A24 Appendix 2 2D The Elements Symbol actinium (Greek aktis, ray) aluminum (from alum, salts of the form KAl(SO4)212H2O) americium (the Americas) antimony (probably a corruption of an old Arabic word; Latin stibium) argon (Greek argos, inactive) Ac 89 (227) s, m 10.07 1230 Al 13 26.98 s, m 2.70 660 Am 95 (243) s, m 13.67 990 Sb 51 121.76 s, md 6.69 631 Ar 18 39.95 g, nm 1.66‡ 189 arsenic (Greek arsenikos, male) astatine (Greek astatos, unstable) barium (Greek barys, heavy) berkelium (Berkeley, California) beryllium (from the mineral beryl, Be3Al2SiO18) As 33 74.92 s, md 5.78 613§ At 85 (210) s, nm Ba 56 137.33 s, m 3.59 710 Bk 97 (247) s, m 14.79 986 Be 4 9.01 s, m 1.85 1285 Bi 83 208.98 s, m 8.90 271 Bh 107 (262) — B 5 10.81 s, md 2.47 2300 Br 35 79.90 1, nm 3.12 7 Cd 48 112.41 s, m 8.65 321 Ca 20 40.08 s, m 1.53 840 Cf 98 (251) s, m C 6 12.01 s, nm 2.27 3700§ Ce 58 140.12 s, m 6.71 800 Element bismuth (German weisse Masse, white mass) bohrium (Niels Bohr) boron (Arabic buraq, borax, Na2B4O710H2O; bor(ax) (carb)on bromine (Greek bromos, stench) cadmium (Greek Cadmus, founder of Thebes) calcium (Latin calx, lime) californium (California) carbon (Latin carbo, coal or charcoal) cerium (the asteroid Ceres, discovered 2 days earlier) Molar mass,* gmol1 Normal state† Density, gcm3 Melting point, °C Atomic number — — — 300 — — Experimental Data Boiling point, °C Ionization energies, kJmol1 Electron affinity, kJmol1 3200 499, 1170, 1900 —u 1.1 2467 577, 1817, 2744 43 2600 578 1750 834, 1794, 2443 186 1520 A25 Atomic radius, pm Ionic radius, pm 3 188 118(3) 1.6 3 143 57(3) —u 1.3 3 173 107(3) 103 2.1 3, 3, 5 182 89(3) 0 u— 0 174 —Uu uu 125 222(3) Principal oxidation states Electronegativity — 947, 1798 78 2.2 3, 3, 5 350 1037, 1600 270 2.0 1 — 227(1) 14 0.89 2 217 143(2) 601 —u 1.3 3 — 87(4) 2470 900, 1757 0 1.6 2 113 34(2) 1650 703, 1610, 2466 91 2.0 3, 5 155 96(3) —u — 5 128# 83(5)# 27 2.0 3 83 23(3) 325 3.0 1, 1, 3, 4, 5, 7 114 196(1) 1640 — — 3931 502, 965 660 799, 2427, 3660 59 1140, 2104 765 868, 1631 0 1.7 2 149 103(2) 590, 1145, 4910 2 1.3 2 197 106(2) — 608 —u 1.3 3 169 117(2) — 1090, 2352, 4620 122 2.6 4, 1, 2, 4 77 260(4) 3000 527, 1047, 1949 50 1.1 3, 4 1490 183 107(3) (continued) A26 Appendix 2 Element cesium (Latin caesius, sky blue) chlorine (Greek chloros, yellowish green) chromium (Greek chroma, color) cobalt (German Kobold, evil spirit; Greek kobalos, goblin) copper (Latin cuprum, from Cyprus) curium (Marie Curie) dubnium (Dubna) dysprosium (Greek dysprositos, hard to get at) einsteinium (Albert Einstein) erbium (Ytterby, a town in Sweden) europium (Europe) fermium (Enrico Fermi, an