Safety Data Sheet
Revision Date: 11/22/16
www.restek.com
1. IDENTIFICATION
Catalog Number / Product Name:
Company:
Address:
Phone#:
Fax#:
Emergency#:
Email:
Revision Number:
Intended use:
30727 / DHA Olefins Standard
Restek Corporation
110 Benner Circle
Bellefonte, Pa. 16823
814-353-1300
814-353-1309
800-424-9300 (CHEMTREC)
703-527-3887 (Outside the US)
www.restek.com
2
For Laboratory use only
2. HAZARD(S)IDENTIFICATION
Emergency Overview:
GHS Hazard
Symbols:
GHS
Classification:
Flammable Liquid Category 1
Carcinogenicity Category 1B
Germ Cell Mutagenicity Category 2
Hazardous to the aquatic environment - Chronic Category 3
GHS Signal
Word:
GHS Hazard:
Danger
Extremely flammable liquid and vapour.
Suspected of causing genetic defects.
May cause cancer.
Harmful to aquatic life with long lasting effects.
GHS
Precautions:
Safety
Precautions:
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ventilation and lighting equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
First Aid
Measures:
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF exposed or concerned: Get medical advice/attention.
In case of fire: Use extinguishing media in section 5 for extinction.
Storage:
Store in a well-ventilated place. Keep cool.
Store locked up.
Disposal:
Dispose of contents/container according to section 13 of the SDS.
Single
Exposure
No data available.
30727 / DHA Olefins Standard
Page 1 of 7
Target Organs:
Repeated
No data available.
Exposure
Target Organs:
3. COMPOSITION / INFORMATION ON INGREDIENT
Chemical Name
CAS #
EINEC #
% Composition
1-octene
111-66-0
203-893-7
11.339000
1-hexene
592-41-6
209-753-1
11.249000
1-pentene
109-67-1
203-694-5
8.786000
1-nonene
124-11-8
204-681-7
6.912000
1-heptene
592-76-7
209-767-8
6.787000
cis-4-nonene
10405-84-2
trans-3-Heptene
14686-14-7
238-728-8
3.747000
isoprene
78-79-5
201-143-3
3.680000
trans-2-octene
13389-42-9
236-463-2
3.453000
2-methyl-2-pentene
625-27-4
210-883-6
3.444000
cis-2-heptene
6443-92-1
229-242-7
3.418000
2-methyl-1-nonene
2980-71-4
4-Methyl-1-pentene
691-37-2
211-720-1
3.398000
cis-3-nonene
20237-46-1
243-624-0
3.027000
cis-2-hexene
7688-21-3
231-697-1
2.921000
trans-2-pentene
646-04-8
211-461-4
2.852000
trans-3-nonene
20063-92-7
243-495-0
2.315000
cis-2-octene
7642-04-8
231-577-9
2.312000
trans-2-nonene
6434-78-2
229-216-5
2.282000
1-decene
872-05-9
212-819-2
2.265000
2-methyl-1-butene
563-46-2
209-250-7
2.211000
trans-2-hexene
4050-45-7
223-752-3
1.632000
3-methyl-1-butene
563-45-1
209-249-1
1.534000
cis-2-pentene
627-20-3
210-988-7
1.107000
cis-3-heptene
7642-10-6
trans-2-Heptene
14686-13-6
4.365000
3.412000
1.020000
238-727-2
0.530000
4. FIRST-AID MEASURES
Inhalation:
Eyes:
Skin Contact:
Ingestion:
Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. If not
breathing, give artificial respiration and have a trained individual administer oxygen. Get
medical attention immediately
Flush eyes with plenty of water for at least 20 minutes retracting eyelids often. Tilt the head to
prevent chemical from transferring to the uncontaminated eye. Get immediate medical
attention.
Wash with soap and water. Remove contaminated clothing and launder. Get medical
attention if irritation develops or persists.
No data.
