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MaterialSafetyDataSheet
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Creation Date: JAN.18, 2006
Revision Date: JUN.08, 2015
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᱀ऍᡆौᐛӝ૷䬶୤ᴿ䲆‫ޢ‬ਮ®
TANGSHAN
HAOXUCHENG CHEMICAL TRADING CO., LTD.
CCC:ProductCode:______________________
#"3*6.):%309*%&0$5"):%3"5&
CCC:ProductName:______________________________________
NO.118-8, XINHUA WEST ROAD, ROOM33, NO.15 BLDG TANGSHAN 063000 CHINA
Material Safety Data Sheet
Barium Hydroxide Octahydrate
(Canadian Vision)
SECTION 1- PRODUCT AND COMPANY IDENTIFICATION
Product Identification:
Product Name:
Barium Hydroxide Octahydrate
Trade Names:
Barium Hydroxide Octahydrate
Chemical Name:
Barium Hydroxide, Octahydrated
Catalog Codes:
TSHXC-BHO
Chemical Family:
Inorganic
Product Grade:
Tech-Grade
Synonyms:
Barium Hydroxide, Octahydrate; Barium Hydrate; Barium Hydroxide 8-hydrate; Barium salt
Molecular Formula:
Ba (OH) 2.8H2O
Molecular Weight:
315.48 g/mol
Identified Usage:
Water treatment; PVC stabilizer; Metal treatment; Pharmaceutical industry; Beet sugaring; Internal combustion
engine lubricating products; Barium-based grease.
Company Identification:
TANGSHAN HAOXUCHENG CHEMICAL TRADING CO., LTD.
Address:
No.118-8, XINHUA WEST RD, ROOM33, NO.15 BLDG TANGSHAN
24 hour Emergency Call:
++86 315 5269898
Contact Person:
Park Zhang; John Yu
FAX:
HEBEI Prov. P.R. CHINA 063000
++86 315 5267279
SECTION 2- HAZARDS IDENTIFICATION
WHMIS Classification and Labeling:
-
Class D1B Toxic Material Causing Immediate and Serious Toxic Effects ı1%
-
Class E Corrosive Material ı1%
Toxic (Acute effects)
E: Corrosive
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of
the information required by the CPR
General Information:
Appearance: Crystalline
Colour: White
Odour: Odorless
1
Emergency Overview:
Toxic! Corrosive! May be fatal if swallowed. Harmful if inhaled or absorbed through skin. Cause respiratory tract irritation. Causes severe
eye and skin irritation.
Signs and Symptoms of Exposure:
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin. Cough, Shortness of breath,
Headache, Nausea
Acute Health Effects:
Severe eye irritation, watering, redness and swelling of the eyelids.
Eye:
Burns.
Risk of serious or permanent eye lesions.
Severe skin irritation, redness and swelling of the skin.
Skin:
Burns.
In case of repeated contact: risk of skin ulceration.
Severe irritation of the nose and the throat.
Inhalation:
Cough and difficulty in breathing.
In case of repeated or prolonged exposure: risk of sore throat, nosebleeds, and chronic bronchitis.
Feeling of fatigue and cold sweat.
Severe irritation and risk of burns to the mouth, throat, esophagus and stomach.
Ingestion:
Risk of throat edema and suffocation. Abundant salivation. Nausea, vomiting, abdominal cramps and diarrhea.
Trembling, muscle cramps followed by general weakness and paralysis of the extremities.
Risk of convulsions, pulmonary arrest and death.
Risk of cardiac rhythm alteration, sudden cardiac failure.
Risk of shock.
May cause kidney damage.
Estimated lethal dose lies between 1 to 15 grams.
Chronic Health Effects:
Repeated or prolonged exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.
Carcinogenicity:
None
Other Toxicity Effects:
See section 11- Toxicological Information
Environmental Effects:
See section 12- Ecological Information
SECTION 3- COMPOSITION, INFORMATION ON INGREDIENTS
Composition:
Chemical Name
Barium Hydroxide Octahydrate
CAS#
12230-71-6
EINECS/ELINCS
241-234-5
LD50 [ORAL, RAT]
308 mg/kg
ACGIH- TLV
% By Weight
3
TWA=0.5mg/m as Ba
Ba (OH) 2.8H2O
2
ı99%
SECTION 4-FIRST AID MEASURES
Eye Contact:
Check for and remove any contact lenses.
Rinse thoroughly with plenty of water for at least 15 minutes, also under the eyelids.
