP
d
VP
VD
Sol
Yellow to red Odorless N/A
N/A
N/A
N/A
N/A
N/A
142.6 @ 25
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard; may ignite or
explode on contact with combustible
materials.
Inhalation
Severe irritation, sore throat, coughing, Ventilation, local
and shortness of breath.
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, and pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation, abdominal pain,
nausea, vomiting, and diarrhea.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Avoid contact with
Water spray.
combustible materials.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
92
4-Chloroacetanilide
C8H8ClNO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
539-03-7
Solid
White
N/A
N/A
N/A
177–179
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Low fire hazard. Emits toxic
fumes under fire conditions.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Irritant if inhaled.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritant to skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritant to eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible; seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
93
Chloroacetyl Chloride
C2H2Cl2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
79-04-9
Liquid
Colorless
Acrid
N/A
105–106
-22
1.418
60
3.9
Decomposes
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under fire No flames, no
conditions.
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Toxic. Corrosive. Inhalation may result
Ventilation, local
in spasm, inflammation, and edema of the exhaust.
larynx and bronchi.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful and causes burns
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic if swallowed. Exposure to and/or
consumption of alcohol may increase
toxic effect. Exposure can cause burning
sensation, wheezing, headache and
vomiting.
Do not eat or drink If swallowed wash out
in the laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
94
4-Chlorobenzaldehyde
C7H5ClO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
104-88-1
Solid
White
N/A
87
213–214
45
1.196 @ 61
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Moderate fire hazard.
Inhalation
Irritation, tracheobronchitis,
Ventilation, local
pulmonary edema, bronchopneumonia, exhaust.
and bronchospasms.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, erythema, swelling, nerve
irritation, hyperemia, and
pigmentation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Strong irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Not a known carcinogen.
Mutagenicity
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
95
Chlorobenzene
C6H5Cl
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-90-7
Liquid
Colorless
Almondlike
28
132
-45
1.107
11.8 @ 25
3.9
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable; emits irritating or toxic
fumes or gases in a fire.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
water spray, foam, carbon
dioxide.
Inhalation
Drowsiness, headache, nausea,
unconsciousness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, roughness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
96
2-Chlorobenzoic Acid
C7H5ClO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
118-91-2
Solid
White
Odorless
173
285
142
1.544
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
No flames, no sparks, Dry chemical powder,
conditions. Avoid contact with strong no contact with hot
carbon dioxide, water,
oxidizing agents.
surfaces. No contact
regular foam.
with oxidizing agents.
Inhalation
Causes respiratory tract irritation.
Skin
Irritation and may be absorbed through Protective gloves and
skin.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Causes gastrointestinal irritation with
nausea, vomiting and diarrhea.
Do not eat or drink in
the laboratory.
Never give anything by
mouth to an unconscious
person. Get medical aid.
Do not induce vomiting. If
conscious and alert, rinse
mouth and drink 2-4
cupfuls of milk or water.
Carcinogenicity
Suspected carcinogen.
Ventilation, local
exhaust.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
97
4-Chlorobenzoic Acid
C7H5ClO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
74-11-3
Solid
Colorless
N/A
238
N/A
239-241
1.541 @ 24
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, absorption may occur.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
98
4-Chlorobenzyl Alcohol
C7H7ClO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
873-76-7
Solid
White
N/A
N/A
234
70–72
N/A
N/A
N/A
Poor
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder, foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation; may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
99
1-Chlorobutane
C4H9Cl
CAS No.
PS
109-69-3
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Unpleasant
FP
BP
MP
-9
78
-123
d
VP
0.89 80 @20
VD
Sol
3.2
Insoluble
Acute Hazards/Symptoms
Prevention
Fire
Highly flammable; emits irritating
or toxic fumes or gases in a fire.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Cough. Drowsiness. Sore throat.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal cramps, nausea.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
First Aid/Fire
Dry chemical powder,
foam, carbon dioxide.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
100
4-Chlorocinnamic Acid
C7H7ClO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1615-02-7
Solid
White
N/A
N/A
311
248–250
N/A
N/A
N/A
Slightly soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Forms hychloric acid upon
combustion.
Avoid heat, sparks and Use water spray, alcoholflames.
resistant foam, dry
chemical or carbon
dioxide
Inhalation
May cause irritation of respiratory
tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
May cause skin irritation
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
May cause irritation of digestive tract.
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
101
α-Chloro-2,6-dimethylacetanilide
C10H12ClNO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1131-01-7
Solid
White
N/A
N/A
N/A
150−151
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Irritating, may be harmful if absorbed
through the skin.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating, may be harmful if absorbed
through the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating, may be harmful to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
102
Chloroform
CHCl3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
67-66-3
Liquid
Colorless
Sweet
N/A
60.5–61.5
-63
1.492
160 @ 20
4.12
0.82 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Negligible fire hazard.
Inhalation
Irritation, central nervous system
Ventilation, local
depression may be preceded by
exhaust.
excitation and inebriation, dizziness,
headache, fatigue, nausea, and vomiting.
Remove from exposure
immediately and seek
medical advice.
Skin
Inflammation, destruction of the
epithelium, moderate necrosis; some
absorption possible, resulting in weight
loss and degenerative kidney changes.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Burning pain, lacrimation, redness,
damage to corneal epithelium.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning of the mouth, throat, esophagus, Do not eat or drink
and stomach, nausea, vomiting, diarrhea, in the laboratory.
cyanosis, muscle cramps, irregular
respiration, respiratory failure, and liver
damage.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Suspect carcinogen.
Possible mutagen.
Carcinogenicity
N/A
First Aid/Fire
Mutagenicity
Dry chemical powder,
regular foam, water.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
103
Chloroform-d [Deuteriochloroform]
CDCl3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
865-49-6
Liquid
Colorless
Sweet
N/A
60.9
-64
1.48
160
4.1
0.82 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not combustible. Emits toxic fumes
under fire conditions.
Avoid heat, sparks,
and flames.
Use extinguishing media
appropriate for
surrounding fire.
Inhalation
May be harmful if inhaled. May be
irritating to mucous membranes and
upper respiratory tract. Exposure can
cause vomiting and gastrointestinal
disturbances.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Skin absorption may occur. May be
harmful if absorbed through the skin.
Causes skin irritation. Exposure can
cause vomiting and gastrointestinal
disturbances.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Exposure can
cause vomiting and gastrointestinal
disturbances.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Suspect carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
104
2-Chloro-2-methylbutane
C5H11Cl
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
594-36-5
Liquid
Colorless
N/A
-9
85–86
-73
0.866
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water
Inhalation
Irritation, narcotic.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, central nervous system
depression.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Narcotic.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
105
3-(4-Chlorophenyl)propanoic Acid
C9H9ClO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2019-34-3
Solid
White
N/A
N/A
N/A
127–131
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Forms hydrochloric acid upon
combustion.
No open flames or
sparks.
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
Causes serious eye damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
106
Chloroplatinic Acid
H2PtCl6 . 6H2O
CAS No.
PS
16941-12-1
Solid
Types of
Hazard/Exposure
Color
Odor
Brownish- Odorless
yellow
FP
BP
MP
d
VP
VD
Sol
N/A
115
60
2.43
N/A
18
Soluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not a fire hazard.
Keep away from steel Water spray, carbon
and other common
dioxide, or dry chemical
metals.
powder.
Inhalation
Exposure can cause severe allergies
affecting the nose, skin and lungs.
Irritation and even ulcers can develop
in the nose. May cause platinosis.
Symptoms include wheezing,
coughing, tightness of the chest,
cyanosis, and pronounced asthmatic
symptoms.
Ventilation, local
exhaust.
Skin
May cause platinosis; symptoms may
include severe irritation, eczema,
urticaria, itching, and dermatitis. May
cause skin allergy.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause irritation, itching, and
conjunctival vasodilation.
Safety goggles.
Ingestion
May cause vomiting and bloody
diarrhea.
Do not eat or drink in Induce vomiting
the laboratory.
immediately as directed by
medical personnel. Get
medical attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
107
Chlorosulfonic Acid
ClHO3S
CAS No.
PS
7790-94-5
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
N/A
158
N/A
Acute Hazards/Symptoms
d
VP
1.753 1 @ 20
Prevention
VD
Sol
4.02
Reacts
First Aid/Fire
Fire
Negligible fire hazard; reacts violently Keep dry.
with water.
Carbon dioxide, dry
chemical powder.
Inhalation
Severe mucous membrane irritation,
coughing, choking, headache,
dizziness and weakness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, pain, burns, and
brownish or yellowish stains.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Corneal and conjunctival edema, iritis, Safety goggles.
corneal erosion and opacity, pain,
blurred vision, and photophobia.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Severe burning pain in the mouth,
Do not eat or drink in
throat and abdomen, nausea, vomiting, the laboratory.
diarrhea, and bloody stools.
Give large amounts of
water; allow vomiting to
occur; when vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
108
Chromic Anhydride
Cr2H2O7
CAS No.
PS
Color
1333-82-0
Solid
Types of
Hazard/Exposure
Odor
Dark red Odorless
FP
BP
MP
d
VP
VD
Sol
N/A
Decomposes
197
2.7
N/A
N/A
63
Acute Hazards/Symptoms
Prevention
Fire
Not combustible but enhances
combustion of other substances.
Many reactions may cause fire or
explosion.
Inhalation
Cough, labored breathing, shortness of Ventilation, local exhaust. Remove from exposure
breath, sore throat, wheezing.
immediately and seek
medical advice.
Skin
Redness, skin burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, permanent loss of
vision, severe deep burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal cramps.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; do not induce
vomiting. Give copious
amounts of water to drink.
Seek medical advice.
Known carcinogen.
Mutagenicity
Carcinogenicity
No contact with
combustible substances
and reducing agents.
First Aid/Fire
Dry chemical powder,
water spray, foam, carbon
dioxide.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
109
Cinnamaldehyde
C9H8O
CAS No.
PS
104-55-2
Liquid
Types of
Hazard/Exposure
Color
Odor
Yellowish Cinnamon
FP
BP
MP
d
VP
VD
Sol
71
248
-80
1.05
0.03 @ 25
4.6
Slightly
Acute Hazards/Symptoms
Prevention
Fire
Combustible liquid. Fire hazard when
exposed to heat or flame.
Inhalation
Causes irritation to the respiratory tract. Ventilation, local
Symptoms may include coughing or
exhaust.
shortness of breath.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation to skin. Symptoms
Protective gloves
include redness, itching, and pain. May and clothing.
cause allergic reaction in sensitive
individuals.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May cause vomiting and bloody
diarrhea.
Do not eat or drink
in the laboratory.
Give large quantities of
water. Do not induce
vomiting; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
Not a known carcinogen.
No flames, no
sparks, no contact
with hot surfaces.
First Aid/Fire
Mutagenicity
Dry chemical powder,
foam, or carbon dioxide.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
110
(E)-Cinnamic Acid [trans-Cinnamic Acid]
C9H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
140-10-3
Solid
White
N/A
N/A
300
132–135
1.248
N/A
N/A
0.446
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Irritant, may be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant, may be harmful to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is irritating to the eyes,
may be harmful.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
111
N-Cinnamyl-m-nitroaniline
C15H14N2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
22774-96-5
Solid
N/A
N/A
N/A
N/A
115
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A *
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
N/A *
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
N/A *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
N/A *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A *
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
N/A *
Mutagenicity
Carcinogenicity
N/A *
* Toxicological information for the listed chemical is not available; refer to aniline and m-nitroaniline.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
112
N-Cinnamylidene-m-nitroaniline
C15H12N2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
22856-77-5
Solid
N/A
N/A
N/A
N/A
92
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A *
Avoid heat, sparks,
flames.
Inhalation
N/A *
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
N/A *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
N/A *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A *
Do not eat or drink in the
laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
N/A*
Mutagenicity
Carcinogenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
N/A*
* Toxicological information for the listed chemical is not available; refer to cinnamaldehyde and m-nitroaniline.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
113
Citral
C10H16O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
5392-40-5
Liquid
Colorless
Sharp
lemony
90
207
N/A
0.88
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not considered a fire hazard.
Keep away from
open flames and
sparks.
Carbon dioxide, dry
chemical powder,
universal-type Foam.
Inhalation
May be irritating.
Ventilation or local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be irritating.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May be irritating.
Safety goggles.
Ingestion
May be harmful.
Do not eat or drink in Give water; if vomiting
the laboratory.
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
114
Copper
Cu
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7440-50-8
Solid
Reddish
Odorless
N/A
2585
1083
8.92
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Non-flammable.
N/A
N/A
Inhalation
Dust may irritate respiratory tract.
Local Exhaust to
maintain below TLV.
Dust/Mist Respirator.
Remove from exposure
immediately and seek
medical advice.
Skin
Contact can cause irritation and
dermatitis.
Protective gloves and
clothing.
Wash affected skin with
soap and water for 15
minutes. Seek medical
advice. Solid generally
does not irritate the skin.
Eyes
Contact can cause irritation.
Safety goggles.
Flush eyes with plenty of
water for at least 15
minutes. Seek medical
advice.
Ingestion
Can cause nausea, vomiting, and
diarrhea.
Do not eat or drink in
the laboratory.
Seek medical advice. If
vomiting occurs, keep
head lower than hips.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Not a known carcinogen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
115
Cupric Acetate
C4H6CuO4
CAS No.
PS
Color
Odor
FP
BP
MP
D
VP
VD
Sol
6046-93-1
Solid
Green
N/A
N/A
240
115
1.882
N/A
6.9
7.2
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Inhalation
Sore throat, coughing, shortness of
Ventilation, local
breath, digestive disorders, fever, and exhaust.
illness similar to the common cold,
with sensations of chills and stuffiness
of the head.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, and irritation.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, blurred vision, possibly Safety goggles.
conjunctivitis, corneal ulcerations, and
turbidity.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, salivation, abdominal
pain, vomiting, diarrhea, and
hemorrhagic gastritis.
Give water; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Protective gloves and
clothing.
Not a known carcinogen.
Do not eat or drink in
the laboratory.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
116
Cupric Sulfate (pentahydrate)
CuSO4 . 5 H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7758-98-7
Solid
Blue
N/A
N/A
N/A
200
3.603
N/A
N/A
14.3 @ 0
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Negligible fire hazard.
Inhalation
Sore throat, coughing, shortness of
Ventilation, local
breath, chest pain, a metallic taste,
exhaust.
spasm, inflammation, edema of larynx
and bronchi, headache, nausea,
chemical pneumonitis, pulmonary
edema, and laryngitis. Corrosive to
mucous membranes.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, itching, papulovesicular Protective gloves and
and eczematoid lesions, and corrosive clothing.
to skin.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, blurred vision, Safety goggles.
and corrosive to eyes. Copper
deposition in the cornea.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, gastroenteric pain, blue
discoloration of gums and tongue,
hepatic cirrhosis, brain damage,
demyelination.
Give water; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
N/A
First Aid/Fire
Not a known carcinogen.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Do not eat or drink in
the laboratory.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
117
Cuprous Bromide
BrCu
CAS No.
PS
7787-70-4 Powder
Types of
Hazard/Exposure
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
N/A
N/A
N/A
504
4.71
0.5 torr @ 20 oC
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable or combustible.
No flames, no sparks, no
contact with hot surfaces.
Carbon dioxide, dry
chemical powder, foam,
water.
Inhalation
May be harmful. Irritating to
respiratory tract.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed
through skin. Causes irritation.
Protective gloves and
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes serious eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; do not induce
vomiting; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately. Call a
poison center.
Carcinogenicity
Not a known carcinogen
clothing.
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
118
Cyclododecanol
C12H24O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1724-39-6
Solid
White
N/A
N/A
125 @ 12
77–78
0.961
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
No specific data available, possibly
central nervous system depression.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, possibly skin absorption and
allergic dermatitis.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
No specific data available, possibly
central nervous system depression.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
119
Cyclododecanone
C12H22O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
830-13-7
Solid
White
N/A
118
106
60
0.906
0.8 @ 20
N/A
0.0045 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
No signs of toxicity reported.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
120
Cyclohexane
C6H12
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
110-82-7
Liquid
Colorless
Sweet
-18
80.7
6.5
0.779
95 @ 20
2.90
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Moderate
No flames, no sparks,
explosion hazard; vapors or gases may no contact with hot
ignite at distant ignition sources.
surfaces.
Dry chemical powder,
carbon dioxide, water for
cooling, regular foam.
Inhalation
Irritation, central nervous system
depression with headache, dizziness,
dullness, nausea, vomiting,
degenerative changes in the heart,
lungs, liver, kidneys, and brain.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, and dryness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, tearing, redness, and
conjunctivitis.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Central nervous system depression;
aspiration may result in chemical
pneumonitis.
Do not eat or drink in
the laboratory.
Give water; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
121
Cyclohexane-cis-1,2-dicarboxylic Acid
C8H12O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
610-09-3
Solid
White
N/A
N/A
N/A
193– 195
N/A
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, flames,
sparks.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
122
cis-1,2-Cyclohexanediol
C6H12O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1792-81-0
Solid
Colorless
N/A
N/A
N/A
99–101
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid heat, sparks and
flames.
Water spray, carbon
dioxide, dry chemical
powder, or appropriate
foam.
Inhalation
Irritant to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed through
the skin. May cause skin irritation.
Wear protective
clothing and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if ingested.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
123
trans-1,2-Cyclohexanediol
C6H12O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1460-57-7
Solid
Colorless
N/A
134
N/A
101
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid heat, sparks and
flames.
Water spray, carbon
dioxide, dry chemical
powder, or appropriate
foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed through
the skin. May cause skin irritation.
Wear protective
clothing and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if ingested.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
124
Cyclohexanol
C6H12O
CAS No.
PS
108-93-0
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
D
VP
VD
Sol
67
160
20–22
0.948
1.0 @ 21
3.5
Soluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases No flames, no sparks,
may ignite at distant ignition sources. no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam, alcoholresistant foam.
Inhalation
Irritation, central nervous system
depression, dizziness, drowsiness,
headache, nausea, and vomiting.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, defatting of the skin,
Protective gloves and
absorption may lead to central nervous clothing.
system depression, headache,
dizziness, drowsiness, nausea, and
vomiting.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation, coughing, abdominal pain,
diarrhea, central nervous system
depression, headache, weakness,
dizziness, drowsiness, nausea, and
vomiting.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
immediate medical
attention.
Carcinogenicity
Not a known carcinogen.
Ventilation, local
exhaust.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
125
Cyclohexanone
C6H10O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-94-1
Liquid
Colorless
Minty
46
155
-47
0.947
2 @ 20
3.4
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases No flames, no sparks,
may ignite at distant ignition sources. no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, regular
dry chemical powder.
Inhalation
Irritation, changes in the sense of
smell, respiratory system changes,
narcosis, central nervous system
depression, headache, dizziness,
lethargy, and unconsciousness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, burns, labored breathing,
hypnotic signs, defatting, dermatitis,
and peritoneal and intestinal
congestion.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, pain, redness, lacrimation,
and corneal injury.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Coughing, central nervous system
depression, dullness, gastrointestinal
irritation, and unconsciousness.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
126
Cyclohexanone Semicarbazone
C7H13N3O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1589-61-3
Solid
Colorless
N/A
N/A
N/A
167
1.223
N/A
N/A
6
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions. *
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled. *
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be irritating to the skin. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Dust, vapor, or mist may be irritating
to the eyes. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed. *
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Mutagenicity
Not a known mutagen.*
Carcinogenicity
Not a know carcinogen.*
* Toxicological information for the listed chemical is not available. Information given pertains to acetone
semicarbazone and is intended to be used for comparison of a similar compound. Other effects may result from
contact, inhalation, or ingestion.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
127
Cyclohexene
C6H10
CAS No.
PS
Color
Odor
FP
BP
MP
110-83-8
Liquid
Colorless
Sweet
-20
82
-104
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.8102 67 @ 20
Prevention
VD
Sol
2.8
Insoluble
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation, central nervous system
depression, headache, dizziness,
drowsiness, labored breathing, and
kidney and liver damage.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Defatting of the skin, redness, and
burning sensation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, labored breathing, central
Do not eat or drink in
nervous system involvement,
the laboratory.
pulmonary aspiration, and pneumonia.
