Material Safety Data Sheet (MSDS)
1. Identification of the substance/preparation and of company/undertaking
Identification of the product
Manufacturer/Supplier identification
Company: Better Equipped
Tel: 0800 970 7142
Fax: 0800 066 4443
Email: [email protected]
Product Name: Copper II Carbonate Basic
2. Hazards identification
Classification of the substance or mixture
According to Regulation (EC) No1272/2008
Acute toxicity, category 4, oral
Acute toxicity, category 4, inhalation
Hazardous to the aquatic environment, acute, category 1
Hazardous to the aquatic environment, chronic, category 1
According to European Directive 67/548/EEC as amended.
Harmful by inhalation and if swallowed. Very toxic to aquatic life. Very toxic to aquatic life with long
lasting effects.
Label elements:
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H332 Harmful if inhaled.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statement(s)
P260: Do not breathe dust.
P264: Wash thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P312: Call a POISON CENTER or doctor if you feel unwell.
P330: Rinse mouth.
According to European Directive 67/548/EEC as amended.
Symbol:
Harmful Env Hazard
R-phrases: R: 20/22-50/53
Harmful by inhalation and if swallowed. Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-phrases: S: 26-36
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear
suitable protective clothing.
Classification System
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies
3. Composition/information on ingredients
Chemical classification: Inorganic solid
Copper II Carbonate
Cas No: 12069-69-1
EC No: 235-113-6
Index No: Classification: Acute Tox. 4; Acute Tox. 4; Aquatic Acute 1; Aquatic Chronic 2; H302-H332-H400-H410
Xn; R20/22-50/53
Concentration: For the full text of the H-Statements mentioned in this Section, see Section 16.
4. First aid measures
Eye Contact: Bathe the eye with running water for 15 minutes. Consult a doctor..
Skin Contact: Remove all contaminated clothes and foot wear immediately unless stuck to skin.
Drench the affected skin with running water for 10 minutes or longer if substance is still on skin.
Consult a doctor.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a
doctor.
Ingestion: Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water
to drink
immediately. Consult a doctor. .
5. Fire-fighting measures
Fire Risks: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with
skin and eyes..
Exposure hazards: In combustion emits toxic fumes.
Suitable Extinguishing Media: Suitable extinguishing media for the surrounding fire should be used.
Use water spray to cool containers.
6. Accidental release measures
Personal: Refer to section 8 of SDS for personal protection details. If outside do not approach from
downwind. If outside keep bystanders upwind and away from danger point. Mark out the
contaminated area with signs and prevent access to unauthorised personnel.
Environmental precautions: Do not discharge into drains or rivers.
Spillage: Transfer to a closable, labelled salvage container for disposal by an appropriate method.
7. Handling and storage
Handling: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.
Do not handle in a confined space. Avoid the formation or spread of dust in the air.
Storage: Store in cool, well ventilated area. Keep container tightly closed. The floor of the storage
room must be impermeable to prevent the escape of liquids.
8. Exposure controls/personal protection
Exposure controls:
Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety
practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection: Safety glasses with side-shields conforming to EN166 Use equipment for eye
protection tested and approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must
be selected according to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory protection: For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle
respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143)
respirator cartridges. Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU).
9. Physical and chemical properties
Physical State: Solid
Appearance: Green
Odour: Odourless
Molecular Formula: CuCO3.Cu.(OH)2
Molecular Weight: 221.12
Freezing/melting Point: 200°C
Flash point: >93°C
pH: 5-6
Solubility in water: Insoluble.
10. Stability and reactivity
Reactivity: no data available
Chemical stability: Stable.
Possibility of hazardous reactions: In combustion emits toxic fumes.
Conditions to avoid: Heat.
Incompatible materials: Strong oxidising agents. Strong acids
11. Toxicological information
Acute toxicity: LD50 Oral - rat - 159 mg/kg
LD50 Oral - rabbit - 159 mg/kg
LD50 Oral - Mam - 625 mg/kg
Relevant hazards for substance:
Hazard Route Basis
Acutetoxicity(ac. tox. 4) INH ING Based ontest data
Skin corrosion/irritation: no data available
Serious eye damage/eye irritation: no data available
Respiratory or skin sensitization: no data available
Germ cell mutagenicity: no data available
Carcinogenicity: IARC: No component of this product present at levels greater than or equal to 0.1%
is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity: no data available
Specific target organ toxicity - single exposure: Inhalation - May cause respiratory irritation.
Potential health effects
Skin contact: There may be irritation and redness at the site of contact.
Eye contact: There may be irritation and redness. The eyes may water profusely.
Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain
may occur.
There may be vomiting.
Inhalation: There may be irritation of the throat with a feeling of tightness in the chest.
12. Ecological information
Toxicity: no data available
Persistence and degradability: Not biodegradable.
Bioaccumulative potential: Bioaccumulation potential.
Mobility in soil: no data available
Results of PBT and vPvB assessment: no data available
Other adverse effects: Toxic to aquatic organisms. Toxic to soil organisms.
13. Disposal considerations
Chemical residues are generally classified as special waste, and as such are covered by regulations
which vary according to location. Contact your local waste disposal authority for advice, or pass to a
chemical disposal company.
Rinse out empty containers thoroughly before returning for recycling.
14. Transport information
Land Transport ADR:
UN: 3077
PK: III
Class: 9
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S (Copper
carbonate)
LQ: 5KG
Transport category / (Tunnel restriction code): 3 (E)
Maritime Transport IMDG:
UN: 3077
PK: III
Class: 9
Marine Pollutant:
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S (Copper
carbonate)
Air Transport IATA:
UN: 3077
PK: III
Class: 9
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S (Copper
carbonate)
15. Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture: no data
available
Chemical Safety Assessment: No Chemical Safety Assessment has been carried out
16. Other information
Text of H-code(s) and R-phrase(s) mentioned in Section 3
H302: Harmful if swallowed.
H332: Harmful if inhaled.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
R20/22: Harmful by inhalation and if swallowed.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Issued March 2013