J^[M[_pcWdd ?dij_jkj[0 6EdlZg]djhZ d[:cZg\nGZhZVgX] The Weizmann Institute: A Powerhouse of Energy Research Table of contents A Powerhouse of Innovative Energy Research ............................................ 6 Why Weizmann?.......................................................................................... 10 Biofuels: New Power from Plants.................................................................. 22 Clean Fuel Synthesis..................................................................................... 36 The Promise of Super-Hot Plasmas................................................................ 42 A Safer, More Plentiful Nuclear Energy Source............................................... 44 Teaching Tomorrow’s Energy Scientists and the Public................................... 46 What the Future Holds................................................................................. 48 Milestones in Weizmann Alternative Energy Research.................................... 52 Thanks to our Friends who Support Energy Research in Israel........................ 55 5 6 The innovative program of energy research AERI serves as the framework for accelerating, at the Weizmann Institute is based on the coordinating, and sharing alternative energy conviction that only basic science can provide research at the Institute. the radical, paradigm-shifting changes needed A Powerhouse of Innovative Energy Research to make a major difference in the world’s It should be noted that many of the groups energy outlook in this century. Alternative conducting alternative energy research at energy research received a major boost in Weizmann have received grants from the 2006 with a pledge and a challenge from Mr. European Research Council, the European Yossie Hollander, an Israeli business leader and equivalent of the McArthur Foundation grants in alternative energy advocate. The result was the the U.S., which are dubbed the ‘genius grants.’ Alternative and sustainable Energy Research ERC grants are substantial and are given over Initiative (AERI), followed by the Mary and Tom the course of five years, enabling recipients Weizmann Institute scientists are responding particularly in solar technologies. Israel leads the Beck-Canadian Center for Alternative Energy to conduct innovative research at the highest to one of the world’s greatest challenges: the world in the per-capita use of solar power and Research, established in 2007, to create an levels. Weizmann scientists in the alternative need to create clean, affordable, sustainable has ambitious plans for a clean-tech economy endowment for AERI and thus for future energy energy area who have received ERC grants energy that will enable food production, provide founded on scientific and technical innovation. research at the Weizmann Institute. Other include Dr. Asaph Aharoni, Prof. Naama Barkai, clean water, foster economic growth, address The Weizmann Institute stands out among the donors with a shared vision for expanding Prof. Avraham Levy, Prof. Leeor Kronik, Dr. Ron global climate change, close the gaps between world’s centers of scientific discovery because research in clean and sustainable energy Milo, Prof. David Milstein, and Dr. Asaf Vardi. rich and poor, and reduce political instability. of its dedication to pure science, its robust have contributed generously to these funds. It is an increasingly urgent need, given the interdisciplinary culture, and its heritage as a burgeoning global population and the world’s national center for innovation and technological dependence on oil and gas. The physical spinoffs. Its founder and the first President of security of Israel and the energy security of the State of Israel, Dr. Chaim Weizmann, was the world depend on the development of new a biotech entrepreneur and organic chemist sources of economical and renewable energy. with more than 40 patents, including a process for making acetone from fermentation. The Weizmann Institute and Israel are poised to make a critical difference in sustainable energy This booklet highlights some of the research. Israel, with few natural resources but Weizmann Institute’s major milestones in an abundance of sunshine and brainpower, is an energy research, current groundbreaking innovative powerhouse in energy research, and investigations, and plans for the future. 7 8 Canadian Connections at the Weizmann Institute A group of generous Canadian donors have To that end, in 1982, Weizmann Canada held fostered energy research at the Weizmann fundraising dinners in Montreal and in Toronto. Institute of Science from well before the A dinner was also held in Vancouver in honor Canadian solar tower on campus. The fifth of Morris Wosk in 1984, which established president of the Institute, Prof. Israel Dostrovsky, one wing of the Center. Another wing was dreamed of creating an ultramodern solar established by the Toronto families of Wilfred energy research facility. His vision inspired both Posluns and James Kay. The two research the President of the Canadian Society for the buildings are named after Jacob Hendeles Weizmann Institute of Science, James Kay, and and Leo Perkell of Toronto. A plaza in front of its Executive Vice President, the late James the building was created for Helen and Sam Senor, to establish the Canadian Institute for Steinberg of Montreal. Jake Hendeles was the Energies and Applied Research (CIEAR), a involved with every stage of planning and facility for basic and applied energy research. co-chaired with Morris Kerzner, the Energy Sub-committee of the Canadian Society, which oversaw the construction and financing. In 1986 Tom Beck took over as President of the Canadian Society and undertook to raise the funds to complete the project. The full list of supporters appears at the end of this booklet. The solar tower and laboratories of the Canadian Institute for the Energies and Applied Research were completed in 1987, one of the most advanced facilities for research in concentrated solar energy ever built on an academic campus. The solar tower research facility on Weizmann Institute campus 9 10 Why Weizmann? The Weizmann Institute of Science focuses on can be captured by solar (photovoltaic) cells. the basic scientific challenges of energy research. There have been a number of “firsts” from The synergy of its interdisciplinary approach Weizmann research already, such as the first rallies the strengths of physics, chemistry, biology solar “batteries” that can both convert solar and mathematics, including also environmental, into electrical energy and store it as such, plant, materials and computer sciences, and solar-pumped lasers that can be tuned to drive other perspectives to the challenge of producing specific chemical reactions, and new types of clean, dependable, and affordable energy for the nano solar cells. Solar cell researchers are now future. In a field that is often distracted by short- being joined by optical science experts to find term solutions and quick fixes, the Weizmann new ways to manipulate sunlight for more Institute’s focus is on long-term solutions, efficient solar to electrical energy conversion. which requires the patience of basic research. Direct conversion of sunlight into chemical The Institute’s strategy for producing electricity energy is the realm of photosynthesis. Weizmann from sunlight is to begin with analyzing how scientists are searching plant genomes for species light particles, photons, transfer their energy and traits with potential for biofuels—fuels whose to atoms and molecules; how electrons and source is derived from plants and algae. They ions, move within and between materials; and are looking at ways to modify the metabolism how to increase the part of the sunlight that of plants to increase the plant’s production of the building blocks for biofuels. Our scientists The Weizmann Institute’s long experience with are also investigating new ways to break down concentrated solar energy is focused on finding common crop wastes, such as cellulose, into basic ways to convert solar energy into chemical energy sugars that are useable for fuel. One approach by high temperature chemistry, so as to provide has been to combine the cellulose-degrading storable clean fuels. For instance, they have elements from bacteria, fungi, and algae into pioneered solar-driven chemistry to refine zinc bioengineered artificial “organelles”, microscopic from zinc oxide, which is usable for fuel cells. biological factories. In addition, a major research They have demonstrated solar thermal splitting effort is well underway at Weizmann focusing of methane and solar reforming of hydrocarbons on identifying new algae-based biofuels. for synthetic fuels. Another promising approach has been to use a solar-heated “melt” of The lessons learned in our scientists’ research on salts to convert carbon dioxide into carbon photosynthesis and solar cells will contribute to monoxide (easily turned into fuel) and oxygen. a major, long-term goal of our alternative energy research program, which is to advance the As plants do not use concentrated sunlight, understanding of, and the likely road blocks and research is also underway to convert non- show stoppers for “artificial photosynthesis”— concentrated sunlight to electrical energy. i.e., finding ways to mimic photosynthesis by A Weizmann group has developed a novel efficiently converting sunlight into usable fuel—in clean catalyst that uses sunlight to speed the a way that will not compete with food production. hydrolysis of water into hydrogen and oxygen. 