If vomiting occurs, keep
head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
128
4-Cyclohexene-cis-1,2-dicarboxylic Acid
C8H10O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
935-79-5
Solid
N/A
N/A
N/A
N/A
103–104
N/A
N/A
N/A
Partially
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. *
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Sore throat and coughing. *
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritation. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Redness, pain, and irritation. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the throat and
abdominal spasms. *
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Not a known carcinogen.*
Mutagenicity
Carcinogenicity
Dry chemical powder,
carbon dioxide, water,
regular foam.
Not a known mutagen.*
*Toxicological information for the listed chemical is not available. Information given pertains to phthalic acid and
is intended to be used for comparison of a similar compound. Other effects may result from contact, inhalation, or
ingestion.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
129
1,3-Cyclopentadiene
C5H6
CAS No.
PS
542-92-7
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Petroleum
-like
FP
BP
MP
d
VP
VD
Sol
25
40
N/A
0.8021
249 @ 12
2.3
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, headache, dizziness,
dullness, and central nervous system
effects.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, local redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, nausea.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips. Get
medical attention if
needed.
Not a known carcinogen.
Mutagenicity
Carcinogenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
130
Decanedioyl Dichloride
C10H16Cl2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
111-19-3
Liquid
Colorless
Pungent
>110
168 @ 12
N/A
1.121
N/A
N/A
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks
and flames.
Carbon dioxide, dry
chemical.
Inhalation
Irritation, coughing, choking, pain, burns,
pulmonary edema, and tightness in the
chest.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, pain, burns.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, pain, burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Pain, severe burns, discoloration of the
Do not eat or drink
tissues, and swallowing and speech may be in the laboratory.
difficult or impossible.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
131
Dibasic Potassium Phosphate
HK2O4P
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7758-11-4
Solid
White
Odorless
N/A
N/A
>465
N/A
N/A
N/A
150
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not considered a fire hazard.
Avoid open flames
and sparks.
Use any means suitable for
extinguishing surrounding
fire.
Inhalation
Not expected to be a health hazard.
Ventilation, local
exhaust, or breathing
protection.
Remove from exposure
immediately and seek
medical advice.
Skin
No adverse effects expected.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
No adverse effects expected but dust
may cause mechanical irritation.
Safety goggles.
Ingestion
Symptoms may include vomiting,
lethargy, diarrhea, blood chemistry
effects, cardiac effects and central
nervous system effects.
Do not eat or drink in Give several glasses of
the laboratory.
water to drink to dilute. If
large amounts were
swallowed or symptoms
occur, get medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
132
Di-tert-butyl Dicarbonate
C10H18O5
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
24424-99-5
Solid
Colorless
N/A
88
56–57 @ 0.5
22–24
0.95
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam.
Inhalation
Irritation of the mucous
membrane and lungs. Possible
sensitization and dyspnea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, scaling,
blistering and pain. Possible
sensitization.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice.
Eyes
Irritation, watering, itching,
redness, and pain.
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Gastrointestinal irritation and
diarrhea.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately. Do not
induce vomiting.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
133
m-Dichlorobenzene
C6H4Cl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
541-73-1
Liquid
Clear
N/A
63
172–173
-24
1.288
5 @ 38.8
N/A
Negligible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Emits toxic fumes under fire
conditions.
Do not use near
ignition sources.
Inhalation
Material is irritating to mucous
Ventilation, local
membranes and upper respiratory tract. exhaust.
Harmful if inhaled.
First Aid/Fire
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation. Harmful if
absorbed through the skin.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
134
o-Dichlorobenzene
C6H4Cl2
CAS No.
PS
95-50-1
Liquid
Types of
Hazard/Exposure
Color
Odor
Pale Odorless
yellow
FP
BP
MP
d
VP
VD
Sol
66
180
-17
1.006
1.2 @ 20
5.1
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
water spray, foam, carbon
dioxide.
Inhalation
Cough, drowsiness, sore throat.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, burning sensation, blisters.
Symptoms may be delayed.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation, diarrhea, nausea,
vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water and seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
135
1,2-Dichlorobutane
C4H8Cl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
78-83-1
Liquid
Colorless
N/A
26
125
N/A
1.112
28
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable liquid. Emits toxic fumes. No flames, no sparks,
Vapor may travel a distance to ignition no contact with hot
source and flash back. Forms
surfaces.
explosive mixtures in air.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Harmful if inhaled. Symptoms of
exposure may include burning
sensation, coughing, shortness of
breath, headache, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lachrymator. Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Symptoms of
exposure may include burning
sensation, coughing, laryngitis,
shortness of breath, headache, nausea,
and vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
136
1,3-Dichlorobutane
C4H8Cl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1190-22-3
Liquid
Colorless
N/A
30
134
N/A
1.115
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable liquid. Emits toxic fumes No flames, no sparks,
under fire conditions. Vapor may
no contact with hot
travel considerable distance to ignition surfaces.
source and flash back. Forms
explosive mixtures in air.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Harmful if inhaled. Symptoms of
exposure may include burning
sensation, coughing, wheezing,
laryngitis, shortness of breath,
headache, nausea, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lachrymator. Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Symptoms of
exposure may include burning
sensation, coughing, wheezing,
laryngitis, shortness of breath,
headache, nausea, and vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
137
1,4-Dichlorobutane
C4H8Cl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
110-56-5
Liquid
Colorless
N/A
39
161–163
-38
1.160
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable liquid. Emits toxic fumes No flames, no sparks,
under fire conditions. Vapor may
no contact with hot
travel considerable distance to ignition surfaces.
source and flash back. Forms
explosive mixtures in air.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Harmful if inhaled. Symptoms of
exposure may include burning
sensation, coughing, shortness of
breath, headache, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lachrymator. Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Symptoms of
exposure may include burning
sensation, coughing, shortness of
breath, headache, and vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
138
Dichloromethane [Methylene Chloride]
CH2Cl2
CAS No.
PS
Color
Odor
FP
BP
MP
75-09-2
Liquid
Colorless
Sweet
N/A
39.6
-97
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.325 400 @ 24
Prevention
Sol
2.9
1.32 @ 20
First Aid/Fire
Fire
Slight fire hazard.
Inhalation
Irritation, lightheadedness, tingling,
Ventilation, local
numbness of the extremities, sensation exhaust.
of heat, sensation of fullness in the
head, mental confusion, nausea,
headache, and fatigue.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, possibly burns. Skin
absorption may occur causing effects
detailed in inhalation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Pain and extreme irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Rapid, then slowed respiration,
Do not eat or drink in
gastrointestinal ulceration and
the laboratory.
hemorrhage, and unconsciousness,
central nervous system depression, and
liver and kidney damage.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Known carcinogen.
Possible mutagen.
Carcinogenicity
Avoid heat, flames,
sparks.
VD
Mutagenicity
Carbon dioxide, dry
chemical powder, and
water.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
139
Dicyclopentadiene
C10H12
CAS No.
PS
77-73-6
Solid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
32
BP
MP
d
VP
164–172 dec 32–35 0.979 @ 20 1.4 @ 20
Acute Hazards/Symptoms
Prevention
VD
Sol
4.6
Insoluble
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases may
ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation of mucous membranes and
upper respiratory tract, headache,
vomiting, nausea, dizziness, sneezing,
coughing, and narcotic effects.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation and redness.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, smarting, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, nausea, and focal
hemorrhage of the kidney, intestine,
stomach, bladder, and lung.
Do not eat or drink
in the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
140
Diethyl Benzylphosphonate
C11H17O3P
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1080-32-6
Liquid
Colorless
N/A
109
106–108
N/A
1.095
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, regular
chemical powder, foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
141
Diethyl Ether (anhydrous and technical/solvent grades)
C4H10O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
60-29-7
Liquid
Colorless
Sweet
-4
35
-116
0.7
442 @ 20
2.6
6.9
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard, severe explosion
No flames, no sparks,
hazard, may form explosive peroxides; no contact with hot
vapors or gases may ignite at distant
surfaces.
ignition sources.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Central nervous system depression
with drowsiness, dizziness, nausea,
headache, and lowering of the pulse
and body temperature.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, defatting, and drying of the
skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Painful inflammation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Central nervous system depression
Do not eat or drink in
with nausea, vomiting, drowsiness,
the laboratory.
dizziness; stomach may become
promptly distended, which may hinder
breathing.
Seek medical advice
immediately.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
142
Diethylamine
C4H11N
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
109-89-7
Liquid
Colorless
Fish-like
-29
55
-50
0.707
731
2.5
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Toxic. Corrosive. Lachrymator.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Toxic.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic if swallowed. Exposure to
and/or consumption of alcohol may
increase toxic effects.
Do not eat or drink in
the laboratory.
If swallowed wash out
with water. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
143
N,N-Diethyl-2,6-dimethylacetanilide
C12H22N2O
CAS No.
PS
Color
Odor
FP
BP
MP
D
VP
VD
Sol
137-58-6
Solid
White
N/A
71.1
180–182 @ 4
66–69
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under No flames, no sparks,
fire conditions.
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Harmful if inhaled.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through the skin. Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May be irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Ventilation, local
exhaust.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
144
Diethylene Glycol
C4H10O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
111-46-6
Liquid
Colorless
Odorless
124
245
-6.5
1.12
1 @ 91.8
3.66
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
alcohol-resistant foam,
water in large amounts,
carbon dioxide.
Inhalation
Coughing, dizziness.
Ventilation, local
exhaust.
Remove from exposure
immediately; fresh air,
rest.
Skin
Redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, nausea, vomiting,
dizziness, drowsiness, confusion.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. Give a slurry of
activated charcoal in water
to drink. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
145
N,N-Diethyl-m-toluamide [DEET]
C12H17NO
CAS No.
PS
Color
134-62-3
Liquid
Faint yellowgreen
Types of
Hazard/Exposure
Odor FP
N/A
95
BP
MP
d
VP
VD
Sol
160 @19
N/A
0.998
<0.01
6.7
N/A
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable. Emits toxic fumes
under fire conditions.
Inhalation
May be harmful if inhaled. Material
Ventilation, local
may be irritating to mucous
exhaust.
membranes and upper respiratory tract.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation. May be harmful Protective clothing
if absorbed through the skin.
and gloves.
Neurological hazard. Possible
sensitizer.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Neurological
hazard. Possible sensitizer.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Avoid heat, sparks and Water spray, carbon
flames.
dioxide, dry chemical
powder or appropriate
foam.
Mutagenicity
Mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
146
Dimethyl Fumarate
C6H8O4
CAS No.
PS
624-49-7
Solid
Types of
Hazard/Exposure
Color
Odor
Colorless Odorless
FP
BP
MP
d
VP
VD
Sol
N/A
192–193
104–107
1.37
N/A
N/A
Slightly
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks
and flames.
Dry chemical powder,
carbon dioxide, regular
foam.
Inhalation
Irritation, coughing, and dyspnea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Ingestion
Relatively non-toxic; large amounts
may cause sore throat, vomiting, and
abdominal pain.
Do not eat or drink in Wash out mouth with
the laboratory.
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
147
Dimethyl Maleate
C6H8O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
624-48-6
Liquid
Colorless
N/A
91
204–205
N/A
1.152
1 @ 45.7
4.97
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, regular
foam.
Inhalation
Irritation, coughing, and dyspnea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, and pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, and corneal
erosion.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, abdominal pain, and
vomiting.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
148
Dimethyl Sulfoxide [DMSO]
C2H6OS
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
67-68-5
Liquid
Colorless
N/A
87
189
18.4
1.100
0.42 @ 25
2.7
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible liquid. Emits toxic fumes No open flames or
under fire conditions. Can react
sparks.
violently with several reagents. When
heated above boiling point
formaldehyde, methyl mercaptan, and
sulfur dioxide are given off.
Water spray, Carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be harmful if inhaled.
Remove from exposure
immediately and seek
medical advice.
Skin
Readily absorbed through skin. Avoid Protective gloves and Remove contaminated
contact with DMSO solutions
clothing.
clothes/jewelry,
containing toxic material. DMSO may
thoroughly wash skin with
carry such materials into the body.
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Ingestion
May be harmful if swallowed.
Do not eat drink or If swallowed, wash out
smoke during work.
mouth with water
provided person is
conscious.
Carcinogenicity
Ventilation, local
exhaust, or breathing
protection.
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
149
2,6-Dimethylaniline
C8H11N
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
87-62-7
Liquid
Pale
yellow
N/A
91
214@739
10−12
0.984
<0.01
N/A
0.7 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible. Emits toxic fumes under Avoid heat, sparks,
fire conditions. Container may
flames.
explode under fire conditions.
Water spray, Dry
chemical, foam, or carbon
dioxide.
Inhalation
Highly toxic if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Toxic if in contact with skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water
provided person is
conscious. Seek medical
advice.
Possible carcinogen.
Mutagenicity
Carcinogenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
150
2-(2,4-Dimethylbenzoyl)benzoic Acid
C16H14O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
577-56-0
Powder
White
Odorless
N/A
N/A
116–118
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions. *
Avoid heat, sparks,
flames.
Water spray, dry chemical,
foam, or carbon dioxide.
Inhalation
Irritating to respiratory system.*
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May irritate the skin. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May irritate the eyes. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed. *
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Mutagenicity
Not a known mutagen.*
Carcinogenicity
Not a known carcinogen.*
* Toxicological information for the listed chemical is not available. Information given pertains to 2-actylbenzoic
acid and is intended for comparison of a similar compound. Other effects may result from contact, inhalation, or
ingestion.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
151
4,4-Dimethyl-2-cyclohexen-1-one
C8H12O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1073-13-8
Liquid
Colorless
N/A
64
72–73.5
N/A
0.944
N/A
N/A
Poor
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, regular
chemical powder, foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
152
N,N-Dimethylformamide [DMF]
C3H7NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
68-12-2
Liquid
Colorless
Pungent,
fishy
58
153
-61
.94
2.7 @ 20
2.5
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits irritating or toxic
fumes or gases in a fire.
No flames, no sparks,
no contact with hot
surfaces. No contact
with oxidizing agents.
Dry chemical powder,
alcohol-resistant foam,
water spray, carbon
dioxide.
Inhalation
Abdominal pain, diarrhea, nausea,
vomiting, nervous agitation, facial
flushing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be absorbed. Dry skin, redness,
roughness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice. Refer for
medical attention.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, diarrhea, nausea,
vomiting, nervous agitation, facial
flushing.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. Refer for medical
attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
153
2,6-Dimethylnitrobenzene
C8H9NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
81-20-9
Liquid
Light
yellow
N/A
87
225
14–16
1.112
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible liquid. Emits toxic fumes No flames, no sparks,
under fire conditions.
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Highly toxic if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Toxic if absorbed through skin.
Causes skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
154
1,3-Dinitrobenzene
C6H4N2O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
99-65-0
Powder
Orange
N/A
N/A
297
88–90
1.368
N/A
N/A
0.808
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
May be shock sensitive. Emits toxic
fumes under fire conditions. Capable
of creating a dust explosion. May
explode when heated.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Highly toxic by inhalation. Danger of
cumulative effect.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be fatal if absorbed through skin.
Causes cyanosis, which may be
delayed 2-4 hours.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Symptoms of exposure may include
burning sensation, coughing,
wheezing, nausea, and vomiting.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
155
3,5-Dinitrobenzoic Acid
C7H4N2O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
99-34-3
Solid
White
N/A
N/A
N/A
205–207
N/A
N/A
N/A
0.1–1.0
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, flames and
sparks.
Inhalation
Irritation.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Dry chemical powder,
carbon dioxide, water,
regular foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
156
3,5-Dinitrobenzoyl Chloride
C7H3ClN2O5
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
99-33-2
Solid
Yellow
Pungent
N/A
196
69–71
1.33
9–12 @ 196
7.6–8.0
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
regular foam.
Inhalation
Spasm, inflammation, and edema of
the larynx and bronchi, chemical
pneumonitis, and pulmonary edema.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Corrosive.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Corrosive.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Corrosive.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately; give large
amounts of water or milk,
allow vomiting to occur;
when vomiting occurs,
keep head lower than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
157
3,5-Dinitrophenylhydrazine
C6H6N4O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
119-26-6
Solid
Orange
N/A
14
N/A
197–200
0.84 @ 20
N/A
N/A
0.1-1
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Severe explosion
hazard.
Avoid friction, shock, Flood with water. If water
and heat.
is unavailable, use dry
chemical powder or earth.
Inhalation
Irritation, cyanosis, nausea, central
nervous system effects with tremors,
excitability, and convulsions.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, skin absorption may occur.
Sensitization dermatitis may occur in
previously exposed persons. If
sufficient amounts are absorbed,
systemic toxicity may occur as
detailed in acute inhalation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Systemic toxicity may occur as
detailed in acute inhalation.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; do not induce
vomiting; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
158
1,4-Dioxane
C4H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
123-91-1
Liquid
Colorless
N/A
12
100–102
11.8
1.034
40 @ 25
3
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable; may form explosive
peroxides.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, or
appropriate foam.
Inhalation
Irritation, nausea.
Ventilation, local
exhaust.
Remove from exposure
immediately and get
medical attention.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes and jewelry;
thoroughly wash skin with
soap and water for at least
15 minutes.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, vomiting, headache, and
sweating.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips.
Seek medical attention, if
needed.
Carcinogenicity
Probable carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
159
Diphenyl Ether
C12H10O
CAS No.
PS
101-84-8
Solid
Types of
Hazard/Exposure
Color
Odor
Colorless Unpleasant
FP
BP
MP
d
VP
VD
Sol
115
259
26–30
1.073
0.0213 @ 20
5.8
0.0021
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and
flames.
Dry chemical powder,
carbon dioxide. Water or
foam may cause frothing.
Inhalation
Irritation, nausea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, vomiting, sore throat,
abdominal pain, and diarrhea.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
160
Diphenylacetylene
C14H10
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
501-65-5
Solid
White
N/A
N/A
170 @ 19
59–61
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, regular
chemical powder, foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
161
Disodium Hydrogen Phosphate
HNa2O4P
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7558-79-4
Solid
White
Odorless
N/A
N/A
48.1
1.7
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Not considered to be a fire hazard.
Inhalation
May cause irritation to the respiratory Ventilation, local
tract. Symptoms may include coughing exhaust.
and shortness of breath.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause irritation with redness and
pain.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause irritation, redness and pain. Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Symptoms may include vomiting,
lethargy, diarrhea, blood chemistry
effects, heart disturbances and central
nervous system effects.
Give large amounts of
water to drink. If vomiting
occurs, keep head lower
than hips. Get medical
attention.
Carcinogenicity
Not a known carcinogen.
N/A
First Aid/Fire
Use any means suitable for
extinguishing surrounding
fire.
Protective gloves and
clothing.
Do not eat or drink in
the laboratory.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
162
Dry Ice [Carbon Dioxide, solid]
CO2
CAS No.
PS
Color
Odor
FP
BP
MP
124-38-9
Solid
White
Odorless
N/A
-79
-78.5 1.56 @ -79
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
Sol
569 @ -82
1.52
1.6
Prevention
Fire
Negligible fire hazard.
Inhalation
Acidic taste, headache, vertigo,
Ventilation, local
nausea, labored breathing, weakness, exhaust.
drowsiness, increase in blood pressure,
pulse, and respiratory rate, visual
disturbances, profuse perspiration, and
loss of consciousness.
Remove from exposure
immediately and seek
medical advice.
Skin
Frostbite with redness, tingling, pain,
numbness, hard and white skin, and
blisters.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Stinging, frostbite, redness, pain, and
blurred vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Frostbite.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
N/A
First Aid/Fire
Not a known carcinogen.