5. FIRE- FIGHTING MEASURES
Extinguishing Media:
Fire and/or Explosion Hazards:
30727 / DHA Olefins Standard
Use alcohol resistant foam, carbon dioxide, or dry chemical extinguishing
agents. Water spray or fog may also be effective for extinguishing if
swept across the base of the fire. Water can also be used to absorb heat
and keep exposed material from being damaged by fire.
Vapors may be ignited by heat, sparks, flames or other sources of
ignition at or above the low flash point giving rise to a Class B fire.
Vapors are heavier than air and may travel to a source of ignition and
flash back
Page 2 of 7
Fire Fighting Methods and Protection:
Hazardous Combustion Products:
Do not enter fire area without proper protection including self-contained
toxic breathing apparatus and full protective equipment. Fight fire from a
safe distance and a protected location due to the potential of hazardous
vapors and decomposition products. Flammable component(s) of this
material may be lighter than water and burn while floating on the surface.
Use water spray/fog for cooling.
Carbon dioxide, Carbon monoxide
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions and Equipment:
Methods for Clean-up:
Exposure to the spilled material may be irritating or harmful. Follow
personal protective equipment recommendations found in Section 8 of
this SDS. Additional precautions may be necessary based on special
circumstances created by the spill including; the material spilled, the
quantity of the spill, the area in which the spill occurred. Also consider the
expertise of employees in the area responding to the spill.
Prevent the spread of any spill to minimize harm to human health and the
environment if safe to do so. Wear complete and proper personal
protective equipment following the recommendation of Section 8 at a
minimum. Dike with suitable absorbent material like granulated clay.
Gather and store in a sealed container pending a waste disposal
evaluation.
7. HANDLING AND STORAGE
Handling Technical Measures and Precautions:
Storage Technical Measures and Conditions:
Harmful or irritating material. Avoid contacting and avoid
breathing the material. Use only in a well ventilated area. Use
spark-proof tools and explosion-proof equipment
Store in a cool dry ventilated location. Isolate from
incompatible materials and conditions. Keep container(s)
closed. Keep away from sources of ignition
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
United States:
Chemical Name
1-octene
1-hexene
1-pentene
1-nonene
1-heptene
cis-4-nonene
trans-3-Heptene
isoprene
trans-2-octene
2-methyl-2-pentene
cis-2-heptene
2-methyl-1-nonene
4-Methyl-1-pentene
cis-3-nonene
cis-2-hexene
trans-2-pentene
trans-3-nonene
cis-2-octene
trans-2-nonene
1-decene
2-methyl-1-butene
trans-2-hexene
3-methyl-1-butene
cis-2-pentene
cis-3-heptene
trans-2-Heptene
CAS No.
IDLH
111-66-0
592-41-6
109-67-1
124-11-8
592-76-7
10405-84-2
14686-14-7
78-79-5
13389-42-9
625-27-4
6443-92-1
2980-71-4
691-37-2
20237-46-1
7688-21-3
646-04-8
20063-92-7
7642-04-8
6434-78-2
872-05-9
563-46-2
4050-45-7
563-45-1
627-20-3
7642-10-6
14686-13-6
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Personal Protection:
Engineering Measures:
Respiratory Protection:
30727 / DHA Olefins Standard
ACGIH STEL
ACGIH TLV-TWA
No TLV
50 ppm TWA
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
No TLV
OSHA Exposure
Limit
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
No data available.
Local exhaust ventilation is recommended when generating excessive levels of
vapors from handling or thermal processing.
Respiratory protection may be required to avoid overexposure when handling this
product. General or local exhaust ventilation is the preferred means of protection.
Page 3 of 7
Use a respirator if general room ventilation is not available or sufficient to
eliminate symptoms.
Wear chemically resistant safety glasses with side shields when handling this
product. Do not wear contact lenses.
Wear protective gloves. Inspect gloves for chemical break-through and replace at
regular intervals. Clean protective equipment regularly. Wash hands and other
exposed areas with mild soap and water before eating, drinking, and when
leaving work
Eye Protection:
Skin Protection:
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance, color:
Odor:
Physical State:
pH:
Vapor Pressure:
Boiling Point:
Flash Point:
Flammability:
Upper Flammable/Explosive Limit, % in air:
Lower Flammable/Explosive Limit, % in air:
Autoignition Temperature:
Decomposition Temperature:
Evaporation Rate:
Odor Threshold:
Solubility:
Partition Coefficient: n-octanol in water:
VOC % by weight:
Molecular Weight:
No data available.