Cold water may be used
In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
Get medical attention immediately.
Skin:
I In case of contact, remove contaminated clothing and shoes.
Immediately flush skin with plenty of water. Cold water may be used. Cover the irritated skin with an emollient.
Wash clothing before reuse.
Get medical attention immediately.
Inhalation:
Immediately remove person to fresh air.
If breathing is difficult, give oxygen.
If not breathing, give artificial respiration.
Consult with a physician in case of respiratory and nervous symptoms.
Get medical attention immediately.
Ingestion:
Get medical attention immediately. Take victim immediately to hospital.
Conscious:
If swallowed, rinse mouth with water immediately (only if the person is conscious).
Give to drink 30 grams of sodium sulfate in 250 ml of fresh water.
Do NOT induce vomiting unless directed to do so by medical personnel.
Artificial respiration and/or oxygen may be necessary.
Unconscious but Breathing:
Never give anything by mouth to an unconscious person.
Artificial respiration and/or oxygen may be necessary.
Notes to Physician:
Treat symptomatically and supportively. Sodium sulfate can be given in case of ingestion to precipitate out the
barium as barium sulfate.
Acute barium poisoning results in hypokalemia (low potassium levels). The administration of fluids containing
dilute concentrations of potassium salts may be indicated.
Monitor patients with significant ingestion for respiratory, cardiovascular, and blood pressure status. Watch for
cardiac arrhythmias, respiratory failure due to flaccid paralysis of respiratory muscles, pulmonary edema, vocal
cord paralysis, severe hypertension, and late effect kidney failure
SECTION 5-FIRE-FIGHTING MEUSURES
Extinguishing Media:
Non-combustible. Use extinguishing media that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media:
None
Special Exposure Hazards in a Fire:
Non-combustible
Hazardous Decomposition Products:
When heated to decomposition, may emit Carbon dioxide and soluble Barium salts (Barium Oxide)
3
Special Protective Equipment for Fire-fighters:
Wear self-contained breathing apparatus (NIOSH-approved) with full facepiece operated in the pressure demand or other positive pressure mode.
Wear fire resistant personnel protective equipment.
Wear chemical resistant oversuit
Additional Information:
Special Remarks on Fire Hazards:
Not Available
Special Remarks on Explosion Hazards:
Not Available
Sensitivity to Mechanical Impact:
Not expected to be sensitive to mechanical impact.
Sensitivity to Static Discharge:
Not expected to be sensitive to static discharge.
SECTION 6- ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Use personal protective equipment.
Sweep-up to eliminate slipping hazard
Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.
Refer to protective measures listed in sections 7 and 8.
Environmental Precautions:
Shall not be released into the environment.
Methods for Cleaning Up:
Avoid dust formation. Ensure adequate ventilation.
Sweep up and shovel into a convenient waste disposal container.
Ventilate area and wash spill site after material pickup is complete.
Large spills: Dike for later disposal.
Place unusable material into a closed labeled container compatible with the product.
Treat recovered material as described in the section 13 " WASTE DISPOSAL ".
Additional Information:
Poisonous solid. Can be dangerous if allowed to enter drinking water intakes. Do not contaminate domestic or
irrigation water supplies.
SECTION 7- HANDLING & STORAGE
Handling:
Avoid formation of dust and aerosols. Use only in well-ventilated areas.
Use only equipment and materials that are compatible with the product.
Storage:
Keep container tightly closed.
Keep container in a cool, dry, well-ventilated area.
Keep away from Incompatible products.
Equipment for handling, transportation and storage shall not be made of: Zinc and its alloys, Chlorinated
Rubber
Packaging material:
Paper + PE coating.
Other information:
Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment.
Wear suitable protective clothing.
Avoid contact with skin and eyes.
If you feel unwell, seek medical attention and show the label when possible.
Provide tight electrical equipment well protected against corrosion.
4
SECTION 8- EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Limit Values---:
Authorized limit Values:
Barium Hydroxide Octahydrate
US. ACGIH TLV 01 2006
Time Weighted Average = 0.5 mg/m3
Remarks: as Ba
US. OSHA PEL NIOSH REL 1989
Time Weighted Average = 0.5 mg/m3
Remarks: as Ba
ACGIH And TLV are both registered trademarks of the American Conference of Governmental Industrial Hygienists
Time Weighted Average (TWA) for 8 hour workdays
No Specific TLV STEL (Short Term Exposure Level) has been set.
