Mohammad Ali Fahimipour 7/29/2013 Strong but light: the new generation of metals A recent breakthrough in the field of material science has created a new metal that may have a tremendous impact on the world. The metal is an ultralow-density material that has all of the strengths of chemically similar compounds, while being significantly lighter. Engineers designed this material by applying architectural ideas used to create strong lightweight building, such as the Eiffel Tower. As a result of this design, the micro-lattice metals are extremely light and as strong as bulkier metals. The material is manufactured from a periodic array of hollow nickel phosphorous tubes. The tubes are approximately one thousand times thinner than a single strand of human hair, which is the reason that micro-lattice metals are almost entirely composed of air. This metal is currently being limited by the means in which it is produced, as there is no reliable method to produce it in large scales. Researchers at the University of California Irvine are currently working on overcoming this problem and investigating its possible applications. Introduction There is no doubt that humans could not have made any significant progress in agriculture, architecture, or transportation without the discovery of metals. With that being said, it cannot be neglected that each of the naturally existing metals has positive and negative characteristics associated with it, which makes them not very flexible for use in today’s advanced society. To increase the capabilities of different metals, engineers and scientists have constantly tried to alter the nature of metals in a way that enhances their positive characteristics while eliminating the negative ones. Changing the chemical properties by combining different materials with metals was one of the earliest techniques used to improve metals; however, improving one property has always impacted the other in a negative way. This trade-off is a problem that is slowing down the advancement of a number of technologies. A new method for strengthening the properties is being researched by material scientists. They are experimenting with new ways of designing the structure of each metallic compound in order to improve the characteristics. Specifically, engineers at the University of California Irvine UCI), CalTech and HRL laboratories have used some architectural techniques to fabricate new metals in ways that would decrease their weight while maintaining their strength [1]. These techniques resulted in the development of an extremely strong lightweight metal, named micro-lattice nickel. Due to the micro-lattice nickel being both strong and light, it has the potential to revolutionize the aerospace, marine, and automotive industries. In 2012 Popular Mechanics Magazine declared micro-lattice nickel as one of the “10 World-Changing Innovations” [2]. This advanced metal is created by connecting thin fibers that are formed by microlattice nickel phosphorous tubes. The tubes are made up of ninety nine percent air and are approximately one thousand times thinner than a single strand of human hair [1]. The density of micro-lattice nickel was approximated to be 0.9 mg/cm3 that placed this metal in the category of ultralow-density materials [3] (Fig. 1). 1 Figure 1. A clever demonstration of the lightweight nature of micro-lattice nickel [1]. Background Low-density materials such as micro-lattice metals are significant due to their cellular architecture (the spatial configuration of solid and voids) and their strength. These materials are categorized in different regimes and the lightest of which is known as ultralow regime with the density below 10 mg/cm3. Currently, there exist no more than five types of materials that fall in the ultralow regime. Some examples of materials from the ultralow regime are: metallic foams with a density of about 10 mg/cm3, carbon nanotube aerogels with a density of 4 mg/cm3, and silica aerogels with a density of approximately 1 mg/cm3. Micro-lattice metals with the density of 0.9 mg/cm3 possess the lowest value of density among solids. Due to their unique properties, ultralowdensity materials are widely applicable in different industries, such as aerospace and automobile. Some of their common applications are, but not limited to, thermal insulation, acoustic absorption, and shock or vibration damping [3]. It is important to understand that the source of strength for these low-density materials comes from their “random cell structure” and not their chemical formulas. The idea of the “random cellular architecture” of low-density materials and micro-lattice metals can be easily understood by using the structure of the Eiffel Tower as a model. The Eiffel Tower’s structure demonstrates a hierarchy featured by the difference in the size of the structural holes. This random size difference is the architectural inspiration 2 behind the design of most of the low-density materials that results in many beneficial properties. However, the improvement to strength and density can cause some negative side effects, such as a decrease in conductive efficiency. What differs micro-lattice metals from other ultralow-density materials is their “ordered hollow-tube structure”. This new design substantially improves the low-density materials’ properties and makes their good characteristics competitive with that of bulkier materials. In the next section, the method through which the lightest and strongest metal has been created will be explained [3]. Synthesis The structure of micro-lattice nickel is made of a “periodic array of hollow tubes that connect at nodes, forming an octahedral unit cell without any lattice member in the basal plane” [3] (Fig 2). Figure 2. Synthetic process of micro-lattice nickel [3] To fabricate such a sophisticated structure (shown in Fig 2), the HRL/Caltech/UCI research team started with preparing a polymer template. For constructing the template a reservoir full of UV-curable resin, a perforated mask, and an ultraviolet (UV) laser were required. The procedure started by covering the reservoir by the mask and exposing it to UV light. As the light passed though the holes of the mask, 3 the resin gradually solidified. While the resin was solidifying, under each hole of the mask, a light beam, just like an optical fiber, got trapped and created a thin polymer fiber along the path of the light. To form the three dimension lattice structure, multiple fibers were interconnected by using multiple light beams to produce the polymer fibers. Then a technique called electro-less nickel-plating (EN) was performed on the polymer template, which coated the polymers with a thin layer of nickel (other metals can be used, however nickel was chosen due to the ease in which it can be fabricated [1]). Finally, the coated polymer was etched out to create the porous structure of microlattice nickel [3]. Properties The micro-lattice metals’ structure can be separated into “three levels of hierarchy” [3]. The biggest element is the unit cell, then the hollow tube, and finally the wall of the hollow tubes. By controlling and changing each of those elements, the properties (for example, density and stiffness) of the resulting micro-lattice metal can be modified [3]. As it was previously mentioned, the unique structure of micro-lattice metals resulted in their great strength. But how strong can a featherweight metal be? This question was answered by a series of compression tests. Through the first cycle of the experiments, a block of micro-lattice nickel was compressed to 50 percent of its volume. After removing the load from the block, it was observed that the metal recovered its original volume and shape almost entirely. Therefore, micro-lattice metals proved that it takes a great amount of force before they go through permanent deformations. This experiment showed the micro-lattice metals’ high strength and stiffness [3]. The above experiment demonstrated not only the strength of the substance, but also its high level of resilience. After the load was removed from block, the micro-lattice metal recovered very rapidly. This property could have great applications in the automobile industry that are going to be discussed in the following section [3]. Applications The material science division at UCI is investigating the possible applications of micro-lattice metals in several fields. They are looking into the way in which it can be used in impact protection, aerospace engineering, acoustic damping, and automotive engineering [4]. One example of where such a light and strong metal could make an immediate impact is in the aerospace industry. In fact, Boeing, as one of the biggest companies in the industry of aerospace, is one of the sponsors of micro-lattice metal’s project. This shows the crucial role that this metal could play in the aerospace industry. It is not hard to imagine that a significant drop in the weight of airplanes can result in less fuel consumption. The result of this improvement in fuel efficiency would be 4 comparable to the difference from the Boeing 787 and Airbus 350A. The difference between these two airplanes is the amount of some light material that was incorporated in them. This difference is only three percent, and, yet the Airbus 350A consumes twenty five percent less fuel despite still using material much heavier than the innovative micro-lattice [5]. This metal could also have a substantial impact on the automotive industry. Glen Daehn, a researcher at Ohio State University, reports for every ten percent in weight reduction a seven percent improvement in fuel economy could be created. When this is applied to the millions of vehicles on the roads it becomes a monumental amount of savings. Anthony Luscher, another researcher at Ohio State University believes that in the future all vehicles will be made up of these lightweight composite materials. Additionally he believes that the use of these materials will go beyond cars and planes, reaching to every form of transportation such as bikes, boats, and trains [6]. While the light nature of micro-lattice metals can help to produce energy efficient cars without reducing their sizes, their ability to absorb a great amount of stress without going through permanent deformation can also greatly contribute to the automobile industry. For instance, if micro-lattice metals were incorporated in the body of cars, their great resilience could make the cars resistant to accidents. In other words, using microlattice metals in the body of cars could cut from the amount fuel they burn and, at the same time, add to their safety [4]. Issues Since the micro-lattice metals are relatively new, they still require more research to reach their maximum capabilities and become available for widespread use. Some modifications in the cellular properties such as cell size or tube diameter can result in exceptionally high strength and stiffness [7]. These types of changes must be made relative to the field where the micro-lattice metals are going to be used. However, the greatest challenge that is stopping the micro-lattice metals from being used more is the limitations in their production. Although the production of these materials in small scales is relatively easy, scaling up this production is difficult. A method for scaling up the production of these materials must be discovered before they can become widely used. The fusing of different materials with different properties such as metals (nickel) and nonmetals (polymers) is a necessary step in the production of the lightweight structures, yet it is a complex and often extremely difficult task. This is currently being worked on at the Ohio State University, and appears to be the only obstacle stopping the lightweight materials from living up to their potential as revolutionary materials [6]. Conclusion: The micro-lattice material, created by the University of California Irvine, CalTech and HRL Laboratories has the potential to greatly enhance a wide range of scientific fields. 5 This material is extremely light, thin, and durable while being composed of almost entirely air. This material offers superior strength in comparison to heavier metals, while being several orders of magnitude lighter. With this combination of benefits, the microlattice metal can lead to significant savings to consumers by reducing travel expenses, while also improving safety. The development of this lightweight micro-lattice metal is a promising sign that advancements in engineering are leading towards a more ecofriendly environmental age of technology. 6 References: [1] B. Liggett. (2011, December 29). Scientists Develop World’s Lightest Metal, 100x Lighter than Styrofoam. [Online]. Available: http://fuel-‐efficient-‐vehicles.org/energy-‐news/?p=1127 [2] R. Sterling. (2012, October 29). The World’s Lightest Material. [Online]. Available: http://www.boeing.com/Features/2012/10/bds_hrl_10_29_12.html [3] T.A. Schaedler et al. (2011, November 18). Ultralight Metallic Microlattices. [Online]. Available: http://www.sciencemag.org.libproxy.usc.edu/content/334/6058/962.full [4] K. Hall-Geisler. Micro-lattice Metal: The future of lightweight cars? [Online]. Available: http://auto.howstuffworks.com/fuel-efficiency/vehicles/micro-lattice-metal.htm [5] Change in the air. (2011, September 3). [Online]. Available: http://www.economist.com/node/21527035 [6] IIEglobal. (2012, September 28). Lightweight Metal-Based Vehicle Structures. [Online]. Available: http://www.youtube.com/watch?v=670-ofQobe8 [7] HRL's breakthrough development of ultralight microlattice materials recognized. (2012, October 5). [Online]. Available: http://phys.org/news/2012-10-hrl-breakthrough-ultralightmicrolattice-materials.html 7
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