11 12 The road ahead enhance the available yearly funding for The biggest research challenge is finding ways alternative sustainable energy research to overcome the loss of energy during the at the Weizmann Institute, and builds on Racing Toward New Energy Options energy-conversion process. Today’s promising a strong framework of research projects alternative energy options all rely on the that have garnered important insights. Thanks to a landmark gift from the Helmsley Charitable Trust, the Weizmann Institute and the Technion join hands in a major initiative to advance alternative energy research The Leona M. and Harry B. Helmsley Charitable focuses primarily on basic research with minor Trust announced a gift of $15 million over three technological components, while the Technion years to fund joint research in solar energy and emphasizes engineering technologies using biofuels between the Weizmann Institute of basic research-derived insights. Combining the Science and the Technion – Israel Institute of best talent in Israel working in these areas will Technology. The research projects combine the significantly accelerate solar energy research. institutions’ outstanding brainpower and research capabilities in three key areas: biofuels research, The partnership builds on Israeli Center of solar cells, and optics to improve solar light Research Excellence (ICORE) in alternative energy, harvesting. All these areas show great promise for in which the Weizmann Institute participates dramatically advancing alternative energy options. with the Technion and Ben-Gurion University. The ICORE program is designed to concentrate Israeli T h e We i z m a n n a n d Te c h n i o n s o l a r government research funding in areas where energy conversion programs are strongly it can be most effective, and also encourage complementary: The Weizmann Institute top Israeli scientists to return from abroad. quantum conversion of sunlight. They are: biofuels—the use of biological resources such One of the major advantages of the Helmlsey as wheat straw and algae to create clean- grant is that it will enable scientists to work burning fuels; photovoltaics—the conversion on all three areas—biofuels solar cells, and of sunlight into electricity; and optics, to optics—in parallel, which is highly important more effectively absorb and better utilize because the best solutions may involve sunlight. The hope and expectation is that combinations of all of them, explains Prof. insights from these areas will coalesce to pave David Cahen of the Department of Materials the way towards artificial photosynthesis, and Interfaces and director of AERI, who will mimicking the process of energy conversion direct the Weizmann projects. Prof. Cahen has method of plants to generate synthetic fuels. worked closely with his Technion counterpart, Prof. Gideon Grader, head of the Grand- The single-largest conversion loss in solar Technion Energy Program, and he and other conversion to biofuel, to electricity, or Weizmann scientists have joint research and to synthetic fuels is in fact that only part publications with several Technion scientists. of all the sunlight is absorbed during the energy conversion process and only part of By the third year of the Helmlsey-backed project that absorbed light is actually converted to there will be a fully operational, state-of-the-art electrical or chemical energy. Thus, in this new core facility for biofuels research based at the partnership Weizmann and Technion scientists Weizmann Institute. This facility will include will include basic research in optics to find automated cell handling, genetic manipulation, suitable, smart, and innovative light manipulation and biochemical analysis equipment needed for to overcome or bypass some of these losses. the scientists involved in biofuel research from the departments of Plant Sciences, Biological The Helmsley advantage Chemistry, Molecular Genetics, and other The Helmsley energy program will significantly disciplines. The equipment will be available . 13 14 for continuing work within the AERI and ICORE Current Research in Direct Sunlight directly to electricity (photovoltaic cells) biofuel programs and help make Weizmann Solar Energy Conversion 3. Sunlight to fuel, which includes the Institute scientists more competitive for all Sunlight is by far the most abundant carbon- conversion of solar energy using a chemical future biofuel-related grants. neutral energy resource. More solar energy process and efforts to store solar energy strikes the land surface of the earth in three In the previous sections the construction of the hours (or, about 24 hrs, if we limit ourselves to solar tower and its commercial spinoffs served the inhabitable parts) than is obtained from all to highlight some of the major developments of the fossil fuels consumed globally in a year. in the sunlight-to-concentrated-thermal But, for solar to become a major provider of energy strategy, which in different ways, the world’s energy needs it must offer cost- advances the work of Profs. Jacob Karni of effective solutions for power production, fuel the Department of Environmental Sciences and alternatives, long-term storage, and convenient Igor Lubomirsky of the Department of Materials transportation options. Therefore, Weizmann and Interfaces. In the following section, we Commercialization of Weizmann Solar Technologies Three commercial efforts using solar- scientists are pursuing three main strategies powered gas turbines that are based on for converting sunlight to usable energy: will describe the other major approach to concentrated solar power designs proven at 1. Sunlight-to-thermal energy for heat and direct conversion of sunlight, by way of the the Weizmann Institute are in various stages power production photovoltaic effect, which is basis of solar cells. of implementation, and a fourth is pending: 2 . • A 75 kW demonstration plant was completed in Nanjing, China, in 2005 in a project that involved cooperation between Chinese and Israeli industries and Hohai University of Nanjing • A new project to commercialize this technology has been launched in southern Israel near Eilat, beginning with a 100kW plant built at Kibbutz Samar (see photo) • A 170 kW thermal energy plant is being tested in Almeira, Spain, for water desalinization and power production • A program to commercialize an advanced version of this system is in an early stage of development in the U.S. Built by Aora Solar, a 30m-high tower stands in a field of mirrors on 0.5 acre (2,000 sq.m.) of land at Kibbutz Samar near Eilat. It can generate 100kW of electric power in addition to 170kW of thermal power per hour. Solar Cells Beginning with the basics Charge separation induced by light is critical for solar energy conversion. Our research focuses on trying to understand the limits of photovoltaic cells and using that understanding to improve their ability to absorb sunlight and its transfer into usable energy. Electron Transfer (ET) reactions are among the most fundamental processes in chemistry and biology. In biology, ET is crucial for various energy conversion processes, from respiration to photosynthesis. It is clear to Weizmann scientists that understanding both of these basic processes are critical to developing future generations of solar cells. 15 16 The extremely thin absorber (ETA) solar cell Prof. David Cahen formulated criteria, based them to experiment with new generations They recently discovered (and are currently on solar cell and module performance data, of self-assembled layers. Such layers provide developing) a new type of conducting polymer, that serve to evaluate and compare all types a general approach to new materials, based conducting polyselenophenes; and a new of today’s solar cells. With his colleagues, he on the pioneering work of Weizmann’s Prof. type of a shorter molecule, an oligomer, assessed the data to gauge how much significant Jacob Sagiv in the early 1980s, to create called alpha oligofuran, both of which Today’s crystalline silicon cells, the most progress can be expected for the various cell light-harvesting materials and solar cells. show promise for solar cell applications. The common type of solar cells, require large oligofuran molecule is directly obtainable energy input for their manufacturing process, types and, most importantly, from both the science and technology points of view, if there Dr. Rybtchinski and his team design nanodevices from biomass, and could be used for organic which results in an energy payback time of are upper boundaries that could limit progress to self-assemble in water. The unique chemistry semiconductors and other “green electronics”. several years. Basic studies at the Weizmann in each of these basic solar cell types. Defining of water (the basis of all life) provides the tools such limits places into a clearer framework the to direct the assembly process. In this wet enormous efforts of today’s research on solar environment, the team is developing adaptable cells, including those at the Weizmann, and systems that can change their function in helps focus efforts on ways to overcome them, in response to an external stimulus. Most biological order to pave the way for the creation of cheap, molecules are either repelled or attracted to sustainable, and practical energy conversion. water molecules, and this property determines their position in living cells and tissues. Prof. Rybtchinski uses sophisticated molecular New materials and new concepts methods to exploit the hydrophobic—that is, Weizmann scientists have copied a key concept into solar-energy-converting units. Like many from nature in creating new combinations of biological molecules, such systems could be materials that “self-assemble” in solution. These multi-functional, capable of rearranging their versatile structures can be used for complex structure through simple chemical reactions. “water-hating”—properties of certain organic molecules, manipulating them to self-assemble functions such as light harvesting and control of surface properties (smart materials). Thus, Prof. Bendikov and his group design, synthesize, the research of organic chemists Profs. Michael and develop novel types of organic electronic Bendikov and Boris Rybtchinski complements materials. Their work significantly expands the that of Profs. Gary Hodes and David Cahen in the variety of materials available for application Department of Materials and Interfaces, enabling in organic solar cells, organic field effect transistors, and organic light-emitting diodes. Prof. David Cahen 17 18 Institute during the latter half of the 1990s that the problems with copper actually made removed a major psychological obstacle for CIGS cells more stable than any of the other the (now commercialized) thin film solar cells solar cell materials. Their experimental work based on the materials copper indium selenide was borne out also by experiments in the and copper indium gallium selenide (CIGS). harsh environment of space (by the European The complexity of cells made up of three or Space Agency). They showed that the reason four elements, and the fact that one of the is elementary: Most of the damage that can elements (copper) is very mobile within the occur in the material is indeed related to the material (an anathema in normal electronics), fact that the copper can move, but it can and was thought to make CIGS solar cells less does also move back! Thus, the chemistry of the stable than others. Prof. Cahen, working with material dictates it to be self-healing–that is, it Prof. Kronik and European colleagues, showed repairs itself. They showed how this property makes CIGS solar cells remarkably stable ones. The big brother of CIGS cells in the so-called it. In addition Prof. Hodes developed an alternative 2nd generation of solar cells uses the material stable contact, which further solved the problem. cadmium tellurium. For decades it was plagued FS cells became commercial soon after NREL by a real instability problem. Towards the end scientists confirmed the Weizmann results. of the 1990s the U.S. Department of Energy’s National Renewable Energy Lab (NREL) turned The trick in a good solar cell is to get the to two Weizmann scientists, Profs. Cahen and negatively charged electrons that have been Hodes, to take a new look at the problem as part freed by light absorption from the atoms, of its effort to help First Solar (FS), an American to flow out of the cell (and through the company, commercialize these cells. Within a external circuit, to do the electrical work, few years, the Weizmann experts showed that