Italian physicist) fluorine (Latin fluere, to flow) francium (France) gadolinium (Johann Gadolin, a Finnish chemist) gallium (Latin Gallia, France; also a pun on the discoverer’s forename, Le Coq) germanium (Latin Germania, Germany) gold (Anglo-Saxon gold; Latin aurum, gold) hafnium (Latin Hafnia, Copenhagen) hassium (Hesse, the German state) helium (Greek helios, the sun) Symbol Atomic number Molar mass,* gmol1 Cs 55 132.91 Cl 17 Cr Normal state† Density, gcm3 Melting point, °C s, m 1.87 35.45 g, nm 1.66‡ 101 24 52.00 s, m 7.19 1860 Co 27 58.93 s, m 8.80 1494 Cu 29 63.55 s, m 8.93 1083 Cm 96 (247) s, m 13.30 1340 Db 105 (262) s, m 29 Dy 66 162.50 s, m Es 99 (252) s, m Er 68 167.26 s, m 9.04 1520 Eu 63 151.96 s, m 5.25 820 Fm 100 (257) s, m F 9 19.00 g, nm Fr 87 (223) s, m Gd 64 157.25 s, m 7.87 1310 Ga 31 69.72 s, m 5.91 30 Ge 32 72.61 s, md 5.32 937 Au 79 196.97 s, m 19.28 1064 Hf 72 178.49 s, m 13.28 2230 Hs 108 (265) — — He 2 4.00 g, nm 8.53 — — 1.51‡ — 0.12‡ 28 — 1410 — — 220 27 — — Experimental Data Boiling point, °C Electron affinity, kJmol1 Electronegativity 376, 2420 46 0.79 1 34 1255, 2297 349 3.2 2600 653, 1592, 2987 64 1.7 1, 1, 3, 4, 5, 6, 7 2, 3 2900 760, 1646, 3232 64 1.9 2567 785, 1958, 3554 118 678 Ionization energies, kJmol1 A27 Atomic radius, pm Ionic radius, pm 265 165(1) 99 181(1) 125 84(2) 3, 6 125 64(3) 1.9 1, 2 128 72(2) 1.3 3 174 99(3) 5 139# 68(5)# Principal oxidation states — 581 —uu — 640 —uu 572, 1126, 2200 —uu 1.2 3 177 91(3) 619 50 1.3 3 203 98(3) 2600 589, 1151, 2194 50 1.2 3 176 89(3) 1450 547, 1085, 2404 50 3 204 98(3) 627 —uu 1.3 3 — 91(3) 328 4.0 1 71 133(1) 400 44 0.7 1 270 180(1) 3000 592, 1167, 1990 50 1.2 2, 3 180 97(3) 2403 577, 1979, 2963 29 1.6 1, 3 122 62(3) 2830 784, 1557, 3302 116 2.0 2, 4 123 90(2) 2807 890, 1980 223 2.5 1, 3 144 91(3) 5300 642, 1440, 2250 0 1.3 4 156 84(3) 126# 80(4)# 2600 — — 188 677 — 269 1680, 3374 750 2370, 5250 — — —uu — 3 0 — 0 128 —Uu uu (continued) A28 Appendix 2 Element holmium (Latin Holmia, Stockholm) hydrogen (Greek hydro genes, water-forming) indium (from the bright indigo line in its spectrum) iodine (Greek ioeide–s, violet) iridium (Greek and Latin iris, rainbow) iron (Anglo-Saxon iron; Latin ferrum) krypton (Greek kryptos, hidden) lanthanum (Greek lanthanein, to lie hidden) lawrencium (Ernest Lawrence, an American physicist) lead (Anglo-Saxon lead; Latin plumbum) lithium (Greek lithos, stone) lutetium (Lutetia, ancient name of Paris) magnesium (Magnesia, a district in Thessaly, Greece) manganese (Greek and Latin magnes, magnet) meitnenium (Lise Meitner) mendelevium (D. Mendeleev) mercury (the planet Mercury; Latin