Use extinguishing agents
appropriate for
surrounding fire.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
163
Ethanol (anhydrous)
C2H6O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
64-17-5
Liquid
Colorless
Sharp
13
78
N/A
0.7893
40 @ 19
1.59
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation, central nervous system
depression with headache, stupor,
dizziness, drowsiness, dullness,
lassitude, and loss of appetite may
occur.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, burning, contact dermatitis,
skin absorption may occur.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Immediate burning, stinging, reflex
closure of the lids, tearing, and
temporary injury of the corneal
epithelium.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Emotional lability, decreased
inhibitions, exhilaration, visual
impairment, muscular noncoordination, sensory disturbances,
dilated pupils, rapid pulse, nausea,
vomiting, sweating, drowsiness, and
stupor.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
164
Ethanol (95%)
C2H6O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
64-17-5
Liquid
Colorless
Sharp
N/A
78
N/A
0.79–0.81
44
1.6
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors are
heavier than air and can travel
distances to ignition sources and flash
back.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical, carbon
dioxide or alcoholresistant foam. Water may
be ineffective.
Inhalation
High concentrations may cause of
eyes, nose, and throat. Exposure may
result in drowsiness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
High concentrations may cause
headache, irritation of eyes, nose, and
throat. Exposure may result in
drowsiness and inability to
concentrate.
Do not eat or drink in
the laboratory.
If conscious, give plenty
of water. If vomiting
occurs, keep head lower
than hips. Get medical
attention or call poison
control.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
165
Ethyl Acetate [Ethyl Ethanoate]
C4H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
141-78-6
Liquid
Colorless
Sweet
-3
76.5–77.5
-84
0.902
73 @ 20
3
8.7
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors or gases may No flames, no sparks, Alcohol-resistant foam,
ignite at distant ignition sources.
no contact with hot
carbon dioxide, dry
surfaces.
chemical powder, water.
Inhalation
Irritation, headache, coughing,
dizziness, shortness of breath, narcotic
effects, and unconsciousness.
Ventilation, local
exhaust.
Skin
Irritation, redness, and defatting action
on the skin.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, and
lacrimation.
Safety goggles.
Ingestion
Sore throat, abdominal pain, diarrhea,
central nervous system depression,
dizziness, headache, fatigue, and
unconsciousness.
Do not eat or drink in Seek medical advice
the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
166
Ethyl Acetoacetate
C6H10O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
141-97-9
Liquid
Colorless
N/A
73.5
181
-43
1.028
2.6@50
4.48
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Flammable.
Inhalation
May be harmful if inhaled. Material is Ventilation, local
irritating to upper respiratory tract and exhaust.
mucous membranes.
Remove from exposure
immediately and seek
medical advice.
Skin
Cause skin irritation. May be harmful
if absorbed through the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Not a known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
167
Ethyl 4-Aminobenzoate [Benzocaine]
C9H11NO2
CAS No.
PS
Color
Odor
FP
BP
MP
D
VP
VD
Sol
94-09-7
Solid
White
Odorless
N/A
N/A
88–90
1.11
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Noncombustible. Emits toxic fumes
under fire conditions.
Avoid heat, sparks,
flames.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
168
Ethyl Benzoate
C9H10O2
CAS No.
PS
Color
Odor
FP
BP
MP
93-89-0
Liquid
Colorless
Fruity
93.4
212
-34
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.045 1 @ 44
Prevention
VD
Sol
5.18
Insoluble
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
169
Ethyl p-Hydroxybenzoate
C9H10O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
120-47-8
Solid
White
N/A
N/A
297–298
114–117
1.291
N/A
N/A
0.885 g/L
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
No open flames or
sparks.
Dry chemical powder,
carbon dioxide, water,
alcohol-resistant foam.
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
Ingestion
N/A
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medial advice.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
170
Ethyl 6-Methyl-2-oxo-4-phenyl-1,2,3,4-tetrahydropyrimidine-5-carboxylate
C14H16N2O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
5395-36-8
Solid
White
N/A
N/A
N/A
206–207
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid heat, sparks,
and flames.
Water, carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Could be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation may occur.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
Harmful to the eyes.
Safety goggles.
Ingestion
May be harmful if swallowed.
Do not eat or drink in If swallowed, wash out
the laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
171
Ethyl Propionate [Ethyl Propanoate]
C5H10O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
105-37-3
Liquid
Colorless
Fruity
12
99
-73
0.888
30 @27
3.52
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
172
Ethylbenzene
C8H10
CAS No.
PS
100-41-4
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Aromatic
FP
BP
MP
d
VP
VD
Sol
22
136
N/A
0.8670
7.1 @ 20
3.7
0.015
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water for
cooling, regular foam.
Inhalation
Severe irritation, cough, fatigue,
depression, dizziness, and headache.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, inflammation, first- or
second-degree burns; absorption
through skin may cause systemic
toxicity.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and lacrimation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, nausea, vomiting,
aspiration with extensive edema and
hemorrhage of lung tissue.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hip.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
173
Ferric Bromide
FeBr3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
10031-26-2
Solid
Redbrown
Odorless
200
Sublimes
N/A
4.5
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Sol
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
May cause respiratory irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes serious eye irritation
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed
Do not eat or
drink in the
laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
174
Ferric Chloride
FeCl3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
10025-77-1
Solid
Yellow
Unpleasant
N/A
280–285
37
1.82
1
N/A
92 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Severe respiratory tract irritation, sore
throat, cough, and labored breathing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, pain, and burns.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, blurred vision, lacrimation, Safety goggles.
corneal injury and burns.
Ingestion
Abdominal pain, prolonged vomiting,
watery and then tarry diarrhea, intense
dehydration, shock, cyanosis, rapid
respiration, drowsiness, and dilated
pupils.
Carcinogenicity
Not a known carcinogen.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Do not eat or drink Seek medical advice
in the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
175
Ferrous Ammonium Sulfate
Fe(NH4)2(SO4)2·6H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
10045-89-3
Solid
Pale bluegreen
Odorless
N/A
N/A
110–112
1.86
N/A
>1
26.9
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not considered to be a fire hazard.
No open flames or
sparks.
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Causes irritation to the respiratory
tract. Symptoms may include
coughing, shortness of breath.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation to skin. Symptoms
include redness, itching, and pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Causes irritation to the gastrointestinal Do not eat or drink in
tract. Symptoms may include nausea, the laboratory.
vomiting and diarrhea. Low toxicity in
small quantities but larger dosages
may cause nausea, vomiting, diarrhea,
and black stool. Pink urine
discoloration is a strong indicator of
iron poisoning.
Induce vomiting
immediately; keep head
lower than hips. Seek
medical advice.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
176
Fluorene
C13H10
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
86-73-7
Solid
Colorless
N/A
N/A
298
114–116
1.202
10 @ 146
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder, carbon
flames.
dioxide, water, regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek medical
advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep head
lower than hips; get medical
attention, if needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
177
9-Fluorenone
C13H8O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
486-25-9
Solid
Yellow
N/A
163
342
80–83
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, Dry foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, tumors, and may be harmful
if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
178
Fluorescein
C20H12O5
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2321-07-5
Powder
Orange-brown
N/A
N/A
N/A
320
N/A
N/A
N/A
0.05
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. If
vomiting occurs, keep
head lower than hips.
Seek medical advice.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Not a known carcinogen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
179
4-Fluorocinnamic Acid
C9H7FO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
459-32-5
Solid
White
N/A
N/A
N/A
209-210
1
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Forms hydrogen fluoride upon
combustion.
Avoid heat, sparks and Use water spray, alcoholflames.
resistant foam, dry
chemical or carbon
dioxide.
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
180
3-(4-Fluorophenyl)propanoic Acid
C9H9FO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
459-31-4
solid
white
N/A
N/A
N/A
86–91
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
Avoid heat, sparks and Use water spray, alcoholflames.
resistant foam, dry
chemical or carbon
dioxide
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
181
Formic Acid
CH2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
64-18-6
Liquid
Colorless
Pungent
69
100.8
8.5
1.2
23 @ 20
1.6
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard; vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, regular
foam, alcohol-resistant
foam.
Inhalation
Irritation, lightheadedness, nausea,
cough, rhinitis, nasal discharge,
corrosion, dyspnea, bronchitis,
pulmonary edema, shock, and death.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, pain, corrosion,
subsequent dermatitis, second degree
burns, vesiculation, keloid formation,
and absorbed through the skin
producing severe toxic effects.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, lacrimation, acute
inflammation of the eyes,
conjunctivitis, keratitis, redness,
blurred vision, burns, tissue damage,
and permanent corneal scarring.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation in the mouth,
salivation, corrosion of the glottis,
esophagus, and stomach, abdominal
pain, nausea, diarrhea, and difficulty
breathing.
Do not eat or drink in
the laboratory.
Seek medical attention
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
182
D-Fructose
C6H12O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
57-48-7
Solid
Colorless
Odorless
N/A
N/A
119–122
1.60
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emit toxic fumes under fire conditions. No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
183
2-Furaldehyde [Furfural]
C5H4O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
98-01-1
Liquid
Colorless
Pungent
58
162
-36
1.160
1.7 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
VD
Sol
3.31 8.3 @ 20
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
Inhalation
Burning sensation, coughing,
Ventilation, local
laryngitis, headache, nausea, vomiting. exhaust.
May cause sensitization.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes burns. May cause
sensitization. May cause allergic
reactions and photosensitivity.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Toxic and causes burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation in the mouth,
Do not eat or drink in
coughing, laryngitis, headache, nausea, the laboratory.
vomiting. May cause nervous system
disturbances.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Possible carcinogen.
Not a known mutagen.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Dry chemical powder,
carbon dioxide,
appropriate foam.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
184
2-Furaldehyde Semicarbazone
C6H7N3O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2411-74-7
Solid
Off-white
Odorless
N/A
N/A
202
N/A
N/A
N/A
Poor
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes
under fire conditions. *
No flames, no sparks, no
contact with hot surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled. *
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be irritating to the skin. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Dust, vapor, or mist may be
irritating to the eyes. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed. *
Do not eat or drink in the
laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.*
Mutagenicity
Not a known mutagen.*
* Toxicological information for the listed chemical is not available. Information given pertains to acetone
semicarbazone and is intended to be used for comparison of a similar compound. Other effects may result from
contact, inhalation, or ingestion.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
185
Glass Wool
CAS No.
PS
Color
Odor
FP
BP
MP
D
VP
VD
Sol
65-17-3
Solid
Colorless
None
N/A
N/A
N/A
Varies
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable. Emits toxic fumes
under fire conditions.
Inhalation
Irritation or soreness in throat and
Ventilation, local
nose. May be irritating to mucous
exhaust.
membranes and upper respiratory tract.
Remove from exposure
immediately. Drink water
to clean throat and blow
nose to evacuate fibers.
Skin
Mechanical irritant to skin. May be
harmful is absorbed through the skin.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Temporary irritation or redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Maybe harmful if swallowed. May
cause temporary irritation of GI tract.
Do not eat or drink in
the laboratory
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips.
Seek immediate medical
advice.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks, Media suitable for
no contact with hot
surrounding fire. Carbon
surfaces.
dioxide, dry chemical
powder or appropriate
foam.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
186
D-Glucose
C6H12O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
50-99-7
Solid
Colorless
Odorless
N/A
N/A
83
1.56
N/A
N/A
90.9
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not considered to be a fire hazard.
N/A
Use any means suitable for
extinguishing surrounding
fire.
Inhalation
No adverse health effects expected
from inhalation.
Ventilation, local
exhaust.
Not expected to require
first aid measures.
Skin
Not expected to be a health hazard
from skin exposure.
Protective gloves and
clothing.
Not expected to require
first aid measures.
Eyes
No adverse effects expected but dust
may cause mechanical irritation.
Safety goggles.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Ingestion
Extremely large oral dosages may
produce gastrointestinal disturbances.
Do not eat or drink in
the laboratory.
Give several glasses of
water to drink to dilute. If
vomiting occurs, keep
head lower than hips. If
large amounts were
swallowed, get medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
187
tris-[3-(Heptafluoropropylhydroxymethylene)-(+)-camphorato]europium
C42H42EuF21O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
34788-82-4
Solid
Yellow
N/A
N/A
N/A
156–158
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May irritate skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be harmful to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
188
Heptane
C7H16
CAS No.
PS
142-82-5
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Gasolinelike
FP
BP
MP
d
VP
VD
Sol
-4
91
-91
0.697
40 @ 20
3.5
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry foam, carbon dioxide.
No water.
Inhalation
Dullness, headache.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Dry skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal cramps, burning sensation, Do not eat or drink in
nausea, vomiting.
the laboratory.
Wash mouth out with
water. Do not induce
vomiting. Rest. Seek
medical advice.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
189
Hexane
C6H14
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
110-54-3,
107-83-5
Liquid
Colorless
Gasolinelike
-7
69
-95
0.660
125
3
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapor may travel
considerable distance to ignition
source and flash back.
Inhalation
Toxic by inhalation. Vapor is
Ventilation, local
irritating to the upper respiratory track. exhaust.
Symptoms may include headache,
dizziness, and nausea.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic by ingestion. Symptoms may
include headache, dizziness and
nausea.
Do not eat or drink in
the laboratory.
If swallowed, wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Dry chemical powder,
carbon dioxide,
appropriate foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
190
1,6-Hexanediamine [Hexamethylenediamine]
C6H16N2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
6055-52-3
Solid
Colorless
Fishy
N/A
204–205
41–42
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, flames,
and sparks.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
191
1-Hexene
C6H12
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
592-41-6
Liquid
Colorless
Pleasant
-26
63
-140
0.67
310 @ 20
3.0
Negligible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
foam, carbon dioxide.
Inhalation
Cough, dizziness, drowsiness, sore
throat, vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Dry skin, redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Cough, dizziness, drowsiness, sore
throat, vomiting.
Do not eat or drink in
the laboratory.
Wash mouth out with
water. Do not induce
vomiting. Refer for
medical attention.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Not a known carcinogen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
192
Hydrazine (8%)
H4N2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
521-31-3
Solid
Yellow
N/A
52
113
1.4
N/A
10 @ 30
1
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks, no Carbon dioxide, dry
contact with hot
chemical power, or
surfaces.
appropriate foam.
Inhalation
Burning sensation, headache, and
nausea. Extremely destructive to
tissue of mucous membranes and
upper respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, corrosion,
subsequent dermatitis, burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Acute inflammation of the eyes,
pain, redness and burning.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation in the mouth,
salivation, abdominal pain, nausea,
vomiting, and difficulty breathing.
Do not eat or drink in the Wash out mouth with
laboratory.
water. Do not induce
vomiting. Seek medical
advice.
Carcinogenicity
Suspect carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
193
Hydrobromic Acid (concentrated)
HBr
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
10035-10-6
Liquid
Colorless
Irritating
N/A
74 @ 100
N/A
1.5
N/A
2.8
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
Inhalation
Irritation, coughing, choking, burns of the Ventilation, local
mucous membranes, headache, nausea,
exhaust.
pulmonary edema, tightness in the chest,
dizziness, and weak, rapid pulse.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe pain, burns, and brownish or
yellowish stains.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Pain, lacrimation, photophobia, burns,
and blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate pain, difficulty or inability to Do not eat or drink
swallow or speak, thirst, nausea,
in the laboratory.
vomiting, diarrhea, weak, rapid pulse, and
shallow respiration.
Seek medical advice
immediately. Give water;
if vomiting occurs, keep
head lower than hips.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
N/A
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
194
Hydrochloric Acid (solutions, 9-37%)
HCl
CAS No.
PS
7647-01-0
(Hydrogen
Chloride)
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Irritating
or yellow
FP
BP
MP
N/A
65.5–110
N/A
Acute Hazards/Symptoms
d
VP
1.07–1.18 30 @ 20
Prevention
VD
Sol
1.3
Soluble
First Aid/Fire
Fire
Negligible fire hazard.
Inhalation
Burning of the throat, coughing,
Ventilation, local
choking, inflammation, ulceration of the exhaust.
nose, throat or larynx, bronchitis,
pneumonia, palpitations, and headache.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, inflammation,
ulceration, necrosis, chemical burns,
shock, rapid pulse, sweating, and
collapse.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Severe irritation, conjunctivitis, corneal
necrosis, and burns with impairment or
permanent loss of vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burns of the mouth, throat, esophagus
and stomach, pain, uneasiness, nausea,
salivation, vomiting, diarrhea, chills,
shock and intense thirst.
Do not eat or drink
in the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
N/A
Not a known carcinogen.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
195
Hydrogen Peroxide (solutions, 3–30%)
H2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7722-84-1
Liquid
Colorless
Pungent
N/A
126
-40
1.11
23.3 @ 20
1
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard; may ignite or
explode on contact with combustible
materials.
Avoid contact with
Water or other appropriate
combustible materials. extinguishers for the fire.
Inhalation
Irritation, sore throat, coughing,
shortness of breath, headache,
dizziness, vomiting, diarrhea, and
numbness.
Ventilation, local
exhaust.
Skin
Irritation, tingling and whitening of the Protective gloves and
skin, erythema or vesicle formation,
clothing.
severe burns, ulceration.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, stinging, tearing, blurred
vision, severe corneal or conjunctival
ulceration.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation and injury to the mouth and Do not eat or drink in
throat, distention of the esophagus and the laboratory.
stomach, and stomach and chest pains.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Safety goggles.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
196
4-Hydroxyacetanilide [Acetaminophen]
C8H9NO2
CAS No.
PS
Color
103-90-2
Solid
Types of
Hazard/Exposure
White
Odor
FP
BP
Odorless
N/A
N/A
MP
d
VP
VD
Sol
0
N/A
N/A
168–172 1.29
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Inhalation
May cause respiratory irritation.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice
Eyes
Causes serious eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice
Ingestion
Harmful if swallowed.
Do not eat or drink in the
laboratory.
If swallowed wash out
mouth with water. Seek
medial advice.
Carcinogenicity
Not a known carcinogen.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
197
Hydroxylamine Hydrochloride
ClH4NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
5470-11-1
Solid
Colorless
Odorless
N/A
N/A
152
1.67
N/A
N/A
83
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not combustible. Emits irritating or
toxic fumes or gases in a fire.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Blue lips or fingernails, blue skin,
headache, dizziness, nausea,
confusion.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Blue lips or fingernails, blue skin,
headache, dizziness, nausea,
confusion.
Do not eat or drink in
the laboratory.
Wash mouth out with
water. Give a slurry of
activated charcoal in water
to drink. Refer for medical
attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
198
3-Hydroxy-3-methyl-2-butanone
C5H10O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
115-22-0
Liquid
Colorless
N/A
42
140–141
N/A
0.95
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible and flammable.
Vapor may travel back to distant
ignition sources.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Maybe harmful if inhaled. May
cause irritation.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful and cause
irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May be harmful and cause
irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Maybe be harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
199
Iodine
I2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7553-56-2
Solid
Purple to
black
Pungent
N/A
184.4
113.5
4.93
0.305 @
25
8.8
0.03 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard. May ignite or
explode on contact with combustible
materials.
Avoid contact with
Use extinguishing agents
combustible materials. appropriate for
surrounding fire.
Inhalation
Severe irritation of the mucous
membranes, severe cough, headache,
headaches, and feeling of tightness in
the chest.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Brown discoloration of the skin with
marked erythema, desquamation, and
vesiculation with weeping and
crusting.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Burning sensation, irritation, and
lacrimation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Inflammation and corrosion of the
gastrointestinal tract, brown
discoloration of the lips and mucous
membranes, a burning sensation,
nausea, vomiting, diarrhea, intense
thirst, metallic taste, and fever.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give milk,
then starch solution; if
vomiting occurs, keep
head lower than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
200
Iodine Monochloride
ICl
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7790-99-0
Solid
Red
Pungent
N/A
N/A
27.2
3.240
N/A
N/A
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard. May ignite or
explode on contact with combustible
materials.
Avoid contact with
Use extinguishing agents
combustible materials. appropriate for
surrounding fire.
Inhalation
Sore throat, coughing, labored
breathing, fatigue, respiratory
irritation, and pulmonary edema.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Potent lachrymator, burning, and
corneal injury.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, labored breathing,
gastrointestinal irritation, abdominal
pain, nausea, and vomiting.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
201
Isobutyl Chloroformate
C5H9ClO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
543-27-1
Liquid
Colorless
Sharp
82
129
N/A
1.053
N/A
N/A
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam. Do not
use water.
Inhalation
Burning sensation, coughing,
wheezing, laryngitis, headache,
nausea, and vomiting. Destructive to
the tissue of the mucous membrane.