Excursions in exposure level may exceed 3 times the TLV TWA for no more than a total of 30 minutes during a workday and under no circumstances should they
exceed 5 times the TLV TWA.
Engineering Controls:
Ensure adequate ventilation.
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits.
If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below
the exposure limit.
Apply technical measures to comply with the occupational exposure limits.
Personal Protective Equipment:
Respiratory Protection:
In case of insufficient ventilation, wear suitable respiratory equipment.
Use respirators and components tested and approved under appropriate government standards such as
NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.
Self-contained breathing apparatus in medium confinement/insufficient oxygen/in case of large uncontrolled
emissions/in all circumstances when the mask and cartridge do not give adequate protection
Immediately Dangerous to life and health (IDLH) value: 50mg/m3 as Ba. That means the most protective
respiratory equipments are failed to work. Evacuate the people from the contaminated environment a.s.a.p.
Hand Protection:
Chemical impervious and resistant gloves. Recommended materials: PVC, neoprene or rubber.
Have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Eyes:
Wear chemical resistant goggles for all industrial operations. Dust proof goggles obligatory.
Contact lenses should not be worn when working with this substance.
Skin:
Wear Apron/boots made from PVC or neoprene; long sleeves clothing to prevent contact with skin.
Hygiene Measures:
An eyewash bottle with pure water and safety shower should be nearby and ready for use.
Do not eat, drink or smoke in areas where this material is handled.
Use good hygiene practices when handling this product including changing work clothes after use.
SECTION 9-PHYSICAL&CHEMICAL PROPERTIES
Physical Appearance:
Crystalline
Colour: White
Odour: Odorless
Important Health, Safety and Environmental Information:
pH:
13.11 (18g/l) @ 20e
eC (68eF) in saturated Aqueous solution
Boiling Point:
780eC (1,436eF)
Melting Point:
78 °C (172 °F)
5
Decomposition Temperature:
> 780e
eC (1,436eF) (Anhydrous form)
Relative density / Density:
2.18 g/cm3 @16 °C (61 °F)
Bulk Density:
900 - 1,100 kg/m3Not Flammable
Granulometry:
20 % < 0.075 mm
Vapor Pressure (mm Hg):
ca. [email protected] °C (Hydration not specified)
Vapor Density (air=1):
Not Applicable
Vapor Pressure:
Not Applicable
Partition coefficient˖
Not Applicable (inorganic; dissociation)
Solubility in Water:
16.7 g/l (0 °C); 38.9 g/l (20 °C); 974 g/l (78 °C); 974 g/l (100 °C)
Solubility:
Soluble: ether, dilute acids
Flash Point:
Not Flammable
Auto-flammability:
Not Flammable
Flammability:
Not Flammable
Explosive Properties:
Not Explosive
Oxidizing Properties:
Non Oxidizer
Basicity (pKb)
-2.02
Refractive index (nD)
1.50 (octahydrate)
Hygroscopic ( readily absorbs water)
Slightly Soluble: methanol, ethanol
Insoluble: acetone
SECTION 10-STABILITY AND REACTIVITY
Stability:
Stable under recommended storage conditions.
Condition to Avoid:
None
Decomposition will begin @780eC (1,436eF)
Materials and Substances to Avoid:
Incompatibles Acids, oxidizers, chlorinated rubber. Corrosive to metals such as Zinc and its alloys.
Hazardous decomposition products:
Carbon dioxide and soluble Barium salts (Barium Oxide)
Corrosivity:
Non-corrosive with glass.
Polymerization:
Will not occur
Additional information:
Very Alkaline. Rapidly absorbs CO2, becoming completely insoluble in water.
SECTION 11- TOXICOLOGICAL INFORMATION
RTECS#: CQ9200000
Routes of Entry:
Eye and Skin Contact; Inhalation; Ingestion
Acute Toxicity:
Acute Oral Toxicity
Acute Inhalation Toxicity
Acute Dermal Toxicity
6
LD50, rat: 557 mg/kg
N/A; The substance is corrosive
N/A; The substance is corrosive
LC50, rat: Not Available
Toxicity, Other Information:
Workers - Hazard Via Inhalation Route
1.24 mg/m³ (Short- Term) -DNEL- NOAEL
0.62 mg/m³(Long- Term) -DNEL- NOAEL
General Population - Hazard Via Inhalation Route:
0.12 mg/m³(Long- Term) -DNEL (Derived No Effect Level)- NOAEL
General Population - Hazard Via Oral Route:
3.4 mg/kg bw/day(Long- Term)-DNEL (Derived No Effect Level)- NOAEL
Corrosiveness and Irritation:
Skin Irritation:
Skin corrosion (Category 1A) by GHS
Eyes Irritation:
Eye Damage (Category1) by GHS
Respiratory tract Irritation:
Sensitization:
Classified as Corrosive to the Respiratory Tract by GHS
Not Be Regarded as A Skin Sensitizer Based on the Results Barium Chloride Dihydrate
Acute Health Effects:
Eye Contact:
Risk of serious damage to eyes.