before flowing back into the cell) before they the cause of the instability was embarrassingly return to the now positively charged atoms. In simple—essentially uncontrolled exposure to the very thin (less than tens of nanometers), oxygen and water—and found ways to overcome active light absorber in an ETA cell this direct recombination of photogenerated electrons and the positively charged “holes” left in the absorber should compete much less with charge removal than in the thicker absorber materials used in today’s cells. As a result, the researchers expect that poorer quality (and less expensive) materials can be used in an ETA cell, which would expand the choice of semiconductors over those currently in use. Prof. Gary Hodes, a world expert in ETA cells, ultrathin films, and in nano-solar cells in general, works with his colleagues to maximize the efficiency of solar cells while exploring new ways to make them less expensive. They currently explore how to optimize new types of ETA solar cells. Prof. Michael Bendikov 19 20 Organic solar cells Solar cells made with organic materials offer a potentially efficient and low-cost way to convert sunlight to electrical power. Scientists have already demonstrated the proof-of-principle of such devices. However, the difficult processing conditions required and the limited efficiency of current organic solar cells hampers their commercialization. Prof. Milko van der Boom in the Department of Organic Chemistry works on redesigning these experimental organic solar cells using thermally and photochemically robust organic materials that are easily available and processed. In fact, part of the cell would be self-assembling because it would be based on organic molecules that would attach and build themselves into a buffering layer between two components of the experimental organic solar cells. Prof. van der Boom’s novel, bottom-up method enables his group to grow and self- Prof. Milko van der Boom assemble custom-designed molecules, which they then integrate into a very thin film, (about 2 to 40 nanometers thick). Instead of adding precise layers of molecules on a growing film surface, the film itself acts as an active component, serving as a reservoir for metal ions needed for its formation and resulting in exponential growth. Helping solar cells to use sunlight more efficiently Prof. Gary Hodes and other scientists on projects that aim to minimize some of the losses inherent in the basic science of the solar energy conversion process. The most fundamental limits result Solar energy is so attractive that we often from the fact that the light-to-electrical or light- overlook its problems. One of these is that, to-chemical energy conversion is a threshold except for conversion to heat, many promising process and the energy extracted from high- and sophisticated uses of sunlight require its energy photons is limited to the threshold of direct conversion to electrical or chemical energy, the absorber. If the threshold is, say, in the and such conversion is woefully inefficient, red-light part of the solar spectrum, all infrared even for the much more efficient conversion to solar radiation cannot be used, as its energy electricity. The problem is that there are basic is below the threshold. At the same time, scientific limitations. While scientists cannot only the red-energy part of light that is above change the laws of nature, there are ways to the threshold can be used (e.g., only about circumvent the limits dictated by these laws. half of the blue light energy would be used). Dr. Dan Oron (Department of Physics of Complex Systems) and Profs. Gary Hodes and David Cahen are working with theorist Prof. Leeor Kronik (Materials and Interfaces), Concentrating sunlight Weizmann scientists are exploring redesigning a solar cell in new ways to maximize their use of the incoming light. Possibilities include designing Prof. Leeor Kronik cells with three different types of absorbers, each using a different part of the spectrum; or using a mirror or prism to split the incoming light and redirect it to absorbers for different wavelengths. A third possibility is “stacking” three nanoscale layers of extremely thin absorbers on a single cell. There are costs and tradeoffs to be weighed and new materials to be explored. There are several other ways to concentrate sunlight that involve even more elegant physics. Prof. Nir Davidson and Dr. Dan Oron, both 21 22 How do QDs work? energetics of different sizes of QDs deposited “up-conversion.” However, for up-conversion to Understanding how QD-sensitized solar cells experimental findings showed them how the photons reaching solar cells to make use of be efficient, it requires presently a tremendously operate requires, among other challenges, size of the QD affects its electrical properties available sunlight more efficiently. Together, they large optical flux, typically thousands to a accurate determination of the relative (size matters more than expected) and how the will explore methods for light concentration. million times higher than that of direct sunlight. energies of the highest energy electrons (the strength of the QD-electrode interaction allows a “energetics”) in the various components of the highly efficient QD to electrode charge transfer. from the Department of Physics of Complex energy photons (i.e., quanta of light) to a single Systems, are working with Prof. Yehiam Prior, photon with a higher energy, a process called Dean of the Faculty of Chemistry, to “manage” On the macro scale, they are experimenting with the geometry of lenses and diffraction There has been progress worldwide in quantum- cell, the quantum dots and the electrodes. The screens and reflectors to concentrate the dot sensitized solar cells in the last few years, with researchers and Prof. Ron Naaman (Department incoming light. On the nanoscale, they are reported solar-to-electrical energy conversion of Chemical Physics) and their students used developing various nanostructures and ways efficiencies growing rapidly. Dr. Oron and several sophisticated optical and ultra-high of manipulating light to significantly enhance colleagues from Bar-Ilan University recently vacuum spectroscopy methods, to measure the the absorption rate of the target materials. described a new way to create quantum-dot Quantum-dot solar cells A quantum dot is a tiny particle of a semiconductor material, so small that the semiconductor behaves like a large molecule. Its name comes from the fact that it has clearly observable quantum mechanics effects at room temperature (instead of at the very low temperatures, normally required to see such effects in semiconductors). Dr. Oron is leading a project to use quantum dots as the basis for a new generation of light harvesting devices. He has shown that these tiny nanocrystals of semiconducting materials can serve as light absorbers. There have been many attempts to reduce the loss of lowenergy sunlight (the infra-red parts) by using advanced optical methods to “fuse” two low on titanium oxide (TiO2) electrodes. Their (QD) solar cells that could achieve much higher conversion rates. Their new strategy called Förster resonant energy transfer (FRET), involves transfer of energy from the QD to a molecule and transfer of electrons from the molecules. In this design, QDs serve as “antennas” that funnel the absorbed energy to nearby dye molecules via FRET rather than being used directly as a source of electrons. This opens up a great number of possibilities for possible donor/acceptor pairings. This geometry can potentially reduce in a dramatic manner the required electrode thickness and opens the possibility of use of a solid electrolyte, of the type that Prof. Gary Hodes uses in his ETA cells, and an expected increase in the cell’s voltage. Dr. Dan Oron Prof. Nir Davidson 23 24 Plant biomass can serve as a feedstock to produce energy-rich feedstock. In addition, novel enzyme different types of biofuels: The two leading types complexes are being developed for digesting of biofuel are based on converting sugars to the plant biomass into sugars that can be used alcohol, mostly ethanol; and converting oils (fatty by improved yeast strains for fermentation acids) into biodiesel. Photosynthetic organisms and alcohol production. Twelve teams of can also serve as bioreactors to produce hydrogen, Weizmann Institute scientists are working a third possibility for clean fuel from plants. together on a number of basic science projects related to enhancing biofuels production in a Biofuels: New Power from Plants Not all our energy needs can be supplied Plants are the central players in the interaction by electrical energy and we urgently need between humanity and the biosphere. Over 80 renewable chemical energy sources, especially percent of the land and water used by humanity liquid fuels for transportation, that can be is dedicated to growing plants for food, fuel, produced in a sustainable manner. In a world and building material. Therefore, one of the key economy sensitive to fossil fuel prices, biofuels questions being asked by scientists is whether offer a sustainable option that would require large amounts of biofuel can be produced minimal changes in existing transportation without compromising the global capacity for technology, infrastructure, and distribution food production. Weizmann scientists think it’s networks. However, at the genetic level, existing possible. One of their solutions is to use algae crops are not optimal for large-scale biofuel that can grow in the desert and other marginal production. Domestication and breeding lands, or in brackish or salty water not suitable has focused on developing plants mostly for conventional agricultural. Another option for food production. Weizmann scientists they propose is to use plant biomass from are pursuing a range of strategies to make agriculture and urban wastes. There is plenty different varieties of plants a better source of of such biomass to use, and this way arable energy without compromising food production. land is not lost in the effort to produce biofuel. Research at the Weizmann Institute is aimed consortium coordinated by Prof. Avraham Levy, at understanding how plants and algae can Head of the Department of Plant Sciences. serve to provide biofuels and then to search for responsible ways to engineer them with improved metabolic pathways that would enable them to generate larger amounts of Prof. Avraham Levy 25 26 Built on the grounds of one of Israel’s first the salt-tolerant Dunaliella algae as a source agricultural research stations, the Weizmann of nutrients such as beta carotene, that are Institute of Science has a long history of major players in Israel’s agro-biotech sector. innovations in plant and algal sciences. For oil production for use in airplanes. Weizmann Speeding up the carbon cycle scientists have developed a unique know-how Dr. Ron Milo (Department of Plant Sciences) in making more efficient food sources and studies the fundamental processes that govern exploiting natural biodiversity to improve the carbon cycle on