None
No data available.
No data available.
No data available.
No data available.
-63
Extremely Flammable
No data available.
No data available.
No data available. deg C
No data available.
No data available.
No data available.
Not determined
No data available.
0
No data available.
10. STABILITY AND REACTIVITY
Stability:
Conditions to Avoid:
Materials to Avoid / Chemical Incompatiability:
Hazardous Decomposition Products:
Stable under normal conditions.
No data available.
Strong oxidizing agents
No data available.
11. TOXICOLOGICAL INFORMATION
Routes of Entry:
Inhalation, Skin Contact, Eye Contact, Ingestion
Target Organs Potentially Affected By Exposure: No data available.
Chemical Interactions That Change Toxicity:
None Known
Immediate (Acute) Health Effects by Route of Exposure:
Inhalation Irritation:
Can cause moderate respiratory irritation, dizziness, weakness, fatigue, nausea
and headache.
Skin Contact:
Can cause moderate skin irritation, defatting, and dermatitis. Not likely to cause
permanent damage.
Eye Contact:
Contact with the eyes may cause moderate to severe eye injury. Eye contact
may result in tearing and reddening, but not likely to permanently injure eye
tissue. Temporary vision impairment (cloudy or blurred vision) is possible.
Ingestion Irritation:
May be harmful if swallowed.
Long-Term (Chronic) Health Effects:
Carcinogenicity:
Reproductive and Developmental Toxicity:
Inhalation:
Skin Contact:
Component Toxicological Data:
NIOSH:
Chemical Name
1-Octene
30727 / DHA Olefins Standard
CAS No.
111-66-0
Contains a probable or known human carcinogen.
No data available to indicate product or any components
present at greater than 0.1% may cause birth defects.
Upon prolonged and/or repeated exposure, can cause
moderate respiratory irritation, dizziness, weakness, fatigue,
nausea and headache.
Upon prolonged or repeated contact, can cause
moderate skin irritation, defatting, and dermatitis. Not
likely to cause permanent damage.
LD50/LC50
Dermal LD50 Rabbit >10 g/kg (no deaths
occurred); Inhalation LC50 Rat 8050 ppm 4 h;
Page 4 of 7
1-Hexene
Isoprene
2-Pentene, 2-methyl-
Component Carcinogenic Data:
OSHA:
Chemical Name
Isoprene
592-41-6
78-79-5
625-27-4
CAS No.
78-79-5
ACGIH:
Chemical Name
No data available.
CAS No.
NIOSH:
Chemical Name
No data available.
CAS No.
NTP:
Chemical Name
No data available.
CAS No.
IARC:
Chemical Name
No data.
No data.
Isoprene
Oral LD50 Rat >5000 mg/kg
Dermal LD50 Rabbit >2000 mg/kg
Dermal LD50 Rat >1 mL/kg
Inhalation LC50 Rat 114 g/m3 4 h (Source:
IUCLID)
Present
CAS No.
Group No.
Group 1
Group 2A
Group 2B
78-79-5
12. ECOLOGICAL INFORMATION
Overview:
Mobility:
Persistence:
Bioaccumulation:
Degradability:
Ecological Toxicity Data:
This material is not expected to be harmful to the ecology.
No data
No data
No data
No data
No data available.
13. DISPOSAL CONSIDERATIONS
Waste Description of Spent Product:
Disposal Methods:
Waste Disposal of Packaging:
Spent or discarded material is a hazardous waste.
Dispose of by incineration following Federal, State, Local,
or Provincial regulations.
Comply with all Local, State, Federal, and Provincial
Environmental Regulations.