Skin Contact:
Severe skin irritation.
Inhalation:
Severe respiratory irritant.
Ingestion:
Harmful if swallowed.
Chronic Toxicity:
Germ Cell Mutagenicity Data: Based on available data, the classification criteria for germ cell mutagenicity are not met.
(i) Gene mutation (OECD 476, mouse lymphoma cells): negative
(ii) Bacterial reverse mutation assay (Ames test, OECD 471, S. typhimurium): negative
(iii) in vitro mammalian chromosome aberration test (OECD 473, Chinese hamster ovary (CHO)): negative
Based on the negative results in thein-vitro test for the soluble barium compound (BaCl2; 263 g/L; 20 -25°C) and assuming that the
mutagenic/genotoxicity effects will be based on the cation concentration, read across to the soluble Ba(OH)2 (37.4 g/L; 20°C) is possible.
Carcinogenicity Data:
Not classed as carcinogenic by ACGIH (A4), IARC, OSHA, NTP or EPA; No classification of the substance as CMR substance is required.
No specific data are available for Barium Hydroxide, But a two-year drinking water study with barium Chloride (104 -105 weeks; NOAEL:
91mg/kg) in rats and mice revealed no carcinogenic potential of Barium.
Toxicity for Reproduction and Development:
Reproductive Toxicity:
Read across- NOAEL based on a screening study conducted with barium chloride dihydrate (oral in drinking water) in rats could be derived for
effect on fertility.
Fertility impairment in female rats: NOAEL of 179.5 mg Ba2+/kg bw/d; relates to 412 mg barium hydroxide ctahydrate/kg bw/day
Fertility impairment in male rats: NOAEL of 201.5 mg Ba2+/kg bw/d; relates to 462 mg barium hydroxide octahydrate/kg bw/day
7
Developmental Toxicity and Teratogenicity:
Read across- Daily administration of barium chloride dihydrate at dose levels of 0, 10, 30 or 100 mg/kg body weight to pregnant rats from gestation
day 1 up to and including gestation day 20, resulted in maternal toxicity as evidenced by the spontaneous deaths of two animals on gestation day 21
and the conditional decline of another animal on gestation day 21 in the high dose group. No developmental toxicity was observed.
The NOAEL for maternal toxicity was therefore 30 mg/kg body weight (recalculated for barium chloride: 25.6 mg/kg bw/day) . In absence of
developmental effects the NOAEL for prenatal developmental toxicity in the rat was ı100 mg/kg body weight (recalculated for barium chloride:
ı85.3 mg/kg bw/day).
Metabolism: Study Scientifically Unjustified
The following default dermal absorption factors for metal cations are proposed (reflective of full-shift exposure, i.e. 8 hours):
From exposure to liquid/wet media: 1.0
From dry (dust) exposure: 0.1 %
This approach is consistent with the methodology proposed in HERAG guidance for metals (HERAG fact sheet - assessment of occumpational
dermal exposure and dermal absorption for metals and inorganic metal compounds; EBRC Consulting GmbH / Hannover /Germany; August 2007)
STOT-Single Exposure: The substance or mixture is not classified as specific target organ toxican.
Based on physical-chemical properties the substance is classified as corrosive. Thus, classification criteria for STOT-single exposure do not apply.
STOT-Repeated Exposure: The substance or mixture is not classified as specific target organ toxicant.
Aspiration hazard: No Hazard Expected
CMR Effects: Barium hydroxide octahydrate does not fulfil the criteria for CMR according to Regulation (EC) 1272/2008.
Comments:
The expected toxic properties of the substance are considered to be related to its corrosive properties and to the toxic effects of the barium ion
(nervous, cardio-vascular, respiratory and gastro- intestinal troubles).