earth, including the major crops such as wheat. Weizmann Institute role of photosynthetic organisms. “Carbon insights in plant biology have led to commercial fixation,” i.e., taking carbon dioxide up from spinoffs such as the commercial production of the atmosphere, stripping it of its oxygens and Institute’s founder, Prof. Chaim Weizmann, for and specificity of Rubisco, the key enzyme storing energy and accumulating biomass in operating in the Calvin–Benson cycle however the living world. The rate of carbon fixation they have achieved only limited success. can significantly limit growth of photosynthetic instance, the first crop its scientists investigated was castor beans, upon the request of the making it into sugars, is the main pathway for Dr. Ron Milo organisms. Hence increasing the rate of carbon Based on a survey of 5,000 naturally occurring fixation is of major importance in the quest enzymes and the mechanics of the six carbon for agricultural and food security as well as for fixation pathways found in nature, Dr. Milo biofuel production. Carbon dioxide emissions are reported that there were some promising suspected to be the main cause of global warming, carbon-fixing pathways that could be up to so sequestration of carbon dioxide via efficient two or three times faster than the conventional carbon fixation can alleviate the greenhouse Rubisco path. He developed algorithms that effect and contribute to sustainable life on earth. compared all possible metabolic pathways based on kinetics, energetics, and topology. His initial Photosynthetic organisms use sunlight to findings point to a new family of synthetic carbon drive carbon fixation through a complex fixation pathways that utilize the most effective series of enzymatic steps that reduce carbon carbon-fixing enzyme, PEP carboxylase. It works dioxide into sugars and then convert them as part of the so-called “C4” carbon-fixing cycle into metabolic building blocks. The Calvin– used by plants such as corn and sugarcane Benson cycle is the most prevalent carbon to assimilate atmospheric CO2 into biomass. fixation pathway in plants. However, nature He is now testing these alternative carbon employs several alternative carbon fixing fixation cycles in microorganisms that depend pathways. Dr. Milo is asking whether more on carbon fixation as their sole carbon input. efficient novel synthetic cycles could be devised. In agriculture in which water, light, and nutrients are abundant, carbon fixation could become a significant growth-limiting factor. Hence, increasing the fixation rate is of major importance in the road toward sustainability in food and energy production. There have been recent attempts to improve the rate 27 28 Unlocking the potential of… from producing primary metabolites, plants also Plant metabolomics are known to date. Therefore, a thorough, in- Biofuels research requires the separation, depth understanding of metabolic pathways is detection, identification, and quantification a pre-requisite to engineer and optimize plants of numerous small molecules produced by and microorganisms for biofuel production. In the plant: monomers, oligomers, polymers, the Department of Plant Sciences, Prof. Asaph complex carbohydrates, fatty acids, and Aharoni and Prof. Gad Galili are focusing on lipids. This “metabolomics analysis” requires direct analysis of plant metabolism using the plant sophisticated gas and liquid chromatography metabolomics methods they have pioneered. synthesize a vast range of secondary (or specialized) metabolites; more than 200,000 such structures and specialized mass spectrometers. This Prof. Yuval Eshed work provides the data for the dissection of They have used metabolic engineering approaches complex biosynthesis pathways that make to increase specific nutrition-associated and the molecules used in the different types health-associated secondary metabolites. For the genes that regulate lysine synthesis and and soft, and a mature plant whose stalks of fuels, mostly lipids or carbohydrates. example, Prof. Galili found ways to induce learn how to manipulate lysine accumulation and leaves are “tough” and high in lignin, a plants to produce up to 1,000 times their usual to produce a product such as high-lysine feed complex chemical compound. Juvenile plants The metabolic network of plants is by far more amounts of the essential amino acid lysine. But corn. Prof. Galili has similar ideas for how to that are low in lignin are easier to digest and extensive than in most other organisms. Apart first, he and his research group had to discover optimize plants for alcohol production through turn into simple sugars, and generally make guiding the conversion of primary metabolism for better-quality biomass for fuel production. into secondary metabolites that can be further Prof. Gad Galili converted into biofuel-efficient alcohols. Prof. Eshed helped show that a microRNA called miR156 is a general regulator of the Plant growth juvenile-to-adult transition, and its effects are In groundbreaking work, Prof. Yuval Eshed universal in plants. He showed that plants in (Department of Plant Sciences) and colleagues which miR156 is over-expressed—i.e., have identified a group of genes controlling plant more miR156—produce larger amounts of a leaf growth. When this group of genes was biomass that is easier to digest. In this way, suppressed, it enabled leaves to grow to extremely both the quality and quantity of biomass can large sizes. Now he is concentrating on another be improved as a feedstock for biofuel. Prof. set of genes that control the transition between Eshed is using the tools of genomics to identify a juvenile plant, whose leaves are “tender” additional genes related to the transition from 29 30 juvenile to adult plant, which will add to the Cellulose Their “first generation” re-engineered Prof. Ed Bayer (Department of Biological cellulosomes used cellulases (enzymes involved Chemistry) pioneered the field of cellulose in breaking down cellulose) from Thermobifida degradation in bacteria and the digestion of Fusca, a common, heat-loving type of soil bacteria The discoveries from Prof. Eshed’s lab can cellulose with microorganisms and enzymes. often found in active compost. Three of the six be applied to a broad range of crops for the Cellulose is the most abundant organic polymer T. fusca cellulases were converted by replacing improvement of both food and fuel production. on Earth. However, most of its potential energy their cellulose-binding modules (CBMs) with as food or a fuel is trapped in hard-to-digest a connecting structure called a dockerin, and Wheat cell walls. Prof. Bayer focuses on cellulosomes, the resultant recombinant “cellulosomized” Wheat straw is an abundant commodity, and its multi-enzyme complexes found in bacteria and enzymes were incorporated into scaffolding production is not at the expense of food. The fungi that can degrade and digest cellulose, proteins together with a CBM. The activities a simple but incredibly resilient polymer. of the resultant “designer” cellulosomes were growing toolkit of ways to manipulate plants to make their output more useful for humans. world production of wheat straw, the inedible stalks that are a byproduct of wheat farming, is Prof. Ed Bayer compared with an equivalent mixture of wild-type about 700 billion tons, with similar amounts of Cellulose is composed solely of the common enzymes, and showed that some of their designs wastes for rice and corn—all cellulosic products sugar glucose that could be used to produce food had marked improvements in performance over the same mix of cellulases acting independently. with minimal food value. It is estimated that collections of wild wheat that grow in Israel. (sugars) and fuel (alcohols and ethanol). Since the conversion of just one billion tons of this They hope to identify the genes that control discovering the cellulosome with a colleague cellulosic biomass could provide 30 percent these traits and to transfer these traits to in 1983, Prof. Bayer has emerged as a world For their next-generation designer cellulosome, of the U.S. needs in liquid fuel. However, its modern wheat strains. In the first year of screening, expert on this potential solution to liberating they added another cellulase and tinkered main challenges as feedstock for biofuel are its the scientists tested the wild emmer wheat the building blocks for food and energy from with the structure, order, and combinations high lignin and silica content that hinder the that is the direct progenitor of domesticated cellulose. His in-depth studies of the structure and of the modules, looking for ways to improve deconstruction of cellulosic biomass into simple wheat, other primitive wheat types, and several functioning of the cellulosomes found in nature efficiency. Their engineered systems out- sugars that can easily be turned into biofuels. modern strains. The team is encouraged by inspired him to start tinkering with its Lego-like performed the mixtures of wild-type enzymes the results, and has so far identified several construction of the different functional modules by working up to 2.9 times faster and Prof. Avraham Levy’s group is working to candidate genes whose expression could possibly that are built on a simple biological scaffold— converting up to 28 percent of the wheat improve the composition of wheat straw for contribute to lower lignin levels in modern wheat. aptly called scaffoldin. He envisioned taking the straw, without any prior treatment of the straw. biofuel. Working with Prof. Aharoni’s plant most efficient components found in nature and metabolomics lab and genomics tools, the The new wheat lines to be developed reassembling them into “designer cellulosomes” The ability to design and produce artificial scientists are conducting a large-scale screen of in the laboratory of Prof. Levy will be that could speed up cellulose degradation cellulosomes of such precise composition wild wheat, looking for types with low -lignin, tested by Prof. Ed Bayer for the enzymatic immensely. He and colleagues have now created provides a superb way to break down a low-silica, and high-wax levels. They are using digestibility of their straw into simple sugars. several proof-of-concept designer cellulosomes. variety of products into simple sugars and the Prof. Naama Barkai 31 32 Yeast defined the growth and ethanol production biofuel production is still in its infancy and Prof. Naama Barkai in the Department of of all their strains when provided glucose, requires extensive research and development. Molecular Genetics is using the tools of galactose, xylose, or xylulose as a carbon computational biology and metabolomics (the source. They found an interesting range Prof. Avihai Danon (Department of Plant the study of the mechanics of metabolism) to of diversity in their test groups, and are Sciences) uses high-throughput genetic screens develop yeast strains that can produce ethanol working to isolate the genes and metabolic to identify algae mutants rich in oil production. or butanol from xylose. An abundant sugar pathways