Toxic by inhalation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, corrosion, subsequent
dermatitis, burns, blistering
vesiculation, keloid formation, and
absorbed through the skin producing
severe toxic effects.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry, wash with
5% sodium bicarbonate,
soap and water, and seek
medical advice.
Eyes
Watering of the eyes, acute
Safety goggles.
inflammation of the eyes, pain, redness
and burning. Material is a
lachrymator.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation in the mouth,
salivation, corrosion of the glottis,
esophagus, and stomach, abdominal
pain, nausea, and difficulty breathing.
Wash out mouth with
water. Do not induce
vomiting. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Do not eat or drink in
the laboratory.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
202
Isobutylbenzene
C10H14
CAS No.
PS
538-93-2
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Aromatic
FP
BP
MP
d
VP
VD
Sol
54
170 @ 736
-51
0.853
4.22
NA
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible and Flammable.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, carbon
dioxide, dry chemical
powder, or appropriate
foam.
Inhalation
May be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
203
(-)-Isopinocampheol
C10H18O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
25465-65-0
Solid
White
N/A
93
219
52–55
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, flames,
sparks.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
204
Isopropylbenzene
C9H12
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
98-82-8
Liquid
Colorless
Aromatic
31
152.4
-962
0.862
3.2 @ 20
4.2
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Highly flammable.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
foam, carbon dioxide.
Inhalation
Ataxia, cough, dizziness, drowsiness,
headache, sore throat.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Dry skin.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin
with soap and water, and
seek medical advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several
min, removing contact
lenses if possible, and
seek medical advice.
Ingestion
Ataxia, cough, dizziness, drowsiness,
headache, sore throat.
Do not eat or drink
in the laboratory.
Wash mouth out with
water. Do not induce
vomiting. Refer for
medical attention.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
205
Isopropylxylenes
C11H16
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Liquid
Colorless
Mild
aromatic
N/A
193–216
N/A
0.85
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible liquid.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled. Irritation to
respiratory system. Prolonged exposure
can cause nausea, headache, and
vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin. May cause drying,
cracking and redness.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes. May cause redness
and stinging.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed. May cause Do not eat or drink If swallowed wash out
irritation to the gastrointestinal tract.
in the laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
206
Lead Acetate
C4H6PbO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
301-04-2
Solid
White
Pungent
N/A
N/A
280
3.25
N/A
N/A
44 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Metallic taste, thirst, a burning
sensation in the mouth and throat,
excessive salivation, abdominal pain,
vomiting, fatigue, sleep disturbances,
dullness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Metallic taste, thirst, a burning
sensation in the mouth and throat,
excessive salivation, abdominal pain,
vomiting, fatigue, sleep disturbance.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. If vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
207
Lemongrass Oil
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
8007-02-1
Liquid
N/A
Lemon-like
90
N/A
N/A
0.9
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible. Emits toxic fumes under Avoid heat, sparks and Water spray, carbon
fire conditions.
open flames.
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Irritating to mucous membranes and
upper respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation.
Wear protective
clothing and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if ingested.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
208
Magnesium
Mg
CAS No.
PS
Color
Odor
FP
BP
MP
7439-95-4
Solid
Silver
Odorless
N/A
1107
649
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.7 @ 5 1 @ 621
Prevention
VD
Sol
N/A
Reacts
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
sand, lime, soda ash.
Inhalation
Burning sensation, coughing,
wheezing, laryngitis, and headache.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe local lesions if particles
perforate the skin or gain access
through cuts.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Formation of hydrogen bubbles.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Gastrointestinal irritation, nausea,
vomiting, chills, fever, muscle and
joint pain, anorexia, abdominal pain,
and diarrhea.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
209
Magnesium Sulfate (anhydrous)
MgSO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7487-88-9
Solid
White
N/A
N/A
N/A
1124
2.65
0.1 @20
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Non-flammable.
N/A
Use extinguishing media
appropriate for
surrounding fire.
Inhalation
May cause respiratory tract irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May cause gastrointestinal irritation
with nausea, vomiting and diarrhea.
Do not eat or drink in
the laboratory.
Given 2–4 cups of milk or
water if conscious. If
unconscious get medical
attention immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
210
Maleic Anhydride
C4H2O3
CAS No.
PS
Color
Odor
FP
BP
MP
108-31-6
Solid
Colorless
Irritating
103
200
54–56
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.314 @ 60 1 @ 44
Prevention
VD
Sol
3.4
Reacts
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Alcohol-resistant foam,
flames.
carbon dioxide.
Inhalation
Irritation; fumes cause: burning
sensation in the throat, coughing, and
vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, inflammation, blistering,
burns, and possibly absorbed through
skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, severe burns; fumes cause
conjunctivitis, corneal damage or
edema,, double vision, and
lacrimation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Corrosion, sore throat, abdominal pain, Do not eat or drink in
nausea, and vomiting.
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
211
Mercuric Oxide
HgO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
21908-53-2
Solid
Orange-red
Odorless
N/A
N/A
500
11.14
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Strong oxidizer; heat of reaction with
reducing agents or combustibles may
cause ignition. Upon heating, forms
oxygen, increasing flammability of
combustibles.
No open flames or
sparks.
Use any means suitable for
extinguishing surrounding
fire.
Inhalation
Irritation to the respiratory tract.
Symptoms include sore throat,
coughing, pain, tightness in chest,
breathing difficulties, and headache.
Can be absorbed through inhalation
with symptoms to parallel ingestion.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation. Symptoms include
redness and pain. May cause burns.
May cause sensitization. Can be
absorbed through the skin with
symptoms to parallel ingestion.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation and burns to eyes.
Symptoms include redness, pain,
blurred vision; may cause serious and
permanent eye damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Highly toxic! May cause burning of
the mouth and pharynx, abdominal
pain, vomiting, corrosive ulceration,
bloody diarrhea.
Do not eat or drink in
the laboratory.
Induce vomiting
immediately, keep head
lower than hips and get
medical attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
212
Methanol [Methyl Alcohol]
CH4O
CAS No.
PS
Color
Odor
FP
BP
MP
67-56-1
Liquid
Colorless
Sharp
11
64.6–64.7
-98
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.7914 97.25 @ 20
Prevention
VD
Sol
1.11
Soluble
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases may
ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation, coughing, unsteady gait,
twitching, constipation, numbness, and
shooting pains in the hands and
forearms.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, skin absorption may lead to
Protective gloves
metabolic acidosis and effects on the
and clothing.
eyes and central nervous system given in
acute ingestion.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, violent inflammation of the
Safety goggles.
conjunctiva, and epithelial defects on the
cornea.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Inebriation, drowsiness, coughing,
headache, dullness, weakness, vertigo,
dizziness, nausea, vomiting, occasional
diarrhea, and blindness.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Do not eat or drink
in the laboratory.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
213
Methyl Acetoacetate
C5H8O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
105-45-3
Liquid
Colorless
N/A
69
169–170
-80
1.076
N/A
4
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible liquid.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Irritating to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Can cause blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
214
Methyl L-Alanyl-L-phenylalaninate Tetrafluoroacetate
C15H18F4N2O5
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Solid
White
N/A
N/A
N/A
185–186
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
215
Methyl Benzoate
C8H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
93-58-3
Liquid
Colorless
Fruity
82
198–199
-12
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.094 1 @ 39
Prevention
VD
Sol
4.68
Insoluble
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
216
Methyl N-tert-Butoxycarbonyl- L-alanyl- L-phenylalaninate
C18H26N2O5
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Solid
White
N/A
N/A
N/A
83–84
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips,
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
217
Methyl Iodide
CH3I
CAS No.
74-88-4
PS
Color
Liquid Colorless
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
Acrid
N/A
42
-66.1
2.28
400 @ 25
4.9
14
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not considered to be a fire hazard. Fire
may produce poisonous or irritating
gases.
No open flames or
sparks.
Dry chemical powder,
foam, carbon dioxide, or
water spray.
Inhalation
Inhalation of vapors can irritate the
respiratory tract. Overexposure may
produce symptoms of vertigo, delirium
and mental disturbances. Other
symptoms may include slurred speech,
drowsiness, coughing, nausea and
vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation, rash and blister
Protective gloves and
formation. Prolonged contact can cause clothing.
skin burns. Can be absorbed through skin
with toxic effects.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapors can cause irritation. Splashes
may cause severe irritation with eye
damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Ingestion may damage the gastrointestinal tract. Severe intoxication can
occur with symptoms of central nervous
system depression.
Do not eat or drink in
the laboratory.
Induce vomiting
immediately; keep head
lower than hips. Get
medical attention
immediately.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
218
Methyl Isobutyrate [Methyl 2-Methylpropanoate]
C5H10O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
547-63-7
Liquid
Colorless
Fruity
3
90
N/A
0.891
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable.
No open flames or
sparks.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
May be harmful by inhalation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Ingestion
May be harmful if swallowed.
Do not eat or drink in If swallowed wash out
the laboratory.
mouth with water
provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
219
Methyl L-Phenylalaninate.Hydrochloride
C10H14ClNO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7524-50-7
Solid
White
N/A
N/A
N/A
158–162
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately, get medical
attention.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Wash out mouth with
water. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
220
Methyl Propionate [Methyl Propanoate]
C4H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
554-12-1
Liquid
Colorless
Fruity
-2
79
-88
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.915 40 @ 11
Prevention
VD
Sol
3.04
Insoluble
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
221
3-Methylbenzoic Acid
C8H8O2
CAS No.
PS
Color
Odor
FP
99-94-5
Solid
White
Odorless
N/A
Types of
Hazard/Exposure
BP
MP
274−275 180−182
Acute Hazards/Symptoms
d
VP
VD
Sol
1.27
N/A
N/A
0.33
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under No flames, no sparks,
fire conditions.
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Harmful if inhaled. Irritating to
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the Safety goggles.
eyes.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Do not eat or drink in
the laboratory.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
222
(+/-)-α-Methylbenzylamine
C8H11N
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
618-36-0
Liquid
Colorless
N/A
79
185 @ 756
-65
0.940
N/A
N/A
Poor
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Inhalation
Extremely destructive to tissue of the Ventilation, local
mucous membranes and upper
exhaust.
respiratory track. Symptoms may
include burning sensation, coughing,
shortness of breath, headache,
nausea, and vomiting.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Extremely destructive to tissue of
skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Symptoms
may include burning sensation,
coughing, shortness of breath,
headache, nausea, and vomiting.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth wish water. Seek
medical advice.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
Not a known carcinogen.
Mutagenicity
Dry chemical powder,
carbon dioxide,
appropriate foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
223
Methylcyclohexane
C7H14
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-87-2
Liquid
Colorless
Sweet
-3
101
-126–126.3
0.77
37 @ 20
3.4
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Moderate explosion No flames, no sparks,
hazard, vapors or gases may ignite at
no contact with hot
distant ignition sources.
surfaces.
Dry chemical powder,
carbon dioxide, water for
cooling, regular foam.
Inhalation
Irritation, light-headedness,
drowsiness, lacrimation, salivation,
labored breathing, diarrhea, and liver
and kidney damage.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, hardening, ulceration, and
defatting.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Conjunctival congestion.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation, lethargy, severe diarrhea,
liver and kidney damage, and
circulatory collapse.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
224
N-Methylimidazole
C4H6N2
CAS No.
PS
616-47-7 Liquid
Types of
Hazard/Exposure
Color
Odor
FP
BP
MP
d
VP
VD
Sol
Colorless
N/A
92
198
-6
1.03
0.5 @ 20
N/A
N/A
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible/flammable liquid.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
May be harmful. Irritating to
respiratory tract.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Toxic in contact with skin. Causes
irritation.
Protective gloves and
Eyes
Causes serious eye damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water; do not induce
vomiting; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately. Call a
poison center.
Carcinogenicity
Not a known carcinogen
clothing.
Mutagenicity
Carbon dioxide, dry
chemical powder, foam,
water.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
225
N-Methylmorpholine
C5H11NO
CAS No.
PS
109-02-4
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
d
VP
VD
Sol
24
115
-66
0.92
5 @ 20
3.5
Soluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, water
spray or alcohol-resistant
foam.
Inhalation
Irritiation, pneumonitis, and
pulmonary edema.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, pain, and burning.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, burning and
conjunctivitis.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Gastrointestinal irritation, pain,
nausea, vomiting, and diarrhea.
Do not eat or drink in
the laboratory.
If victim is conscious, give
2–4 cupfuls of milk or
water. Seek medical
advice. Do not induce
vomiting.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
226
4-Methylphenylboronic acid
C7H9BO2
CAS No.
PS
Color
Odor
FP
BP
MP
5720-05-8
Solid
Colorless
N/A
N/A
N/A
256-263
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
Sol
N/A N/A
N/A
N/A
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no
sparks, no
contact with hot
surfaces.
Inhalation
May be harmful. Irritating to respiratory tract.
Ventilation, local Remove from exposure
exhaust.
immediately and seek
medical advice.
Skin
Irritation; may be harmful if absorbed through
skin.
Protective gloves Remove contaminated
and clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes serious irritation.
Safety goggles.
Thoroughly flush eyes
with water for at least 15
min, removing contact
lenses if possible, and seek
medical advice.
Ingestion
Toxic if swallowed.
Do not eat or
drink in the
laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Carbon dioxide, dry
chemical powder, alcoholresistant foam, water.
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
227
2-Methylpropanal [Isobutyraldehyde]
C4H8O
CAS No.
PS
78-84-2
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
d
VP
VD
Sol
-25
63–64
-65
0.7938
66 @ 25
2.5
Slightly
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition
sources.
Inhalation
Irritation, central nervous system
Ventilation, local
depression, and symptoms similar to exhaust.
alcohol intoxication.
Remove from exposure
immediately, get medical
attention.
Skin
Irritation, burns, lethal amounts may Protective gloves and
be absorbed through skin.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lacrimation, irritation, and burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Central nervous system depression
and symptoms similar to alcohol
intoxication.
Do not eat or drink in the Seek medical attention
laboratory.
immediately. If vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks, no Alcohol-resistant foam,
contact with hot
carbon dioxide, dry
surfaces.
chemical powder, water.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
228
Methyltrioctylammonium Chloride
C25H54ClN
CAS No.
5137-55-3
PS
Color
Viscous Colorless
liquid
to pale
orange
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
109
N/A
N/A
0.884
N/A
N/A
Partially
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Harmful if inhaled. Symptoms may
include burning, coughing, headache,
nausea, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed. Symptoms
may include burning, coughing,
headache, nausea, and vomiting.
Do not eat or drink in
the laboratory.
If swallowed, wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
229
4'-Methyl(1.1’-biphenyl)-4-)methanol
C14H14O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
79757-92-9
Solid
Colorless
N/A
N/A
N/A
128.5–129.5
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder, foam,
water.
Inhalation
May be harmful. Irritating to
respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Toxic in contact with skin.
Protective gloves and
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
clothing.
Eyes
May cause irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately. Call a poison
center.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult thefor this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
230
2-Methyl-2-butanol
C5H12O
CAS No.
PS
75-85-4
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
d
VP
VD
Sol
21
102
-12
0.805
10 @ 17.2
3.0
Slightly
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition
sources.
No flames, no sparks, no Alcohol-resistant foam,
contact with hot
carbon dioxide, dry
surfaces.
chemical powder, water
for cooling.
Inhalation
Headache, dizziness, nausea,
vomiting, diarrhea, coughing,
shortness of breath, excitement and
delirium.
Ventilation, local
exhaust.
Skin
Irritation. May be absorbed through Protective gloves and
the skin, causing headache,
clothing.
dizziness, nausea, vomiting,
flushing, rapid pulse and respiration,
drop in blood pressure, and
unconsciousness.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Conjunctivitis, double vision and
Safety goggles.
irritation. May be absorbed, causing
headache, dizziness, cough,
shortness of breath, vomiting,
excitement and delirium.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, vomiting, diarrhea,
headache, shortness of breath,
cough, dizziness, excitement and
delirium followed by coma.
Carcinogenicity
Not a known carcinogen.
Remove from exposure
immediately and seek
medical advice.
Do not eat or drink in the If vomiting occurs, keep
laboratory.
head lower than hips; get
medical attention
immediately.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
231
2-Methyl-1-butene
C5H10
CAS No.
PS
563-46-2
Liquid
Types of
Hazard/Exposure
Color
Odor
FP
Colorless Unpleasant <-7
BP
MP
D
VP
VD
Sol
31-32
N/A
0.6504
N/A
2.4
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
No flames, no sparks,
may ignite at distant ignition sources. no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water
for cooling.
Inhalation
Irritation, central nervous system
depression, asphyxia
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation to the gastrointestinal tract;
aspiration into the lungs may cause
death due to chemical pneumonitis.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. If vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
232
2-Methyl-2-butene
C5H10
CAS No.
PS
513-35-9
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Unpleasant
FP
BP
MP
d
VP
VD
Sol
-20
37–38
-134
0.663
N/A
2.4
Slightly
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
Inhalation
Irritation, central nervous system
Ventilation, local
depression with dizziness,
exhaust.
disorientation, headache, vomiting and
nausea; respiratory and cardiac
depression, burning sensation.
Remove from exposure
immediately and seek
medical advice.
Skin
Erythema.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Diarrhea and central nervous system
depression with labored breathing and
respiratory failure. Aspiration may
result in chemical pneumonitis.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water
for cooling.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
233
2-Methyl-3-butyn-2-ol
C5H8O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
115-19-5
Liquid
Colorless
N/A
25
104
2.6
0.868
N/A
N/A
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide or dry
chemical powder. Do not
use water.
Inhalation
Causes irritation to respiratory tract
and mucous membranes.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Can irritate skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Can irritate eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Causes irritation to mucous
membranes.
Do not eat or drink in
the laboratory.
Requires antidote. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
234
2-Methyl-3-heptanol
C8H18O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
14979-39-6
Liquid
Colorless
N/A
54
98−99 @75
N/A
0.827
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible. Flammable.*
Avoid heat, sparks,
and flames.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Irritating to respiratory system.*
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.*
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes.*
Safety goggles.
Ingestion
May be harmful if swallowed.*
Do not eat or drink in If swallowed, wash out
the laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen. *
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen. *
* Toxicological information for the listed chemical is not available. Information given pertains to 4-methyl-3heptanol and is intended to be used for comparison of a similar compound. Other effects may result from contact,
inhalation, or ingestion.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
235
4-Methyl-2-pentanol
C6H14O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-11-2
Liquid
Colorless
Sweet
41
132
-90
0.802
2.8 @ 20
3.53
Slight
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard; vapors or gases
may ignite at distant ignition sources.
Inhalation
Irritation, sore throat, coughing,
Ventilation, local
headache, shortness of breath, and
exhaust.
central nervous system depression with
weakness, nausea, and fatigue.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation with redness and pain,
absorbed through the skin and may
cause central nervous system
depression with weakness, dizziness,
drowsiness, vomiting and fatigue.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and blurred vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea,
Do not eat or drink in
and central nervous system depression. the laboratory.
If vomiting occurs, keep
head lower than hips, get
immediate medical
attention.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Regular dry chemical,
carbon dioxide, regular
foam, alcohol-resistant
foam.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
236
2-Methyl-1-pentene
C6H12
CAS No.
763-29-1
PS
Color
Liquid Colorless
Types of
Hazard/Exposure
Odor
FP
BP
MP
Sharp
-9
62
-136
Acute Hazards/Symptoms
d
VP
0.682 325 @ 37.7
Prevention
VD
Sol
N/A
Insoluble
First Aid/Fire
Fire
Severe fire hazard Vapors or gases may
ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, regular
chemical powder, foam,
water for cooling.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation; may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
237
2-Methyl-2-pentene
C6H12
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
625-27-4
Liquid
Colorless
NA
-12
67
-135
0.690
267 @ 100
NA
NA
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
No flames, no sparks,
may ignite at distant ignition sources. no contact with hot
surfaces.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Harmful if inhaled. Symptoms of
exposure may include burning
sensation, coughing, wheezing,
laryngitis, headache, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Symptoms of exposure may include
burning sensation, coughing,
wheezing, laryngitis, headache,
nausea, and vomiting. Can cause
CNS depression.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water
provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
238
4-Methyl-1-pentene
C6H12
CAS No.
