UNIT 2 – MATTER AND ITS PROPERTIES INDEX 1. What is matter 2. States of matter Macroscopic approach Microscopic approach, kinetic theory Changes of state 3. Properties of matter General properties Mass, volume, temperature.... Characteristic properties Density Boiling point Melting point 4. The gaseous state Boyle’s law Charles’ law Gay –Lussac’s law 29 UNIT 2 – MATTER AND ITS PROPERTIES 1.WHAT IS MATTER? Matter is everything that has mass, occupies a volume and has properties that can be measured. 2.STATES OF MATTER Macroscopic approach: SOLIDS: • • • They have a fixed volume ( they can´t be compressed) They have a fixed shape They can´t flow LIQUIDS • • • They have a fixed volume (they can be slightly compressed) They take the shape of the container They can flow GASES • • They fill the whole container. They have an indefinite volume.(they can be compressed) They take the shape of the container. They have an indefinite shape 30 UNIT 2 – MATTER AND ITS PROPERTIES Microscopic approach: Kinetic matter theory: SOLIDS: • • • Particles of solids are tightly packed in a regular pattern. Particles vibrate around a fixed position. Particles are strongly attracted to each other. LIQUIDS • • • Particles of solids are randomly packed (In a mess) Particles can move around. Particles are attracted to each other. GASES • • • Particles of gases don´t touch each other Particles can move around fast in all directions The forces of attraction are very weak. Microscopic Explanation of Properties of Solids Solids have a definite shape and a definite volume because the particles are locked into place Solids are not easily compressible because there is little free space between particles. Solids do not flow because the particles cannot move and the forces between them are very strong. 31 UNIT 2 – MATTER AND ITS PROPERTIES Microscopic Explanation of Properties of Liquids Liquids have an indefinite shape because the particles can slide past one another. Liquids are not easily compressible and have a definite volume because there is little free space among the particles. Liquids flow easily because the particles can move and the forces between them are not so strong. Microscopic Explanation of Properties of Gases Gases have an indefinite shape and an indefinite volume because the particles can move past one another. Gases are easily compressible because there is a great deal of free space between particles. Gases flow very easily because the particles randomly move and the forces between them are very weak. Changes of state The names for the changes are: The change from liquid to solid is solidifying (in the case of water is freezing) The change from solid to gas is sublimation The change from gas to solid is deposition Language: The names of some changes end in –ing: melting, boiling, condensing, freezing, solidifying. But we say sublimation and deposition! When we are speaking about a substance (for example water) we say : 32 UNIT 2 – MATTER AND ITS PROPERTIES It melts, it boils, it freezes, it condenses, it solidifies, it sublimates. When a liquid becomes a gas (in general we call it vaporisation), it can happen in two ways: Evaporation: It happens when only the particles on the surface of the liquid become a gas. It happens at any temperature. Boiling: It happens when particles throughout the liquid become bubbles of gas and rise to the surface and escape from the liquid. It happens at a certain temperature for each liquid. When water is in the gaseous state we call it steam. 33 UNIT 2 – MATTER AND ITS PROPERTIES 3.PROPERTIES OF MATTER We can classify the properties in two groups: General properties Characteristic properties General properties: They are physical features that describe matter but can change without changing the substance. Examples: size, shape, texture, temperature, state, volume. Characteristic properties: They are fixed properties that do NOT change, they have always the same value for the same substance Examples: boiling point, melting point, solubility, conductivity, hardness ,pH, flammability, density. In this unit we are going to study: Density Boiling point Melting point As characteristic properties are not affected by physical changes, they can be used to identify matter DENSITY Density = amount of matter per volume unit. D = m/v (g/cm3) • Mass is usually expressed in grams • Volume is usually expressed in cm3 or liters, etc. So the units can be: g/ml g/ cm3 Kg/l Kg/m3 34 UNIT 2 – MATTER AND ITS PROPERTIES MELTING POINT It is the temperature at which a solid becomes a liquid. It always happens at the same temperature. It is also the temperature at what a liquid becomes a solid.