responsible for the differences. Triglycerides are the chief building blocks of that is one of the main components (~30%) precursors to other potential fuels. Dr. Bayer fats and oils, and function to store chemical of plant cell walls, xylose is wasted in most Algae energy in plants and animals. Scientists have fermentation processes because current yeast There are many advantages to algae as a source observed that under certain stress conditions, strains do not feed on it. In collaboration with of energy. Single-celled microalgae grow quickly some micro-algae species accumulate large Prof. Avi Levy, Prof. Barkai is working to identify and in abundance; they can be cultivated in amounts of triglycerides, up to 50 percent genes that increase yeast growth and alcohol areas that are not suitable for agriculture; they of their dry weight, which can easily be production when using xylose as a growth media. can grow in brackish water or seawater; and converted into high-quality biodiesel fuel. is working with Prof. Dan Tawfik (Department their growth and fuel cycle releases no net of Biological Chemistry), a leading expert in Prof. Barkai, a molecular geneticist and a leader greenhouse gas (carbon dioxide). That said, Prof. Danon is trying to identify the network of enzyme evolution and the development and in systems biology, is using yeast genetics, the use of microalgae for commercial scale genes that regulate the synthesis of triglycerides application of directed evolution technologies, genomics, and evolution experiments in yeasts to further develop this promising tool for to find the critical regulatory nodes that could efficient degradation of cellulose into glucose. be “tuned” in order to rewire the metabolic flow. She is concentrating on xylose metabolism As they continue to refine their artificial in the budding yeast to identify the regulatory cellulosomes, Prof. Bayer will be testing the changes that would improve the conversion straw from any promising low-lignin strains of into simple sugars for ethanol production. wheat developed by Profs. Levy and Aharoni, and providing the group of Prof. Barkai with samples Her group is developing new high-throughput of end products resulting from the action of both methods in budding yeast species (S. cerevisiae, designer cellulosomes and native cellulosomes, and in strains of S. paradoxus, its closest relative) since yeasts are the most cost-effective way to quickly measure the growth and ethanol to convert glucoses to alcohols for fuel. production of yeast. Using this system, they Dr. Assaf Vardi 33 34 to enhance triglyceride discovered that many of these viruses can productivity. His team has completely modify the lipid production of their identified several potential algal host and exploit their host as a lipid factory. candidates for enhancing He is working to trace the viral mechanisms triglyceride biosynthesis in for manipulating host lipid production and to the widely grown micro- unravel their molecular mechanics by coupling algae Dunaliella salina. the power of metabolomics and global gene expression profiling during the infection process. Prof. Avihai Danon in micro-algae. This involves a large variety of help optimize algal oil production, but it also function genes: (1) oil molecule producers; (2) oil will provide important basic information on molecule transporters and packaging specialists; the alga’s sensing and regulatory mechanisms. (3) regulators of oil production in response to environmental signals; and (4) coordinators In a related project, Prof. Uri Pick is studying of oil production with other processes, such the regulation of accumulation of triglycerides as photosynthesis. Prof. Danon and his team in green algae to generate strains that produce established an automated, high-throughput, massive amounts of triglycerides that are suitable genome-wide screen of algal genes. In the for commercial production of biodiesel. Prof. process, they have identified several stable Pick’s team has sought to isolate triglyceride- mutants of common algae that can produce overproducing strains of two robust micro- up to three times the lipid content of their algae, Dunaliella salina and a Chlorella species, parent strains. His group is analyzing the genetic which are suitable for commercial cultivation. differences that produced these new variations Prof. Pick also has been working to identify and is working to understand how the genes triglyceride regulatory proteins and genes as control lipid production. Not only will his work potential candidates for genetic manipulation Marine algae The metabolomics expertise of the combined Dr. Assaf Vardi, an expert teams at the Weizmann Institute may help in marine biology, is testing him discover novel virus and algae genes saltwater algae species as that are involved in the regulation of lipid platforms for fatty acids production. He is biosynthesis in the host algae, and find possible fascinated with the immense and sudden ways to use them for biofuel production. blooms of algae, the so-called red tides, that can quickly cover hundreds of square miles of ocean; and the fast-acting viruses that can kill them off almost overnight. He recently Prof. Uri Pick 35 36 Photosynthesis at extreme lessons from cyanobacteria to engineer algae temperatures and plants that can grow at higher temperatures. To ensure that growing crops for energy does not displace the growing of vital food Towards artificial photosynthesis crops, scientists like Prof. Avigdor Scherz are Finally, Weizmann scientists are looking at investigating how photosynthesis can operate the basic process of photosynthesis itself and efficiently at extreme temperatures, which searching for ways to make it more efficient and would make marginal lands and extreme harness it in new ways. Artificial photosynthesis climate areas available for production. is at an embryonic stage, but Weizmann scientists expect it to be a viable and thus extremely Cyanobacteria are among the oldest Dr. Dror Noy important long-term solar energy solution. photosynthetic organisms in nature. They are relatively simple to cultivate, requiring only Dr. Dror Noy and his lab team hope to devise sunlight, water, CO2, and a few nutrients. His processes that mimic natural photosynthesis— group has already isolated a number of traits whereby carbon dioxide and water combine found in thermophilic (heat-loving) cyanobacteria with sunlight to create energy—but will be that enable photosynthetic microorganisms more efficient in producing energy than natural to grow in temperatures of up to 30°C (86°F) photosynthesis, in which most energy is used above their normal range. Prof. Scherz replaced for growth, upkeep, and reproduction. Unlike genes for two proteins in a photobacterium biomass energy, artificial photosynthesis would that grows well at moderate temperatures not require arable land. For instance, it can be Their cooperative action drives remarkably with their counterparts from a thermophilic done on roof tops or in the desert, eliminating the difficult chemical reactions that enable plants cyanobacterium. The genetically engineered concern about competing with the food supply. and algae to use light and water as their primary bacteria grew well at temperatures as hot as Prof. Avigdor Scherz source of energy and electrons. In the process, 43°C, where the control strain would have died Plants and evolutionarily older photosynthetic light is captured very efficiently. Then, the ensuing out under the same conditions. One of his goals organisms such as cyanobacteria are a source biochemical reactions can be adapted for using is to create a cyanobacteria suitable for mass of inspiration for designing artificial devices for hydrogen atoms obtained through water splitting production in arid/semi-arid regions near power solar energy conversion and storage. Natural to produce hydrogen gas (H2) which can be plants (to capture CO2) with high sunlight and photosynthesis features an elaborate system of used directly as a fuel, or which can be used elevated temperatures. He also is applying the enzymes embedded in a specialized membrane. to produce other types of hydrocarbon fuels. 37 38 Clean Fuel Synthesis A good high school chemistry class might include difficult, the “power density” of hydrogen a demonstration of the hydrolysis of water into as a fuel is considerably less than any of the its components of hydrogen and oxygen. If the available fossil fuels. To rival propane, for teacher has a flair for the dramatic, he or she instance, the hydrogen must be pressurized, might have held a match to the end of a test costing more energy and causing a problem tube where the hydrogen gas was collected with safe storage and handling, especially and impressed the students with the sharp in collision-prone automobiles and trucks. “pop” of the mini explosion to demonstrate producing usable fuel on a commercial scale A step towards efficient water splitting from hydrolysis is still a dream for scientists. A unique approach developed by Prof. David the flammability of this potential clean fuel. But, after decades of displaying this simple chemistry with two electrodes and a beaker of water, Milstein and colleagues in the Department of There are two basic problems: the first is that it Organic Chemistry provides an important step takes energy—in the case of the lab experiment, for overcoming this challenge. In 2009, the an electric current to the electrodes—to produce team demonstrated a sequence of reactions to the burnable hydrogen. The second is more liberate hydrogen and oxygen in consecutive thermal- and light-driven steps, mediated by The next stage of the process is the “heat stage.” a unique ingredient—a special metal complex When the water solution is heated to 100˚C, that Prof. Milstein’s team designed in previous hydrogen gas—a potential source for clean studies. Their metal complex of the element fuel—is released from the complex and another ruthenium is a “smart” complex in which the OH group is added to the metal center. But metal center and the organic part attached the most unique part is the third “light stage.” to it cooperate in the cleavage of the water When the third complex was exposed to light molecule. The team found that upon mixing at room temperature, not only was oxygen gas this complex with water, the bonds between produced, but the metal complex also reverted the hydrogen and oxygen atoms break, with back to its original state, which could be recycled one hydrogen atom ending up binding to its for use in further reactions. This overcame organic part, while the remaining hydrogen one of major bottlenecks for splitting water. and oxygen atoms (OH group) bind to its metal center. Their results were published in the journal Additional experiments have indicated that during Science. Prof. Milstein was awarded the Israel the third stage, light provides the energy required Prize in Chemistry in 2012 for his pioneering to cause the two OH groups to get together to work in catalysis and “green” chemistry. form hydrogen peroxide (H2O2), which