PS
Color
Odor
FP
BP
MP
691-37-2
Liquid
Colorless
Sharp
-7
53-54
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.6642 424 @ 38
Prevention
VD
Sol
2.9
Insoluble
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Regular dry chemical,
carbon dioxide, water for
cooling, regular foam.
Inhalation
Irritation and may cause central
nervous system depression with
vomiting, dyspnea, cyanosis, vertigo,
and loss of consciousness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
No specific data available; central
Do not eat or drink in
nervous system depression may occur. the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips.
Get medical attention
immediately.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
239
4-Methyl-2-pentene, cis- and transC6H12
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
4461-48-7
Liquid
Colorless
Sharp
<-7
56–59
N/A
0.669
N/A
2.90
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Regular dry chemical,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, possible narcotic and may
cause CNS depression with vomiting,
dyspnea, cyanosis, vertigo, loss of
consciousness, and even death at high
concentrations.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
No specific data available; CNS
depression may occur.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips.
Get medical attention
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
240
2-Methyl-1-propanol
C4H10O
CAS No.
PS
78-83-1
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Pungent
FP
BP
MP
d
VP
VD
Sol
28
108
-108
0.801
8
2.55
Soluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable liquid, emits toxic fumes, No flames, no sparks,
vapor may travel considerable distance no contact with hot
to ignition source and flash back.
surfaces.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
May be harmful if inhaled. Symptoms Ventilation, local
of exposure may include burning
exhaust.
sensation, coughing, wheezing,
laryngitis, headache, and vomiting.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation, May be harmful Protective gloves and
if absorbed through skin. Causes
clothing.
dermatitis.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes severe eye irritation. Risk of
serious damage to eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Symptoms of exposure may include
burning sensation, coughing,
laryngitis, shortness of breath,
headache, nausea, and vomiting.
Do not eat or drink in
the laboratory.
Wash out mouth with
water if person is
conscious. If vomiting
occurs, keep head lower
than hips. Seek medical
advice.
Mutagenicity
Not a known mutagen.
Carcinogenicity
Not a known carcinogen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
241
2-Methyl-2-propanol
C4H10O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
75-65-0
Liquid
Colorless
N/A
11
83
25–26
0.775
44
2.5
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Irritating to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic, harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
242
Mineral Oil (Nujol)
CH3(CH2)nCH3
CAS No.
PS
8042-47-5
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Odorless
FP
BP
MP
d
VP
VD
Sol
N/A
N/A
N/A
N/A
N/A
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable. Emits toxic fumes
under fire conditions.
Avoid heat, sparks and Water spray, carbon
open flames.
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Maybe harmful if inhaled. May be
irritating to mucous membranes and
upper respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation. May be
harmful if absorbed through the skin.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Maybe be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed, wash out
mouth with water
provided person is
conscious. If vomiting
occurs, keep head lower
than hips. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
243
Naphthalene
C10H8
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
91-20-3
Solid
White
Mothballs
N/A
218
80.5
0.963
N/A
4.4
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Explosion
possible.
Inhalation
Irritation, headache, nausea, vomiting, Ventilation, local
abdominal cramps, diarrhea, edema,
exhaust.
perspiration, and confusion.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and severe dermatitis.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, conjunctivitis, injury to the
cornea, cataracts, and diminished
visual acuity.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal cramps, nausea, vomiting, Do not eat or drink in
diarrhea, headache, profuse
the laboratory.
perspiration, bladder irritation,
hemolytic anemia, hemoglobinuria,
convulsions, liver injury with jaundice
and acute renal failure.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips;
get medical attention
immediately.
Possible carcinogen.
Not a known mutagen.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Dry chemical powder,
sand, earth, regular foam,
water
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
244
2-Naphthalenesulfonic Acid
C10H8SO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
120-18-3
Solid
Colorless
N/A
N/A
N/A
124−125
1.441
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Reacts violently with water. Emits
Avoid heat, sparks,
toxic fumes under fire conditions. May and flames.
accelerate combustion.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Harmful if inhaled. Inhalation may
result in spasm, inflammation, and
edema of the larynx and bronchi,
pulmonary edema.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, pain, and burns.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes. Extremely
destructive to tissue in eyes.
Safety goggles.
Ingestion
May be fatal if swallowed. Exposure
Do not eat or drink in If swallowed wash out
can cause burning sensation, wheezing, the laboratory.
mouth with water. Seek
laryngitis, shortness of breath and
medical advice.
vomiting.
Carcinogenicity
Carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
245
1-Naphthol [αNaphthol]
C10H8O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
90-15-3
Solid
White
Phenolic
N/A
278–280
95–96
1.10
1 @ 94
4.5
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Inhalation
Causes irritation to the respiratory tract. Ventilation, local
Symptoms may include coughing,
exhaust.
shortness of breath. Inhalation may
result in symptoms and problems similar
to ingestion.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause severe irritation, redness, and Protective gloves
pain. May be absorbed through the skin and clothing.
with symptoms paralleling ingestion and
causing kidney damage. Local action
may cause peeling of the skin which
may be followed by persistent
pigmentation.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation, redness, pain, and
Safety goggles.
injury to the cornea and lens of the eyes.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Large doses may cause abdominal pain,
nausea, vomiting, sweating, intense
thirst, cyanosis.
Induce vomiting, keep
head lower than hips. Get
medical attention.
Carcinogenicity
No flames, no
sparks, no contact
with hot surfaces.
Not a known carcinogen.
Do not eat or drink
in the laboratory.
Mutagenicity
Water spray, Dry chemical
powder, alcohol foam, or
carbon dioxide.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
246
2-Naphthol [Naphthol]
C10H8O
CAS No.
PS
Color
Odor
FP
135-19-3
Solid
White
Mothballs
153
Types of
Hazard/Exposure
BP
MP
285-286 122-123
Acute Hazards/Symptoms
d
VP
VD
Sol
1.2
3.6 @ 130
4.97
Slightly
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, regular
dry chemical.
Inhalation
Sweating, intense thirst, nausea,
vomiting, diarrhea, hyperactivity,
stupor, hypotension, hyperapnea, and
abdominal pain.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Blanching, erythema, tissue
destruction, may be absorbed to cause
effect as given under inhalation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May cause effects as given under
inhalation.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. If vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
247
1-Naphthyl Isocyanate
C11H7NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
86-84-0
Liquid
Colorless
Sharp
109
267 @ 761
N/A
1.177
N/A
5.8
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, regular
foam.
Inhalation
Irritation, coughing, chest pains,
difficulty breathing, allergic
respiratory reaction, and
unconsciousness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Allergic skin reaction, irritation, pain,
and possibly burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, pain, and burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Bile stasis and the cessation of bile
flow.
Do not eat or drink in
the laboratory.
If vomiting occurs keep
head lower than hips, get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
248
Nitric Acid (concentrated)
HNO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7697-37-2
Liquid
Colorless
to yellow
Sharp
N/A
100
N/A
1.36–1.41
45 @ 25
1
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard. May ignite or
explode on contact with combustible
materials.
Inhalation
Severe respiratory irritation, coughing, Ventilation, local
choking, yellowish burns of the
exhaust.
mucous membranes, headache, and
nausea.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe pain, burns, yellowish stains.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Pain, lacrimation, photophobia, burns,
blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Corrosion of the mucous membranes
of the mouth, throat and esophagus,
immediate pain and difficulty or
inability to swallow or speak,
vomiting, and diarrhea.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Avoid contact with
Dry chemical powder,
combustible materials. soda ash, water.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
249
Nitric Acid (fuming)
HNO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
Nitric Acid
7697-37-2
Nitrogen
Dioxide 1010244-0
Liquid
Yellow to red
Sharp
N/A
100
N/A
1.4
62 @ 25
1
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard. May ignite or
explode on contact with combustible
materials.
Avoid contact Dry chemical powder,
with
soda ash, water.
combustibles.
Inhalation
Nitric acid: coughing, headache, dizziness,
and weakness, dryness of throat/nose, and
chest pain or tightness. Nitrogen dioxide:
usually no symptoms at time of exposure;
delayed symptoms: fatigue, cough.
Ventilation,
Remove from exposure
local exhaust. immediately and seek
medical advice.
Skin
Nitric acid: immediate severe and
penetrating burns, staining the skin yellow
or yellowish-brown. Nitrogen dioxide:
severe irritation, pain, yellow-brown
discoloration, and burns.
Protective
gloves and
clothing.
Eyes
Nitric acid: pain, photophobia, tearing,
Safety
edema, corneal ulceration, and severe burns. goggles.
Nitrogen dioxide: severe irritation with
redness, pain, blurred vision, edema of the
eyelids, corneal ulceration, and burns.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nitric acid: immediate pain in the mouth,
throat, and stomach, nausea, vomiting, and
diarrhea. Nitrogen dioxide: acid taste,
nausea, and vomiting.
Do not eat or
drink in the
laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Mutagenicity Not a known mutagen.
Carcinogenicity
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
250
3-Nitroaniline
C6H6N2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
99-09-2
Solid
Yellow
N/A
N/A
N/A
112–114
N/A
N/A
N/A
0.089
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Avoid contact with
Carbon dioxide, dry
combustible materials. chemical powder or
appropriate foam.
Inhalation
Harmful by inhalation. May be fatal if
inhaled. May cause cyanosis, onset
may be delayed 2-4 hours.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be fatal if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be fatal if swallowed. May cause Do not eat or drink in
cyanosis, onset may be delayed for 2-4 the laboratory.
hours.
Wash out mouth with
water, provided person is
conscious. If vomiting
occurs, keep head lower
than hips. Seek medical
advice.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
251
4-Nitroaniline
C6H6N2O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
100-01-6
Solid
Pale
yellow
N/A
164
260
@100
-36
1.160
Types of
Hazard/Exposure
Acute Hazards/Symptoms
VP
VD
1.7 @ 20 3.31
Sol
0.08 @ 18.5
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, dry chemical
foam, or carbon dioxide.
Inhalation
Exposure can cause headache,
unconsciousness, coughing, chest
pains, difficulty breathing and
vomiting
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Toxic if in contact with skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic if swallowed. Exposure to
Do not eat or drink in
and/or consumption of alcohol may
the laboratory.
increase toxic effects. Exposure can
cause chest pains, difficulty breathing,
diarrhea, vomiting.
If swallowed wash out
mouth with water
provided person is
conscious. Seek medical
advice.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
252
Nitrobenzene
C6H5NO2
CAS No.
98-95-3
PS
Color
Odor
Liquid Pale yellow Almond-like
Types of
Hazard/Exposure
FP
BP
MP
d
VP
VD
Sol
88
211
-5.7
1.2
1 @ 44.4
4.3
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible. Gives off irritating or toxic No flames, no sparks,
fumes (or gases) in a fire.
no contact with hot
surfaces.
Dry alcohol-resistant
foam, water spray, carbon
dioxide.
Inhalation
Blue lips or fingernails, blue skin,
dizziness, headache, nausea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be absorbed. Blue lips or
fingernails, blue skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapors cause eye irritation. Splashes
cause severe irritation, possible corneal
burns and eye damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May cause headache, shallow
respiration, dizziness, vomiting,
weakness.
Do not eat or drink in
the laboratory.
Wash mouth out with
water. Induce vomiting,
keep head lower than hips.
Rest. Refer for medical
attention.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
253
3-Nitrobenzyl Alcohol
C7H7NO3
CAS No.
PS
Color
Odor
FP
BP
MP
619-25-0
Solid
Colorless
N/A
N/A
175-180 @ 3
30-32
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
Sol
1.29 N/A
N/A
N/A
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks, Carbon dioxide, dry
no contact with hot
chemical powder, foam,
surfaces.
water.
Inhalation
May be harmful. Irritating to respiratory
tract.
Ventilation, local
exhaust.
Skin
Irritation; may be harmful if absorbed
through skin.
Protective gloves and Remove contaminated
clothes/jewelry,
clothing.
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause irritation.
Safety goggles.
Ingestion
Toxic if swallowed.
Do not eat or drink in Wash out mouth with
the laboratory.
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
254
4-Nitrobenzyl Alcohol
C7H7NO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
619-73-8
Solid
Pale yellow
N/A
N/A
185 @ 12
92–94
N/A
N/A
N/A
2 g/L
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks, Carbon dioxide, dry
no contact with hot
chemical powder, foam,
surfaces.
water.
Inhalation
May be harmful. Irritating to respiratory
tract.
Ventilation, local
exhaust.
Skin
Irritation; may be harmful if absorbed
through skin.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause irritation.
Safety goggles.
Ingestion
Toxic if swallowed.
Do not eat or drink in Wash out mouth with
the laboratory.
water; if vomiting occurs,
keep head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
255
4-Nitrocinnamic Acid
C9H7NO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
612-41-9
Solid
Light
yellow
N/A
154
346
289 dec
1.411
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
No flames, no sparks,
no contact with hot
surfaces.
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
256
3-(4-Nitrophenyl)propanoic Acid
C9H9NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
16642-79-8
Solid
Yellow
N/A
N/A
382.7
164–168
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
Harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice
Skin
Harmful if contacts with skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
257
3-Nitrophthalhydrazide
C8H5N3O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
3682-15-3
Solid
Yellow
N/A
N/A
N/A
300
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks, no Carbon dioxide, dry
contact with hot
chemical powder, or
surfaces.
appropriate foam.
Inhalation
Irritation of the respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract.
Do not eat or drink in the Wash out mouth with
laboratory.
water. Do not induce
vomiting. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
258
3-Nitrophthalic Acid
C5H5NO6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
603-11-2
Solid
Pale yellow
N/A
N/A
N/A
213–216
N/A
N/A
7
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam.
Inhalation
Irritation of the respiratory tract.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract,
vomiting, and diarrhea.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Wash out mouth with
water. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
259
Norbornene [Bicyclo[2.2.1]hept-2-ene]
C7H10
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
498-66-8
Solid
White
Sharp
-14
96
44–46
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
sand, earth, regular foam,
water.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
260
exo-Norborneol [exo-Bicyclo[2.2.1]heptane-2-ol]
C7H12O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
497-37-0
Solid
White
N/A
N/A
176–177
124–126
N/A
N/A
N/A
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, Dry foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips;
get medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
261
Nutmeg
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
N/A
Solid
Brown
Spicy, fragrant
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable.
Avoid heat, sparks and Triclass, dry chemical fire
flames.
extinguisher.
Inhalation
May cause irritation to mucous
membranes in some individuals.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation is some
individuals.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
N/A
Do not eat or drink in
the laboratory.
If swallowed, give large
quantities of water. Call a
physician or poison
control at once.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this material.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
262
Nylon-6,10
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
9008-66-6
Solid
White
N/A
N/A
N/A
N/A
1.040
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
Inhalation
May be harmful by inhalation. Do not Ventilation, local
breathe vapor.
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Dry chemical powder,
carbon dioxide,
appropriate foam.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
263
Palladium on Carbon (10%)
Pd/C
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
540-69-2
Solid
Black
Odorless
N/A
2963
1560
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
May cause respiratory irritation.
Ventilation, local
exhaust
Remove from exposure
immediately and seek
medical advice
Skin
Causes skin irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
Causes serious eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
264
Pentane
C5H12
CAS No.
109-66-0
PS
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Gasolinelike
FP
BP
MP
d
VP
VD
Sol
-49
35–36
-130
0.626
434 @ 20
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapor may travel
considerable distance to ignition
source and flash back.
No flames, no sparks, no Dry chemical powder,
contact with hot
carbon dioxide,
surfaces.
appropriate foam.
Inhalation
May be harmful by inhalation.
Vapor is irritating to the upper
respiratory track. Symptoms may
include headache, dizziness, and
nausea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful if absorbed though
skin. May cause skin irritation,
dermatitis.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation. Symptoms
may include redness, blurred vision,
tears.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Symptoms may include headache,
dizziness and nausea. Aspiration
hazard if swallowed.
Do not eat or drink in the If swallowed, wash out
laboratory.
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
265
3-Pentanone
C5H10O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
96-22-0
Liquid
Colorless
Sharp, mint-like
-7
101
-42
0.813
37.5 @ 28
2.97
29
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Highly flammable.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
foam, carbon dioxide.
Inhalation
Cough, dizziness, dullness,
headache, nausea, shortness of
breath, vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be absorbed through skin.
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness. Pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Dizziness. Drowsiness. Headache.
Do not eat or drink in
the laboratory.
Wash out mouth with
water and give copious
amounts of water to drink;
if vomiting occurs, keep
head lower than hips.
Seek medical advice
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
266
Petroleum Ether (30–60 °C)
CAS No.
PS
Multiple
components
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Gasolinelike
FP
BP
MP
d
VP
VD
Sol
-46
37–56
N/A
0.643
714 @ 38
2.5
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no sparks,
no contact with hot
surfaces. Avoid
strong oxidizing
agents.
Dry chemical, foam or
carbon dioxide. Water
may be ineffective.
Inhalation
Dullness, headache.
Ventilation, local
exhaust.
Remove from exposure
immediately, get medical
attention.
Skin
Dry skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal cramps, burning sensation, Do not eat or drink in
nausea, vomiting.
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
267
Petroleum Ether (60–90 °C)
CAS No.
PS
Multiple
components
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Gasolinelike
FP
BP
MP
~ -130 ~60–56 N/A
Acute Hazards/Symptoms
d
VP
VD
Sol
0.69–0.80
@ 20
40 @ 20
2.5
Insoluble
Prevention
First Aid/Fire
Fire
Severe fire hazard.
No flames, no
sparks, no contact
with hot surfaces.
Avoid strong
oxidizing agents.
Dry chemical, foam or
carbon dioxide. Water
may be ineffective.
Inhalation
Dullness, headache.
Ventilation, local
exhaust.
Remove from exposure
immediately, get medical
attention.
Skin
Dry skin.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal cramps, burning sensation,
nausea, vomiting.
Do not eat or drink
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
268
Phenol
C6H6O
CAS No.
PS
Color
Odor
FP
BP
MP
108-95-2
Solid
Colorless
Tar-like
79
182
40–42
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
1.071 0.35 @ 25
Prevention
VD
Sol
3.24
5
First Aid/Fire
Fire
Moderate fire hazard; vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
regular foam, alcoholresistant foam.
Inhalation
Severe irritation of the mucous
membranes, profuse sweating,
headache, intense thirst, nausea,
vomiting, abdominal pain, and
diarrhea.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Local anesthesia, skin necrosis,
painless burns due to damage to nerve
endings, readily absorbed through the
skin causing symptoms given in
inhalation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Severe irritation, redness, pain, blurred Safety goggles.
vision, severe blindness, and loss of
the eye.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning of the mouth and throat,
Do not eat or drink in
abdominal pain, pale face, contracted the laboratory.
or dilated pupils, circulatory collapse,
tachypnea, paralysis, convulsions,
coma, jaundice, necrosis of mouth and
gastrointestinal tract.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
269
Phenolphthalein
C20H14O4
CAS No.
PS
77-09-8
Solid
Types of
Hazard/Exposure
Color
Odor
Variable Odorless
FP
BP
MP
d
VP
VD
Sol
N/A
N/A
261
N/A
N/A
N/A
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks, Water spray, carbon
no contact with hot
dioxide, dry chemical
surfaces.
powder or appropriate
foam.
Inhalation
May be irritating if inhaled.
Ventilation, local
exhaust.
Skin
Irritating to the skin.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice.
Eyes
Vapor or mist is irritating to the eyes.
Safety goggles.
Ingestion
Toxic, harmful if swallowed.
Do not eat or drink in Wash out mouth with
the laboratory.
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
270
3-Phenylpropanoic Acid
C9H10
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
501-52-0
Liquid
Colorless
N/A
113
280
45–48
1.07
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
N/A
N/A
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide
Inhalation
N/A
Ventilation, local
exhaust
Remove from exposure
immediately and seek
medical advice
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible.
Ingestion
N/A
Do not eat or drink in
the laboratory.
