Exercise 12.2a Stoichiometry I - Answers DIRECTIONS: On a separate sheet of paper, solve the following problems. 1. Given the equation NH3 + HCl NH4Cl, find the number of formula units of NH4Cl formed if 65.0 g of NH3 reacts with an excess of HCl. 1NH3 + 1HCl → 1NH4Cl Analyze, rewrite, balance equation 65.0 g ? p. Solve for only reactant 2. 65.0 g NH3 x 6.02 x1023 p. NH4Cl 1 mol NH4Cl = 2.30 x 1024 p. NH4Cl x 1 mol WO3 6.02 x1023 p. WO3 x 1 mol W 1 mol WO3 183.84g W 1 mol W x = 12 300 g W 7.02 x 1014 p. CrCl3 1 mol CrCl3 6.02 x1023 p. CrCl3 x 2 mol CrCl2 2 mol CrCl3 x x 6.02 x1023 p. CrCl2 1 mol CrCl2 = 7.02 x 1014 p. CrCl2 1 mol RbCl 6.02 x1023 p. RbCl x 1 mol RbClO4 1 mol RbCl x x 184.917g RbClO4 1 mol RbClO4 = 0.154 g RbClO4 Given the equation C3H5(NO3)3 N2 + O2 + CO2 + H2O, find the mass of CO2 formed if 5.62 g C3H5(NO3)3 decomposes. 4C3H5(NO3)3 → 6N2 + 1O2 + 12CO2 + 10H2O Analyze, rewrite, balance equation 5.62 g ?g 5.62 g C3H5(NO3)3 x 1 mol C3H5(NO3)3 227.085 g C3H5(NO3)3 x 12 mol CO2 4 mol C3H5(NO3)3 x 44.009g CO2 1 mol CO2 = 3.27 g CO2 Given the equation NH3 + HC1 NH4Cl, find the mass of NH3 needed to form 15.0 g of NH4Cl. 1NH3 + 1HCl → 1NH4Cl Analyze, rewrite, balance equation ?g 15g Solve for only reactant 7. 4.03 x 1025 p. WO3 5.00 x 1020 p. RbCl Solve for only reactant 6. 1 mol NH4Cl 1 mol NH3 Given the equation RbCl + O2 RbClO4, find the mass of RbClO4 formed if 5.00 x 1020 formula units of RbCl reacts with an excess of O2. 1RbCl + 2O2 → 1RbClO4 Analyze, rewrite, balance equation 5.00 x 1020 p. ?g Solve for only reactant 5. x Given the equation Zn + CrCl3 CrCl2 + ZnCl2, find the number of formula units of CrCl2 formed if 7.02 x 1014 formula units of CrCl3 reacts with an excess of Zn. 1Zn + 2CrCl3 → 2CrCl2 + 1ZnCl2 Analyze, rewrite, balance equation 7.02 x 1014 p. ? p. Solve for only reactant 4. 1 mol NH3 17.031g NH3 Given the equation WO3 + H2 W + H2O, find the mass of W formed if 4.03 x 10 25 formula units of WO3 reacts with an excess of H2. 1WO3 + 3H2 → 1W + 3H2O Analyze, rewrite, balance equation 4.03 x 1025 p. ?g Solve for only reactant 3. x 15.0 g NH4Cl x 1 mol NH4Cl 53.492g NH4Cl x 1 mol NH3 1 mol NH4Cl x 17.031g NH3 1 mol NH3 = 4.78 g NH3 Given the equation WO3 + H2 W + H2O, find the mass of WO3 needed to form 7.30 x 1021 formula units of W. 1WO3 + 3H2 → 1W + 3H2O Analyze, rewrite, balance equation ?g 7.3 x 1021 p. Solve for only reactant 7.30 x 1021 p. W x 1 mol W 6.02 x1023 p. W x 1 mol WO3 1 mol W x 231.837g WO3 1 mol WO3 = 2.81 g WO3 Exercise 12.2a Stoichiometry I - Answers 8. Given the equation Zn + CrCl3 CrCl2 + ZnCl2, find the mass of ZnCl2 formed if 1.20 x 1024 formula units of CrCl3 reacts with an excess of Zn. 1Zn + 2CrCl3 → 2CrCl2 + 1ZnCl2 Analyze, rewrite, balance equation 1.2 x 1024 p. . ?g Solve for only reactant 9. 1.20 x 1024 p. CrCl3 1 mol CrCl3 6.02 x1023 p. CrCl3 x x 1 mol ZnCl2 2 mol CrCl3 x 136.286g ZnCl2 1 mol ZnCl2 = 136 g ZnCl2 Given the equation RbCl + O2 RbClO4, find the mass of O2 necessary to completely react 87.5 g RbCl. 1RbCl + 2O2 → 1RbClO4 Analyze, rewrite, balance equation 87.5 g ?g Solve for only reactant 87.5 g RbCl x 1 mol RbCl 120.921 g RbCl x 2 mol O2 1 mol RbCl x 31.998g O2 1 mol O2 = 46.3 g O2
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