quickly Prof. David Milstein 39 40 breaks up into oxygen and water. “Because An example is zinc oxide, which reacts with Turning carbon dioxide into clean fuels can be burned directly in turbines or generators, hydrogen peroxide is considered a relatively carbon when heated to temperatures of 1,200- The significant increase in the amount of or converted on-site into liquid fuel. Although unstable molecule, scientists have always 1,300 degrees C. The gaseous zinc is released, carbon dioxide in the atmosphere has spurred it’s toxic in high concentrations, CO has been disregarded this step, deeming it implausible; then condensed and stored; when reacted intensive efforts to use sunlight to turn CO2 into used for over a hundred years as an intermediate but we have shown otherwise,” says Prof. with water, it yields zinc oxide and hydrogen. higher-energy products in order to store solar chemical product; tens of millions of tons are energy as chemical energy for renewable fuels. synthesized each year from coal or wood in one Milstein. Moreover, the team has provided evidence showing that the bond between the Dr. Michael Epstein, director of the Solar Research two oxygen atoms is generated within a single Facility Unit at the Weizmann Institute, compared Prof. Igor Lubomirsky of the Department of molecule—not between oxygen atoms residing thermodynamic analysis and experimental Materials and Interfaces has demonstrated a The CO is generated from CO2 in a relatively on separate molecules, as commonly believed results obtained for different reactants such novel alternative for converting solar energy into straightforward chemical process using a setup —and it comes from a single metal center. as boron, zinc, tin and cadmium looking for fuel. His method is comparatively inexpensive, that’s something like a large, hot battery. the hallmarks of the most efficient processes. produces no environmentally hazardous waste, Inside a special cell, a chemical compound So far, Prof. Milstein’s team has demonstrated a and is very efficient. The new method produces is heated to around 900°C and an electric mechanism for the formation of hydrogen and carbon monoxide (CO)—a non-corrosive gas that current is passed through the compound. oxygen from water, without the need for sacrificial chemical agents, through individual steps, using heat and light. They are now working to combine these stages to create an efficient catalytic system. Solar-driven hydrolysis Solar energy can combine with a metal catalyst to split water. These cycles usually consist of two steps: metal hydrolysis followed by solar reduction or thermal decomposition of the metal oxide. Weizmann scientists have experimented with a number of such catalysts, most notably zinc oxide (ZnO). Concentrated sunlight can be used to extract metals from their oxides, which can then react with water, releasing hydrogen. of the most developed of industrial processes. Prof. Jacob Karni Prof. Igor Lubomirsky 41 42 When CO2 is continuously fed into the cell, when carbon dioxide is catalytically reacted burning as a fuel) and oxygen (photoreduction). the result is pure CO and oxygen. Ideally, the with methane (CH4). The product can be However, like most similar approaches, their CO2 would come from the smokestack of a stored and transported to a user site where catalyst used amines (chemicals that are produced power plant or other carbon dioxide source, so the reaction is reversed, generating enough from ammonia) to help the reaction. Other the greenhouse gases would be removed and heat—about 600°C—to power an engine. The approaches required ultraviolet (UV) light. recycled before they reach the atmosphere. The methane and carbon dioxide regenerated in this Therefore, they set their sights on replacing metal used in the process is titanium, which is stage can be returned to the solar reforming the amines with a more renewable resource, many times cheaper and more available than plant; or, the syngas can be used for fuel and using visible light as the energy source. such precious metals as platinum that are often enrichment since the syngas has about 30 used in similar devices. Other advantages of the percent higher heating value than methane. method include a thermodynamic efficiency First, they were able to demonstrate using water instead of amines. They prepared a of over 85 percent (not counting the energy Prof. Jacob Karni in the Department of new hybrid compound that works with a needed to heat the system), which is almost Environmental Sciences and Energy Research photoactive polyoxometalate. However, this unheard of in the world of energy conversion, recently tested a new solar volumetric reactor new compound required UV light for the and the ease of transporting and burning CO. for reforming of CH4 and CO2 at the solar tower. reaction (called reduction in chemical lingo) The reactor design was based on extensive of CO2 to CO. Finally, Prof. Neumann’s group In a recent study he was able to show, both previous experimental work with a volumetric was able to demonstrate using hydrogen theoretically and experimentally, a range of receiver for heating air, and used a newly and visible light to reduce CO2 to CO and temperatures and concentrations of Li2O developed ruthenium catalyst. His results H2O by using a new hybrid complex that he in the Li2CO3 melt that are in equilibrium indicate that this type of volumetric reactor synthesized. They feel that using renewable with atmospheric CO2 and are therefore can be used effectively for CO2 reforming of hydrogen represents a significant advance capable of absorbing CO 2 from air. CH4, and further work aimed at improving the that may also prove useful in the myriad of total efficiency of the system is in progress. other photo-reduction reactions that presently Synthetic gas from CO2 and methane to carbon monoxide (CO) Recognizing the potential of solar reforming of In 2010, Prof. Ronny Neumann and his group in methane as a means for storing and transporting the Department of Organic Chemistry reported solar energy, scientists have studied it since the first example using light and an inorganic, the 1980s. Concentrated solar energy can photo-stable, easily synthesized catalyst to produce “syngas,” consisting of CO and H2, separate CO2 into carbon monoxide (suitable for use amines as sacrificial reducing agents. Photoreduction of carbon dioxide (CO2) Prof. Ronny Neumann 43 44 The Promise of Super-Hot Plasmas Controlled nuclear fusion has the potential scientific community investigating hot and to provide the world with clean and plentiful dense plasmas in an effort to progress towards electricity. Fusion produces substantially less their efficient production. Prof. Maron received radioactive waste than nuclear fission and the 2009 American Physical Society Plasma has no harmful byproducts like the carbon Physics prize for his work. The group develops dioxide waste associated with fossil fuels. methods to measure the plasma properties and Moreover, the fuel required for fusion (hydrogen to investigate what processes take place in this isotopes) is abundant in seawater. There’s just super-hot, highly charged matter —which are one catch: under the conditions available difficult to measure and analyze—in hopes today, the energy required for creating the that the understanding can be used to reach super-hot plasma needed to generate nuclear the conditions for viable fusion-based energy fusion is greater than the energy produced. production. One of the most challenging While the production of fusion can only be diagnostics to capture is the magnetic field examined on very large scale facilities, the distribution in the plasma. Magnetic fields fundamental physics issues can be studied much have a central role in fusion research. They more efficiently in university-scale machines. are used for compressing and heating up the plasma, and serve as a vessel to contain Prof. Yizhak Maron of the Institute’s Department the hot plasma (no material can contain hot of Particle Physics and Astrophysics, and the plasma; the plasma would either damage the Plasma Laboratory Group is part of the global material or the material would cool the plasma). The traditional method for magnetic field This new magnetic-field diagnostic method diagnostics is based on changes in the radiation is expected to lead to a significant advance emitted from the plasma due to the presence in hot-plasma studies, and has drawn much of magnetic fields. But what’s tricky about interest in the plasma research community, this method is that it’s hard to tell, under leading to collaborations with Cornell the extreme high-energy-density conditions, University in New York, the United States Naval whether changes in the emitted radiation Research Laboratory, in Washington, DC, and are the result of the magnetic field or other Sandia National Laboratories in New Mexico. phenomena. A novel approach, recently developed by Prof. Maron’s group, allows for discriminating the effects of magnetic fields on the radiation from all other factors. Prof. Yizhak Maron 45 46 the waste produced by light-water reactors. So it’s not hanging around the Earth for that long. Sounds perfect, so what’s the catch? Very strong sources of fast neutrons are needed for thorium conversion on an industrial scale. Prof. Michael Hass of the Dept. of Particle Physics and Astrophysics is investigating the A Safer, More Plentiful Nuclear Energy Source Enormous advances in waste reprocessing 238 and reactor safety have made nuclear could find a practical way to use thorium energy a promising alternative to fossil fuels. as nuclear fuel, it could provide a plentiful However, nuclear power is also one of the source to run reactors for hundreds of years. U also fits into this category. If scientists There are many other advantages to using thorium as a nuclear fuel source as opposed to Conventional nuclear reactors are based on 235 fission—a process in which the nucleus of the radioactive, is about 1,000 times less radioactive atom is split into smaller particles—of U than uranium. It is easy to transport safely with (a type of uranium isotope which comprises minimal shielding required, and it is safer to mine. one percent of natural uranium) and 235 239 a state-of-the-art accelerator at Israel’s SOREQ Research Center as a source of neutrons. The machinery is the newly-constructed 40 MeV, superconducting SARAF (Soreq Applied Research Accelerator Facility) accelerator. Prof. Hass then aims to launch an experimental program for measuring transmutation and thorium conversion yields at the shared facility. Prof. Michael Hass most controversial alternative energies due to safety issues and the toxic waste it creates. options and laying the groundwork for using U. For starters, it’s safer: Thorium, although Pu (plutonium) isotopes. But there’s another It also is dramatically cleaner. Compared to option that scientists are exploring: thorium, conventional light-water reactors which utilize which, among other benefits, is much more 235 abundant than uranium. But thorium (232Th) is 0.1 