Consult physician
immediately
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
271
L-Phenylalanine
C9H11NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
63-91-2
Solid
White
Odorless
N/A
N/A
283
1.29
N/A
N/A
1–5
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately, get medical
attention.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Sore throat, gastric pain, nausea,
vomiting, and allergic reactions.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Wash out mouth with
water. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
272
Phenylhydrazine
C6H8N2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
100-63-0
Liquid
Red-brown
Faint
aromatic
88
243.5
19
1.1
1 @ 71.8
3.7
Slightly
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible. Gives off irritating or toxic
fumes (or gases) in a fire.
No flames, no
sparks, no contact
with hot surfaces.
Water spray, alcoholresistant foam, carbon
dioxide.
Inhalation
Coughing, labored breathing, sore throat,
cyanosis.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be absorbed. Dry skin, redness,
pain.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, diarrhea, nausea,
vomiting, weakness, vertigo.
Do not eat or drink
in the laboratory.
Wash out mouth with
water. Rest. If vomiting
occurs, keep head lower
than hips. Refer for
medical attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
273
Phenylhydrazine Hydrochloride
C6H9ClN2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
59-88-1
Solid
N/A
N/A
N/A
N/A
240
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under No flames, no sparks,
fire conditions.
no contact with hot
surfaces.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
May be irritating if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with 5% aqueous
sodium bicarbonate, soap
and water, and seek
medical advice.
Eyes
Vapor or mist is irritating to the eyes. Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic, harmful if swallowed.
If swallowed wash out
mouth with water provided
person is conscious. Seek
medical advice.
Carcinogenicity
Do not eat or drink in
the laboratory.
Carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
274
Phenylmagnesium Bromide (1 M in THF)
C5H5MgBr
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
100-58-3
Liquid
solution
N/A
N/A
-17
N/A
N/A
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Extremely flammable. Emits toxic
fumes under fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Very toxic.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Very caustic, may cause burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is very irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Very toxic, harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
275
p-Phenylphenol
C12H10O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
92-69-3
Solid
White
N/A
165–167
321
164–166
>1
N/
A
5.9
0.7 g/L
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
N/A
Fire
N/A
Inhalation
Causes skin irritation.
Skin
N/A
Eyes
N/A
Ingestion
Carcinogenicity
Not a known carcinogen.
First Aid/Fire
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
regular foam, alcoholresistant foam.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice
Do not eat or drink
in the laboratory.
If swallowed, wash out
mouth with water. Seek
medial advice.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
276
Phthalic Anhydride
C8H4O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
85-44-9
Solid
White
N/A
N/A
284
131–133
1.494
<0.01
5.1
Decomposes
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled. Irritating
to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
277
Picric Acid
C6H3N3O7
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
88-89-1
Solid
Yellow
Odorless
150
N/A
122
1.77
N/A
N/A
1.4
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable solid. Dangerous fire hazard
when exposed to heat or flame.
Inhalation
Causes irritation to respiratory tract.
Ventilation, local
Symptoms include coughing, shortness of exhaust.
breath. Systemic poisoning can cause
headache, dizziness, nausea, vomiting,
abdominal pain and diarrhea.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes irritation to skin. Symptoms
include redness, itching, and pain. May
cause allergic skin reactions. May be
absorbed through the skin with possible
systemic effects.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Fume is irritating to the eyes. Splashes
can cause eye injury.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Causes irritation to the gastrointestinal
tract. Symptoms may include nausea,
vomiting and diarrhea. Other symptoms
may parallel those from inhalation.
Do not eat or drink
in the laboratory.
Do not induce vomiting.
Give large quantities of
water. Get medical
attention.
Carcinogenicity
Not a known carcinogen.
No flames, no
sparks, no contact
with hot surfaces.
Mutagenicity
Fight fire from protected
location or maximum
distance. Do not use carbon dioxide or halogenated extinguishing agents.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
278
(+)--Pinene
C10H16
CAS No.
PS
7785-70-8
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Petroleum
-like
FP
32
BP
154–156
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
N/A
0.857–0.862
N/A
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
Inhalation
Irritation, destruction to tissue, burning Ventilation, local
sensation, coughing, wheezing,
exhaust.
shortness of breath, dizziness, headache,
nausea, and vomiting.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, dermal eruptions, and may be Protective gloves and
absorbed through skin and cause effects clothing.
as detailed in inhalation.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and burning sensation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Effects as detailed in inhalation.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks,
no contact with hot
surfaces.
Mutagenicity
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water
for cooling.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
279
Polystyrene
(C8H8)n
CAS No.
PS
Color
Odor
FP
BP
MP
9003-53-6
Solid
White
Odorless
345–360
N/A
86–91
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
Sol
1.04–1.13 N/A
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
N/A
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
280
Potassium Bromide
KBr
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7758-02-3
Solid
White
Odorless
N/A
N/A
734
2.750
<0.01
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Non-flammable. Emits toxic fumes
under fire conditions.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
May be harmful if inhaled. Irritating
to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
281
Potassium tert-Butoxide
C4H9OK
CAS No.
PS
Color
Odor
FP
BP
865-47-4
Solid
White
Odorless
N/A
N/A
Types of
Hazard/Exposure
MP
d
VP
VD
256–258 dec 1.850 1 @ 220 N/A
Acute Hazards/Symptoms
Prevention
Sol
Reacts
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
N/A
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Harmful if inhaled. Very irritating to
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Caustic, may burn skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water
provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
282
Potassium Carbonate
K2CO3
CAS No.
PS
Color
Odor
584-08-7
Solid
White
Odorless
Types of
Hazard/Exposure
FP
BP
N/A Decomposes
MP
d
VP
VD
Sol
891
2.29
N/A
N/A
112 @ 20
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
Inhalation
Irritation, coughing, choking, pain, burns Ventilation, local
of the mucous membranes, and
exhaust.
pulmonary edema.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe pain, burns, and brownish stains. Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Pain, burns, edema, corneal
opacification, permanent opacity, and
blindness.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate pain, corrosion of the mucous Do not eat or drink
membranes, shortness of breath,
in the laboratory.
laryngitis, headache, nausea, vomiting,
profuse salivation, and difficulty or
inability to swallow or speak.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
N/A
Safety goggles.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
283
Potassium Chloride
KCl
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7447-40-7
Solid
White
Odorless
N/A
N/A
770
1.984
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Non-flammable. Emits toxic fumes
under fire conditions.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
May be harmful if inhaled. Irritating
to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
284
Potassium Ferricyanide
K3Fe(CN)6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
13746-66-2
Solid
Orange
N/A
N/A
N/A
N/A
1.850
N/A
NA
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Non-flammable. Emits toxic fumes
under fire conditions.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Harmful if inhaled. Very irritating to
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
285
Potassium Fluoride
KF
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7789-23-3
Solid
White
Odorless
N/A
N/A
860
2.480
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Non-flammable. Emits toxic fumes
under fire conditions.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
May be harmful if inhaled. Very
irritating to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
286
Potassium Hydroxide
KOH
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1310-58-3
Solid
White
Odorless
N/A
1316
360
2.044
1.0 @ 719
N/A
110
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
Inhalation
Irritation, coughing, choking, pain, burns Ventilation, local
of the mucous membranes, and tightness exhaust.
in the chest.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe pain, burns, and brownish stains. Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Pain, burns, edema, destruction of
epithelium, permanent opacity, and
blindness.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate pain, corrosion of the mucous Do not eat or drink
membranes, profuse salivation, and
in the laboratory.
difficulty or inability to swallow or
speak.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
N/A
Safety goggles.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
287
Potassium Iodide
KI
CAS No.
PS
Color
Odor
FP
BP
MP
7681-11-0
Solid
White
Odorless
N/A
1330
681
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
3.13 @ 15 1 @ 745 N/A
Prevention
Sol
129 @ 6
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, coughing, and chest
discomfort.
Ventilation, local
exhaust.
Remove from exposure
immediately, get medical
attention.
Skin
Pimples, boils, hives, blisters, black and
blue spots.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, corrosive.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Gastrointestinal upset, nausea, and
vomiting.
Do not eat or drink
in the laboratory.
Seek medical advice
immediately. Give milk
then starch solution; if
vomiting occurs, keep
head lower than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
288
Potassium Permanganate
KMnO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7722-64-7
Solid
Purple
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard, but may
ignite or explode on contact with
combustible materials.
Avoid contact with
combustible materials.
Inhalation
Irritation, labored breathing,
choking, pain in the nose, mouth
and throat, and burns of the
mucous membranes.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Burns, redness, and pain.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Burns, redness, pain, lacrimation,
and blurred vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Inflammation, nausea, vomiting,
and difficulty speaking or
swallowing. Overexposure can
cause anemia and kidney damage.
Do not eat or drink in the
laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
289
1-Propanol [n-Propyl Alcohol]
C3H8O
CAS No.
PS
71-23-8
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Alcoholic
FP
BP
MP
d
VP
VD
Sol
23
97
-127
0.804
21 @ 25
2.07
Miscible
Acute Hazards/Symptoms
Prevention
First Aid/Fire
No flames, no sparks,
no contact with hot
surfaces.
Water spray, dry chemical
powder, alcohol foam, or
carbon dioxide.
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
Inhalation
Vapors have a mild narcotic effect and Ventilation, local
act as an upper respiratory tract
exhaust.
irritant. Symptoms may include
irritation of the eyes, nose, and throat,
drowsiness, headache, and lack of
coordination.
Remove from exposure
immediately and seek
medical advice.
Skin
Defatting agent. May cause skin
irritation. Skin absorption may occur
with symptoms paralleling those from
inhalation exposure.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapors are irritating to the eyes.
Splashes may cause severe irritation,
with stinging, tearing, redness and
pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May cause nausea, vomiting,
drowsiness, gastrointestinal pain,
cramps and diarrhea.
Do not eat or drink in
the laboratory.
Give large amounts of
water to drink. If vomiting
occurs, keep head lower
than hips. Get medical
attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
290
2-Propanol [Isopropyl Alcohol]
C3H8O
CAS No.
PS
67-63-0
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Alcoholic
FP
BP
MP
d
VP
VD
Sol
12
82.4
-89.5
0.7855
40 @ 24
2.1
Miscible
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Irritation, chest tightness, wheezing,
and large amounts may cause
symptoms similar to acute ingestion.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, contact dermatitis, and large Protective gloves and
amounts may result in symptoms
clothing.
similar to acute ingestion.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, transitory injury,
conjunctivitis, iritis, and corneal
opacity.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, nausea, vomiting,
and hemorrhage, hypoglycemia,
tenderness and edema of muscles, and
arrhythmias, vomiting with aspiration
may cause aspiration pneumonia.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips. Get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
291
Propionic Acid [Propanoic Acid]
C3H6O2
CAS No.
PS
79-09-4
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Vinegary
FP
BP
MP
d
VP
VD
Sol
54
141
-21
0.993
2.4 @ 20
2.56
Soluble
Acute Hazards/Symptoms
Prevention
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam, alcoholresistant foam
Inhalation
Irritation, pharyngeal edema, chronic
bronchitis, coughing, shortness of
breath, laryngitis, pulmonary edema,
and hypotension.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, pain, blisters, burns and
superficial destruction of the skin;
readily absorbed through the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
water and 5% aqueous
sodium bicarbonate, and
seek medical advice.
Eyes
Irritation, lacrimation, corneal erosion, Safety goggles.
opacification, iritis, and possibly loss
of sight.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Severe ulceronecrotic lesions, stricture Do not eat or drink in
of the esophagus, diarrhea, shock,
the laboratory.
vomiting, abdominal spasms.
Seek medical advice. Give
large amounts of water
and allow vomiting to
occur; when vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
First Aid/Fire
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
292
n-Propyl Benzoate [1-Propyl Benzoate]
C10H12O2
CAS No.
PS
Color
Odor
FP
2315-68-6
Liquid
Colorless
Fruity
98.0 229.5 @ 766
Types of
Hazard/Exposure
BP
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
51.6
1.026
0.13
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
293
n-Propyl Propionate [1-Propyl Propanoate]
C6H12O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
106-36-5
Liquid
Light
yellow
Fruity
19
122
-76
0.881
10.7 @ 20
4.01
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard. Vapors or gases
may ignite at distant ignition sources.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain, vomiting, diarrhea, and Do not eat or drink
depression.
in the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
294
Propylene Glycol [1,3-Propanediol]
C3H8O2
CAS No.
PS
57-55-6
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Odorless
FP
BP
MP
d
VP
VD
Sol
23
99
-59
1.0361
0.129 @ 25
2.6
Miscible
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
foam, water or carbon
dioxide.
Inhalation
No adverse health effects via
inhalation.
Ventilation, local
exhaust.
Not expected to require
first-aid measures.
Skin
Mild irritant and defatting agent,
especially on prolonged contact.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause transitory stinging and
tearing.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Relatively non-toxic. Ingestion of
sizable amount (over 100 mL) may
cause some gastrointestinal upset and
temporary central nervous system
depression.
Do not eat or drink in
the laboratory.
Not expected to require
first aid measures. Give
several glasses of water to
drink to dilute. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
295
Pyridine
C5H5N
CAS No.
PS
Color
Odor
FP
BP
MP
110-86-1
Liquid
Colorless
Fish-like
20
115–116
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.978 18 @ 20
Prevention
VD
Sol
2.72
Soluble
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition sources.
Inhalation
Irritation, unpleasant taste in the mouth, Ventilation, local
narcosis, dizziness, drowsiness, and
exhaust.
headache.
Skin
Redness, irritation, burns,
photosensitivity and sensitization
reactions, and subdermal hemorrhages.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and corneal damage.
Safety goggles.
Ingestion
Nausea, fatigue, mental depression,
vomiting, and diarrhea.
Do not eat or drink in Seek medical advice
the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks, Alcohol-resistant foam,
no contact with hot
carbon dioxide, dry
surfaces.
chemical powder, water
for cooling.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
296
Pyridinium Tribromide
C5H6Br3N
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
39416-48-3
Solid
Red
N/A
N/A
Decomposes
135–
137
N/A
N/A
11.0
Decomposes
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Hazardous decomposition products
formed under fire conditions: carbon
oxides, nitrogen oxides (NOx), gaseous
hydrogen bromide
Inhalation
May be harmful if inhaled. Material is
Ventilation, local
extremely destructive to the tissue of the exhaust
mucous membranes and upper respiratory
tract
Remove from exposure
immediately and seek
medical advice
Skin
May be harmful if absorbed through skin. Protective gloves
Causes skin burns.
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes eye burns
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink Consult physician
in the laboratory.
immediately
Carcinogenicity
Not a known carcinogen
No flames, no
sparks, no contact
with hot surfaces.
Mutagenicity
Use water spray, alcoholresistant foam, dry
chemical or carbon
dioxide.
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
297
Resorcinol
C6H6O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-46-3
Solid
White
Phenolic
170
178 @ 16
110–113
N/A
1
3.8
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes
under fire conditions.
No flames, no sparks, no
contact with hot surfaces.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Harmful if inhaled. Irritating to
respiratory system.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Vapor or mist may be irritating
to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic, harmful if swallowed.
Do not eat or drink in the
laboratory.
Wash out mouth with
water provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
298
p-Rosaniline Hydrochloride [Basic Fuchsin]
C20H20ClN3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
569-61-9
Solid
Green
N/A
N/A
N/A
250
1.22
N/A
N/A
0.1−0.5
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Irritant, may be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant, may be harmful to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is irritating to the eyes,
may be harmful.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations: CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d = density or specific
gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD = vapor density relative to air (1.0);
Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A = not available or not applicable.
299
Salicylamide
C7H7NO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
65-45-2
Solid
White
N/A
N/A
N/A
140–144
N/A
N/A
N/A
0.2 @30
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, carbon
dioxide, dry chemical
powder or appropriate
foam.
Inhalation
Harmful if inhaled. Irritating to
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic, harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density (g/mL); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise stated; N/A
= not available or not applicable.
300
Salicylic Acid
C7H6O3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
69-72-7
Solid
White
Odorless
to slight
phenolic
157
211
157–159
1.44
1 @ 114
4.8
0.222
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Combustible.
No flames, no sparks, no
contact with hot surfaces.
Inhalation
Cough. Sore throat.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Redness, pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, vomiting, ear ringing.
Do not eat or drink in the
laboratory.
Wash out mouth with
water. Induce vomiting,
keep head lower than hips.
Refer for medical
attention.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Carbon dioxide, water
spray, powder.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
301
Semicarbazide Hydrochloride
CH6ClN3O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
563-41-7
Solid
White
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, regular
dry chemical.
Inhalation
Nausea, vomiting, fever, headache,
hypotension, weakness, and fatigue.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Redness and irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Nausea, vomiting, sore throat,
abdominal pain, and diarrhea.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give large
amounts of water or
activated charcoal slurry;
when vomiting occurs,
keep head lower than hips.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
302
Silica Gel (70-230 mesh)
SiO2 x H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
112926-00-8
Solid
White
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Not flammable. Emits toxic fumes
under fire conditions.
N/A
Use extinguishing media
appropriate to surrounding
fire conditions.
Inhalation
Maybe harmful if inhaled. Material
may be harmful if absorbed through
the skin.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation. May be
harmful if absorbed through the skin.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
May cause eye irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Maybe be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
303
Silicon Carbide [Carborundum]
CSI
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
409-21-2
Solid
Colorless
Odorless
N/A
N/A
2730 dec
3.21
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Nonflammable
N/A
N/A
Inhalation
N/A
N/A
N/A
Skin
No skin irritation
N/A
N/A
Eyes
N/A
N/A
N/A
Ingestion
N/A
N/A
N/A
Carcinogenicity
Not a carcinogen
Mutagenicity
Not a mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
304
Silicon Dioxide [Sand]
SiO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
238-878-4
Solid
White
Odorless
N/A
4064
3110
2.65
0
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Not flammable. Not combustible.
Inhalation
Dust is irritating to respiratory tract.
Ventilation, local
Chronic inhalation of crystalline silica exhaust.
may lead to fibrotic lung disease,
silicosis or cancer.
Remove from exposure
immediately and seek
medical advice.
Skin
Dust may cause mechanical irritation.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Dust may cause mechanical irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May cause irritation to digestive tract.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips.
Seek medical advice.
Carcinogenicity
Cancer suspect agent.
N/A
First Aid/Fire
Use extinguishing media
most appropriate for the
surrounding fire.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
305
Silver Nitrate
AgNO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7761-88-8
Liquid
White
N/A
N/A
440
212
4.352
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard; may ignite or
explode on contact with combustible
materials.
Avoid contact with
Use extinguishing agents
combustible materials. appropriate for
surrounding fire.
Inhalation
Irritation, sore throat, coughing and
shortness of breath, headache, nausea,
vomiting.
Ventilation, local
exhaust.
Skin
Irritation, redness, pain, ulceration, and Protective gloves and
discoloration.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, burns,
discoloration, and blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning mouth and throat, salivation,
violent abdominal pain and rigidity,
diarrhea, headache, nausea, vomiting,
and cyanosis.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give salt
water; if vomiting occurs,
keep head lower than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
306
Sodium
Na
CAS No.
PS
Color
Odor
FP
BP
MP
d
7440-23-5
Solid
Silver
Odorless
115
881.7
97.8
0.968
Types of
Hazard/Exposure
VP
VD
1.2 @ 400 0.003
Sol
Reacts
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable solid, water reactive.
Reacts vigorously with water, steam,
acids to release flammable/explosive
hydrogen. Dangerous in presence of
oxidants. May ignite spontaneously in
moist air or oxygen. May re-ignite
after fire is extinguished.
Avoid open flames or
sparks. Keep from
water.
Use only dry soda ash, dry
salt, sand, graphite
powder, or metal-fireextinguishing dry powder.
Do not use water.
Inhalation
Inhalation produces damaging effects
on the mucous membranes and upper
respiratory tract. Symptoms may
include irritation of the nose and
throat, and labored breathing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Corrosive; causes serious burns upon Protective gloves and
ireaction with water, especially on
clothing.
moist skin. If metal ignites, very deep
burns and tissue destruction can occur.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Corrosive. May cause redness, pain,
blurred vision, and damage from
severe alkali burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Extremely dangerous, corrosive
material. Will react immediately with
saliva to cause serious burns and
possible local combustion.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Give large quantities of
water. Get medical
attention immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
307
Sodium Acetate (anhydrous)
C2H3O2Na
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
127-09-3
Solid
White
Odorless
N/A
N/A
324 dec
1.528
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Inhalation
Irritation, coughing, and shortness of Ventilation, local
breath.