hydrargyrum, liquid silver) molybdenum (Greek molybdos, lead) neodymium (Greek neos didymos, new twin) neon (Greek neos, new) Density, gcm3 Melting point, °C s, m 8.80 1470 1.0079 g, nm 0.089‡ 259 49 114.82 s, m 7.29 156 I 53 126.90 s, nm 4.95 114 Ir 77 192.22 s, m 22.56 2447 Fe 26 55.85 s, m 7.87 1540 Kr 36 83.80 g, nm 3.00‡ 157 La 57 138.91 s, m 6.17 Lr 103 (262) s, m — Pb 82 207.2 s, m 11.34 328 Li 3 6.94 s, m 0.53 181 Lu 71 174.97 s, m 9.84 1700 Mg 12 24.31 s, m 1.74 650 Mn 25 54.94 s, m 7.47 1250 Mt 109 (266) — — — Md 101 (258) — — — Hg 80 200.59 l, m 13.55 39 Mo 42 95.94 s, m 10.22 2620 Nd 60 144.24 s, m 7.00 1024 Ne 10 20.18 g, nm 1.44‡ 249 Symbol Atomic number Molar mass,* gmol1 Ho 67 164.93 H 1 In Normal state† 920 — Experimental Data Boiling point, °C Electron affinity, kJmol1 Electronegativity 581, 1139 50 1.2 3 1310 73 2.2 2080 556, 1821 29 184 1008, 1846 4550 880 2760 759, 1561, 2957 2300 253 153 Ionization energies, kJmol1 1350, 2350 Principal oxidation states Atomic radius, pm A29 Ionic radius, pm 177 89(3) 1, 1 78 154(1) 1.8 1, 3 163 92(3) 295 2.7 1, 1, 3, 5, 7 133 196(1) 151 2.2 3, 4 136 75(3) 16 1.8 2, 3 124 82(2) 2 189 169(1) 0 — 538, 1067, 1850 50 1.1 3 188 122(3) — —uu 1.3 3 — 88(3) 1760 716, 1450 35 2.3 2, 4 175 132(2) 1347 519, 7298 60 1.0 1 152 78(1) 3400 524, 1340, 2022 50 1.3 3 173 85(3) 1100 736, 1451 0 1.3 2 160 79(2) 2120 717, 1509 0 1.6 2, 3, 4, 7 137 91(2) 2 — 83(2) — 90(3) 3450 — — 840 —uu — 635 —uu 1.3 3 357 1007, 1810 18 2.0 1, 2 160 112(2) 4830 685, 1558, 2621 72 2.2 4, 5, 6 136 92(2) 3100 530, 1035 0 1.1 3 182 104(3) — —Uu uu 246 2080, 3952 0 — — 0 (continued) A30 Appendix 2 Element neptunium (the planet Neptune) nickel (German Nickel, Old Nick, Satan) niobium (Niobe, daughter of Tantalus; see tantalum) nitrogen (Greek nitron genes, soda-forming) nobelium (Alfred Nobel, the founder of the Nobel prizes) osmium (Greek osme, a smell) oxygen (Greek oxys genes, acid-forming) palladium (the asteroid Pallas, discovered at about the same time) phosphorus (Greek phosphoros, light-bearing) platinum (Spanish plata, silver) plutonium (the planet Pluto) polonium (Poland) potassium (from potash; Latin kalium and Arabic qali, alkali) praseodymium (Greek prasios didymos, green twin) promethium (Prometheus, the Greek god) protactinium (Greek protos aktis, first ray) radium (Latin radius, ray) radon (from radium) rhenium (Latin Rhenus, Rhine) rhodium (Greek rhodon, rose; its aqueous solutions are often rose-colored) Molar mass,* gmol1 Normal state† Symbol Np 93 (237) s, m 20.45 640 Ni 28 58.69 s, m 8.91 1455 Nb 41 92.91 s, m 8.57 2425 N 7 14.01 g, nm 1.04‡ 210 No 102 (259) s, m — Os 76 