14. TRANSPORTATION INFORMATION
United States:
DOT Proper Shipping Name:
UN Number:
Hazard Class:
Packing Group:
Flammable liquids, n.o.s. (Isoprene, 1-hexene)
UN1993
3
II
International:
IATA Proper Shipping Name:
UN Number:
Hazard Class:
Packing Group:
Flammable liquids, n.o.s. (Isoprene, 1-hexene)
UN1993
3
II
Marine Pollutant: No
Chemical Name
CAS#
Marine Pollutant
Severe Marine
Pollutant
No data available.
15. REGULATORY INFORMATION
30727 / DHA Olefins Standard
Page 5 of 7
United States:
Chemical Name
1-octene
1-hexene
1-pentene
1-nonene
1-heptene
cis-4-nonene
trans-3-Heptene
isoprene
trans-2-octene
2-methyl-2-pentene
cis-2-heptene
2-methyl-1-nonene
4-Methyl-1-pentene
cis-3-nonene
cis-2-hexene
trans-2-pentene
trans-3-nonene
cis-2-octene
trans-2-nonene
1-decene
2-methyl-1-butene
trans-2-hexene
3-methyl-1-butene
cis-2-pentene
cis-3-heptene
trans-2-Heptene
CAS#
CERCLA
SARA 313
111-66-0
592-41-6
109-67-1
124-11-8
592-76-7
10405-84-2
14686-14-7
78-79-5
13389-42-9
625-27-4
6443-92-1
2980-71-4
691-37-2
20237-46-1
7688-21-3
646-04-8
20063-92-7
7642-04-8
6434-78-2
872-05-9
563-46-2
4050-45-7
563-45-1
627-20-3
7642-10-6
14686-13-6
X
-
X
-
The following chemicals are listed on CA Prop 65:
Chemical Name
CAS #
Isoprene
78-79-5
State Right To Know Listing:
Chemical Name
CAS#
1-octene
111-66-0
1-hexene
592-41-6
1-pentene
109-67-1
1-nonene
124-11-8
1-heptene
592-76-7
cis-4-nonene
10405-84-2
trans-3-Heptene
14686-14-7
isoprene
78-79-5
trans-2-octene
13389-42-9
2-methyl-2-pentene
625-27-4
cis-2-heptene
6443-92-1
2-methyl-1-nonene
2980-71-4
4-Methyl-1-pentene
691-37-2
cis-3-nonene
20237-46-1
cis-2-hexene
7688-21-3
trans-2-pentene
646-04-8
trans-3-nonene
20063-92-7
cis-2-octene
7642-04-8
trans-2-nonene
6434-78-2
1-decene
872-05-9
2-methyl-1-butene
563-46-2
trans-2-hexene
4050-45-7
3-methyl-1-butene
563-45-1
cis-2-pentene
627-20-3
cis-3-heptene
7642-10-6
trans-2-Heptene
14686-13-6
New Jersey
X
X
X
X
X
X
X
-
SARA EHS
313
-
TSCA
Pennsylvania
X
X
X
X
X
X
X
X
X
X
X
X
California
X
-
Regulation
Prop 65 Cancer
Massachusetts
X
X
X
X
X
X
X
X
X
X
X
X
16. OTHER INFORMATION
30727 / DHA Olefins Standard
X
X
X
X
X
X
X
X
X
X
X
X
-
Page 6 of 7
Prior Version Date:
Other Information:
References:
Disclaimer:
04/24/14
Any changes to the SDS compared to previous versions are marked by a vertical
line in front of the concerned paragraph.
No data available.
Restek Corporation provides the descriptions, data and information contained
herein in good faith but makes no representation as to its comprehensiveness or
accuracy. It is provided for your guidance only. Because many factors may affect
processing or application/use, Restek Corporation recommends you perform an
assessment to determine the suitability of a product for your particular purpose
prior to use. No warranties of any kind, either expressed or implied, including
fitness for a particular purpose, are made regarding prodcuts described, data or
information set forth. In no case shall the descriptions, information, or data provided
be considered a part of our terms and conditions of sale. Further, the descriptions,
data and information furnished hereunder are given gratis. No obligation or liability
for the description, data and information given are assumed. All such being given
and accepted at your risk.
30727 / DHA Olefins Standard
Page 7 of 7