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain and vomiting.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Avoid heat, sparks and
flames.
Not a known carcinogen.
Mutagenicity
Dry chemical powder,
carbon dioxide, water,
regular foam.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
308
Sodium Acetate (trihydrate)
C2H3O2Na · 3H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
6131-90-4
Solid
White
Odorless
N/A
123
58
1.45
N/A
N/A
76.2 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
Avoid heat, sparks and Dry chemical powder,
flames.
carbon dioxide, water,
regular foam.
Inhalation
Irritation, coughing, and shortness of
breath.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal pain and vomiting.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
309
Sodium Bicarbonate
NaHCO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
144-55-8
Solid
White
Odorless
N/A
N/A
300
2.159
N/A
N/A
10.3
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, sore throat, and coughing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, and pain.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the mouth, esophagus, and Do not eat or drink in
stomach. Alkalosis.
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips;
get medical attention, if
needed.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
310
Sodium Bisulfite
NaHSO3
CAS No.
PS
Color
Odor
FP
7631-90-5
Solid
White
N/A
N/A Decomposes Decomposes 1.32
Types of
Hazard/Exposure
BP
MP
Acute Hazards/Symptoms
d
VP
VD
Sol
N/A
N/A
Soluble
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, sore throat, coughing, and
shortness of breath.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, corrosion.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, corrosion, and grayness and
irregularity of the corneal epithelium.
Safety goggles.
Ingestion
Irritation of the stomach, abdominal
Do not eat or drink in
pain, and nausea. Those with
the laboratory.
preexisting respiratory conditions may
experience hypersensitivity: symptoms
include bronchospasm, gastrointestinal
disturbances, hypotension, and shock.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
311
Sodium Borohydride
NaBH4
CAS No.
PS
Color
Odor
FP
BP
16940-66-2
Solid
White
Odorless
318
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
MP
d
300–400 dec 1.074
Prevention
VP
VD
Sol
N/A
1.3
55
First Aid/Fire
Fire
Moderate fire hazard.
Inhalation
Severe irritation, sore throat, coughing, Ventilation, local
shortness of breath, and headache.
exhaust.
Skin
Chemical and thermal burns, fatal
systemic poisoning due to skin
absorption.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Severe irritation and chemical and
thermal burns.
Safety goggles.
Ingestion
Sore throat, abdominal pain, diarrhea,
headache, dizziness, and corrosion of
the gastric mucosa.
Do not eat or drink in Seek medical advice
the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
No flames, no sparks, Dry chemical powder,
no contact with hot
sand, lime, soda ash.
surfaces.
Not a known carcinogen.
Mutagenicity
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
312
Sodium Bromide
NaBr
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7647-15-6
Solid
White
Odorless
N/A
1390
755
3.210
1 @ 806
N/A
73.3 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Inhalation
Irritation, rashes (especially acne,
furunculosis).
Ventilation, local exhaust. Remove from exposure
immediately. Get medical
attention.
Skin
Irritation, rashes (especially acne,
furunculosis).
Protective gloves and
clothing.
Remove contaminated
clothing, jewelry, and
shoes immediately.
Thoroughly wash with
water.
Eyes
N/A
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Immediate abdominal pain, nausea,
vomiting, kidney damage, systemic
poisoning, paralysis, and coma.
Do not eat or drink in the
laboratory.
If vomiting occurs, keep
head lower than hips. Get
medical attention.
Carcinogenicity
Not a known carcinogen.
Use extinguishing agents
appropriate for
surrounding fire.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
313
Sodium Carbonate (anhydrous)
Na2CO3
CAS No.
PS
Color
497-19-8
Solid
White
Types of
Hazard/Exposure
Odor
FP
BP
Odorless N/A Decomposes
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
851
2.536
N/A
N/A
30 @ 20
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, coughing, and shortness of
breath.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Severe irritation, redness, pain, and
blurred vision.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Corrosion of the gastric mucosa, sore
throat, gastrointestinal disturbances,
nausea, vomiting, abdominal pain, and
diarrhea.
Do not eat or drink Seek medical advice
in the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
314
Sodium Chlorate
NaClO3
CAS No.
PS
Color
Odor
FP
7775-09-9
Solid
White
N/A
N/A
Types of
Hazard/Exposure
BP
MP
Decomposes 248-261
Acute Hazards/Symptoms
d
VP
VD
Sol
2.49
N/A
N/A
79 @ 0
Prevention
First Aid/Fire
Fire
Negligible fire hazard; may
ignite or explode on contact
with combustible materials.
Avoid contact with
combustible materials.
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation with sore throat,
coughing, headache, dizziness,
and faintness.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the gastrointestinal Do not eat or drink in the
mucosa, abdominal pain,
laboratory.
nausea, vomiting, and diarrhea.
Seek medical advice
immediately. If vomiting
occurs, keep head lower
than hips.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
315
Sodium Chloride
NaCl
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7647-14-5
Solid
White
Odorless
N/A
1413
801
2.165
N/A
N/A
35.9
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Inhalation
Coughing, dryness, and sore
throat.
Ventilation, local exhaust. Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Redness, pain, irritation and a
stinging sensation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Dryness of mucous membranes, a Do not eat or drink in the
violent inflammatory reaction in laboratory.
the gastrointestinal tract, and
ulceration if very large doses are
taken.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Use extinguishing agents
appropriate for
surrounding fire.
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
316
Sodium Citrate (dihydrate)
Na3C6H5O7 · 2H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
6132-04-3
Solid
White
N/A
N/A
N/A
>300
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes
under fire conditions.
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled. Irritating
to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin
with soap and water, and
seek medical advice.
Eyes
Irritating to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several
min, removing contact
lenses if possible, and
seek medical advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink
in the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
317
Sodium Dichromate (dihydrate)
Na2Cr2O7 · 2H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7789-12-0
Solid
Red to
orange
N/A
N/A
N/A
91
2.350
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Toxic. Harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin, may cause burns. Protective gloves and
May be toxic.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritating to the eyes. May be toxic.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Carcinogenic.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
318
Sodium Hydrosulfite
Na2S2O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7775-14-6
Solid
White
N/A
N/A
N/A
300
N/A
N/A
N/A
23 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Addition of small amounts of water or
temperatures above 100 C may cause
self-ignition.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry
chemical power, or
appropriate foam. Do not
use water.
Inhalation
Irritation of the mucous membrane.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and redness.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and redness.
Safety goggles.
Thoroughly flush eyes
with water for 15 minutes,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the digestive tract.
Do not eat or drink in
the laboratory.
Do not induce vomiting.
Wash out mouth with
water. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
319
Sodium Hydroxide
NaOH
CAS No.
PS
Color
Odor
FP
BP
MP
1310-73-2
Solid
White
Odorless
N/A
1390
318
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
VD
2.130 100 @ 1111
Prevention
>1
Sol
Soluble
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, sore throat, burning
sensation, laryngitis, coughing,
destruction of mucous membranes,
headache, nausea, vomiting, and
delayed pulmonary edema.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, cutaneous burns, and skin
fissures.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Disintegration and sloughing of
conjunctival and corneal epithelium,
corneal opacification, edema,
ulceration, and blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Corrosion of the lips, mouth, tongue
and pharynx, severe esophageal and
abdominal pain, and vomiting.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
320
Sodium Hydroxide (50% solution)
NaOH
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
1310-72-2
Liquid
White
None
N/A
105-140
-10 to -12
1.327
18
>1
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions.
Inhalation
Material is extremely destructive to the Ventilation, local
tissue of mucous membranes and
exhaust.
upper respiratory tract. Maybe
harmful if inhaled.
Remove from exposure.
Get medical attention. If
not breathing, give
artificial respiration. If
breathing is difficult, give
oxygen.
Skin
Corrosive. Causes burns. May be
harmful if absorbed through skin.
Protective clothing
and gloves.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash mouth out with
water, provided person is
conscious. Seek medical
advice. Do not induce
vomiting.
Carcinogenicity
Avoid heat, sparks and Dry chemical powder. Do
flames.
not use water.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
321
Sodium Hypochlorite
NaClO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7681-52-9
Liquid
Yellowgreen
Chlorinelike
N/A
N/A
N/A
1.097
17.5 @ 20
N/A
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard; may ignite or
explode on contact with combustible
materials.
Avoid contact with
Use extinguishing agents
combustible materials. appropriate for
surrounding fire.
Inhalation
Severe burns, severe bronchial
irritation, sore throat, blistering,
coughing, nausea, and labored
breathing.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, blistering, itchy
eczema, and chemical burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Severe pain, hemorrhages, corneal
opacification, edema, ulceration, and
blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Inflammation of the mouth and
Do not eat or drink in
digestive system, circulatory collapse, the laboratory.
confusion, delirium, and drop in blood
pressure.
Seek medical advice
immediately. Do not
induce vomiting; give
milk; if vomiting occurs,
keep head lower than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
322
Sodium Iodide
NaI
CAS No.
PS
Color
Odor
FP
BP
MP
7681-82-5
Solid
White
Odorless
N/A
1304
661
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
3.67 1 @ 767
Prevention
VD
Sol
N/A
179.7 @ 20
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation. Prolonged exposure may
produce iodism in sensitive
individuals.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Enlargement of salivary glands or
lymph glands.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips;
get medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
323
Sodium Lead Alloy
NaxPby
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
12740-44-2
Solid
Gray
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Decomposes
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Extremely flammable, reacts violently No flames, no sparks,
with water, liberating extremely
no contact with hot
flammable gases.
surfaces.
Use approved class D
extinguisher or smother
with dry sand; do not use
water or carbon dioxide.
Inhalation
Harmful if inhaled. Very irritating to
respiratory system, causes burns.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Very caustic, causes burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist very caustic to the eyes. Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
If swallowed wash out
mouth with water. Seek
medial advice.
Carcinogenicity
Do not eat or drink in
the laboratory.
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
324
Sodium Nitrite
NaNO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7632-00-0
Solid
White
Odorless
N/A
N/A
271
2.168 @ 0
N/A
N/A
82 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard; may ignite or
explode on contact with combustible
materials.
Avoid contact with
Use extinguishing agents
combustible materials. appropriate for
surrounding fire.
Inhalation
Irritation, sore throat, and shortness of
breath.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness and irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and dilation of pupils.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Gastrointestinal irritation with nausea,
vomiting, diarrhea, and abdominal
pains, dizziness, confusion, and
lethargy.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; turn
head to side, and get
medical attention
immediately.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
325
Sodium Nitroprusside
Na2Fe(CN)5NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
13755-38-9
Solid
Dark red
N/A
N/A
N/A
N/A
1.720
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Noncombustible. Emits toxic fumes
under fire conditions.
Avoid heat, sparks,
flames.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Highly toxic, may be fatal if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Highly toxic, may be fatal if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is highly toxic.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Highly toxic, may be fatal if
swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
326
Sodium Sulfate (anhydrous)
Na2SO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7757-82-6
Solid
White
Odorless
N/A
N/A
884
2.671
N/A
N/A
18.5 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Diarrhea, fluid loss, blood in stools,
and hypotension.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. If vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
327
Spearmint Oil
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
8008-79-5
Liquid
Slightly
yellowgreen
Minty
94
220
N/A
0.95
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Flammable. Emits toxic fumes under
fire conditions.
Inhalation
May be harmful if inhaled. Material is Ventilation, local
irritating to mucous membranes and
exhaust.
upper respiratory tract.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes skin irritation. May be harmful Wear protective
if absorbed through the skin. May
clothing and gloves.
cause dermatitis.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation to mucous membranes and
upper respiratory tract.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Maybe harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water, provided person is
conscious. Seek medical
advice.
Carcinogenicity
Not a known carcinogen.
Avoid heat, sparks,
and flames.
First Aid/Fire
Mutagenicity
Water spray, carbon
dioxide, dry chemical or
appropriate foam.
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
328
(E)-Stilbene [trans-Stilbene]
C14H12
CAS No.
PS
Color
Odor
FP
103-30-0
Solid
Colorless
N/A
N/A 305–307
Types of
Hazard/Exposure
BP
Acute Hazards/Symptoms
MP
d
VP
VD
Sol
122–125
0.970
N/A
N/A
Insoluble
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
N/A
Ventilation, local
exhaust.
Remove from exposure
immediately. Get medical
attention.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, itching, lacrimation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips.
Get medical attention.
Not a known carcinogen.
Mutagenicity
Possible mutagen.
Carcinogenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
329
(Z)-Stilbene [cis-Stilbene]
C14H12
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
645-49-8
Liquid
Pale yellow
N/A
>110
82-84
-5
1.02
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, Dry foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
330
d,l-Stilbene Dibromide
C14H12Br2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
5789-30-0
Solid
White
N/A
N/A
N/A
113–115
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
conditions. *
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
May be harmful if inhaled. Vapor is
irritating to respiratory system.
Symptoms may include burning,
coughing, shortness of breath,
headache, nausea, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation. *
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lachrymator. Vapor or mist is
irritating to the eyes. *
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Symptoms may include burning,
coughing, shortness of breath,
headache, nausea, and vomiting. *
Do not eat or drink in
the laboratory.
If swallowed, wash out
mouth with water. Seek
medical advice.
Mutagenicity
Not a known mutagen. *
Carcinogenicity
Not a known carcinogen. *
* Toxicological information for the listed chemical is not available. Information given pertains to meso-stilbene
dibromide and is intended to be used for comparison of a similar compound. Other effects may result from contact,
inhalation, or ingestion.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
331
meso-Stilbene Dibromide
C14H12Br2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
13440-24-9
Solid
White
N/A
N/A
N/A
241
N/A
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire conditions.
Avoid flames,
Water spray, dry chemical,
sparks, and contact foam, or carbon dioxide.
with hot surfaces.
Inhalation
May be harmful if inhaled. Vapor is
irritating to respiratory system.
Symptoms may include coughing,
headache, nausea, and vomiting.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May cause skin irritation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Lachrymator. Vapor or mist irritating to
the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed. Symptoms Do not eat or drink If swallowed, wash out
may include burining sensation,
in the laboratory.
mouth with water. Seek
coughting, wheezing, headache, nausea,
medical advice.
and vomiting.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
332
Styrene
C8H8
CAS No.
PS
Color
Odor
FP
BP
MP
100-42-5
Liquid
Colorless
Sharp
31
145–146
-31
Types of
Hazard/Exposure
Acute Hazards/Symptoms
d
VP
0.909 10 @ 31
Prevention
VD
Sol
3.6
0.03
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases may No flames, no
ignite at distant ignition sources.
sparks, no contact
with hot surfaces.
Dry chemical powder,
carbon dioxide, water for
cooling, regular foam.
Inhalation
Irritation, headache, fatigue, difficulty in Ventilation, local
concentrating, central nervous system
exhaust.
depression, nausea, weakness, dizziness,
and inertia.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, redness, cracking,
inflammation, defatting and degreasing
of the skin; absorption may result in
symptoms given in inhalation.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation, redness, pain, lacrimation,
blurred vision, and slight reversible
corneal damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Irritation of the mouth, throat, and
gastrointestinal tract, and symptoms
given in inhalation.
Do not eat or drink Wash out mouth with
in the laboratory.
water. If vomiting occurs,
keep head lower than hips;
get medical attention, if
needed.
Carcinogenicity
Suspected carcinogen.
Mutagenicity
Known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
333
Succinic Acid [Butanedioic Acid]
C4H6O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
110-15-6
Solid
White
N/A
N/A
235
187–190
1.55
0.009
N/A
56.5
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Irritating if inhaled, may be toxic.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin, may be harmful.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is severely irritating to
the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
334
Sucrose
C12H22O11
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
57-50-1
Solid
N/A
Odorless
N/A
N/A
160–186
1.59
N/A
N/A
300
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Not considered to be a fire
hazard.
Inhalation
Not expected to be a health
Ventilation, local exhaust.
hazard. Nuisance dust.
Inhalation of high
concentrations may cause
coughing and upper respiratory
tract irritation.
Remove from exposure
immediately and seek
medical advice.
Skin
No adverse effects expected.
Not expected to require
first-aid measures.
Eyes
No adverse effects expected but Safety goggles.
dust may cause mechanical
irritation.
Flush with water.
Ingestion
Extremely large oral dosages
may produce gastrointestinal
disturbances.
If large amounts were
swallowed, give water to
drink and get medical
advice.
Carcinogenicity
N/A
First Aid/Fire
Use extinguishing agents
appropriate for
surrounding fire.
Protective gloves and
clothing.
Do not eat or drink in the
laboratory.
Not a known carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
335
Sulfanilamide
C6H8N2O2S
CAS No.
PS
Color
63-74-1
Solid
White
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
Odorless N/A
N/A
165–167
1.08
N/A
N/A
0.5
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard.
N/A
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Cyanosis, anorexia, vomiting,
dizziness, and drowsiness.
Do not eat or drink in
the laboratory.
Seek medical advice
immediately. Give
sodium bicarbonate
solution; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
336
3-Sulfolene
C4H6O2S
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
77-79-2
Solid
White
N/A
109
N/A
65–66
N/A
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Moderate fire hazard.
No flames, no sparks,
no contact with hot
surfaces.
Carbon dioxide, dry foam,
water.
Inhalation
May be harmful.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, may be harmful if absorbed
through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in
the laboratory.
Wash out mouth with
water. If vomiting occurs,
keep head lower than hips;
get medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
337
Sulfuric Acid (fuming)
H2SO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
Sulfuric acid
7664-93-9
Sulfur trioxide
7446-11-9
Liquid
Yellow
Pungent
N/A
100
N/A
1.84
1
<0.3
Reacts
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Negligible fire hazard.
Inhalation
Sore throat, labored breathing,
Ventilation, local
coughing, choking, chronic respiratory exhaust.
tract damage, and chronic bronchitis.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, pain, and burns.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap/water;
seek medical advice.
Eyes
Severe damage and blindness.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Serious burns of the mouth and
esophagus, pain in the abdomen,
vomiting, and diarrhea.
Do not eat or drink Seek medical advice
in the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
N/A
First Aid/Fire
Known carcinogen.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
338
Sulfuric Acid (solutions)
H2SO4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7664-93-9
Liquid
Colorless
N/A
N/A
100
N/A
1.84
1
<0.3
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Negligible fire hazard. May ignite or
explode on contact with combustible
materials.
Avoid contact with
combustible
materials.
Use extinguishing agents
appropriate for
surrounding fire.
Inhalation
Irritation, shallower and more rapid
breathing, sneezing, a burning or
tickling sensation in the nose and
throat, and cough.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Second and third degree skin burns,
necrosis, charring, and shock.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Burning or stinging sensation,
lacrimation, blurred vision, and
conjunctival congestion.
Safety goggles.
Ingestion
Burning pain in the mouth, throat,
esophagus and abdomen, nausea, and
vomiting.
Do not eat or drink in Seek medical advice
the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
Known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
339
Sulfuryl Chloride
Cl2SO2
CAS No.
PS
Color
Odor
FP
BP
MP
d
7791-25-5
Liquid
Colorless
to pale
yellow
Sharp
N/A
68–70
-54
1.680
Types of
Hazard/Exposure
Acute Hazards/Symptoms
VP
VD
100 @17.8 4.65
Sol
Decomposes
Prevention
First Aid/Fire
Fire
Flammable, reacts violently with
water. Emits toxic and extremely
flammable fumes under fire
conditions.
No flames, no sparks,
no contact with hot
surfaces.
Extinguish with dry
chemical extinguisher; do
not use water.
Inhalation
Extremely destructive to mucous
membranes, may be fatal if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes burns, may be fatal if absorbed Protective gloves and
through skin.
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is very damaging to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
340
D-Tartaric Acid
C4H6O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
87-69-4
Solid
White
N/A
150
N/A
170–172
1.760
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Fire possible at elevated temperatures
or by contact with an ignition source.