percent of the amount that uranium does. a much more difficult to use in a sustainable And the waste that is produced has a half-life chain reaction of nuclear fission. The isotope of only 30 years, compared to 10,000 years for U, thorium reactors produce very little waste— 47 48 featured keynote lectures by leading experts Green Campus from both academia and industry, with the main Today’s kids learn in school that caring for the emphasis on students presenting their own work. environment begins at home. Dr. Ron Milo of the Department of Plant Sciences would Teaching Tomorrow’s Energy Scientists and the Public Education of the next generation of sponsors one such conference, every 1-2 years. alternative energy scientists goes hand-in- For alternative energy in particular, the value of hand with the Weizmann Institute research such conferences is tremendous, because they program. Energy education ranges from allow students the opportunity to “connect the graduate studies to textbook development dots” between what they are studying in the to improving high school science curricula lab and potential real-world applications. These focused on energy and the environment. conferences are national ones, i.e., students from all Israeli universities are invited and participate. At the Weizmann Institute, MSc and PhD students conduct research in labs alongside The first conference of this type, on solar energy Weizmann Institute scientists doing work on as an alternative energy source, was held in energy and the environment. Like all other 2010 in Zichron Ya’acov. In 2011 the Biology graduate students on campus, the bulk of for Renewable Energy Workshop (BREW) was their training occurs in the lab. In addition, held in Ramot overlooking the Sea of Galilee. student-led conferences give budding scientists Both provided an informal forum for students, the opportunity to present their work and hear scientists, and postdocs to share information about developments in the field both from and discuss the latest developments U.S. and seasoned scientists and experts in industry. AERI current challenges in the field. Their programs The education agenda reaches well outside agree–and so he started with his Weizmann the campus walls. For instance, Prof. David home. He and his colleagues initiated a “green Cahen, head of the Alternative Sustainable campus” project that encourages all scientists Energy Research Initiative, recently published a and staff to use resources efficiently by saving major university-level textbook on energy and on water and electricity, recycling, and biking sustainability with co-author Dr. David Ginley and walking when possible. The project’s website of the (U.S.) National Renewable Energy Lab, www.weizmann.ac.il/green has a carpooling “Fundamentals of Materials for Energy and database and other resources. “Saving water Environmental Sustainability” (Cambridge and electricity and recycling are all things I do University Press, 2012). It covers the full range of in my daily life with my family,” says Dr. Milo. subjects with which a new researcher entering “Now, I have the chance to try to influence the the field should be familiar, including recent habits of 3,000 people and convince them to advances in clean and sustainable energy. be environmentally aware and responsible.” 50 storable, and transportable energy source. adjusting and coordinating the power needs of Long-term research on this potential solution each individual device or millions of devices from will combine Weizmann Institute strengths in a central location. Benefits include significant chemistry, physics, biology and other fields improvements in energy efficiency, enhanced that can be brought to bear on the challenge. cyber-security, and the integration of different sources of electricity (wind, solar). Because of the readily available expertise in mathematics Smart grids Improving sustainability also means maximizing and computer sciences, networks and complex systems, the Weizmann Institute has the potential to become a hub of activity in this area. What the Future Holds the efficiency and reliability of the energy At the Weizmann Institute, sustainability, mechanism to convert solar energy, and, more resources on one network. Much in the way Solar paint eco-efficiency, and basic multidisciplinary importantly, store it? Artificial photosynthesis is that today’s “smart” phone means a phone Scientists have been dreaming about the possibility research are guiding the development of the currently at an embryonic stage, and Weizmann with a computer in it, a “smart” grid means of developing a soup of the components needed next generation of materials, processes, and Institute scientists are taking exploratory steps computerizing the electric utility grid. The for a solar cell that will be almost like paint and products. Weizmann scientists highlight five in advancing the science. For them it is clear grid includes wires, substations, transformers, can thus be applied as such on any suitable feasible research directions in which they that artificial photosynthesis has the potential to switches and much more. Field devices on it surface. If this vision can be reduced to reality, plan to invest efforts, all of which involve become a viable long-term source for chemical can be given sensors to gather data (power it presents the future possibility of turning a novel concepts and ideas for creating smarter, energy (fuel) that will not compete with, but meters, voltage sensors, fault detectors), and are wall into a low-cost solar cell, or of creating cleaner ways to generate and store energy: rather complement, food. They aim in the long integrated in a two-way digital communication ultra-thin, multi-layer solar cells cheaper and run to devise a process inspired by natural with the utility’s network operations center. The easier than is possible with today’s technology. photosynthesis and photovoltaics, in which use of automation technology would enable Artificial photosynthesis carbon dioxide and water combine with sunlight For millions of years, plants and other gases. In contrast to other renewable energy photosynthetic organisms have been using light sources (apart from biofuels), which generate to create energy for all their metabolic needs. no fuel product, artificial photosynthesis’s end Can science really improve on this age-perfected product will be a highly concentrated, easily to create a sustainable and carbon-neutral fuel without the production of greenhouse conversion through a comprehensive management system of all available energy 51 52 The main idea behind solar paint is to While each component retains its identity, the couple different types of nanoparticles–one composite material, which typically includes tough semiconductor and the other metal, using natural or synthetic fibers in a softer supporting Self-cleaning and adaptive materials appropriately designed organic linking molecules. matrix, displays macroscopic properties absent Dust and dirt are the major enemies of high- These molecules will provide the self-assembly from its parent constituents, particularly in performance solar cells collectors. Weizmann capabilities, creating inter-penetrating, self- terms of mechanical properties and economic scientists envision that the solar panels of the connecting networks. The coupling must be value. Composite materials with new electrical future may be self-cleaning. And the windows done in such a way that each type will bind to and magnetic properties are known as well. of future energy-efficient buildings may be only one of the two electrical contacts, and to self-cleaning as well as self-tinting, to control one or two of the particle assemblies. Much of Advanced composite materials are playing a vital light and heat gain. Many materials—fibers, the groundwork for this idea has been done role in improved design and reduced operating polymers, synthetics and textiles—can have here already. Weizmann Institute scientists have costs for renewable energy technologies. For improved performance with the ability to repel shown ways to create one-molecule-thick films example, the combination of very strong fibers contaminants. The addition of nano-sized or of mono-materials. They have pioneered creating surrounded by a lightweight plastic matrix micro-sized particles can create a surface that new nano materials such as inorganic fullerenes enables a greater strength-to-weight ratio than inhibits the adherence of contaminants such as and quantum dots, and have extensive projects is possible with conventional metallic materials, dust. Another option is to use light to create underway building molecular-scale electronics. providing tidal and wind turbines with fatigue- a chemical reaction on a treated surface that resistant building blocks. Composites could also will repel dirt. Weizmann scientists are already be designed to minimize energy losses in storage experimenting with self-cleaning, self-healing devices. However, predicting the properties of materials in a number of contexts. Applying these composite materials is a major challenge today ideas to solar panels and building materials may Composite materials are a class of materials that for which chemistry- and physics-based tools boost their efficiency and lower maintenance costs. combine two or more separate components to must be developed. The Weizmann Institute’s form a new product whose properties are well interdisciplinary approach has already created beyond the sum of its parts. Today the most new generations of materials from polymers to common use of composites is for structural nanoparticles, and is poised to produce even more. Composite materials applications (e.g., the Boeing 787 Dreamliner). 