Lecture 4 Problem Set-1 Objectives In this lecture you will learn the following In this lecture, we shall practice solving problems.We will solve 5 representative problems. 1 2 3 4 5 6 7 /7 GO Lecture 4 Problem Set-1 Background Information Mole – Molecular weight expressed in grams. 1 mole of any element has Avogadro number of molecules. Every molecule has 1 nucleus. 1 MeV = 1.603 x 10-13 Joules. Avogadro Number = 6.023 x 10 23. 1 2 3 4 5 6 7 /7 GO Lecture 4 Problem Set-1 Question-1 How may neutrons and protons are there in the nuclei of the following atoms; (a) Li7, (b) Mg 24,(c) Xe 135, (d) Rn 222. Sol. The following website gives properties of isotopes. http://ie.lbl.gov/education/isotopes.htm The Berkeley Laboratory Isotopes Project Isotopes of Lithium (Z=3)Click on an isotope to get more information about its decay Isotope Half-life 6Li stable 7Li stable 8Li 838 ms 9Li 178.3 ms Now from the above source or from any book we can construct the following table. Mass Number 7 Protons/ Electrons 3 Neutrons Li Charge Number 3 Mg 12 24 12 12 4 Xe 54 135 54 81 Rn 86 222 86 136 1 2 3 4 5 6 7 /7 GO Lecture 4 Problem Set-1 Question-2 Tritium ( H3 ) decays by negative beta decay with a half-life of 12.33 years. The atomic weight of H3 is 3.016. What is the mass in grams of 1 mCi of tritium ? Solution - 2 Activity = α = 1 mCi = 3.7 1010 x 10-3 = 3.7 x 107 s-1 = λ N T1/2 = 12.33 years λ = 0.693/T 1/2 =0.693/(12.33 x 365.25 x 24 x 3600) = 1.781 x 10-9 s-1 N= 3.7 x 107/1.781 x 10-9 = 2.08 x 1016 nuclei Mass of Tritium Atom = 3.016/6.023 x 1023 = 5.007 x 10-24 g Hence total mass =5.007 x 10-24 x 2.08 x 1016 = 1.040 x 10-7 g 1 2 3 4 5 6 7 /7 GO Lecture 4 Problem Set-1 Question 3 The radioisotope battery is fuelled with 500g of Pu238C (Plutonium-238 carbide), which has a density of 12.5 g/cm3. The Pu238 has a half life of 89 years, and emits 5.6 MeV per disintegration, all of which may be assumed to be absorbed in the generator. The thermal to electrical efficiency of the system is 6 percent. Calculate (a) the specific power in watts (thermal) per gram of fuel; (b) the power density in watts (thermal) per cm 3; (c) the fuel efficiency in curies per watt (thermal); (d) the total electrical power of the generator. Solution 3 Mol-wt-PuC 250 T 1/2 89 years Energy per disintegration 5.6 MeV Density - PuC 12.5 g/cm3 Total Mass of PuC 500 g Efficiency 0.06 λ = 0.693/T 1/2 = 0.693/(89 x 365.25 x 24 x 3600) = 2.467 x 10-10 s-1 Molecules/unit mass = N = 6.023 x 1023/250 = 2.409 x 1021 g-1 Specific activity = λN = 2.467 x 10-10 x 2.409 x 1021 = 5.944 x 1011 s-1/g = 5.944 x 1011 /3.7 x 1010 = 16.07 Ci/g Specific Power= λNE = 5.944 x 1011 x 5.6 x 1.603 x 10-13 = 0.534 W/g Power Density = λNEρ = 0.534 W/g x 12.5 g/cm3 = 6.67 W/cm 3 Fuel Efficiency = λN/ λNE = 16.07 Ci/g / 0.534 W/g = 30.11 Ci/W Total Power = Specific power x Mass x Conv. Eff. =λnEmη = 0.534 W/g x 500 g x 0.06 = 16.01 W(electric) 1 2 3 4 5 6 7 /7 GO Lecture 4 Problem Set-1 Question 4 Three elements A, B and C, not connected by a chain, decay individually. At t=10s, the ratio of their activities are 1:0.5:0.25, and at t=15s, their activities are in the ratio 1:0.25:0.0625. What would be the ratio of their activities at t=0s. Solution 4 Similarly From above, we can write, Using the data at 10 s, (1) Using the data at 15 s, Dividing the latter by former we get, Substituting the value in Eq. (1), we get Since the ratio of αB/ αC is similar, we can write, 1 2 3 4 5 6 7 /7 GO Lecture 4 Problem Set-1 Question 5 Tata Memorial Hospital has been procuring a short-lived radio-isotope for medical applications. The doctors, of late, had been complaining that the supplied isotope did not have the necessary strength for which the order was placed. In order to verify this, the inspection department carried out the following test. The sample was counted for 1 minute for the number of disintegration, immediately on its arrival. In the first one minute 1791 disintegrations were counted. After 10 minutes from the arrival time, the sample was again counted for 1 minute. This time the number of counts were 1620. Based on the above facts, compute the strength of the source in Becquerels (dps), when supplied. Solution 5 Every disintegration results in a radiation and this can be detected in a counter. Thus if a counter detects N counts, it implies N disintegrations have taken place. Let the Number of nuclei in the sample at t=0 be N(0) Number of Nuclei after one minute = This implies that (1) Similarly, (2) Dividing Eq. (1) by Eq. (2), we get Substituting this in Eq. (1), we get Activity at t = 0 is given by 1 2 3 4 5 6 7 /7 GO
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