Emits toxic fumes under fire
conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Irritant to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant to skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritant to eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
341
L-Tartaric Acid
C4H6O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
87-69-4
Solid
White
N/A
150
N/A
170–172
1.760
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Fire possible at elevated temperatures
or by contact with an ignition source.
Emits toxic fumes under fire
conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Irritant to respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant to skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritant to eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
342
Tetrachloroethylene
C2Cl4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
127-18-4
Liquid
Colorless
N/A
N/A
121
-22
1.623
19
5.83
0.165
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Noncombustible. Emits toxic fumes
under fire condition.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Harmful if absorbed through skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
343
Tetrahydrofuran (anhydrous and solvent grades) [THF]
C4H8O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
109-99-9
Liquid
Colorless
Sweet
-17
65
-108
0.89
160 @ 25
NA
sol
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard, severe explosion
No flames, no sparks,
hazard, may form explosive peroxides; no contact with hot
vapors or gases may ignite at distant
surfaces.
ignition sources.
Alcohol-resistant foam,
carbon dioxide, dry
chemical powder, water.
Inhalation
Central nervous system depression
with drowsiness, dizziness, nausea,
headache, and lowering of the pulse
and body temperature.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation, defatting, and drying of the
skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Painful inflammation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Central nervous system depression
Do not eat or drink in
with nausea, vomiting, drowsiness,
the laboratory.
dizziness; stomach may become
promptly distended, which may hinder
breathing.
Seek medical advice
immediately.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
344
(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl [TEMPO]
C9H18NO
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
2564-83-2
Solid
Red
N/A
67
N/A
36–38
N/A
N/A
N/A
N/A
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Fire
Moderate fire hazard.
Inhalation
May be harmful. Irritating to respiratory Ventilation, local
tract.
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes severe irritation burns.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Protective gloves and
clothing.
Carbon dioxide, dry
chemical powder, foam,
water.
Eyes
Causes severe burns and eye damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
Wash out mouth with
water; do not induce
vomiting; if vomiting
occurs, keep head lower
than hips. Seek medical
advice immediately. Call a
poison center.
Carcinogenicity
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
345
Thionyl Chloride
SOCl2
CAS No.
PS
Color
7719-09-7
Liquid
Pale yellow
Types of
Hazard/Exposure
Odor
FP
BP
MP
d
VP
VD
Sol
Pungent N/A
76
-105
1.64
100 @ 21
N/A
Reacts
Acute Hazards/Symptoms
Prevention
Fire
Not considered to be a fire hazard. May
react violently with water or moist air.
Can liberate flammable hydrogen gas
when in contact with metal and
moisture.
Inhalation
Corrosive. Extremely destructive to
Ventilation, local
tissues of the mucous membranes and
exhaust.
upper respiratory tract. Symptoms may
include burning sensation, coughing,
wheezing, laryngitis, shortness of breath,
headache, nausea and vomiting.
Remove from exposure
immediately and seek medical
advice.
Skin
Corrosive. Liquid contact may cause
blistering burns, irritation, and pain.
Vapors may be severely irritating to the
skin.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with 5% aqueous
sodium bicarbonate, soap and
water, and seek medical
advice.
Eyes
Corrosive. Vapors are irritating and may Safety goggles.
cause damage to the eyes. Contact may
cause severe burns and permanent eye
damage.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Corrosive. May cause burning pain in
throat, abdominal pain, nausea, and
vomiting.
Do not induce vomiting. Give
large quantities of water. Get
medical attention
immediately.
Carcinogenicity
Not a known carcinogen.
N/A
First Aid/Fire
Protective gloves
and clothing.
Do not eat or drink
in the laboratory.
Mutagenicity
Use extinguishing agents
appropriate for surrounding
fire.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
346
Tin
Sn
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7440-31-5
Solid
Silvery
Odorless
N/A
2507
231.9
7.31
1 @ 1609
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Fine dust dispersed in air in sufficient
concentrations and in the presence of
an ignition source is a potential dust
explosion hazard.
No flames, no sparks, Dry sand, graphite,
no contact with hot
dolomite, sodium chloride.
surfaces.
Never use water,
halogenated agents, or
class A, B, or C
extinguishers.
Inhalation
No adverse effects expected but dust
may cause mechanical irritation.
Ventilation, local
exhaust.
Skin
No adverse effects expected. May
cause mild irritation and redness.
Protective gloves and Not expected to require
clothing.
first aid measures. Get
medical advice if irritation
develops.
Eyes
No adverse effects expected but dust
may cause mechanical irritation.
Safety goggles.
Ingestion
Large doses may cause nausea,
vomiting, and diarrhea.
Do not eat or drink in Induce vomiting
the laboratory.
immediately, keep head
lower than hips. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not expected to require
first-aid measures.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
347
Tin (II) Chloride
SnCl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7772-99-8
Solid
Off-white
N/A
N/A
652
246
3.950
N/A
N/A
Decomposes
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Nonflammable
No open flames or
sparks, protect from
moisture.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Extremely destructive to mucous
membranes and lungs.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Corrosive, causes burns.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Extremely destructive to the eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
348
Tin(II) Chloride (dihydrate)
SnCl2 · 2H2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
10025-69-1
Solid
White
N/A
N/A
652
N/A
2.71
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Not flammable. Emits toxic fumes
under fire conditions.
Inhalation
Material is extremely destructive to the Ventilation, local
tissue of mucous membranes and
exhaust.
upper respiratory tract. Inhalation may
result in spasm, inflammation and
edema of larynx and bronchi, chemical
pneumatosis and pulmonary edema.
Remove from exposure
immediately and seek
medical advice.
Skin
Causes burns. May be harmful if
Protective clothing
absorbed through the skin. On contact and gloves.
with moist skin or atmospheric
moisture, this material reacts to form
hydrochloric acid, which may
contribute to its toxicity.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes burns and may cause blindness. Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Harmful if swallowed and may cause
mild to severe burns to the mouth,
throat and digestive tract, difficulty in
swallowing, nausea and vomiting,
followed by diarrhea and respiratory
distress.
Wash mouth out with
water, provided person is
conscious. Seek medical
advice immediately.
Carcinogenicity
Not a known carcinogen.
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Do not eat or drink in
the laboratory.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
349
Toluene
C7H8
CAS No.
PS
108-88-3
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Aromatic
FP
BP
MP
d
VP
VD
Sol
4
110.6
-93
0.865
22 @ 20
3.2
0.05% @ 20
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard. Vapors or gases
may ignite at distant ignition
sources.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide, water for
cooling, regular foam
Inhalation
Fatigue, weakness, confusion,
headache, nausea, and drowsiness.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritation and drying.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation and corneal burns.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Abdominal spasms, systemic effects Do not eat or drink in
given in inhalation, coughing, and
the laboratory.
gagging.
Seek medical advice
immediately. If vomiting
occurs keep, head lower
than hips.
Not a known carcinogen.
Possible mutagen.
Carcinogenicity
Mutagenicity
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
350
p-Toluenesulfonic Acid
C7H8SO3
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
6192-52-5
Solid
White
Weak
180
N/A
100
NA
N/A
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Emits toxic fumes under fire
Avoid heat, sparks,
conditions. May accelerate combustion. and flames.
Carbon dioxide, dry
chemical powder or
appropriate foam.
Inhalation
Harmful if inhaled. Inhalation may
result in spasm, inflammation, and
edema of the larynx and bronchi,
pulmonary edema.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Severe irritation, pain, and burns.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Harmful to the eyes. Extremely
destructive to tissue in eyes.
Safety goggles.
Ingestion
May be fatal if swallowed. Exposure
Do not eat or drink in If swallowed wash out
can cause burning sensation, wheezing, the laboratory.
mouth with water. Seek
laryngitis, shortness of breath and
medical advice.
vomiting.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
351
p-Toluic acid
C8H8O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
99-94-5
Solid
White
N/A
148
274–275
177–180
1.06
Types of
Hazard/Exposure
Acute Hazards/Symptoms
N/A
Fire
N/A
Inhalation
N/A
Skin
N/A
Eyes
N/A
Ingestion
Carcinogenicity
VP
VD
Sol
0.0025 @ 20 N/A 11.6 g/L
Prevention
First Aid/Fire
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder, regular
foam, alcohol-resistant foam.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek medical
advice.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry, thoroughly
wash skin with soap and
water, and seek medical
advice
Safety goggles.
Thoroughly flush eyes with
water for several min,
removing contact lenses if
possible, and seek medical
advice
Do not eat or drink If swallowed wash out mouth
in the laboratory.
with water. Seek medial
advice.
Not a known carcinogen
Mutagenicity
Not a known mutagen
For more detailed information consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water; N/A = not available or not applicable.
352
p-Toluidine
C7H9N
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
106-49-0
Solid
Colorless
Fish-like
88
200
44–46
0.973
N/A
3.9
0.664
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Harmful if inhaled. Irritating to
respiratory system.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritating to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist may be irritating to the
eyes.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Toxic. Harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Possible carcinogen.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
353
Triethylene Glycol
C6H14O4
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
112-27-6
Liquid
Colorless
N/A
165
285
-7
1.125
<0.01
5.2
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Dry chemical powder,
carbon dioxide,
appropriate foam.
Inhalation
Irritant, may be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant, may be harmful to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is irritating to the eyes,
may be harmful.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
354
Trifluoroacetic Acid
C2HF3O2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
76-05-1
Liquid
Colorless
Sharp
N/A
72
-15
1.48
107 @ 25
3.9
Miscible
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Slight fire hazard.
Inhalation
Throat discomfort, lightheadedness, Ventilation, local
nausea, cough, rhinitis, nasal
exhaust.
discharge, corrosion, dyspnea,
bronchitis, pulmonary edema, shock,
and death.
Remove from exposure
immediately and seek
medical advice.
Skin
Redness, pain, corrosion, subsequent Protective gloves and
dermatitis, second degree burns,
clothing.
vesiculation, keloid formation, and
absorbed through the skin producing
severe toxic effects.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Acute inflammation of the eyes,
Safety goggles.
conjunctivitis, keratitis, pain, redness,
blurred vision, burns, and permanent
corneal scarring.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Burning sensation in the mouth,
Do not eat or drink in
salivation, corrosion of the glottis,
the laboratory.
esophagus, and stomach, abdominal
pain, nausea, vomiting, and difficulty
breathing.
Do not induce vomiting.
Wash out mouth with
water. Seek medical
advice.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
No flames, no sparks,
no contact with hot
surfaces.
First Aid/Fire
Mutagenicity
Carbon dioxide, dry
chemical power, or
appropriate foam. Do not
use water.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
355
Trimyristin
C45H86O6
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
555-45-3
Liquid
Colorless
N/A
>110
N/A
56−58
1.080
<0.01
8.95
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Flammable. Emits toxic fumes under
fire conditions.
No flames, no sparks,
no contact with hot
surfaces.
Water spray, dry chemical
powder, carbon dioxide,
appropriate foam.
Inhalation
Irritant, may be harmful if inhaled.
Ventilation, local
exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
Irritant, may be harmful to the skin.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapor or mist is irritating to the eyes,
may be harmful.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful if swallowed.
Do not eat or drink in
the laboratory.
If swallowed wash out
mouth with water. Seek
medical advice.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
356
Triphenylmethanol
C19H16O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
76-84-6
Solid
Colorless
N/A
N/A
380
164
1.1999
N/A
N/A
Insoluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Slight fire hazard.
No flames, no sparks, no
contact with hot surfaces.
Dry chemical powder,
carbon dioxide, water,
regular foam.
Inhalation
May be harmful.
Ventilation, local exhaust.
Remove from exposure
immediately and seek
medical advice.
Skin
May be harmful.
Protective gloves and
clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Irritation.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
May be harmful.
Do not eat or drink in the
laboratory.
If vomiting occurs, keep
head lower than hips; get
medical attention, if
needed.
Carcinogenicity
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
357
Urea
CH4N2O
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
57-13-6
Solid
White
N/A
N/A
Decomposes
135
1.32
N/A
N/A
108 @ 20
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Not considered to be a fire hazard.
Inhalation
Causes irritation to the respiratory tract.
Ventilation, local
Symptoms may include coughing,
exhaust.
shortness of breath. May be absorbed into
the bloodstream with symptoms similar to
ingestion.
Skin
Causes irritation to skin. Symptoms
include redness, itching, and pain.
Protective clothing Remove contaminated
and gloves.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Causes irritation, redness, and pain.
Safety goggles.
Ingestion
Causes irritation to the gastrointestinal
Do not eat or drink
tract. Symptoms include nausea, vomiting in the laboratory.
and diarrhea. May also cause headache,
confusion and electrolyte depletion.
Do not induce vomiting.
Wash mouth out with
water. Seek medical
advice.
Not a known carcinogen.
Not a known mutagen.
Carcinogenicity
Avoid heat, sparks
and flames.
First Aid/Fire
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
358
m-Xylene
C8H10
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
108-38-3
Liquid
Colorless
Aromatic
26
138
-48
0.86
9 @ 20
3.7
Insoluble
Types of
Hazard/Exposure
Fire
Acute Hazards/Symptoms
First Aid/Fire
No flames, no
sparks, no contact
with hot surfaces.
Dry chemical powder,
foam or carbon dioxide.
Inhalation
Inhalation of vapors may be irritating to
Ventilation, local
the nose and throat. Inhalation of high
exhaust.
concentrations may result in nausea,
vomiting, headache, ringing in the ears,
and severe breathing difficulties that may
be delayed in onset.
Remove from exposure
immediately and seek
medical advice.
Skin
Skin contact results in loss of natural oils
and often results in a characteristic
dermatitis. May be absorbed through the
skin.
Protective gloves
and clothing.
Remove contaminated
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Eyes
Vapors cause eye irritation. Splashes
cause severe irritation, possible corneal
burns and eye damage.
Safety goggles.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Ingestion
Ingestion causes burning sensation in
Do not eat or drink Aspiration hazard. Do not
induce vomiting. Give
mouth and stomach, nausea, vomiting and in the laboratory.
salivation.
large quantities of water.
Seek medical attention
immediately. If vomiting
occurs, keep head below
hips.
Carcinogenicity
Severe fire hazard; vapors or gases may
ignite at distant ignition sources.
Prevention
Not a known carcinogen.
Mutagenicity
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
359
p-Xylene
C8H10
CAS No.
PS
106-42-3
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Aromatic
FP
BP
MP
d
VP
VD
Sol
27.2
138
13–14
0.86
9 @ 20
3.7
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors or gases may No flames, no sparks, Dry chemical powder,
ignite at distant ignition sources.
no contact with hot
foam or carbon dioxide.
surfaces.
Inhalation
Inhalation of vapors may be irritating to Ventilation, local
the nose and throat. Inhalation of high exhaust.
concentrations may result in nausea,
vomiting, headache, ringing in the ears,
and severe breathing difficulties that
may be delayed in onset.
Skin
Skin contact results in loss of natural
oils and often results in a characteristic
dermatitis. May be absorbed through
the skin.
Eyes
Vapors cause eye irritation. Splashes
Safety goggles.
cause severe irritation, possible corneal
burns and eye damage.
Ingestion
Ingestion causes burning sensation in
mouth and stomach, nausea, vomiting,
and salivation.
Carcinogenicity
Not a known carcinogen.
Remove from exposure
immediately and seek
medical advice.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Do not eat or drink in Aspiration hazard. Do not
the laboratory.
induce vomiting. Give
large quantities of water.
Seek medical attention
immediately. If vomiting
occurs, keep head below
hips.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
360
Xylenes (mixture o-, m-, and p-Xylene)
C8H10
CAS No.
PS
1330-20-7
Liquid
Types of
Hazard/Exposure
Color
Odor
Colorless Aromatic
FP
BP
MP
d
VP
VD
Sol
9
137–140
25
0.86
8 @ 20
3.7
Insoluble
Acute Hazards/Symptoms
Prevention
First Aid/Fire
Fire
Severe fire hazard; vapors or gases may No flames, sparks, or Dry chemical powder,
ignite at distant ignition sources.
contact with hot
foam or carbon dioxide.
surfaces.
Inhalation
Inhalation of vapors may be irritating to Ventilation, local
the nose and throat. Inhalation may
exhaust.
result in nausea, vomiting, headache,
and severe breathing difficulties that
may be delayed in onset.
Skin
Skin contact results in loss of natural
oils and often results in a characteristic
dermatitis. May be absorbed through
the skin.
Eyes
Vapors cause eye irritation. Splashes
Safety goggles.
cause severe irritation, possible corneal
burns and eye damage.
Ingestion
Ingestion causes burning sensation in
mouth and stomach, nausea, vomiting,
and salivation.
Carcinogenicity
Not a known carcinogen.
Remove from exposure
immediately and seek
medical advice.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
soap and water, and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Do not eat or drink in Aspiration hazard. Do not
the laboratory.
induce vomiting. Give
large quantities of water.
Seek medical attention
immediately. If vomiting
occurs, keep head below
hips.
Mutagenicity
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
361
Zinc Chloride (anhydrous)
ZnCl2
CAS No.
PS
Color
Odor
FP
BP
MP
d
VP
VD
Sol
7646-85-7
Solid
White
Odorless
N/A
732
293
2.91
1
N/A
Soluble
Types of
Hazard/Exposure
Acute Hazards/Symptoms
Prevention
Fire
Negligible fire hazard.
Inhalation
Irritation, metallic taste, lacrimation,
Ventilation, local
sore throat, hoarseness, chest pain,
exhaust.
soreness, nausea, abdominal pain, and
vomiting.
Skin
Irritation, redness, pain, papular and
primary dermatitis, chemical burns,
boils, and ulceration.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, pain, redness, blurred
vision, corneal burns, ulceration,
conjunctivitis, and iritis.
Safety goggles.
Ingestion
Irritation of mucous membranes,
corrosion, swollen lips, sore throat,
chest pain, nausea, vomiting, and
bloody diarrhea.
Do not eat or drink in Seek medical advice
the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
N/A
First Aid/Fire
Possible carcinogen.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Possible mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
362
Zinc Oxide
ZnO
CAS No.
PS
Color
Odor
FP
BP
1314-13-2
Solid
White
Odorless
N/A
NA
Types of
Hazard/Exposure
MP
d
VP
5.6
Acute Hazards/Symptoms
Prevention
Sol
N/A
Insoluble
First Aid/Fire
Fire
Negligible fire hazard.
Inhalation
Irritation, metallic taste, lacrimation,
Ventilation, local
sore throat, hoarseness, chest pain,
exhaust.
soreness, nausea, abdominal pain, and
vomiting.
Skin
Irritation, redness, pain, papular and
primary dermatitis, chemical burns,
boils, and ulceration.
Protective gloves and Remove contaminated
clothing.
clothes/jewelry,
thoroughly wash skin with
5% aqueous sodium
bicarbonate, soap and
water, and seek medical
advice.
Eyes
Irritation, pain, redness, blurred
vision, corneal burns, ulceration,
conjunctivitis, and iritis.
Safety goggles.
Ingestion
Irritation of mucous membranes,
corrosion, swollen lips, sore throat,
chest pain, nausea, vomiting, and
bloody diarrhea.
Do not eat or drink in Seek medical advice
the laboratory.
immediately. Give water
or milk; if vomiting
occurs, keep head lower
than hips.
Carcinogenicity
N/A
VD
Not a known carcinogen.
Mutagenicity
Use extinguishing agents
appropriate for
surrounding fire.
Remove from exposure
immediately and seek
medical advice.
Thoroughly flush eyes
with water for several min,
removing contact lenses if
possible, and seek medical
advice.
Not a known mutagen.
For more detailed information, consult the Material Safety Data Sheet for this compound.
Abbreviations:
CAS No. = Chemical Abstracts Service Registry Number; PS = physical state; FP = flash point
(°C); BP = boiling point (°C) @ 760 torr unless otherwise stated; MP = melting point (°C); d =
density or specific gravity (g/mL); VP = vapor pressure (torr) at specified temperature (°C); VD =
vapor density relative to air (1.0); Sol = solubility in water (g/100 mL) at 25 °C unless otherwise
stated; N/A = not available or not applicable.
363