Wednesday, October 17th Today: Review Quiz Continue Chapter 6 1 © 2013 Pearson Education, Inc. Chapter 6, Section 1 1 Review: Formation of Magnesium Ion, Mg2+ Magnesium achieves an octet by losing its two valence electrons. © 2013 Pearson Education, Inc. Chapter 6, Section 1 2 Group Numbers for Some Positive and Negative Ions © 2013 Pearson Education, Inc. Chapter 6, Section 1 3 Polyatomic Ions A polyatomic ion is a group of atoms. has an overall ionic charge. Examples: NH4+ ammonium SO42− sulfate PO43− phosphate © 2013 Pearson Education, Inc. Chapter 6, Section 1 OH− hydroxide CO32− carbonate 4 Guide to Drawing Electron-Dot Formulas © 2013 Pearson Education, Inc. Chapter 6, Section 1 5 Learning Check Draw the electron-dot formula for PF3. © 2013 Pearson Education, Inc. Chapter 6, Section 1 6 Names of Covalent Compounds When naming a covalent compound, the first nonmetal in the formula is named by its element name, and the second nonmetal is named using the first syllable of its element name, followed by ide. Prefixes are used to indicate the number of atoms present for each element in the compound, and because two nonmetals can form two or more different compounds © 2013 Pearson Education, Inc. Chapter 6, Section 1 7 Learning Check Name the covalent compound N2S5. © 2013 Pearson Education, Inc. Chapter 6, Section 1 8 Writing a Chemical Equation A chemical equation tells us what substances react (reactants) and what substances are formed (products). C(s) + O2(g) reactants CO2(g) product (+) used when there is two or more products or reactants heat is used to start the reaction (s) the compound is a solid (l) the compound is a liquid (g) the compound is a gas (aq) aqueous, the compound is dissolved in water © 2013 Pearson Education, Inc. Chapter 6, Section 1 9 Summary Reaction Types © 2013 Pearson Education, Inc. Chapter 6, Section 1 10 Quiz Time 11 © 2013 Pearson Education, Inc. Chapter 6, Section 1 11 Oxidation and Reduction, Formation of CaS In the reaction: the reactant, Ca has a charge of 0 and the product, CaS contains a Ca2+ ion. calcium loses two electrons, meaning oxidation has taken place. the reactant, S has a charge of 0 and the product, CaS contains an S2− ion. sulfur gains two electrons, meaning reduction has taken place. © 2013 Pearson Education, Inc. Chapter 6, Section 1 12 © 2013 Pearson Education, Inc. Chapter 6, Section 1 13 Counting Units Counting terms are used to describe specific quantities. 1 dozen donuts = 12 donuts 1 ream of paper = 500 sheets 1 case = 24 cans © 2013 Pearson Education, Inc. Chapter 6, Section 1 14 A Mole of Atoms A mole is a counting unit that contains the same number of particles as there are carbon atoms in 12.0 g of carbon 12C. 6.02 x 1023 atoms of an element (Avogadro’s number). © 2013 Pearson Education, Inc. Chapter 6, Section 1 15 A Mole of Sulfur 1 mole of sulfur contains Avogadro’s number of atoms. © 2013 Pearson Education, Inc. Chapter 6, Section 1 16 A Mole of a Compound A mole of a covalent compound has Avogadro’s number of molecules. of an ionic compound contains Avogadro’s number of formula units. © 2013 Pearson Education, Inc. Chapter 6, Section 1 17 Number of Particles in One Mole © 2013 Pearson Education, Inc. Chapter 6, Section 1 18 Avogadro’s Number as an Equality Avogadro’s number (6.02 x 1023) can be written as an equality and two conversion factors. Equality: Conversion Factors: © 2013 Pearson Education, Inc. Chapter 6, Section 1 19 Learning Check How many moles of CO2 are in 2.50 x 1024 molecules of CO2? © 2013 Pearson Education, Inc. Chapter 6, Section 1 20 Solution How many moles of CO2 are in 2.50 x 