The Respiratory irritancy threshold for man was determined by an increased count of cells in respiratory tract lavage fluid after exposure to Barium
Hydroxide. Compared to account in controlled individuals; the irritancy threshold was established to be 1.5mg/m3. (Rat; 3mg/m3)
SECTION 12- ENVIRONMENTAL INFORMATION
Ecotoxicity Effects:
Acute Toxicity Data: According to OECD-guidelines; Based on Barium Chloride Information
(References: OECD Guideline 203 (Fish, Acute Toxicity Test))
Short-term Toxicity to Fish:
Test Organisms:
Endpoint:
Value:
Conditions
Danio Rerio
96h-LC50
>3.5 mg Ba/ (5.4 mg BaCl2/L)
in 0.45 μm-filtered Test Solutions
96h-LC50
>97.5 mg Ba/L ( 149 mg BaCl2/L)
in Non-filtered Test Solutions
96h-LC50
>152 mg BaCl2/L
Nominal Concentrations
Test Organisms:
Endpoint:
Value:
Published Data
Daphnia Magna
48h-EC50
14.5 mg Ba/L
Biesinger and Christensen, 1972
Test Organisms:
Endpoint:
Value:
Published Data
Pseudokirchneriella Subcapitata
72h-ErC50(Growth rate)
!34.3 mg Ba/L
Egeler and Kiefer, 2010b
Acute Toxicity to Aquatic Invertebrates:
Acute Toxicity to Aquatic Plants e.g. Algae:
8
Toxicity to Microorganisms:
Activated Sludge of a
!622 mg/L
3h-EC50
OECD Guideline 209
Predominantly Domestic Sewage
Chronic Ecotoxicity:
Long-term Toxicity to Fish:
(References: OECD Guideline 210 (Fish, Early-Life Stage Toxicity Test) adopted 1992-07-17)
Test Organisms:
Endpoint:
Value:
Conditions
Danio Rerio
33d-NOECs
ı61.1 mg BaCl2/L
Based on Total Barium Concentration
(Mortality)
ı40.3 mg Barium/L
Danio Rerio
33d-NOECs
ı1.91 mg BaCl2/L
(Mortality)
ı1.26 mg Barium/L
Based on Total Barium Concentration
Long-term Toxicity to Aquatic Invertebrates:
Test Organisms:
Endpoint:
Value:
Published Data
Daphnia Magna
21d-NOEC(Reproduction)
2.9 mg Ba/L
Biesinger and Christensen, 1972
258 mg Ba/kg dw
Kuperman et al, 2008
Sediment Toxicity:
Earthworms- Eisenia fetida,Enchytraeus crypticus
Mobility:
Air: Transport as solid aerosols
Suspended Particulate Matter (SPM): log Kd 3.72 L/kg; 5,217 L/kg (Batch equilibrium method); Estimated data (ratio of 1.5 on KD,sediment)
Water/soil: Considerable solubility but mobility reduced by cation precipitation in presence of sulfates or carbonates. Instantaneous ionization with
pH increase.
log Kd(soil/water): log Kp (soil-water) 1.78 Kd: 60.3 L/kg (Batch equilibrium method)
Ref: Crommentuyn et al. (1997)
Soil sediments: Adsorption on mineral and organic soil constituents (Barium).
Typical EU-value: log Kp (sediment-water) 3.54 L/kg; 3478 L/kg (Batch equilibrium method)
Ref: Salminen R et al. (Geochemical Atlas of Europe - Part 1: Background information, Methodology and Maps, 2005)
Persistence and Degradability:
Abiotic--Persistent because of precipitation of Barium salts in Aquatic environments and of stable form in soil.
The OH ions are transformed to water, to metal hydroxides or hydroxo complexes.
Biotic--- The methods for determining biodegradability are not applicable to inorganic substances.
Bioaccumulative Potential:
Bioconcentration /Potential accumulation of the cation
Results of PBTand vPvB Assessment:
Barium Hydroxide is an inorganic substance; A PBT and vPvB assessment is not required.
Additional Remarks:
Hazard for the environment is related to the Substance’s high alkaline pH.
May be hazardous to terrestrial and aquatic plants and animals. Avoid releasing it to the environment.
Can be eliminated from water by precipitation.
9
SECTION 13- WASTE DISPOSAL
Waste /Product Disposal:
In accordance with applicable national, state and local environmental laws and regulations.
Dilute the concentration of substance with plenty of water
Neutralize with acid.
Use a solution of sodium/ magnesium sulfate or a dilute solution of sulfuric acid to form a precipitate of sulfate.