(freezing) BOLILING POINT It is the temperature at which a liquid becomes a gas. It happens always at the same temperature. It is also the temperature at which a gas becomes a liquid.(condensing) 35 UNIT 2 – MATTER AND ITS PROPERTIES Language: Here you have several verbs that you can use to describe the curves: To turn into To increase To rise Rise X raise The sun rises. Please raise your hand Each substance has a certain melting point and a certain boiling point: 36 UNIT 2 – MATTER AND ITS PROPERTIES 4.THE GASEOUS STATE The kinetic matter theory explains that: A gas is composed of small particles. The particles have an insignificant volume and are far apart from one another. There is empty space between particles. Little attractive forces between particles. The particles in a gas move in constant random motion. Particles path is only changed by colliding with another particle or the sides of its container. Gases have several properties: They exert pressure: Gas particles exert pressure by colliding with objects in their path. The sum of all of the collisions makes up the pressure the gas exerts. There are several units for measuring pressure : Atmospheres (atm) Millimeters of Mercury (mmHg) Gases occupy volume: The volume of the gas is simply the volume of the container it is contained in. The metric unit of volume is the cubic metre (m3) Gases have temperature: The temperature of a gas is generally measured with a thermometer in Celsius. All calculations involving gases should be made after converting Celsius to Kelvin temperature. Kelvin = C° + 273 37 UNIT 2 – MATTER AND ITS PROPERTIES GASES LAWS Studies of the behavior of gases have become mathematical laws which we can use to predict quantitative outcomes. https://www.youtube.com/watch?v=Osq71Y82uac ( Hasta 3.52 min) BOYLE´S LAW https://www.youtube.com/watch?v=Xto88gMmDzw (Hasta 4,28) Robert Boyle observed the relationship between pressure and volume of a gas. During his experiments, temperature and the amount of gas weren’t allowed to change Boyle’s Mathematical Law: PV = k What if we had a change in conditions? since PV = k At constant temperature the volume of a gas is inversely roportional to the pressure. As volume increases, pressure decreases. 38 UNIT 2 – MATTER AND ITS PROPERTIES CHARLES’S LAW https://www.youtube.com/watch?v=7ZpuMBkf1Ss (hasta 4.51) Jacques Charles determined the relationship between temperature and volume of a gas. During his experiments, pressure of the system and amount of gas were held constant. Charles’s Mathematical Law: V/T = k What if we had a change in conditions? since V/T = k At constant pressure the temperature of a gas is directly proportional to the volume. As temperature increases, volume increases. 39 UNIT 2 – MATTER AND ITS PROPERTIES GAY-LUSSAC´S LAW https://www.youtube.com/watch?annotation_id=annotation_3630315551&f eature=iv&index=16&list=PLi01XoE8jYoi5fLBY64f6ZUuktgTFb2H3&src_vid =Xto88gMmDzw&v=0Oq7bCSDPxE (hasta 4,46) Lussac determined the relationship between temperature and pressure of a gas. During his experiments volume of the system and amount of gas were held constant. The pressure increases when temperature increases because the molecules are moving faster and colliding against the sides of their containers more often. Therefore, the pressure inside that container is greater, because there are more collisions. Lussac’s Mathematical Law: P/T = k 40 UNIT 2 – MATTER AND ITS PROPERTIES What if we had a change in conditions? since P/T = k At constant volume the temperature of a gas is directly proportional to the pressure. As temperature increases, pressure increases. UNIT 2 - MATTER AND ITS PROPERTIES. Activities A1-States of matter. ( listening activity) You are going to listen to a text and you have to fill the bubbles of the “mind map”. 