1024 molecules of CO2? Step 1 State the given and needed quantities. Given Need 2.50 x 1024 molecules of CO2 moles of CO2 Step 2 Write a plan to convert moles to atoms or molecules. molecules of CO2 → moles of CO2 © 2013 Pearson Education, Inc. Chapter 6, Section 1 21 Solution How many moles of CO2 are in 2.50 x 1024 molecules of CO2? Step 3 Use Avogadro’s number to write conversion factors. © 2013 Pearson Education, Inc. Chapter 6, Section 1 22 Solution How many moles of CO2 are in 2.50 x 1024 molecules of CO2? Step 4 Set up the problem to calculate the number of particles. © 2013 Pearson Education, Inc. Chapter 6, Section 1 23 Subscripts State Atoms and Moles © 2013 Pearson Education, Inc. Chapter 6, Section 1 24 Moles of Elements in a Formula The subscripts in a formula give the relationship of atoms in the formula and the moles of each element in 1 mole of a compound. Glucose C6H12O6 © 2013 Pearson Education, Inc. Chapter 6, Section 1 25 Conversion Factors from Subscripts Subscripts used for conversion factors relate moles of each element in 1 mole of a compound For aspirin, C9H8O4, can be written as: © 2013 Pearson Education, Inc. Chapter 6, Section 1 26 Guide to Calculating Moles © 2013 Pearson Education, Inc. Chapter 6, Section 1 27 Learning Check How many O atoms are in 0.150 mole of aspirin, C9H8O4? © 2013 Pearson Education, Inc. Chapter 6, Section 1 28 Molar Mass Molar mass is the mass of one mole of a substance. the number of grams that equals the atomic mass of that element. Molar mass is rounded to the tenths (0.1 g) place for use in this text. © 2013 Pearson Education, Inc. Chapter 6, Section 1 29 Guide to Calculating Molar Mass © 2013 Pearson Education, Inc. Chapter 6, Section 1 30 Molar Mass of CaCl2 We calculate the molar mass of CaCl2 to the nearest 0.1 g as follows. Analyze the Problem. Given Need formula unit CaCl2 molar mass of Ca, Cl; CaCl2 Step 1 Obtain the molar mass of each element. © 2013 Pearson Education, Inc. Chapter 6, Section 1 31 Molar Mass of CaCl2 We calculate the molar mass of CaCl2 to the nearest 0.1 g as follows. Step 2 Multiply each molar mass by the number of moles (subscript) in the formula. Grams from 1 mole of Ca Grams from 2 moles of Cl © 2013 Pearson Education, Inc. Chapter 6, Section 1 32 Molar Mass of CaCl2 We calculate the molar mass of CaCl2 to the nearest 0.1 g as follows. Step 3 Calculate the molar mass by adding the masses of the elements. © 2013 Pearson Education, Inc. Chapter 6, Section 1 33 Learning Check Determine the molar mass of K3PO4 to 0.1 g. © 2013 Pearson Education, Inc. Chapter 6, Section 1 34 Solution Determine the molar mass of K3PO4 to 0.1 g. Analyze the Problem. Given Need formula unit K3PO4 molar mass of K, P, O; molar mass of K3PO4 Step 1 Obtain the molar mass of each element. © 2013 Pearson Education, Inc. Chapter 6, Section 1 35 Solution Determine the molar mass of K3PO4 to 0.1 g. Step 2 Multiply each molar mass by the number of moles (subscript) in the formula. Grams from 3 moles of K © 2013 Pearson Education, Inc. Chapter 6, Section 1 36 Solution Determine the molar mass of K3PO4 to 0.1 g. Step 3 Calculate the molar mass by adding the masses of the elements. © 2013 Pearson Education, Inc. Chapter 6, Section 1 37 One-Mole Quantities 32.1 g © 2013 Pearson Education, Inc. 55.9 g 58.5 g Chapter 6, Section 1 294.2 g 342.3 g 38 Chemistry and Cooking Bisquick 2 Cups Mix 2 Eggs 1 Cup Milk 8 Pancakes 39 © 2013 Pearson Education, Inc. Chapter 6, Section 1 39 Friday More Chapter 6 Group Assignment 40 © 2013 Pearson Education, Inc. Chapter 6, Section 1 40
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