MATERIAL SAFETY DATA SHEET
August, 2011
Version:
05
August, 2014
Health
0 None
Innophos Fosfatados de Mexico, S. de R.L.. de
0
Fire
0 None
C.V., Complejo Industrial Pajaritos.
0
0
Coatzacoalcos, Veracruz, Mexico
Reactivity
0 None
Emergency tel.: (921)21 15500 Ext. 1296/1111
Specific
None
Hazards
EMERGENCY PHONES IN TRANSPORTATION: For emergencies involving a spill, leak, fire, exposure or accident contact:
TRIPLE SUPERPHOSPHATE
SETIQ
Date Prepared:
Next Date:
CHEMTREC 1-800-424-9300 within the United States or 703-527-3887 for international collect calls
01-800-00-214-00
SECTION I PRODUCT IDENTIFICATION
Commercial Name:
Granulated triple
superphosphate
Inorganic chemical
fertilizer
Chemical Family:
Synonyms:
Chemical Name:
DOT Information:
Monocalcimum
phosphate
Not regulated
Other Data:
SECTION II COMPOSITION/INFORMATION ON PRODUCT
Component
%
Monocalcimu
m phosphate
100
NFPA
Classification
H
I
R
0
0
0
CAS N°
UN N°
TWA
STEL
Special
Risk
7758-23-8
NE
---
---
None
SECTION III HAZARD IDENTIFICATION
MAIN DANGERS
Potential health effects:
Effects of overdose:
PHYSICAL–CHEMICAL HAZARDS
Fire or explosion:
Special risk:
Section IV
Ingestion: Minimal hazard under normal conditions and use. Ingestion of
large amounts may cause gastrointestinal discomfort, vomiting, weakness
or other medically related problems.
Inhalation: Dusty conditions may cause mechanical aggravation to
respiratory mucous membranes.
Eye contact: Dust from this product may cause particulate discomfort to
eyes.
Skin absorption: Not normally absorbed through the skin.
Skin contact: Slight dermal abrasion is possible with prolonged contact,
especially around cuffs and collars.
Ingestion of large doses may cause diarrhea, nausea, abdominal cramps
or formation of methemoglobinemia. Seek medical attention.
No flammable product.
None
FIRST-AID MEASURES
Inhalation:
Skin exposure:
Eyes exposure:
Remove to fresh air. Seek medical attention if condition persists.
Wash with soap and water. Seek medical attention if condition persists.
Flush eyes with running water for at least 15 min. Seek medical attention if
condition persists.
Ingestion:
If large amount is ingested, give 2-3 glasses of water and induce vomiting.
Seek medical attention.
Rescues protection:
Other:
Section V
FIRE FIGHTING MEASURES
Extinguishing Media:
Appropriate:
Not appropriate:
Specific Risks:
Special fire fighting procedures:
Protection to the FIRE fighters:
Section VI
-------
CO2
Foam:
Dry chemical powder:
Others:
Use media suitable to extinguish source of fire.
During extremely high temperature fire conditions, the product may reach
melting point and decompose to release NH3, SOX, POX or CN.
--Use self-contained breathing apparatus and complete protective
equipment.
ACCIDENTAL RELEASE MEASURES
Environmental precautions:
Steps to be taken in case material is
released or spilled :
Keep out of water supplies, lakes, ponds, streams and rivers. This product
is a fertilizer and may promote algae growth.
Keep from entering waterways. Seep up material and place in suitable
container for use as a fertilizer or for disposal.
Section VII STORAGE AND HANDLING
Technical measures:
Necessary cautions:
Using advices:
Store in a cool, dry area. Prevent spillage and separate from strong
oxidizers. Use normal safety procedures and good personal hygiene.
Keep out of reach of children.
----
Section VIII EXPOSURE CONTROL – PERSONAL PROTECTION
Technical measures:
Assure an adequate ventilated area.
PERSONAL PROTECTIVE EQUIPMENT:
Respiratory protection:
Use dust respirator when high concentrations exist.
Eye protection:
In dusty conditions, safety glasses with side shields or goggles may be
necessary.
Hands protection:
Use gloves
Skin and body protection:
Use suitable long-sleeved clothing (i.e., shirts and pants).
Hygiene matters:
Wash hands after handling it.
Other information:
-----
Section IX
PHYSICAL AND CHEMICAL PROPERTIES
Physical appearance:
Solid (granules)
Odor:
odorless
Color:
Off-white
PH: 1 % (in solution)
N/A
N/A
N/A
N/A
Critical temperature:
Critical pressure:
N/A
N/A
N/A
--None
Stream pressure:
Relative density (Water=1):
N/A
N/A
Lightly soluble
----
In organics solvents:
---
CHARACTERISTIC TEMPERATURES:
Meting point (°C):
Boiling Point (°C):
o
Decomposition temperature ( C)
FLAMMABILITY CHARACTERISTIC:
Stream pressure:
Combustibles properties:
Explosives Limit on air:
SOLUBILITY:
In water:
Dynamic viscosity:
Section X REACTIVITY AND STABILITY DATA
Stability:
Substances to avoid:
Polymerization:
Conditions to avoid:
Dangerous products of
decomposition:
Section XI
Stable
Strong oxidizing agents.
None
Extremely high temperatures.
During extremely high temperature fire conditions theproduct may
decompose to realeas NH3, SOX, POX, CN.
TOXICOLOGICAL INFORMATION
Acute Exposure:
Acute Oral Toxicity: LD50 (rat) is 5000-6000 mg/kg (ppm); not acutely
toxic by oral exposure.
Acute symptoms:
Chronic toxicity:
This chemical substance is
considered as:
Reference (NOM-010-STPS)
Complementary information :
----Carcinogen
--
Mutation
--
Teratogenic
--
Other --
No carcinogen property has been found.
Section XII ECOLOGICAL INFORMATION
MOBILITY:
Volatility:
Adsorption / Desorption:
Fate:
ECOTOXICITY:
Effects in environment:
-----
Fish 96-hour LC50 is 1560-5900 mg/l (ppm); daphnia 24-hour EC50: 17901825 mg/l; algae no toxicity up to 87.6 mg/l. Non-toxic to aquatic
organisms.
-
Section XIII DISPOSAL CONSIDERATION
Waste disposal procedures:
Pick up with a shovel and broom and use as a fertilizer by applying to soil
using good agricultural and soil management.
Section XIV TRANSPORTATION INFORMATION
INTERNATIONAL REGULATION:
Via terrestrial:
Via marine:
Notes:
Section XV
Not regulated by DOT.
------
REGULATION IN FORMATIONS
LABEL:
Regulation:
Identification of the product:
Hazardous symbols and indications
Hazard/Health sentences:
In Mexico, NOM-003-SCT2/1994/NOM-050-SCFI-1994/NOM-114-STPS1994
-------
SECTION XVI OTHER INFORMATION
Use type:
Recommended uses:
Contraindicated uses:
------
INFORMACIÓN DEL PRODUCTO:
Chemical formula:
Registration number:
Molecular weight
Ca.2H3PO4
-252.07 g/gmol
Important note:
This Material Safety Data Sheet completes the Technical use pamphlet, but do not changes it.
The information base on own knowledge about the product at date and we give it in good faith.
Also, we remind all users that using a product for others application instead for the application that it was created or advice, may cause
eventually risk. User is obligated to know and apply the legal requirements available for the activity.
User is exclusive responsible about the inherent cautions in using the product.
The group of regulatory prescriptions given above, help user to carry out the gotten obligations when using this product.
This enunciation will keep watch over carrying out others legal obligation, different to the given above, particularly to possessing and using the
product which user is the only responsible.