The IDEAL GAS LAW Shows the relationship among the pressure, volume, temp. and # moles in a sample of gas. P = pressure (atm) The units of R depend V = volume (L) on the units used for P, V & T n = # moles T = temp (K) L!atm R = universal gas constant = 0.0821 mol!K Example 2: Calculate (a) the # moles in, and (b) the mass of an 8.96 L sample of methane, CH4, measured at standard conditions. (a) P = 1.00 atm V = 8.96 L n=? T = 273 K Example 1: What volume would 50.0 g of ethane, C2H6 , occupy at 140 ºC under a pressure of 1820 torr? P = (1820 torr)(1 atm/760 torr) = 2.39 atm V=? n = (50.0 g)(1 mol / 30.0 g) = 1.67 mol T = 140 °C + 273 = 413 K PV = nRT (2.39 atm)(V) = (1.67 mol)(0.0821 L·atm/mol·K)(413 K) V = 24 L Example 2: Calculate (a) the # moles in, and (b) the mass of an 8.96 L sample of methane, CH4, measured at standard conditions. (a) Or the easier way… 8.96L PV = nRT ! 1 mol = 0.400 mol 22.4 L (1 atm)(8.96 L) = (n)(0.0821 L·atm/mol·K)(273 K) n = 0.400 mol Example 2: Calculate (a) the # moles in, and (b) the mass of an 8.96 L sample of methane, CH4, measured at standard conditions. (b) Convert moles to grams… 0.400mol 16.0 g ! = 6.40 g CH4 1 mol Example 3: Calculate the pressure exerted by 50.0 g ethane, C2H6, in a 25.0 L container at 25 ºC? P=? V = 25.0 L n = (50.0 g)(1 mol / 30.0 g) = 1.67 mol T = 25 °C + 273 = 298 K PV = nRT (P)(25.0 L) = (1.67 mol)(0.0821 L·atm/mol·K)(298 K) P = 1.6 atm 1
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