190.23 s, m 22.58 3030 O 8 16.00 1.14 218 Pd 46 106.42 s, m 12.00 1554 P 15 30.97 s, nm 1.82 44 Pt 78 195.08 s, m 21.45 1772 Pu 94 (244) s, m 19.81 640 Po 84 (209) s, md 9.40 254 K 19 39.10 s, m 0.86 64 Pr 59 140.91 s, m 6.78 935 Pm 61 (145) s, m 7.22 1168 Pa 91 231.04 s, m 15.37 1200 Ra 88 (226) s, m 5.00 700 Rn 86 (222) g, nm 4.40‡ 71 Re 75 186.21 s, m 21.02 3180 Rh 45 102.91 s, m 12.42 1963 g, nm Density, gcm3 Melting point, °C Atomic number — Experimental Data Boiling point, °C Ionization energies, kJmol1 Electron affinity, kJmol1 Electronegativity Principal oxidation states Atomic radius, pm A31 Ionic radius, pm 597 —uuu 1.4 5 150 88(5) 2150 737, 1753 156 1.9 2, 3 125 78(2) 5000 664, 1382 86 1.6 5 143 69(5) 1400, 2856 7 3.0 3, 3, 5 71 171(3) — 113(2) 135 81(3) 66 132(2) — 196 — 642 —uuu 1.3 2 5000 840 106 2.2 3, 4 141, 844 3.4 2 805, 1875 54 2.2 2, 4 138 86(2) 1011, 1903, 2912 72 2.2 3, 3, 5 115 212(3) 183 3000 280 1310, 3388 3720 870, 1791 205 2.3 2, 4 138 85(2) 3200 585 —uuu 1.3 3, 4 151 108(3) 960 812 174 2.0 2, 4 167 65(4) 774 418, 3051 48 0.82 1 227 133(1) 3000 523, 1018 50 1.1 3 183 106(3) 3300 536, 1052 50 3 181 106(3) 4000 568 —uuu 1.5 5 161 89(5) 1500 509, 979 —uuu 0.9 2 223 152(2) 62 1036, 1930 0 2 — —uuu 5600 760, 1260 14 1.9 4, 7 137 72(4) 3700 720, 1744 110 2.3 3 134 75(3) — — (continued) A32 Appendix 2 Molar mass,* gmol1 Normal state† Density, gcm3 Melting point, °C Element Symbol Atomic number rubidium (Latin rubidus, deep red, “flushed”) ruthenium (Latin Ruthenia, Russia) rutherfordium (Ernest Rutherford) samarium (from samarskite, a mineral) scandium (Latin Scandia, Scandinavia) Rb 37 85.47 s, m 1.53 39 Ru 44 101.07 s, m 12.36 2310 Rf 104 (261) — — Sm 62 150.36 s, m 7.54 1060 Sc 21 44.96 s, m 2.99 1540 seaborgium (Glenn Seaborg) selenium (Greek sele–ne–, the moon) silicon (Latin silex, flint) silver (Anglo-Saxon seolfor; Latin argentum) sodium (English soda; Latin natrium) Sg 106 (263) — Se 34 78.96 s, nm 4.79 220 Si 14 28.09 s, md 2.33 1410 Ag 47 107.87 s, m 10.50 962 Na 11 22.99 s, m 0.97 98 strontium (Strontian, Scotland) sulfur (Sanskrit sulvere) tantalum (Tantalos, Greek mythological figure) technetium (Greek techne–tos, artificial) tellurium (Latin tellus, earth) Sr 38 87.62 s, m 2.58 770 S 16 32.07 s, nm 2.09 115 Ta 73 180.95 s, m 16.65 3000 Tc 43 (98) s, m 11.50 2200 Te 52 127.60 s, md 6.25 450 terbium (Ytterby, a town in Sweden) thallium (Greek thallos, a green shoot) thorium (Thor, Norse god of thunder, weather, and crops) thulium (Thule, early name for Scandinavia) tin (Anglo-Saxon tin; Latin stannum) Tb 65 158.93 s, m 8.27 1360 Tl 81 204.38 s, m 11.87 304 Th 90 