41 UNIT 2 – MATTER AND ITS PROPERTIES 42 UNIT 2 – MATTER AND ITS PROPERTIES A2-States of matter (speaking activity) Help yourself with this chart: Key words (one or two in each cell) How are they packed? How do they move? How are them attracted to each other? Now, without any help say sentences about particles and your partner has to guess which state you are speaking about: A3-Evaporation and boiling 43 UNIT 2 – MATTER AND ITS PROPERTIES A4-Changes of state (writing and speaking activity) A5-Density 44 UNIT 2 – MATTER AND ITS PROPERTIES A6-Density A7-Density 45 UNIT 2 – MATTER AND ITS PROPERTIES A8-Density (writing and speaking activity) A9-Density 46 UNIT 2 – MATTER AND ITS PROPERTIES A10-Changes of state 47 UNIT 2 – MATTER AND ITS PROPERTIES A11-Pressure A12-Gases Laws (Language activity) A13-Gases laws (Language activity) 48 UNIT 2 – MATTER AND ITS PROPERTIES A14-Gases laws 1 litre of a gas at standard temperature (T=cte) and pressure is compressed to 473 mL. What is the new pressure of the gas? A man heats a balloon in the oven. If the balloon initially has a volume of 0.4 liters and a temperature of 20 0C, what will the volume of the balloon be after he heats it to a temperature of 250 0C? If I initially have a gas at a pressure of 12 atm, a volume of 23 liters, and a temperature of 200 K, and then I raise the pressure to 14 atm and increase the temperature to 300 K, what is the new volume of the gas? 49 UNIT 2 – MATTER AND ITS PROPERTIES UNIT 2-MATTER AND ITS PROPERTIES EXERCISES 1 2 50 UNIT 2 – MATTER AND ITS PROPERTIES 3 4 5 What is the density of a piece of wood that has a mass of 25.0 grams and a volume of 29.4 cm3? 6 A piece of wood that measures 3.0 cm by 6.0 cm by 4.0 cm has a mass of 80.0 grams. What is the density of the wood? Would the piece of wood float in water? (volume = L x W x H) 51 UNIT 2 – MATTER AND ITS PROPERTIES 7 A cup of gold colored metal beads was measured to have a mass 425 grams. By water displacement, the volume of the beads was calculated to be 48.0 cm3. Given the following densities, identify the metal. Gold: 19.3 g/mL Copper: 8.86 g/mL Bronze: 9.87 g/mL 8 I threw a plastic ball in the pool for my dog to fetch. The mass of the ball was 125 grams. What should be the volume to have a density of 0.500 g/mL.? 9 The density of aluminium is 2.70 g/mL. If the mass of a piece of aluminium is 0,244 Kg, what is the volume of the aluminium? 10 52 UNIT 2 – MATTER AND ITS PROPERTIES 11 12 13 53 UNIT 2 – MATTER AND ITS PROPERTIES 14 15 54 UNIT 2 – MATTER AND ITS PROPERTIES 16 Write in right order the particle diagrams 0 17 If I initially have a gas with a pressure of 84 kPa and a temperature of 35 C and I heat it an additional 230 degrees, what will the new pressure be? Assume the volume of the container is constant. of 2600 liters. If the sun heats my car from a 18 My car has an internal volume 0 0 temperature of 20 C to a temperature of 55 C, what will the pressure inside my car be? Assume the pressure was initially 760 mm Hg. 55 UNIT 2 – MATTER AND ITS PROPERTIES 56 UNIT 2 – MATTER AND ITS PROPERTIES LABORATORY - COOLING CURVE. Work in groups of three people. You are going to read the following instructions. First, cut the pictures bellow with the scissors. Then, follow the instructions moving the pictures and doing exactly what you are asked to do. Finally show the teacher how you did it. Ask any questions you are interested in, before carrying out the experiment. Instructions: Put the gauze on the top of the gas heater. Put a beaker over the gauze and fill it with water. Put 5 grams of naphthalene into a Pyrex test tube. Add a thermometre to the test tube. Insert the test tube in a 500 ml beaker of water. Stick the test tube to a stand with a clamp in order to put it vertically and inside the water, without touching the beaker. Light the gas heater. Heat the naphtalene until it melts Switch off the heater and remove the heater from the water bath. Record the temperature of the naphtalene every 15 seconds while it is cooling. Remember to stir the naphtalene with the thermometre gently. Stop measuring the temperature when it gets to 70 degrees. Draw the cooling curve representing the temperature/time data. 57 UNIT 2 – MATTER AND ITS PROPERTIES 58 UNIT 2 – MATTER AND ITS PROPERTIES 59 UNIT 2 – MATTER AND ITS PROPERTIES 60 UNIT 2 – MATTER AND ITS PROPERTIES GLOSSARY boiling [ˈbɔɪlɪŋ] characteristic [ˌkærɪktəˈrɪstɪk] curve [k3ːv] evaporation [ɪˌvæpəˈreɪʃən] flow [fləʊ] indefinite [ɪnˈdefɪnɪt] liquid [ˈlɪkwɪd] matter [ˈmætər] naphthalene [ˈnæfθəliːn] particle [ˈpɑːtɪkl] pressure [ˈpreʃər] raise [reɪz] rise [raɪz] solidify [səˈlɪdɪfaɪ] sublimation [ˌsʌblɪˈmeɪʃən] vaporization [ˌveɪpərəɪˈzeɪʃən] volume [ˈvɒljuːm] 61
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