53 54 1990 Scientists experiment with solar- Self-healing of 2nd generation solar cell demonstrated powered lasers Weizmann Milestones in Energy 1992 Unique mechanism of nanoparticle solar cells elucidated 1993 Color codes: Solar and PV 1975 Weizmann scientists develop improved “optically selective Plants& biomass 1980 Pioneering work in photochemical and photoelectrochemical energy conversion Weizmann scientists pioneer isolating photosynthesizing components from blue-green algae and cyanobacteria 1976 First-ever solar battery developed that can both produce and store electricity generated by sunlight 1977 Synthetic fuels 1994 Experiments with salt-tolerant carotene Consolar develops beam-down optics at solar tower Demonstrate catalyst for cracking carbon-carbon bonds for industrial Principles of operation of dye solar cells unraveled Solar thermal splitting of methane and solar reforming Discovered mechanisms for chemical bath deposition of of hydrocarbons for fuel tested semiconductors and quantum dots used in dye sensitized solar cells Direct solar thermal splitting of water demonstrated 1995 Develop first “porcupine” solar high temperature receiver 1983 Demonstrate commercial potential 1996 Progress in monolayers from organic molecules for molecular-scale Scientists use light for “coherent electronics, nanolithography, optoelectronics, and biosensors for Dunaliella algae 1984 1985 1987 1989 control” of chemical reactions Pioneered field of nanoparticles for solar energy conversion Solar tower used to convert biomass to fuel, experiments in solar-driven hydrogen production Invent high efficiency solar battery Consolar Ltd. consortium between academia and industry formed to promote research in concentrated solar energy in Israel Solar tower and labs of Canadian Institute for Energies & Applied Research (CIEAR) dedicated First-ever quantum dot films made and used as solar cells of carbon dioxide other uses 2000 Fundraising begins for solar tower First demonstration of sunlight- Scientists develop photochromic materials for lenses, films and zinc oxide for fuel cells 1982 driven electrochemical reduction 1979 Solar chemistry refines zinc from chemistry Dunaliella algae as a source of metabolites such as beta surfaces” for solar collectors. Weizmann scientist develops nano-lubricant Zinc-bromine battery made with thin-films 1998 Weizmann scientists use catalysts in “monolayers” 1999 Consolar helps Institute build first solar gas combined cycle turbines 2001 Weizmann scientists show how to stabilize 2nd generation cadmium telluride solar cells (commercialized in collaboration with First Solar) 2002 Consolar power plant’s proof-ofconcept testing completed 2003 Experiments in biomass gasification Demonstrate cheaper, highperformance 2nd generation polycrystalline solar cells 55 2004 2005 2009 Scientists demonstrate new catalyst Demonstrate solar fixing of nitrogen. Improved high temp. solar receivers. for light-driven hydrolysis of water to hydrogen Weizmann scientists demonstrate (then) state-of art nanoporous solar cells 2006 2010 Donors and scientists launch 2011 sensitized nanoporous solar cells defined. research field that is poised to positively affect Demonstrate molten carbonate have joined us on this extraordinary journey the daily lives of people and societies worldwide. to reduce CO2 to CO for use in clean fuels of discovery for the benefit of all mankind. AERI Biofuels Consortium formed, progress in artificial 2012 Thanks to our Friends who Support Energy Research in Israel Demonstrate simple models for algae and photosynthetic bacteria for fuel production in marginal conditions exploring algae for fuels Mechanistic differences between dye cells and semiconductor- contributed to alternative energy research and Identify heat-tolerant stains of Begin new biomass project cellulose and has become a world leader in this critical artificial photosynthesis Institute scientists demonstrate first “molecular keypad” lock Create the world’s first “designer cellulosomes” for degrading many generous donors worldwide who have Second-generation designer cellulosomes produced year” 2008 is advancing groundbreaking investigations New designs for high-voltage, nanoporous solar cells Demonstrate boron and water fuel cell for producing hydrogen Science magazine recognizes Weizmann “green chemistry” method “breakthrough of the acknowledges the invaluable assistance of our photosynthesis Alternative sustainable Energy Research Initiative (AERI) 2007 It is thanks to this support that the Institute material built in Nanjing, China, with Weizmann help In Appreciation The Weizmann Institute of Science gratefully Sb 2 S 3 shown as a novel PV Commercial-scale solar tower 56 Weizmann scientists demonstrate spectral splitting to use more of the sunlight for solar cells Major Benefactors Mary and Tom Beck-Canadian Center for Alternative Energy Research Andrea and Charles Bronfman Demonstrate techniques Philanthropies to increase production of metabolites in plants The Monroe and Marjorie Burk Fund for Alternative Energy Studies 170 kW solar thermal combined cycle energy plant testing in Almeira, Spain Ben B. and Joyce E. Eisenberg Foundation Research basic limits to solar cells Angel Faivovich Foundation for Ecological Endowment Fund Research The Heineman Foundation The Leona M. and Harry B. Helmsley Charitable Trust Yossie and Dana Hollander Roberto and Renata Ruhman Rowland & Sylvia Schaefer Family Foundation, Inc. Dr. Scholl Foundation Center for Water and Climate Research 57 The Bernard and Bernice Dorothy Segall Scholarship Fund Sussman Family Center for the Study of Environmental Sciences The Wolfson Family Charitable Trust 58 Gina (Eugenie) Fromer Michael Levine Brian Steck Lisa Garoon Meyer Levy Fund for Alternative Helen Steinberg llan Gluzman P. & A. Guggenheim-Ascarelli Foundation Estate of Joe Gurwin Estate of Bronia Hacker Supporters Jack N. Halpern Energy Studies Cecil & Hilda Lewis Charitable Trust Robert Lewis Eric Manville Trust W.A. Minkoff Larry and Mucci Taylor Dale and Dennis Weiss Fund for Alternative Energy Fredda Weiss Estate of Martin J. Weiss The Charles and David Wolfson Charitable Robert Aliber Charitable Trust Jake and Dorothy Hendeles Marcelo Astrachan Intel Solomon and Rebecca Baker Foundation Annette Isaacson The Bendit Foundation Scholarship Estate of Sanford Kaplan Estate of Wilhelm and Ruth Berler Estate of Ilse Katz Foundation George Brady Estate of Golda Kaufman Barrie Rose The Brita Fund for Scholarships Research James and Elaine Kay Estate of Abraham Rosenberg Estate of Morris Kerzner David Rosenberg Chair (incumbent Prof. Avihai Danon) Jack and Elisa Klein Foundation Charles Rothschild The Bronfman Professorial Chair of Plant Estate of Lily Klein Prof. Albert B. and Heloisa Sabin The Koret Foundation Martin Kushner Schnur The Jacob and Charlotte Lehrman Gerald Schwartz Levy) Daniel S. Shapiro The Charles and Louise Gartner Professorial And Education Carolito Stiftung Samy Cohn Estate of Magda Collins Eduardo A. De Carvalho David L. Dennis, Q.C. Foundation Feldman Foundation Andrew and Beverly Lengyel Mario Fleck Estate of Nathan Minzly Trust Nikken Sohonsha Corp. Robert Zaitlin Estate of Leo Perkell Arnold (Israel) Ziff Abraham and Sonia Rochlin Sharon Zuckerman Isabel H. Silverman Foundation Professorial Chairs The Henry and Bertha Benson Professorial Science (incumbent Prof. Gad Galili) The Gilbert de Botton Professorial Chair of Plant Sciences (incumbent Prof. Avraham Chair (incumbent Prof. Uri Pick) 59 60 The Peter and Carola Kleeman Professorial Professorial Chair of Bio-Organic Chemistry Chair of Optical Sciences (incumbent Prof. (incumbent Prof. Ed Bayer) Nir Davidson) The Murray B. Koffler Professorial Chair (incumbent Prof. Michael Hass) The Israel Matz Professorial Chair of Organic Chemistry (incumbent Prof. David Milstein) Career Development Chairs The Anna and Maurice Boukstein Career Development Chair in Perpetuity (incumbent Dr. Ron Milo) The Edith and Nathan Goldenberg Career The Stephen and Mary Meadow Professorial Development Chair (incumbent Dr. Assaf Chair of Laser Photochemistry (incumbent Vardi) Prof. Yitzhak Maron) The Recanati Career Development Chair of The Jacques Mimran Professorial Chair Energy Research in Perpetuity (incumbent (incumbent Prof. Yuval Eshed) Dr. Dan Oron) The Bruce A. Pearlman Professorial Chair in Synthetic Organic Chemistry (incumbent Prof. Milko van der Boom) Faculty-Specific Funding Prof. Nir Davidson The Rebecca and Israel Sieff Professorial Chair of Organic Chemistry (incumbent Prof. Ronny Neumann) The Robert and Yadelle Sklare Professorial Chair in Biochemistry (incumbent Prof. Avigdor Scherz) The Maynard I.and Elaine Wishner Helen and Martin Kimmel Center for Nanoscale Science The Mary and Tom Beck Canadian Center for Alternative Energy Research which he heads The Leona M. and Harry B. Helmsley Dr. Dan Oron Charitable Trust Wolfson Family Charitable Trust The Gerhardt M.J. Schmidt Minerva Center Yossie and Dana Hollander European Research Council Prof. Milko Van Der Boom Martin Kushner Schnur, Mary and Tom Beck-Canadian Center for on Supramolecular Architectures which he heads Wolfson Family Charitable Trust The Charles and David Wolfson Charitable Trust Adolfo Eric Labi Alternative Energy Research David Rosenberg Irving and Varda Rabin Foundation of the Wolfson Family Charitable Trust Aboud and Amy Dweck Prof. Gary Hodes Prof. Michael Bendikov Yossie and Dana Hollander Yossie and Dana Hollander Wolfson Family Charitable Trust Wolfson Family Charitable Trust Prof. Gad Galili Gerhardt Schmidt Minerva Center on Carolito Stiftung Lerner Family Plant Science Research Professorial Chair in Energy Research Chair (incumbent Prof. Naama Barkai) European Research Council Alternative Energy Studies Estate of Theodore E. Rifkin Mary and Tom Beck-Canadian Center for The Lorna Greenberg Scherzer Professorial Wolfson Family Charitable Trust The Monroe and Marjorie Burk Fund for Alternative Energy Research The Rowland and Sylvia Schaefer (incumbent Prof. David Cahen) Prof. Leeor Kronik Supramolecular Architectures Nancy and Stephen Grand Center for Sensors and Security Prof. David Cahen Ben B. and Joyce E. Eisenberg Foundation Endowment Fund Jewish Community Foundation Nancy and Stephen Grand Center for Sensors and Security Endowment Fund 61 Prof. Avraham Levy Prof. David Milstein Dr. Assaf Vardi Prof. Jacob Karni The Jacob and Charlotte Lehrman Helen and Martin Kimmel Center for Charles Rothschild Israel Strategic Alternative Energy Foundation Molecular Design which he heads Yossie and Dana Hollander Bernice and Peter Cohn Catalysis Research European Research Council Prof. Levy heads the Melvyn A. Dobrin Center for Nutrition and Plant Research, Fund European Research Council and Jeanette Weinberg Center for Plant Molecular Genetics Research European Research Council Yossie and Dana Hollander Prof. Igor Lubomirsky Adolfo Eric Labi Prof. Naama Barkai Dr. Dror Noy Foundation Luis Stuhlberger Armando and Maria Jinich the Charles W. & Tillie K. Lubin Center for Plant Biotechnology and the Harry Roberto and Renata Ruhman Helen and Martin Kimmel Award for Innovative Investigation Wolfson Family Charitable Trust Nancy and Stephen Grand Center for Sensors and Security Jeanne and Joseph Nissim Foundation for Life Sciences Research Prof. Yitzhak Maron Dr. Ron Milo Prof. Uri Pick Lorna Greenberg Scherze Sandia National Laboratories Lerner Family Plant Science Research Jack N. Halpern Estate of John Hunter Irving and Dorothy Rom Charitable Trust European Research Council Carolito Stiftung Endowment Fund European Research Council Yossie and Dana Hollander The Larson Charitable Foundation Wolfson Family Charitable Trust Estate of David Arthur Barton Anthony Stalbow Charitable Trust Stella Gelerman Prof. Avigdor Scherz The Estate of Hilda Jacoby-Schaerf Prof. Ronny Neumann Wade F.B. Thompson Charitable Foundation Susan G. Komen Breast Cancer Foundation Prof. Michael Hass Yossie and Dana Hollander Yossie and Dana Hollander Carolito Stiftung Bernice and Peter Cohn Catalysis Sharon Zuckerman Estate of David Turner Research Fund Estate of Nathan Baltor Mary and Tom Beck-Canadian Center for Alternative Energy Research A publication of the Department of Resource Development The Weizmann Institute of Science P.O.Box 26, Rehovot, Israel 76100 Tel: 972 8 934 4582 e-mail:[email protected] TalkingBrands.co.il
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