232.04 s, m 11.73 1700 Tm 69 168.93 s, m 9.33 1550 Sn 50 118.71 s, m 7.29 232 titanium (Titans, Greek mythological figures, sons of the Earth) Ti 22 47.87 s, m 4.55 1660 — — — Experimental Data Boiling point, °C Ionization energies, kJmol1 Electron affinity, kJmol1 Electronegativity Principal oxidation states A33 Atomic radius, pm Ionic radius, pm 688 402, 2632 47 0.82 1 250 149(1) 4100 711, 1617 101 2.2 2, 3, 4 134 77(3) 490 —uuu 4 150# 67(4)# — — 1600 543, 1068 50 1.2 3 180 100(3) 2800 631, 1235 18 1.4 3 161 83(3) 6 132# 86(5)# — 730 —uuu — 685 941, 2044 195 2.6 2, 4, 6 215 191(2) 2620 786, 1577 134 1.9 4 117 26(4) 2212 731, 2073 126 1.9 1 144 113(1) 883 494, 4562 53 0.93 1 154 98(1) 1380 548, 1064 5 0.95 2 215 127(2) 445 1000, 2251 200, 532 2.6 2, 4, 6 104 184(2) 5400 761 14 1.5 5 143 72(3) 4600 702, 1472 96 1.9 4, 7 136 72(4) 990 870, 1775 190 2.1 2, 4 143 211(2) 2500 565, 1112 50 3 178 97(3) 1457 590, 1971 19 2.0 1, 3 170 105(3) 4500 587, 1110 —uuu 1.3 4 180 99(4) 2000 597, 1163 50 1.2 3 175 94(3) 2720 707, 1412 116 2.0 2, 4 141 93(2) 3300 658, 1310 1.5 4 145 69(4) 7.6 — (continued) A34 Appendix 2 Element tungsten (Swedish tung sten, heavy stone; from wolframite) uranium (the planet Uranus) vanadium (Vanadis, Scandinavian mythological figure) xenon (Greek xenos, stranger) ytterbium (Ytterby, a town in Sweden) yttrium (Ytterby, a town in Sweden) zinc (Anglo-Saxon zinc) zirconium (Arabic zargun, gold color) Normal state† Density, gcm3 Melting point, °C Symbol Atomic number Molar mass,* gmol1 W 74 183.84 s, m 19.30 3387 U 92 238.03 s, m 18.95 1135 V 23 50.94 s, m 6.11 1920 Xe 54 131.29 g, nm 3.56‡ 112 Yb 70 173.04 s, m 6.97 824 Y 39 88.91 s, m 4.48 1510 Zn 30 65.39 s, m 7.14 420 Zr 40 91.22 s, m 6.51 1850 Experimental Data Boiling point, °C Ionization energies, kJmol1 Electron affinity, kJmol1 Electronegativity Principal oxidation states Atomic radius, pm A35 Ionic radius, pm 5420 770 79 2.4 5, 6 137 62(6) 4000 584, 1420 —uu 1.4 6 154 80(6) 3400 650, 1414 51 1.6 4, 5 132 61(4) 1170, 2046 0 2.6 2, 4, 6 218 190(1) 1500 603, 1176 50 3 194 86(3) 3300 616, 1181 30 1.2 3 181 106(3) 907 906, 1733 9 1.6 2 133 83(2) 4400 660, 1267 41 1.3 4 160 87(4) 108 — *Parentheses around molar mass indicate the most stable isotope of a radioactive element. † The normal state is the state of the element at normal temperature and pressure (20°C and 1 atm). s denotes solid; l, liquid; and g, gas; m denotes metal; nm, nonmetal; and md, metalloid. ‡ The density quoted is for the liquid. § The solid sublimes. Charge in parentheses. # Atomic and ionic radii are estimated.
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