Waste/Spilled product should be disposed of in an EPA approved disposal facility
Containers that cannot be cleaned must be treated as waste and disposed of in an approved industrial incineration
Packaging Treatment:
facility.
RCRA Hazardous Waste:
Listed RCRA Hazardous Waste (40 CFR 302): No
Unlisted RCRA Hazardous Waste (40 CFR 302): Yes
D005 (barium containing waste)
SECTION 14- TRANSPORT INFORMATION
MODE
Shipping Name
Class
UN/NA
PG
Label(s)
MP
Barium Compounds, N.O.S (Barium Hydroxide)
UN1564
6.1
III
Toxic
No
IMDG
Barium Compounds, N.O.S (Barium Hydroxide)
UN1564
6.1
III
Toxic
No
RID/ADR
Barium Compounds, N.O.S (Barium Hydroxide)
UN1564
6.1
III
Toxic
No
IATA
Barium Compounds, N.O.S (Barium Hydroxide)
UN1564
6.1
III
Toxic
No
US DOT
Barium Compounds, N.O.S (Barium Hydroxide)
UN1564
6.1
III
Toxic
No
CANADA-TDG
Emergency info US DOT Emergency Info: ERG: 154
PG- Packing Group
M P- Marine Pollutant
SECTION 15- REGULATORY INFORMATION
CANADA
Inventory Information:
Canadian Domestic Substances List (DSL): All of the components of this product are listed on the Canadian Domestic Substances List.
Canadian Non-Domestic Substances List (NDSL): N/A
WHMIS Classification and labeling:
-
Class D1B Toxic Material Causing Immediate and Serious Toxic Effects ı1%
-
Class E Corrosive Material ı1%
Toxic (Acute effects)
E: Corrosive
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of
the information required by the CPR
Canadian Ingredient Disclosure List
CAS# 12230-71-6 is listed on the Canadian Ingredient Disclosure List.
10
Classification and Labelling According to GHS
Hazard Statement(s)
H332: Harmful if inhaled.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
Precautionary Statement(s)
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
Signal Word: Danger
Hazard Pictogram(s)
US FEDERAL, STATE, REGULATIONS
TSCA 8(b) inventory: Barium Hydroxide
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 302 Extremely Hazardous Substance
(40 CFR 355, Appendix A): Not regulated.
SARA Hazard Designation (SARA 311/312):
-
Acute Health Hazard: Yes.
-
Chronic Health Hazard: Yes.
US. EPA Emergency Planning and Community Right-To-Know Act (EPCRA) SARA Title III Section 313 Toxic Chemicals (40 CFR 372.65)
- Supplier Notification Required: Not regulated.
HMIS (Hazardous Material Information System)
HMIS: H= 2 F= 0 R= 0 PPE = Supplied by User; dependent on local condition
NFPA (National Fire Protection Association)
NFPA: H= 2 F= 0 I= 0 S= None
SECTION 16- ADDITIONAL INFORMATION
Reference:
IUCLID Chemical Data Sheet (Barium Hydroxide) ದ 18.FEB, 2000
Annex I to Directive 67/548/EEC on Classification and Labelling of Dangerous Substances
Annex VI to the CLP Regulations
Regulation (EC) No 1272/2008, OJ L 353 (LexUriServ)
ECHA Web, (http://echa.europa.eu), Public Date: Barium Hydroxide
CRS-barium chloride-2010-11-19 (1)
ljIMDG CODE-INTERNATIONAL DANGEROUS GOODS CODENJ2014
MSDS Creation Date:
JAN.08, 2006
Revision Date:
JUN.08, 2015
11
The information above is believed to be accurate and represents the best information currently available to us. However, we (TANGSHAN
HAOXUCHENG CHEMICAL TRADING CO, LTD) make no warranty of merchantability or any other warranty, express or implied, with respect
to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall we be liable for any claims, losses, or damages of any third party or for lost profits or any
special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if we (TANGSHAN HAOXUCHENG CHEMICAL
TRADING CO, LTD) has been advised of the possibility of such damages.
MATERIAL SAFETY DATA SHEET OF BARIUM HYDROXIDE OCTAHYDRATE
TANGSHAN HAOXUCHENG CHEMICAL TRADING CO,. LTD.
Address: No.118-8, Xinhua West RD. Room33, No 15 BLDG Tangshan Hebei Prov. P R China 063000
24 Hour Emergency Call: ++863155269898 Fax: ++863155267279
12